Problems of Chapter 2

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1 Section 2.1 Heat and Internal Energy Problems of Chapter 2 1- On his honeymoon James Joule traveled from England to Switzerland. He attempted to verify his idea of the interconvertibility of mechanical energy and internal energy by measuring the increase in temperature of water that fell in a waterfall. If water at the top of an alpine waterfall has a temperature of 10.0 C and then falls 50.0 m (as at Niagara Falls), what maximum temperature at the bottom of the falls could Joule expect? He did not succeed in measuring the temperature change, partly because evaporation cooled the falling water, and also because his thermometer was not sufficiently sensitive.. 2- In Joule s experiment, the mass of each of the two blocks is 1.5 kg, and the insulated tank is filled with 200 g of water. What is the increase in the temperature of the water after the blocks fall through a distance of 3 m? Section 2.2 Specific Heat and Calorimetry 3- The temperature of a silver bar rises by 10.0 C when it absorbs 1.23 kj of energy by heat. The mass of the bar is 525 g. Determine the specific heat of silver. 1

2 4- A 50.0-g sample of copper is at 25.0 C. If J of energy is added to it by heat, what is the final temperature of the copper? 5- A 1.5-kg iron horseshoe initially at 600 C is dropped into a bucket containing 20.0 kg of water at 25 C. What is the final temperature? (Ignore the heat capacity of the container, and assume that a negligible amount of water boils away.) 6- An aluminum cup of mass 200 g contains 800 g of water in thermal equilibrium at 80 C. The combination of cup and water is cooled uniformly so that the temperature decreases by 1.50 C per minute. At what rate is energy being removed by heat? Express your answer in watts. 7- A 3 g copper penny at 25 C drops 50 m to the ground. (a) Assuming that 60 % of the change in potential energy of the penny Earth system goes into increasing the internal energy of the penny, determine its final temperature. (b) What If? Does the result depend on the mass of the penny? Explain. 2

3 8- A water heater is operated by solar power. If the solar collector has an area of 6 m 2 and the intensity delivered by sunlight is 550 W/m 2, how long does it take to increase the temperature of 1 m 3 of water from 20 C to 60 C? Section 2.3 Latent Heat 9- How much energy is required to change a 40 g ice cube from ice at -10 C to steam at 110 C? 10- A 50 g copper calorimeter contains 250 g of water at 20 C. How much steam must be condensed into the water if the final temperature of the system is to reach 50 C? 17- A 3 g lead bullet at 30 C is fired at a speed of 240 m/s into a large block of ice at 0 C, in which it becomes embedded. What quantity of ice melts? 3

4 Section 2.4 Work and Heat in Thermodynamic Processes 18- A sample of ideal gas is expanded to twice its original volume of 1.00 m 3 in a quasi-static process for which P = V 2 with = 5 atm/m 6, as shown in Figure. How much work is done on the expanding gas? 19- (a) Determine the work done on a fluid that expands from I to f as indicated in Figure. (b) What If? How much work is performed on the fluid if it is compressed from f to I along the same path? 4

5 20- An ideal gas is enclosed in a cylinder that has a movable piston on top. The piston has a mass m and an area A and is free to slide up and down, keeping the pressure of the gas constant. How much work is done on the gas as the temperature of n mol of the gas is raised from T 1 to T 2? 21- An ideal gas is enclosed in a cylinder with a movable piston on top of it. The piston has a mass of 8000 g and an area of 5 cm2 and is free to slide up and down, keeping the pressure of the gas constant. How much work is done on the gas as the temperature of 0.2 mol of the gas is raised from 20 C to 300 C? Section 2.5 The First Law of Thermodynamics 22- A gas is compressed at a constant pressure of 0.8 atm from 9 L to 2 L. In the process, 400 J of energy leaves the gas by heat. (a) What is the work done on the gas? (b) What is the change in its internal energy? 23- A thermodynamic system undergoes a process in which its internal energy decreases by 500 J. At the same time, 220 J of work is done on the system. Find the energy transferred to or from it by heat. 5

6 24- A gas is taken through the cyclic process described in the Figure. (a) Find the net energy transferred to the system by heat during one complete cycle. (b) What If? If the cycle is reversed that is, the process follows the path ACBA what is the net energy input per cycle by heat? Section 2.6 Some Applications of the First Law of Thermodynamics 25- One mole of an ideal gas does 3000 J of work on its surroundings as it expands isothermally to a final pressure of 1atm and volume of 25 L. Determine (a) the initial volume and (b) the temperature of the gas. 26-An ideal gas initially at 300 K undergoes an isobaric expansion at 2.50 kpa. If the volume increases from 1 m 3 to 3 m 3 and 12.5 kj is transferred to the gas by heat, what are (a) the change in its internal energy and (b) its final temperature? 6

7 27-How much work is done on the steam when 1mol of water at 100 C boils and becomes 1 mol of steam at 100 C at 1 atm pressure? Assuming the steam to behave as an ideal gas, determine the change in internal energy of the material as it vaporizes. 28- An ideal gas initially at Pi, Vi, and Ti is taken through a cycle as in Figure. (a) Find the net work done on the gas per cycle. (b) What is the net energy added by heat to the system per cycle? (c) Obtain a numerical value for the net work done per cycle for 1 mol of gas initially at 0 C. 7

8 29-A 2 mol sample of helium gas initially at 300 K and 0.4 atm is compressed isothermally to 1.20 atm. Noting that the helium behaves as an ideal gas, find (a) the final volume of the gas, (b) the work done on the gas, and (c) the energy transferred by heat. 8

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