Effect of Thermal Aging on Microstructure of Sn-Bi-In Solder Joint

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1 Trnstons o JWRI, Vol.43 (2014), No. 2 Et o Trml An on Mrostrutur o Sn-B-In Solr Jont MOKHTARI Om*, NISHIKAWA Hros** Astrt In ts stuy, t t o n 0.5 n 1 wt% In to Sn 58B solr on ntrmtll ompoun (IMC) lyrs t t ntr n t mrostrutur o t solr lloys wr nvstt urn rlow n trml n y snnn ltron mrosopy. T rsults sow tt t ton o mnor lmnts ws not tv n supprssn t IMC rowt urn rlow; owvr, t ton o 0.5 wt% In ws tv n supprssn t IMC lyr rowt urn trml n. T rsults lso sow tt t mnor ton o In n snntly supprss t orsnn o t B ps. KEY WORDS: (P-r solr), (Sn B solr), (B orsnn), (mrostrutur rnmnt) 1. Introuton T us o solrs s om rul or ntronnts n pkn o nrly ll ruts n ltron vs. Sn t stlty n rllty o solr jonts s solutly ssntl to t untonlty n urlty o ltron prouts, t s ssntl tt t solrs us r optmz n trms o tr mnl proprts n orr to prov roust ntronntons [1]. P-s solrs v n n us or lon tm n ltron mnuturn us o t xllnt proprts o Sn P solr lloys. Howvr, u to t rmul ts o P on umn lt n t nvronmnt, ts us s srously lmt n ltrons mnuturn. Sn B s solr lloys r n ltrntv to P-s solrs or low tmprtur ppltons [2-4]. Low tmprtur solrn s vnts su s t prvnton o t m us y trml xpnson msmt mon t mtrls us n ltron mnuturn n t rton o nxpnsv prnt rut ors wtout tmprtur rsstn. T ton o 58 wt% B nto Sn orms utt wt rltvly low mltn tmprtur o 139 C, n utt Sn B solr t room tmprtur xts r yl n ttr rtur strnt tn Sn P lloys [1]. Howvr, t Sn B solr lloys lso v svnts, su s ors rns, poor utlty, n orsnn mrostrutur urn trml n [5]. In t, B-r pss r nrlly vry rttl n ntur [6-10], w n rsult n poorr mnl proprts or t solr. Trml n n lso us mor B orsnn y nun Rv on * Splly Appont Rsrr ** Assot Prossor prptton o ovrsturt B. T prptt B prtls n tt to t prvously orm B-r ps, w mks t orsn B pss row v trmlly tvt uson. T uson o B ls to Ostwl rpnn s t lr B prtls row t t xpns o t smll ons [7]. A ly rn solr ulk mrostrutur n snntly mprov t mnl proprts o t jonts, ut t woul tv only t rnmnt oul rtn [11,12]. It s lso n sovr tt t Sn Cu rtv proprts r ly snstv to t onntrton o t mnor lmnts. T morpoloy n tknss o t ntrmtll ompoun (IMC) lyrs t t ntr n mpt t tnsl strnt, sotrml sr tu l, n trml tu l [13-15]. It ws oun tt n rton twn t mnor lmnts n t solr, w tnts o prnt rn n t Cu onntrton n t IMC t t ntr oul n t proprts n t rowt rt o t IMC lyrs t t ntr [16-18]. Untl now, mny stus v prov tt t mnor ton o nw lmnt n mprov t stlty o t solr jont y t rnmnt o t mrostrutur o t solr, s wll s supprss t ntrl IMC lyr [2,3,12,15-20]. Cn t l. [7] sow t t o t us o rr rt C n lmtn B orsnn o t Sn A Cu B C solr. Ty monstrt tt us t C tom sz s lrr tn tt o t otr lmnts n ts solr, t rmnn C toms r ll to tr t t rn ounrs, tus rnn t B-r Trnstons o JWRI s puls y Jonn n Wln Rsr Insttut, Osk Unvrsty, Irk, Osk , Jpn 21

2 Et o Trml An on Mrostrutur o Sn-B-In Solr Jont prptts. Ty n lso rn t wol mrostrutur o t solr y tn s n nomonous ntr o nulton [7]. In ts stuy, w os mnor lloyn ton wt lrr tom sz tn Sn n B (In167 > B156 > Sn140). Sn 0.5 wt% [3] n 1 wt% [16] r wllstls mounts or mnor lloyn tons, ts rsr nvstts t t o 0.5 n 1 wt% o In on t mrostrutur o t utt Sn B solr jont tr rlow n trml n. Sr n Cn [21] v lso lm tt In ssolvs nto t Sn sultt o Sn Cu IMCs n orms Cu6(Sn, In)5. In ts stuy w xtn t xstn stus o IMC supprsson t t srv tmprtur (80 C). In ton, t mrostrutur o t Sn 58B, Sn 58B+0.5wt%In, n Sn 58B+1wt%In solrs on Cu sustrts tr rlow n tt tr n wr nvstt systmtlly. 2. Exprmntl 2.1 Alloy n solr prprton T s utt Sn 58B solr us n ts rsr ws ommrlly vll Sn B solr ro. Alloy solrs wt 0.5 n 1 wt% o In (99.99%) r nm s (Sn-B)-1In n (Sn-B)-0.5In wr rt n-ous y ssolvn t orrsponn mtll powrs or wrs t 700 C or 5. A ln wt prson ws us to w t lmnts. T lloyn pross ws prorm n r, n t moltn solr ws strr mnlly n rquntly n orr to ssur omonous lloy. T ompostons o t lloys wr xmn usn nutvly oupl plsm optl msson sptrosopy (ICP-OES) tr t lloyn prour. Tr ml ompostons r sown n Tl I. Bor t pplton o t solrs, 10-mm-mtr Cu sustrt ps wr ln usn 4 vol% HCl n tnol. A mnlly mx solr pst m o 88 wt% rus solr powr n 12 wt% rosn mlly tvt lux ws post onto t surs o t sustrt ps y prntn trou 200-μm-tk stnl. 3-mm-mtr Cu ps, w wr ln wt t sm mto s ov, wr pl on top o t prnt solr pst. Fur 1 sows smt llustrton o t smpl or t rlow pross. Tl I T ml omposton o t solr lloys Sn B In (Sn-B)-0.5In (Sn-B)-1In mm Cu, Cu 10 mm 3 mm F. 1 T smt llustrton o t smpl Solr Pst, 200 μm 2.2 Rlow n n pross T smpls wr pl ns t rlow ovn, prt t 100 C or 150 s, n rlow t 170 C or 60 s. T ooln rt ws 0.16 C/s n t tm ov t lquus ws 176 s (t mltn pont o Sn B s pproxmtly 139 C [2]), w s sunt sn orn to t ntrntonl ltrotnl ommsson (IEC) stnr [22], t tm ov t lquus o l-r solr must lonr tn 90 s. In ton to t s-rlow smpl, som smpls wr sujt to trml n n n ol t t 80 C or 168, n 504. T smpls wr tn ool own to room tmprtur. 2.3 Mrosopy n quntttv nlyss T rlow n smpls wr mount n poxy n ross ston y mnl polsn to rvl tr mrostrutur usn l msson snnn ltron mrosopy (FESEM, JEOL JSM-6500F). In orr to xmn t top vw o t IMCs, t smpls wr p t 6 vol% HCl or mn. T tknss n rn mtr msurmnts o t IMC lyrs wr prorm y ImJ quntttv nlyss sotwr. T tknss msurmnts wr prorm on tr rnt smpls or solr lloy y vn t r o t wol IMC lyr n SEM m y t lnt o t IMC. T ompostons o t IMC lyrs wr nvstt y JEOL JXA- 8530F l msson ltron pro mronlyzr (EPMA). 3. Rsults 3.1 T solr/sustrt ntr T SEM rsults o t IMC lyrs t t solr/sustrt ntr tr rlow n trml n r sown n F. 2. As n sn n F. 2, t ntrl IMC lyrs sow smlr tknsss n sps or ll solr jonts tr rlow. Cu uss rply nto t moltn solr n orms sllop-lk - Cu6Sn5 IMC lyrs twn t solr n t Cu sustrts urn rlow [1]. Fur 2 lso sows tt t morpoloy o t IMC lyrs tr t trml n n snntly. Sn B, (Sn-B)-1In xt lyrlk IMC sps tr trml n or 504, wrs (Sn-B)-0.5In sows sllop-lk IMC sps. 22

3 Trnstons o JWRI, Vol.43 (2014), No. 2 F. 2 T SEM ms rom t solr jonts tr rlow n trml n; Sn B tr ) rlow, ) n or 168, ) 504, (Sn-B)-0.5In tr ) rlow, ) n or 168, ) n or 504, (Sn-B)-1In tr ) rlow ) n or 168, n ) n or 504 Furs 4 sows t top vws o t IMCs t t solr/sustrt ntr tr p tn. As sn n F. 4, t rn szs o t IMCs t t solr/sustrt ntr wr smlr or ll t solr lloys tr rlow. Fur 4 lso sows tt t rn szs o t IMCs nrs tr trml n, n t sms tt t lr rns rw t t xpns o t smllr rns. T IMC rn mtrs tr rlow n trml n wr msur rom t top vw n r sown n F. 5. T rns n t IMC szs rom t top vw r omprl to t msurmnt rsults rom t rossstonl vw, provn tt t ntrl IMC rns or (Sn-B)-0.5In sow lss rowt tr n or 504 tn tos or t otr solr lloys n ts rsr. In ton, t top-vw ms o (Sn-B)-0.5In sows mor unorm rn szs tn t otr solr lloys. T omposton nlyss ws prorm y EPMA n orr to nvstt t tom omposton o t IMCs o ll solr jonts tr rlow n trml n. T rsults sown n Tl II prov tt or t In- rn T vr tknsss o t IMC lyrs tr trml n nrs wt nrsn tm. (Sn-B)-0.5In prov to t most tv ompostons n trms o vn t tnnst IMC lyrs tr trml n. Vno t l. [2] tt son IMC lyr or utt Sn B solrs on Cu sustrts; owvr, t son IMC lyr twn t rst IMC lyr n t Cu sustrt s not lrly vsl n ts rsr. Fur 3 sows t vr tknsss o t IMC lyrs quntttvly. It lso sows tt t IMC lyr tknsss o ll t solr lloys r smlr tr rlow. It lso sows tt t vr tknsss o (Sn-B)- 0.5In s pproxmtly 30% tt o utt Sn B tr n or 504. In orr to trmn t rus o t IMC rns t t solr/sustrt ntr n ompr t rowt o IMC rns n trms o rus n tknss (s sown y t ross-stonl vws, Fs. 2-3), IMCs wr lso xmn rom t top vw. F. 4 T SEM ms o t top vw o t IMCs o t solr jonts tr rlow n trml n; Sn B tr ) rlow, ) n or 168, ) 504, (Sn-B)-0.5In tr ) rlow, ) n or 168, ) n or 504, (Sn-B)-1In tr ) rlow ) n or 168, n ) n or IMC lyr tknss (μm) Sn-B (Sn-B)-0.5In (Sn-B)-1In IMC rn mtr (μm) Sn-B (Sn-B)-0.5In (Sn-B)-1In An tm ( 1/2 ) F. 3 T vr IMC lyr tknss vrsus t root n tm An tm () F. 5 T IMC rn mtr vrsus n tm; t vlus or IMC rn mtrs wr msur rom t top vw 23

4 Et o Trml An on Mrostrutur o Sn-B-In Solr Jont solr lloys urn t rlow pross, In sms to nlu n t IMC lyr to orm Cu6(Sn, In)5 IMCs y susttutn or Sn, w mts wt t rsults vn y otr stus [13,21]. It n lso sn tt t onntrton o In n t IMC omposton o t solr wt 1 wt. %In ton nrss wt nrsn trml n tm. Howvr, t onntrton o In n t IMC omposton o t solr wt 0.5 wt.% In ton os not n urn trml n. Ts nts tt n nrss t uson o In toms rom t solr wt t ton o 1 wt.% In ut t uson o In toms rom t solr wt 0.5 wt.% In os not n. T rson or t rn n t uson o In toms urn n twn t 1 wt.% n 0.5 wt.% In ton s not lr t ts st. 3.2 T solr ulk mrostrutur Fur 6 sows t In ton ts on t mrostrutur o Sn B solr ulk tr rlow n trml n, rsptvly. T lr rt rtnulr sps r orsn B pss. Tl II Atom omposton nlyss o t IMCs tr rlow n trml n 168 n 504 y EPMA Solr lloy Sn Cu In Sn B (Sn-B)-0.5In (Sn-B)-0.5In (Sn-B)-0.5In (Sn-B)-1In (Sn-B)-1In (Sn-B)-1In Corsn B ps Corsn B ps Corsn B ps F. 6 T SEM ms o t ulk solr tr rlow n trml n; Sn B tr ) rlow, ) n or 168, ) 504, (Sn-B)- 0.5In tr ) rlow, ) n or 168, ) n or 504, (Sn-B)- 1In tr ) rlow ) n or 168, n ) n or 504 T szs o t orsn B pss r omptl wt t rsults o Jun t l., n w t sm ooln rt (0.16 C/s) ws ppl [23]. As n sn, y nrsn t trml n tm t orsn B pss om lrr. Howvr, t In- rn solr lloys o not sow lr sn o B orsnn wtn t ulk solr tr tr rlow or tr trml n. Tror, t s sust tt t mnor ton o In not only rns t mrostrutur o Sn B-s solrs tr rlow, ut lso nts B orsnn tr trml n. In ton, t In-rn solr lloys sow mor unorm mrostruturs. T rn twn t mrostrutur o t Inrn solrs n utt Sn B solrs my t rsult o t rn twn t tom szs o In, Sn, n B. T rus o n In tom s nm, wrs t rus o Sn n B r nm n nm, rsptvly. Ts mks t ult or t In tom to rpl Sn n B toms n t mtrx. Consquntly, In tom tn to lomrt t rn ounrs, rsultn n t supprsson o rn rowt n t orsnn o B rns. Don t l. n Cn t l. sow smlr t n Sn B solrs y t ton o tr mounts o rr rt lmnts [6,24]. It sms t nrs n sz o orsn B pss n ttrut to Ostwl rpnn. Tus, t n sust tt t mn t o In ws to supprss t Ostwl rpnn pross. 4. Conluson Ts rsr nvstt t ts o t ton o 0.5 n 1 wt% In on t mrostrutur o utt Sn B solr jonts tr rlow n trml n. T 0.5 wt% In prov to tv tvs or supprssn t IMC lyr rowt. T omposton nlyss o t IMCs sow tt In sms to nlu n t IMC lyr to orm Cu 6 (Sn, In) 5 IMCs y susttutn or Sn n t onntrton o In n t IMC omposton nrs wt nrsn trml n tm or t solr wt 1 wt.% In ton wl In onntrton not n or t solr wt 0.5 wt.% In ton. T ulk solr stuy nvstt t orsnn vor o t B ps n t mrostrutur o Sn B solrs n ts stuy. Bot (Sn-B)-0.5In n (Sn-B)-1In sow promsn rsults s ty wr ly tv n supprssn B orsnn. Rrns 1) H.R. Kot, P.D. Hows n S.H. Mnnn, Mroltron. Rl. 54, 1253 (2014). 2) P.T. Vno, A.C. Klo, n R. Grnt, J. Eltron. Mtr. 24, 1493 (1995). 3) Y.-C. Hun n S.-W. Cn, J. Eltron. Mtr. 40, 62 (2011). 4) S.K. Kn n A.K. Srkl, J. Eltron. Mtr. 23, 701 (1994). 5) P.L. Lu n J.K. Sn, J. Mtr. Rs. 16, 1651 (2001). 6) Q. Zn, H. Zou, n Z.-F. Zn, J. Mtr. Rs. 25, 24

5 Trnstons o JWRI, Vol.43 (2014), No (2010). 7) W. Cn, J. Kon n W.J. Cn, J. Mn. Mtll. St. B Mtll. 47, 11 (2011). 8) H.W. Mo n J.G. Du, Mtr. Cm. Pys. 71, 255 (2001). 9) C.H. Rr, L.E. Flton, V.A. Tnz n D.B. Knorr, J. Eltron. Mtr. 23, 611 (1994). 10) L.E. Flton, C.H. Rr n D.B. Knorr, JOM. 45, 28 (1993). 11) M. MCormk n S.H. Jn, JOM. 45, 36 (1993) 12) I.E. Anrson, J.C. Foly, B.A. Cook, J. Hrrn, R.L. Trpstr n O. Unl, J. Eltron. Mtr. 30, 1050 (2001). 13) F. Go, T. Tkmoto n H. Nskw, Mt. S. En. A-Strut. 420, 39 (2006). 14) K.S. Km, S.H. Hu, n K. Sunum, Mroltron. Rl. 43, 259 (2003). 15) B. L, Y.W. S, Y.P. L, F. Guo, Z.D. X n B. Zon, J. Eltron. Mtr. 34, 217 (2005). 16) J.Y. Ts, Y.C. Hu, C.M. Ts, n C.R. Ko, J. Eltron. Mtr. 32, 1203 (2003). 17) W.T. Cn, C.E. Ho, n C.R. Ko, J. Mtr. Rs. 17, 263 (2002). 18) H.R. Kot, O. Moktr, M. Bottrll, M.P. Clo, M.A. Grn, n S.H. Mnnn, J. Eltron. Mtr. 39, 2720 (2010). 19) H.R. Kot, O. Moktr, M.P. Clo, M.A. Grn, n S.H. Mnnn, J. Alloys Comp. 511, 176 (2012). 20) H. Nskw, J.Y. Po n T. Tkmoto, J. Eltron. Mtr. 35, 1127 (2006). 21) A. Sr n Y.C. Cn, J. Alloys Comp. 390, 67 (2005). 22) VDE-DKE (IEC ) My ) H.R. Jun, H.H. Km n W.J. L, J. Eltron. Mtr. 35, 1067 (2006). 24) W. Don, Y.W. S, Z.D. X, Y.P. L n F. Guo, J. Eltron. Mtr. 37, 982 (2008). 25

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