Introduction to Powder X-Ray Diffraction History Basic Principles
|
|
|
- Meagan Marcia Grant
- 9 years ago
- Views:
Transcription
1 Introduction to Powder X-Ray Diffraction History Basic Principles Folie.1
2 History: Wilhelm Conrad Röntgen Wilhelm Conrad Röntgen discovered 1895 the X-rays he was honoured by the Noble prize for physics. In 1995 the German Post edited a stamp, dedicated to W.C. Röntgen. Basics-in-XRD.2
3 The Principles of an X-ray Tube X-Ray Cathode Fast electrons Anode focus Basics-in-XRD.3
4 The Principle of Generation Bremsstrahlung nucleus Ejected electron (slowed down and changed direction) Fast incident electron electrons Atom of the anodematerial X-ray Basics-in-XRD.4
5 The Principle of Generation the Characteristic Radiation Photoelectron Emission M Kα-Quant L K Electron Lα-Quant Kβ-Quant Basics-in-XRD.5
6 The Generating of X-rays Bohr`s model Basics-in-XRD.6
7 The Generating of X-rays energy levels (schematic) of the electrons M L Intensity ratios Kα1 : Kα2 : Kβ = 10 : 5 : 2 K Kα1 Kα2 Kβ1 Kβ2 Basics-in-XRD.7
8 The Generating of X-rays Anode (kv) Wavelength, λ [Angström ] Kß-Filter Mo 20,0 Kα1 : 0,70926 Kα2 : 0,71354 Kβ1 : 0,63225 Zr 0,08mm Cu 9,0 Kα1 : 1,5405 Kα2 : 1,54434 Ni 0,015mm Kβ1 : 1,39217 Co 7,7 Kα1 : 1,78890 Kα2 : 1,79279 Kβ1 : 1,62073 Fe 0,012mm Fe 7,1 Kα1 : 1,93597 Kα2 : 1,93991 Kβ1 : 1,75654 Mn 0,011mm Basics-in-XRD.8
9 The Generating of X-rays Emission Spectrum of a Molybdenum X-Ray Tube Bremsstrahlung = continuous spectra characteristic radiation = line spectra Basics-in-XRD.9
10 History: Max Theodor Felix von Laue Max von Laue put forward the conditions for scattering maxima, the Laue equations: a(cosα-cosα 0 )=hλ b(cosβ-cosβ 0 )=kλ c(cosγ-cosγ 0 )=lλ Basics-in-XRD.10
11 Laue s Experiment in 1912 Single Crystal X-ray Diffraction Tube Tube Crystal Collimator Film Basics-in-XRD.11
12 Powder X-ray Diffraction Film Tube Powder Basics-in-XRD.12
13 Powder Diffraction Diffractogram Basics-in-XRD.13
14 History: W. H. Bragg and W. Lawrence Bragg W.H. Bragg (father) and William Lawrence.Bragg (son) developed a simple relation for scattering angles, now call Bragg s law. d λ = n 2 sin θ Basics-in-XRD.14
15 Another View of Bragg s Law nλ = 2d sinθ Basics-in-XRD.15
16 Crystal Systems Crystal systems Axes system cubic a = b = c, α = β = γ = 90 Tetragonal a = b c, α = β = γ = 90 Hexagonal a = b c, α = β = 90, γ = 120 Rhomboedric a = b = c, α = β = γ 90 Orthorhombic a b c, α = β = γ = 90 Monoclinic a b c, α = γ = 90, β 90 Triclinic a b c, α γ β Basics-in-XRD.16
17 Reflection Planes in a Cubic Lattice Basics-in-XRD.17
18 The Elementary Cell a = b = c α = β = γ = 90 o c a β γ α b Basics-in-XRD.18
19 Relationship between d-value and the Lattice Constants λ =2dsinθ Bragg s law The wavelength is known Theta is the half value of the peak position d will be calculated 1/d 2 = (h 2 + k 2 )/a 2 + l 2 /c 2 Equation for the determination of the d-value of a tetragonal elementary cell h,k and l are the Miller indices of the peaks a and c are lattice parameter of the elementary cell if a and c are known it is possible to calculate the peak position if the peak position is known it is possible to calculate the lattice parameter Basics-in-XRD.19
20 Interaction between X-ray and Matter d incoherent scattering λco (Compton-Scattering) wavelength λpr intensity Io coherent scattering λpr(bragg s-scattering) absorption Beer s law I = I0*e-µd fluorescence λ> λpr photoelectrons Basics-in-XRD.20
21 History (4): C. Gordon Darwin C. Gordon Darwin, grandson of C. Robert Darwin (picture) developed 1912 dynamic theory of scattering of X-rays at crystal lattice Basics-in-XRD.21
22 History (5): P. P. Ewald P. P. Ewald 1916 published a simple and more elegant theory of X-ray diffraction by introducing the reciprocal lattice concept. Compare Bragg s law (left), modified Bragg s law (middle) and Ewald s law (right). λ d = n 2 sinθ sinθ = 1 d 2 λ σ sinθ = 2 1 λ Basics-in-XRD.22
23 Introduction Part II Contents: unit cell, simplified Bragg s model, Straumannis chamber, diffractometer, pattern Usage: Basic, Cryst (before Cryst I), Rietveld I Folie.23
24 Crystal Lattice and Unit Cell Let us think of a very small crystal (top) of rocksalt (NaCl), which consists of 10x10x10 unit cells. Every unit cell (bottom) has identical size and is formed in the same manner by atoms. It contains Na + -cations (o) and Cl - - anions (O). Each edge is of the length a. Basics-in-XRD.24
25 Bragg s Description The incident beam will be scattered at all scattering centres, which lay on lattice planes. The beam scattered at different lattice planes must be scattered coherent, to give an maximum in intensity. The angle between incident beam and the lattice planes is called θ. The angle between incident and scattered beam is 2θ. The angle 2θ of maximum intensity is called the Bragg angle. Basics-in-XRD.25
26 Bragg s Law A powder sample results in cones with high intensity of scattered beam. Above conditions result in the Bragg equation s or = n λ = 2 d sinθ d λ = n 2 sin θ Basics-in-XRD.26
27 Film Chamber after Straumannis The powder is fitted to a glass fibre or into a glass capillary. X-Ray film, mounted like a ring around the sample, is used as detector. Collimators shield the film from radiation scattered by air. Basics-in-XRD.27
28 Film Negative and Straumannis Chamber Remember The beam scattered at different lattice planes must be scattered coherent, to give an maximum of intensity. Maximum intensity for a specific (hkl)-plane with the spacing d between neighbouring planes at the Bragg angle 2θ between primary beam and scattered radiation. n λ This relation is quantified by Bragg s law. d = 2 sin θ A powder sample gives cones with high intensity of scattered beam. Basics-in-XRD.28
29 D8 ADVANCE Bragg-Brentano Diffractometer A scintillation counter may be used as detector instead of film to yield exact intensity data. Using automated goniometers step by step scattered intensity may be measured and stored digitally. The digitised intensity may be very detailed discussed by programs. More powerful methods may be used to determine lots of information about the specimen. Basics-in-XRD.29
30 The Bragg-Brentano Geometry Tube Detector focusingcircle Sample q 2q measurement circle Basics-in-XRD.30
31 The Bragg-Brentano Geometry Divergence slit Detectorslit Antiscatterslit Monochromator Tube Sample Basics-in-XRD.31
32 Comparison Bragg-Brentano Geometry versus Parallel Beam Geometry Bragg-Brentano Geometry Parallel Beam Geometry generated by Göbel Mirrors Basics-in-XRD.32
33 Parallel-Beam Geometry with Göbel Mirror Göbel mirror Detector Soller Slit Tube Sample Basics-in-XRD.33
34 Grazing Incidence X-ray Diffraction Soller slit Detector Tube Sample Measurement circle Basics-in-XRD.34
35 Grazing Incidence Diffraction with Göbel Mirror Soller slit Detector Göbel mirror Tube Sample Measurement circle Basics-in-XRD.35
36 What is a Powder Diffraction Pattern? a powder diffractogram is the result of a convolution of a) the diffraction capability of the sample (F hkl ) and b) a complex system function. The observed intensity y oi at the data point i is the result of y oi = of intensity of "neighbouring" Bragg peaks + background The calculated intensity y ci at the data point i is the result of y ci = structure model + sample model + diffractometer model + background model Basics-in-XRD.36
37 Which Information does a Powder Pattern offer? peak position dimension of the elementary cell peak intensity content of the elementary cell peak broadening strain/crystallite size scaling factor quantitative phase amount diffuse background false order modulated background close order Basics-in-XRD.37
38 Powder Pattern and Structure The d-spacings of lattice planes depend on the size of the elementary cell and determine the position of the peaks. The intensity of each peak is caused by the crystallographic structure, the position of the atoms within the elementary cell and their thermal vibration. The line width and shape of the peaks may be derived from conditions of measuring and properties - like particle size - of the sample material. Basics-in-XRD.38
X-Ray Diffraction HOW IT WORKS WHAT IT CAN AND WHAT IT CANNOT TELL US. Hanno zur Loye
X-Ray Diffraction HOW IT WORKS WHAT IT CAN AND WHAT IT CANNOT TELL US Hanno zur Loye X-rays are electromagnetic radiation of wavelength about 1 Å (10-10 m), which is about the same size as an atom. The
Crystal Structure Determination I
Crystal Structure Determination I Dr. Falak Sher Pakistan Institute of Engineering and Applied Sciences National Workshop on Crystal Structure Determination using Powder XRD, organized by the Khwarzimic
X-ray Diffraction and EBSD
X-ray Diffraction and EBSD Jonathan Cowen Swagelok Center for the Surface Analysis of Materials Case School of Engineering Case Western Reserve University October 27, 2014 Outline X-ray Diffraction (XRD)
X-ray Diffraction (XRD)
X-ray Diffraction (XRD) 1.0 What is X-ray Diffraction 2.0 Basics of Crystallography 3.0 Production of X-rays 4.0 Applications of XRD 5.0 Instrumental Sources of Error 6.0 Conclusions Bragg s Law n l =2dsinq
X-ray thin-film measurement techniques
Technical articles X-ray thin-film measurement techniques II. Out-of-plane diffraction measurements Toru Mitsunaga* 1. Introduction A thin-film sample is two-dimensionally formed on the surface of a substrate,
Introduction to X-Ray Powder Diffraction Data Analysis
Introduction to X-Ray Powder Diffraction Data Analysis Center for Materials Science and Engineering at MIT http://prism.mit.edu/xray An X-ray diffraction pattern is a plot of the intensity of X-rays scattered
Powder diffraction and synchrotron radiation
Powder diffraction and synchrotron radiation Gilberto Artioli Dip. Geoscienze UNIPD CIRCe Center for Cement Materials single xl diffraction powder diffraction Ideal powder Powder averaging Textured sample
Generation of X-Rays (prepared by James R. Connolly, for EPS400-002, Introduction to X-Ray Powder Diffraction, Spring 2005)
A Bit of History A good discussion of the early x-ray discoveries may be found in Chapter 1 of Moore and Reynolds (1997). I have borrowed freely from a variety of sources for this section. An online sketch
Chapter 7: Basics of X-ray Diffraction
Providing Solutions To Your Diffraction Needs. Chapter 7: Basics of X-ray Diffraction Scintag has prepared this section for use by customers and authorized personnel. The information contained herein is
A NATIONAL MEASUREMENT GOOD PRACTICE GUIDE. No. 52. Determination of Residual Stresses by X-ray Diffraction - Issue 2
A NATIONAL MEASUREMENT GOOD PRACTICE GUIDE No. 52 Determination of Residual Stresses by X-ray Diffraction - Issue 2 The DTI drives our ambition of prosperity for all by working to create the best environment
Applications of New, High Intensity X-Ray Optics - Normal and thin film diffraction using a parabolic, multilayer mirror
Applications of New, High Intensity X-Ray Optics - Normal and thin film diffraction using a parabolic, multilayer mirror Stephen B. Robie scintag, Inc. 10040 Bubb Road Cupertino, CA 95014 Abstract Corundum
Structure Factors 59-553 78
78 Structure Factors Until now, we have only typically considered reflections arising from planes in a hypothetical lattice containing one atom in the asymmetric unit. In practice we will generally deal
POWDER X-RAY DIFFRACTION: STRUCTURAL DETERMINATION OF ALKALI HALIDE SALTS
EXPERIMENT 4 POWDER X-RAY DIFFRACTION: STRUCTURAL DETERMINATION OF ALKALI HALIDE SALTS I. Introduction The determination of the chemical structure of molecules is indispensable to chemists in their effort
Experiment: Crystal Structure Analysis in Engineering Materials
Experiment: Crystal Structure Analysis in Engineering Materials Objective The purpose of this experiment is to introduce students to the use of X-ray diffraction techniques for investigating various types
Relevant Reading for this Lecture... Pages 83-87.
LECTURE #06 Chapter 3: X-ray Diffraction and Crystal Structure Determination Learning Objectives To describe crystals in terms of the stacking of planes. How to use a dot product to solve for the angles
EDS system. CRF Oxford Instruments INCA CRF EDAX Genesis EVEX- NanoAnalysis Table top system
EDS system Most common X-Ray measurement system in the SEM lab. Major elements (10 wt% or greater) identified in ~10 secs. Minor elements identifiable in ~100 secs. Rapid qualitative and accurate quantitative
PHOTOELECTRIC EFFECT AND DUAL NATURE OF MATTER AND RADIATIONS
PHOTOELECTRIC EFFECT AND DUAL NATURE OF MATTER AND RADIATIONS 1. Photons 2. Photoelectric Effect 3. Experimental Set-up to study Photoelectric Effect 4. Effect of Intensity, Frequency, Potential on P.E.
Chapter 3. 1. 3 types of materials- amorphous, crystalline, and polycrystalline. 5. Same as #3 for the ceramic and diamond crystal structures.
Chapter Highlights: Notes: 1. types of materials- amorphous, crystalline, and polycrystalline.. Understand the meaning of crystallinity, which refers to a regular lattice based on a repeating unit cell..
BRUKER ADVANCED X-RAY SOLUTIONS GUIDE TO XRF BASICS
BRUKER ADVANCED X-RAY SOLUTIONS GUIDE TO XRF BASICS This guide was first published in West Germany under the title Introduction to X-ray Fluorescence Analysis (XRF). 2000-2006 Bruker AXS GmbH, Karlruhe,
12.524 2003 Lec 17: Dislocation Geometry and Fabric Production 1. Crystal Geometry
12.524 2003 Lec 17: Dislocation Geometry and Fabric Production 1. Bibliography: Crystal Geometry Assigned Reading: [Poirier, 1985]Chapter 2, 4. General References: [Kelly and Groves, 1970] Chapter 1. [Hirth
Polarization Dependence in X-ray Spectroscopy and Scattering. S P Collins et al Diamond Light Source UK
Polarization Dependence in X-ray Spectroscopy and Scattering S P Collins et al Diamond Light Source UK Overview of talk 1. Experimental techniques at Diamond: why we care about x-ray polarization 2. How
Chapters 2 and 6 in Waseda. Lesson 8 Lattice Planes and Directions. Suggested Reading
Analytical Methods for Materials Chapters 2 and 6 in Waseda Lesson 8 Lattice Planes and Directions Suggested Reading 192 Directions and Miller Indices Draw vector and define the tail as the origin. z Determine
X-ray Powder Diffraction Pattern Indexing for Pharmaceutical Applications
The published version of this manuscript may be found at the following webpage: http://www.pharmtech.com/pharmtech/peer-reviewed+research/x-ray-powder-diffraction-pattern-indexing-for- Phar/ArticleStandard/Article/detail/800851
LMB Crystallography Course, 2013. Crystals, Symmetry and Space Groups Andrew Leslie
LMB Crystallography Course, 2013 Crystals, Symmetry and Space Groups Andrew Leslie Many of the slides were kindly provided by Erhard Hohenester (Imperial College), several other illustrations are from
X-ray Techniques: Overview. Ron Jenkins
X-ray Techniques: Overview Ron Jenkins in Encyclopedia of Analytical Chemistry R.A. Meyers (Ed.) pp. 13269 13288 John Wiley & Sons Ltd, Chichester, 2000 X-RAY TECHNIQUES: OVERVIEW 1 X-ray Techniques:
Crystal Structure of High Temperature Superconductors. Marie Nelson East Orange Campus High School NJIT Professor: Trevor Tyson
Crystal Structure of High Temperature Superconductors Marie Nelson East Orange Campus High School NJIT Professor: Trevor Tyson Introduction History of Superconductors Superconductors are material which
6) How wide must a narrow slit be if the first diffraction minimum occurs at ±12 with laser light of 633 nm?
Test IV Name 1) In a single slit diffraction experiment, the width of the slit is 3.1 10-5 m and the distance from the slit to the screen is 2.2 m. If the beam of light of wavelength 600 nm passes through
Crystal Optics of Visible Light
Crystal Optics of Visible Light This can be a very helpful aspect of minerals in understanding the petrographic history of a rock. The manner by which light is transferred through a mineral is a means
Each grain is a single crystal with a specific orientation. Imperfections
Crystal Structure / Imperfections Almost all materials crystallize when they solidify; i.e., the atoms are arranged in an ordered, repeating, 3-dimensional pattern. These structures are called crystals
WAVELENGTH OF LIGHT - DIFFRACTION GRATING
PURPOSE In this experiment we will use the diffraction grating and the spectrometer to measure wavelengths in the mercury spectrum. THEORY A diffraction grating is essentially a series of parallel equidistant
Basics of X-ray diffraction: From symmetry to structure determination
Basics of X-ray diffraction: From symmetry to structure determination T. N. Guru Row Solid State and Structural Chemistry Unit Indian Institute of Science Bangalore-560012 Email: [email protected]
GAMMA-RAY SPECTRA REFERENCES
GAMMA-RAY SPECTRA REFERENCES 1. K. Siegbahn, Alpha, Beta and Gamma-Ray Spectroscopy, Vol. I, particularly Chapts. 5, 8A. 2. Nucleonics Data Sheets, Nos. 1-45 (available from the Resource Centre) 3. H.E.
Chapter 1 Diffraction and the X-Ray Powder Diffractometer 1.1 Diffraction 1.1.1 Introduction to Diffraction
Chapter 1 Diffraction and the X-Ray Powder Diffractometer 1.1 Diffraction 1.1.1 Introduction to Diffraction Materials are made of atoms. Knowledge of how atoms are arranged into crystal structures and
Rigaku XRD-System Instruction Manual v4/19/03. The Krishnan Group/Wilcox 132, University of Washington
Rigaku XRD-System Instruction Manual v4/19/03 The Krishnan Group/Wilcox 132, University of Washington Contents: - General information - Safety - How to turn on the X-rays - How to turn off the X-rays -
O6: The Diffraction Grating Spectrometer
2B30: PRACTICAL ASTROPHYSICS FORMAL REPORT: O6: The Diffraction Grating Spectrometer Adam Hill Lab partner: G. Evans Tutor: Dr. Peter Storey 1 Abstract The calibration of a diffraction grating spectrometer
Solid State Theory Physics 545
Solid State Theory Physics 545 CRYSTAL STRUCTURES Describing periodic structures Terminology Basic Structures Symmetry Operations Ionic crystals often have a definite habit which gives rise to particular
Lectures about XRF (X-Ray Fluorescence)
1 / 38 Lectures about XRF (X-Ray Fluorescence) Advanced Physics Laboratory Laurea Magistrale in Fisica year 2013 - Camerino 2 / 38 X-ray Fluorescence XRF is an acronym for X-Ray Fluorescence. The XRF technique
Introduction to microstructure
Introduction to microstructure 1.1 What is microstructure? When describing the structure of a material, we make a clear distinction between its crystal structure and its microstructure. The term crystal
Matter Waves. Home Work Solutions
Chapter 5 Matter Waves. Home Work s 5.1 Problem 5.10 (In the text book) An electron has a de Broglie wavelength equal to the diameter of the hydrogen atom. What is the kinetic energy of the electron? How
X-ray diffraction techniques for thin films
X-ray diffraction techniques for thin films Rigaku Corporation Application Laboratory Takayuki Konya 1 Today s contents (PM) Introduction X-ray diffraction method Out-of-Plane In-Plane Pole figure Reciprocal
rotation,, axis of rotoinversion,, center of symmetry, and mirror planes can be
Crystal Symmetry The external shape of a crystal reflects the presence or absence of translation-free symmetry y elements in its unit cell. While not always immediately obvious, in most well formed crystal
Laue lens for Nuclear Medicine
Laue lens for Nuclear Medicine PhD in Physics Gianfranco Paternò Ferrara, 6-11-013 Supervisor: prof. Vincenzo Guidi Sensors and Semiconductors Lab, Department of Physics and Earth Science, University of
D FUNDAMENTALS AND PRACTICE OF XRF ANALYSIS
D FUNDAMENTALS AND PRACTICE OF XRF ANALYSIS Fundamentals of XRF Introduction X-ray spectrochemical analysis is based on the fact that the chemical elements emit characteristic radiations when subjected
Fundamentals of modern UV-visible spectroscopy. Presentation Materials
Fundamentals of modern UV-visible spectroscopy Presentation Materials The Electromagnetic Spectrum E = hν ν = c / λ 1 Electronic Transitions in Formaldehyde 2 Electronic Transitions and Spectra of Atoms
CMA Analytical Workshop Day 1 24th April 2012 XRD/ XRF. Robbie Goodhue
CMA Analytical Workshop Day 1 24th April 2012 XRD/ XRF Robbie Goodhue Discovery of x-rays 8 th November 1895 Wilhelm Röntgen Discovery of x-ray diffraction X-ray beam Copper sulphate Photographic paper
α α λ α = = λ λ α ψ = = α α α λ λ ψ α = + β = > θ θ β > β β θ θ θ β θ β γ θ β = γ θ > β > γ θ β γ = θ β = θ β = θ β = β θ = β β θ = = = β β θ = + α α α α α = = λ λ λ λ λ λ λ = λ λ α α α α λ ψ + α =
THE BOHR QUANTUM MODEL
THE BOHR QUANTUM MODEL INTRODUCTION When light from a low-pressure gas is subject to an electric discharge, a discrete line spectrum is emitted. When light from such a low-pressure gas is examined with
Diffraction Course Series 2015
Diffraction Course Series 2015 Mark Wainwright Analytical Centre Kensington Campus, Chemical Sciences Building F10, Room G37 The Mark Wainwright Analytical Centre is offering a new series of courses covering
3.5.4.2 One example: Michelson interferometer
3.5.4.2 One example: Michelson interferometer mirror 1 mirror 2 light source 1 2 3 beam splitter 4 object (n object ) interference pattern we either observe fringes of same thickness (parallel light) or
Bruker AXS. D2 PHASER Diffraction Solutions XRD. think forward
Bruker AXS D2 PHASER Diffraction Solutions think forward XRD Compact all-in-one desktop design Innovative high-end goniometer design Integrated PC / monitor DIFFRAC.SUITE software Leading detector technology
Oxford Instruments Analytical technical briefing. Wavelength Dispersive X-ray Microanalysis
Oxford Instruments Analytical technical briefing Wavelength Dispersive X-ray Microanalysis Oxford Instruments Analytical technical briefing Introduction Electron probe X-ray microanalysis techniques (Wavelength
Problem Set 6 UV-Vis Absorption Spectroscopy. 13-1. Express the following absorbances in terms of percent transmittance:
Problem Set 6 UV-Vis Absorption Spectroscopy 13-1. Express the following absorbances in terms of percent transmittance: a 0.051 b 0.918 c 0.379 d 0.261 e 0.485 f 0.072 A = log P o /P = log1/t = - log T
Atomic Calculations. 2.1 Composition of the Atom. number of protons + number of neutrons = mass number
2.1 Composition of the Atom Atomic Calculations number of protons + number of neutrons = mass number number of neutrons = mass number - number of protons number of protons = number of electrons IF positive
X-Ray Diffraction: A Comprehensive Explanation for Multipurpose Research
X-Ray Diffraction: A Comprehensive Explanation for Multipurpose Research Adree Khondker 1, Shakir Lakhani 2 1 Westdale S.S., Hamilton, ON, Canada 2 Upper Canada College, Toronto, ON, Canada Abstract: The
EDXRF of Used Automotive Catalytic Converters
EDXRF of Used Automotive Catalytic Converters Energy Dispersive X-Ray Fluorescence (EDXRF) is a very powerful technique for measuring the concentration of elements in a sample. It is fast, nondestructive,
Quick Guide for Data Collection on the NIU Bruker Smart CCD
Quick Guide for Data Collection on the NIU Bruker Smart CCD 1. Create a new project 2. Optically align the crystal 3. Take rotation picture 4. Collect matrix to determine unit cell 5. Refine unit cell
Chapter 8. Low energy ion scattering study of Fe 4 N on Cu(100)
Low energy ion scattering study of 4 on Cu(1) Chapter 8. Low energy ion scattering study of 4 on Cu(1) 8.1. Introduction For a better understanding of the reconstructed 4 surfaces one would like to know
GRID AND PRISM SPECTROMETERS
FYSA230/2 GRID AND PRISM SPECTROMETERS 1. Introduction Electromagnetic radiation (e.g. visible light) experiences reflection, refraction, interference and diffraction phenomena when entering and passing
Using the Bruker Tracer III-SD Handheld X-Ray Fluorescence Spectrometer using PC Software for Data Collection
Using the Bruker Tracer III-SD Handheld X-Ray Fluorescence Spectrometer using PC Software for Data Collection Scott A Speakman, Ph.D Center for Materials Science and Engineering at MIT [email protected]
Amptek Application Note XRF-1: XRF Spectra and Spectra Analysis Software By R.Redus, Chief Scientist, Amptek Inc, 2008.
Amptek Application Note XRF-1: XRF Spectra and Spectra Analysis Software By R.Redus, Chief Scientist, Amptek Inc, 2008. X-Ray Fluorescence (XRF) is a very simple analytical technique: X-rays excite atoms
SPECTROSCOPY. Light interacting with matter as an analytical tool
SPECTROSCOPY Light interacting with matter as an analytical tool Electronic Excitation by UV/Vis Spectroscopy : X-ray: core electron excitation UV: valance electronic excitation IR: molecular vibrations
Preparation of ZnS and SnS Nanopowders by Modified SILAR Technique
Journal of Physical Sciences, Vol. 13, 009, 9-34 ISSN: 097-8791 : www.vidyasagar.ac.in/journal Preparation of ZnS and SnS Nanopowders by Modified SILAR Technique Department of Physics The University of
X-RAY DIFFRACTION RESIDUAL STRESS TECHNIQUES
X-RAY DIFFRACTION RESIDUAL STRESS TECHNIQUES Paul S. Prevéy, Lambda Research, Inc. GENERAL USES Macrostress measurement Nondestructive surface residual stress measurement for quality control. Determination
Theory of X-Ray Diffraction. Kingshuk Majumdar
Theory of X-Ray Diffraction Kingshuk Majumdar Contents Introduction to X-Rays Crystal Structures: Introduction to Lattices Different types of lattices Reciprocal Lattice Index Planes X-Ray Diffraction:
CALCULATION METHODS OF X-RAY SPECTRA: A COMPARATIVE STUDY
243 CALCULATION METHODS OF X-RAY SPECTRA: A COMPARATIVE STUDY B. Chyba, M. Mantler, H. Ebel, R. Svagera Technische Universit Vienna, Austria ABSTRACT The accurate characterization of the spectral distribution
Advanced Physics Laboratory. XRF X-Ray Fluorescence: Energy-Dispersive analysis (EDXRF)
Advanced Physics Laboratory XRF X-Ray Fluorescence: Energy-Dispersive analysis (EDXRF) Bahia Arezki Contents 1. INTRODUCTION... 2 2. FUNDAMENTALS... 2 2.1 X-RAY PRODUCTION... 2 2. 1. 1 Continuous radiation...
Tutorial 4.6 Gamma Spectrum Analysis
Tutorial 4.6 Gamma Spectrum Analysis Slide 1. Gamma Spectrum Analysis In this module, we will apply the concepts that were discussed in Tutorial 4.1, Interactions of Radiation with Matter. Slide 2. Learning
Explain the ionic bonds, covalent bonds and metallic bonds and give one example for each type of bonds.
Problem 1 Explain the ionic bonds, covalent bonds and metallic bonds and give one example for each type of bonds. Ionic Bonds Two neutral atoms close to each can undergo an ionization process in order
SHIMADZU XRD-7000 X-RAY DIFFRACTOMETER. The Fridge. Operating Instructions
The Fridge Operating Instructions Table of Contents Introduction 1 RADIATION SAFETY i 5 DATA ANALYSIS Processing Data 15 Analyzing Data 17 Interactions of X-rays with Matter 2 Radiation Sources in the
Glancing XRD and XRF for the Study of Texture Development in SmCo Based Films Sputtered Onto Silicon Substrates
161 162 Glancing XRD and XRF for the Study of Texture Development in SmCo Based Films Sputtered Onto Silicon Substrates F. J. Cadieu*, I. Vander, Y. Rong, and R. W. Zuneska Physics Department Queens College
A VERSATILE COUNTER FOR CONVERSION MÖSSBAUER SPECTROSCOPY
A VERSATILE COUNTER FOR CONVERSION MÖSSBAUER SPECTROSCOPY I. BIBICU 1, G. NICOLESCU 2, L. CIOLACU 2, L. SERBINA 2 1 National Institute for Materials Physics, Bucharest 77125, Romania, [email protected] 2
Electron Microprobe Analysis X-ray spectrometry:
Electron Microprobe Analysis X-ray spectrometry: 1. X-ray generation and emission 2. X-ray detection and measurement X-ray energy and wavelength E=hν h : Planck's constant (6.626x10-34 Joule.sec or, 6.626x10-34
Production of X-rays. Radiation Safety Training for Analytical X-Ray Devices Module 9
Module 9 This module presents information on what X-rays are and how they are produced. Introduction Module 9, Page 2 X-rays are a type of electromagnetic radiation. Other types of electromagnetic radiation
Coating Thickness and Composition Analysis by Micro-EDXRF
Application Note: XRF Coating Thickness and Composition Analysis by Micro-EDXRF www.edax.com Coating Thickness and Composition Analysis by Micro-EDXRF Introduction: The use of coatings in the modern manufacturing
X-Ray Fluorescence Analytical Techniques
X-Ray Fluorescence Analytical Techniques Moussa Bounakhla & Mounia Tahri CNESTEN CONTENT SECTION I: Basic in X-Ray Fluorescence I. History of X-Ray Fluorescence II. Introduction III. Physics of X-Rays
PARALLEL BEAM METHODS IN POWDER DIFFRACTION AND TEXTURE IN THE LABORATORY.
Copyright(c)JCPDS-International Centre for Diffraction Data 2000,Advances in X-ray Analysis,Vol.43 135 PARALLEL BEAM METHODS IN POWDER DIFFRACTION AND TEXTURE IN THE LABORATORY. R.A. Clapp and M.Halleti
Prussian blue nanoparticles for laser-induced photothermal therapy of tumors
Electronic Supplementary Material (ESI) for RSC Advances. This journal is The Royal Society of Chemistry 2014 Supporting Information Prussian blue nanoparticles for laser-induced photothermal therapy of
X-ray Diffraction Techniques for Structural Determination of Amorphous Materials
UCRL-TR-225388 X-ray Diffraction Techniques for Structural Determination of Amorphous Materials C. K. Saw, T. Lian, S. D. Day, J. C. Farmer October 18, 2006 Disclaimer This document was prepared as an
WAVES AND ELECTROMAGNETIC RADIATION
WAVES AND ELECTROMAGNETIC RADIATION All waves are characterized by their wavelength, frequency and speed. Wavelength (lambda, ): the distance between any 2 successive crests or troughs. Frequency (nu,):
Jorge E. Fernández Laboratory of Montecuccolino (DIENCA), Alma Mater Studiorum University of Bologna, via dei Colli, 16, 40136 Bologna, Italy
Information technology (IT) for teaching X- and gamma-ray transport: the computer codes MUPLOT and SHAPE, and the web site dedicated to photon transport Jorge E. Fernández Laboratory of Montecuccolino
STANDARD REFERENCE MATERIAL 640d FOR X-RAY METROLOGY
172 STANDARD REFERENCE MATERIAL 640d FOR X-RAY METROLOGY Abstract David R. Black, Donald Windover, Albert Henins, David Gil, James Filliben and James P. Cline National Institute of Standards and Technology,
Gamma Rays OBJECT: READINGS: APPARATUS: BACKGROUND:
Gamma Rays OBJECT: To understand the various interactions of gamma rays with matter. To calibrate a gamma ray scintillation spectrometer, using gamma rays of known energy, and use it to measure the energy
THEORY OF XRF. Getting acquainted with the principles. Peter Brouwer
THEORY OF XRF Getting acquainted with the principles Peter Brouwer THEORY OF XRF Getting acquainted with the principles Peter Brouwer First published in The Netherlands under the title Theory of XRF. Copyright
COMPARISON OF TEXTURE IN COPPER AND ALUMINUM THIN FILMS DETERMINED BY XRD AND EBSD *
201 COMPARISON OF TEXTURE IN COPPER AND ALUMINUM THIN FILMS DETERMINED BY XRD AND EBSD * J. Müller 1, D. Balzar 1,2, R.H. Geiss 1, D.T. Read 1, and R.R. Keller 1 1 Materials Reliability Division, National
Part 4-32 point groups
Part 4-32 point groups 4.1 Subgroups 4.2 32 point groups 4.2 Crystal forms The 32 point groups The point groups are made up from point symmetry operations and their combinations. A point group is defined
Spectroscopy and Regions of the Spectrum
Basics 9 Spectroscopy and Regions of the Spectrum Different regions of the spectrum probe different types of energy levels of an atomic or molecular system. It is not uncommon to refer to a spectroscopic
Phase determination methods in macromolecular X- ray Crystallography
Phase determination methods in macromolecular X- ray Crystallography Importance of protein structure determination: Proteins are the life machinery and are very essential for the various functions in the
Introduction to Geiger Counters
Introduction to Geiger Counters A Geiger counter (Geiger-Muller tube) is a device used for the detection and measurement of all types of radiation: alpha, beta and gamma radiation. Basically it consists
USING MATLAB FOR MATERIALS DESIGN: DESCRIBING GRAIN ORIENTATIONS IN METALS Claes Olsson, PhD - Docent / Sandvik Materials Technology
USING MATLAB FOR MATERIALS DESIGN: DESCRIBING GRAIN ORIENTATIONS IN METALS Claes Olsson, PhD - Docent / Sandvik Materials Technology THE SANDVIK GROUP MACHINING SOLUTIONS MINING AND CONSTRUCTION MATERIALS
Ionizing Radiation, Czech Republic, CMI (Czech Metrology Institute)
Ionizing Radiation, Czech Republic, (Czech Metrology Institute) Calibration or Measurement RADIOACTIVITY 1.0E+00 1.0E+02 Bq cm -2 C-14 1.0E+01 1.0E+02 Bq cm -2 Co-60 1.0E+01 1.0E+02 Bq cm -2 Sr-90 1.0E+01
Phase Evolution in Yttria-Stabilized Zirconia Thermal Barrier. Coatings Studied by Rietveld Refinement of X-Ray Powder. Diffraction Patterns *
Phase Evolution in Yttria-Stabilized Zirconia Thermal Barrier Coatings Studied by Rietveld Refinement of X-Ray Powder Diffraction Patterns * Grégoire Witz, Valery Shklover, and Walter Steurer Laboratory
Measurement of Charge-to-Mass (e/m) Ratio for the Electron
Measurement of Charge-to-Mass (e/m) Ratio for the Electron Experiment objectives: measure the ratio of the electron charge-to-mass ratio e/m by studying the electron trajectories in a uniform magnetic
X-ray diffraction in polymer science
X-ray diffraction in polymer science 1) Identification of semicrystalline polymers and Recognition of crystalline phases (polymorphism) of polymers 2)Polymers are never 100% crystalline. XRD is a primary
Simplifying Opto- Mechanical Product Development: How a new product reduces cost, stress, and time to market
Simplifying Opto- Mechanical Product Development: How a new product reduces cost, stress, and time to market Innovation in optical design is exploding. From cell phone cameras to space telescopes, driverless
A Guide to Acousto-Optic Modulators
A Guide to Acousto-Optic Modulators D. J. McCarron December 7, 2007 1 Introduction Acousto-optic modulators (AOMs) are useful devices which allow the frequency, intensity and direction of a laser beam
Chem 106 Thursday Feb. 3, 2011
Chem 106 Thursday Feb. 3, 2011 Chapter 13: -The Chemistry of Solids -Phase Diagrams - (no Born-Haber cycle) 2/3/2011 1 Approx surface area (Å 2 ) 253 258 Which C 5 H 12 alkane do you think has the highest
DIFFRACTION AND INTERFERENCE
DIFFRACTION AND INTERFERENCE In this experiment you will emonstrate the wave nature of light by investigating how it bens aroun eges an how it interferes constructively an estructively. You will observe
X-ray analysis methods
2008 Advanced Materials Characterization Workshop X-ray analysis methods Mauro Sardela, Ph.D. The Frederick Seitz Materials Research Laboratory University of Illinois at Urbana-Champaign Sponsors: Sponsors: