Transport Phenomena I: Fluids

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CHE 231 Transport Phenomena I: Fluids Jeff Heys Arizona State University

about this class... Make sure you have a copy of the syllabus and schedule even though the schedule is tentative. Syllabus Highlights: Office Hours: M 3:00 4:00 and W 9:15 11:15 My office: ERC 287 (480-965-0874) email: jheys@asu.edu Make sure you have the prerequisites?? Text (New): J.O. Wilkes, Fluid Mechanics for ChE, 2 nd Ed. Grades: 20% HW (10), 50% Midterms (2), 30% Final

Schedule Highlights We have two midterms, currently scheduled for Feb. 20 and Apr. 7 (Tentative) Final is on Wed, May 7 at 2:40 (NOT Tentative) I'll be out of town on April 16 so we are unlikely to have class. I'm using a new book, so the schedule is likely to be changed, although the goal of getting through the first 8 chapters is unlikely to change

about me... I conduct research on computational fluid mechanics in tissues and other biological systems I'm married with one daughter, one son, and one cat...'bleu' I like math and have taught it extensively so...prepare! I dislike proprietary file formats (e.g., *.doc and *.ppt) and lecturing with slides...

TA Brad Merchant ERC 356 bmerchan@asu.edu Office Hours:?

Course Goals Model or analyze static fluid systems (Chpt. 1) Use Macroscopic balances (Integrals, Chpt. 2-4) Use Microscopic balances (Diff Eqs., Chpt. 5-6) Understand dimensionless quantities (Chpt. 4) Understand fluid properties (all, starting today) Experimentally measure fluid properties (all)

What's a fluid? Introduction

Introduction What's a fluid? A material that cannot resist a shear stress by a static deflection. Two classes: liquids and gases Static is somewhat subjective because some fluids flow so slowly that they are considered static e.g., asphalt (not glass) the time scale for flow is related to the Deborah Number

Images Flames Different Re Numbers above and a simulation from a tailpipe below.

Images Weather (Vortices)

Images Weather

Images Aircraft

Images Shock waves

Fluid Properties and Analysis

Fluid as a Continuum Even though fluids are made up of Quarks, atoms and molecules, we will assume they are continuous. Hence, nothing we learn can be applied to very small systems (microns or less). Density: = lim V V o m V

Dimensions Dimensions will be both useful and necessary in this class. We will use both SI and British Units In lectures we will sometimes use the generic: M for mass (e.g., kilogram, lbm, or slug) L for length (e.g., meter or foot) T for time (e.g. second) for temperature (e.g. K or o F)

Dimensionality All answers must have units Theoretical equations (F=ma, E=mc2 ) have consistent units and are dimensionally homogeneous (each term has the same units). Empirical (?) equations do not always have consistent units and special attention must be paid towards using the correct units (ex, Antoine's Eq).

Frames of reference Effects mass and energy balances and equations Eulerian On the shore frame of reference Used almost exclusively in fluid dynamics Get pressure, p(x,y,z,t) Lagrangian In the boat frame of reference Used almost exclusively in solid mechanics Get pressure, p(t)

Basic Properties Pressure p Units Pa, lbf/ft 2 Pressure at sea level 1 atm = 1.01325x10 5 Pa Density ρ Units kg/m 3, lbm/ft 3 Water 1000 kg/m 3 or 1 gm/cm 3 (know) Air 1 kg/m 3 Temperature T Units use absolute scale (K or o R)

Basic Properties Velocity (a VECTOR) V x, y, z,t =u x, y, z, t i v x, y,z,t j w x, y, z,t k Magnitude of the velocity vector is the speed

Basic Properties Enthalpy, Entropy secondary interest for us Specific Heats - ditto Transport properties: Viscosity μ ( very important, more soon) Units M/(L Θ), P (poise) Water 2x10-5 P Air 1 x 10-3 P Thermal conductivity ditto

Property Variation Gases: Ideal gas law: p=ρrt Liquids Density is nearly constant Variation is approximated over a limited range by fitting data with a polynomial or something else...

Stresses FORCE/AREA (*Newton's Law, F=ma, still applies to `blobs' of fluid) Normal Stress tensile or compressive Includes PRESSURE Tangential Stress called Shear Stress

Viscosity Measure of a fluids resistance to flow High viscosity means high resistance e.g., honey, tar, heavy oil, Karo syrup SAE 30 oil is 300 times more viscous than water Low viscosity means low resistance e.g., air The Viscosity is a function of many things - Temperature Velocity at which the fluid is moving Shear stresses within the fluid (τ).

Newtonian Fluids Common fluids, like air, water, and oil have a simple relationship between STRESS and DEFORMATION (i.e., velocity profile) τ= μ( dv/dy) The shear stress is proportional to the strain rate (i.e., velocity gradient or rate of change in velocity). The constant of proportionality is the viscosity Fluids that follow this relationship are called Newtonian fluids (more on nonnewtonian fluids later)

Page 14 dv/dy = V/δ τ = F/A = µ V/δ

More on viscosity Varies with pressure (weakly) and temperature (strongly). Often, the kinematic viscosity is reported: ν = µ/ρ Just the viscosity divided by density Units: L 2 /Θ Variation with temperature: µ = µ 0 (T/T 0 ) n The so called power law where n changes between gases, many other correlations (curve fits) are available.

Nonnewtonian Fluids Shear thickening fluids increase thickness with increasing strain rate Pseudoplastics (shear thinning) fluids decreases resistance with increasing strain rate. Bingham plastic require a finite stress before flow (toothpaste)

Applies only to liquids Surface Tension Molecules near the surface are attracted to each other, so increasing the surface area requires a force The coefficent of surface tension, σ, is the force per length of surface tension (0.073 N/m, air-h 2 O), or, equivalently the energy per area (J/m 2 ) Can also be thought of as the surface energy per unit area at the interface A pressure drop (force per area) is required to curve a surface: p=2σ/r (sphere), p=σ/(r 1 +R 2 ) (general)

Vapor Pressure The pressure at which a liquid boils for a given temperature. (or the equilibrium pressure for a given temperature) One important aspect for fluid mechanics occurs when the ambient pressure falls below the vapor pressure resulting in boiling or cavitation. Cavitation number: Ca=2(p a -p v )/ (ρv 2 ).

Boundary Conditions When a fluid is in contact with a solid surface, molecular interactions cause the fluid in contact with the surface to seek momentum and energy equilibrium with that surface. Two consequences: V fluid = V wall (typically zero) *NO SLIP States there is a very thing layer of fluid molecules near the solid surface moving at the solid velocity. T fluid =T wall *no temperature jump condition

Flow Analysis Flows must satisfy three basic laws of mechanics Conservation of mass (very important) Conservation of momentum (very important) Conservation of energy (only important if temperature is changing) Constitutive relationships Ideal gas law Newton's law of viscosity Boundary conditions (hard to get).

Flow Visualization Streamline: line everywhere tangent to the velocity vector. (instantaneous) Pathline: the actual path traversed by a given fluid particle (temporal, one particle) Streakline: locus of particles that have earlier passed through a prescribed point. (temporal, many particles) Timeline: a set of fluid particles that form a line at a given instant. (instantaneous) First three identical in steady flow!

Experimental Flow Visualization Dye, smoke, or bubble discharges (most common) Neutral-density particles Luminescent fluids or bioluminescence Particle image velocimetry Doppler shift with a laser Ultrasound (echocardiography)

Computer Software Options Matlab Excel Engineering Equation Solver I'm reluctant to require everyone to use a specific option I'll likely use Excel (i.e., Open Office Calc)