How To Build An Amd Quas 3 Ar Mass Spectrometer



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Classical and special AMD Magnetic Sector mass spectrometers (extracted from power point presentations) High Resolution Mass Spectromter AMD 402/403 S 6 High Resolution Mass Spectrometer AMD 604 S 8 Version 080321

Page 2, Classical and special AMD Magnetic Sector mass spectrometers (extracted from power point presentations) System for Cluster Ion Deposition 11 Compact High Performance Mass Spectrometer for demanding Process Analysis AMD M202-D Detection of Heavy Water in cooling circulations system of nuclear power stations Measurement of Isotopic Ratio of H 2 und HD under high resolution conditions General Process Analysis applications 52 Version 080321

Astronomic Dimensions in Mass Spectrometry AMD QuAS 3 AR Innovation in Analytical Instrumentation The AMD QuAS 3 AR is designed to meet the demanding challenges and applications for mass spectrometry in Life Sciences, Environmental Analyses, Chemical Research and other Areas The future orientated AMD QuAS 3 AR mass spectrometer combines all advantages of magnetic sector, time of flight and quadrupole technologies resulting in an unmatched summation of success parameters: Quality of Analyses, Sensitivity, Speed, Specificity, Accuracy, Resolving power = QuAS 3 AR Configurations: A unique combination of ionization techniques results in outstanding features including GC/MS, LC/MS and CE/MS methodologies - Dedicated GC/MS with unique in-axis EI and CI sources for simultaneous recording of fragment ions and quasi-molecular ions or rapid switching between the ionization techniques - Dedicated LC/MS with unique in-axis API (ESI/APCI) and EI sources - Dual Chromatography GC/LC/MS for alternating analyses in both chromatography modes - Multi Purpose Systems according to customer demands incorporating additional modules as DEI, DIP, DCI, Liquid SIMS (FAB), FI/FD techniques Features: - Electric recording of mass spectra covering 1.2 mass decades by simultaneous multi channel scanning - Fast scan speed achieving up to 30 spectra per sec for full scan - Accurate mass measurements better than 5 ppm at dynamic working resolution (6000 FWHM) - Outstanding long term stability of external calibration and use of one lock mass for full mass range - Large dynamic range and drastically improved specificity for quantitative SIM analyses Technology: - A compact double focusing magnetic sector analyzer applying Mattauch-Herzog ion optical geometry - Focal plane for the detection of highly resolved ions in a wide mass range at constant magnetic field - Unique AMD QuAS 3 AR technology using parallel multi channel detection system - Latest digital hardware technology for data acquisition and processing and sophisticated software The Innovators in Magnetic Sector Mass Spectrometry Königsberger Straße 1 D-27243 Harpstedt Germany Phone: +49-4244-1062 / Fax: +49-4244-8646 E-mail: khm@amd-analysis.de http://www.amd-intectra.de

AMD QuAS 3 AR Modular Multi Application High Resolution Mass Spectrometer Description of a unique System GC/MS Configuration with EI ion source and DIP/DEI sample introduction GC/MS Configuration with Dual EI/CI Ionization module AMD Analysis & Technology Aktiengesellschaft Königsberger Str. 1 27243 Harpstedt Telefon (04244) 968736 Telefax (04244) 968738 Handelsregister HRB 141560 Amtsgericht Oldenburg USt-ID Nr. DE238516825 Steuer-Nr. 2357/201/12096 Zoll-Nr.: 6602150

Page 2 GC/LC/MS Configuration with EI/CI/ESI Ionization module Module Description Basic System QuAS 3 AR Double focusing magnetic sector mass spectrometer of the new AMD compact class in special EB configuration Integrated system electronics for bipolar mode Universal ion source housing for different ionization techniques, sample inlet systems and coupling with a choice of peripheral chromatographic systems Turbo molecular pumping system, vacuum control unit with safety circuitry Detector Multichannel EI Reference Single channel detector for largest deflection radius with postacceleration and SEM AMD QuAS 3 AR Detector Technology with Multi-Exit slit arrangement, post-acceleration, simultaneous multi-channel ion detection system High Intensity EI-ion source Reference inlet system, 250 0 C, regulation valve, injection volume Analysis & Technology Aktiengesellschaft Königsberger Str. 1 27243 Harpstedt Telefon (04244) 968736 Telefax (04244) 968738 Handelsregister HRB 141560 Amtsgericht Oldenburg Ust-ID Nr. DE238516825 Steuer-Nr. 2357/201/12096 Zoll-Nr.: 6602150

Page 3 Module Control Data System Description Multi-Tasking Instrument-Control-System (AMD MICS) for processor control of system functions incl. all parameters for ion sources, analyzer, detector and sample introduction systems. AMD Data system (version 2012) for simultaneous data acquisition and data processing Dual-Processor PC, state of the art technology, Windows operating system, large TFT-flat screen monitor, LaserJet Printer Acquisition and real time display system with digital IO, digital multi satellite communication interface and A/D-D/A satellites for simultaneous V/E scans in multi spectral ranges, resulting in a full mass range spectrum based on unique AMD QuAS 3 AR Technology Raw data and peak centroid data acquisition in all LR and HR scan modes Exact mass determinations in single channel, multi channel V/E- and B-scan modes Raw data accumulation, spectra averaging and ion chromatography for LR,HR and Selected Ion Monitoring (SIM) Options Data System and Scan Techniques Evaluation AMD NetCDF Writer, conversion of files in CDF Format for evaluation of data by off-line programs according to customers choice Determination of elemental compositions and isotopic distributions Quantification from ion chromatography data in SIM and scan series modes NIST NIST data base and library search interface Batch Control of automatic injection (batch analyses) in scan and SIM modes (GC or LC with auto sampler required) Decon Deconvolution program for determination of molecular weights from multiple charged Ions in ESI mode Analysis & Technology Aktiengesellschaft Königsberger Str. 1 27243 Harpstedt Telefon (04244) 968736 Telefax (04244) 968738 Handelsregister HRB 141560 Amtsgericht Oldenburg Ust-ID Nr. DE238516825 Steuer-Nr. 2357/201/12096 Zoll-Nr.: 6602150

Page 4 Module Description Options Sample Introduction and Ionization Techniques DIP CI-Standard DEI/DCI Direct Inlet System Software controlled direct inlet system (DIP) with high vacuum lock and insertion probe, gas cooled crucible mounting, temperature range from 18 C - 350 C (low temperature cooling possible) CI device CI-Ionization box movable into EI ion source via DIP inlet port for GC/MS and CI/DCI operation, shut-off and regulation valve for reagent gas DEI/DCI sample introduction Software controlled DCI/DEI inlet probe for the direct analysis of thermo labile/polar substances, temperature range from 20 C -1000 C GC-MS GC-MS Interface, Temperature up to 280 C GC API-UDIC ESI Gas Chromatograph (customer choice) with split/split-less injector API interface in AMD UDIC (Unique Dual Ionization Configuration) inaxis configuration for alternating or simultaneous recording of ions from EI and API ion sources, API housing with counter-electrode, corona needle for calibration and testing, nozzle, lens, skimmer stage with fore pump, ion guide quadrupole with turbo pump Electrospray-Ionization (ESI) Module for LC/MS Coupling and Direct Infusion, flow rates 5-100 µl/min, split for higher flow rates Optional configurations GC/LC/MS Transfer CI-UDIC Dual Chromatography GC/LC/MS Configuration structure which allows alternating analyses (injections) in GC/MS or LC/MS modes without system modifications AMD UDIC ion optics (Unique Dual Ionization Configuration) with AMD MICS extension in special in-axis configuration for two ionization modes. Alternatively: API, LSIMS, extended CI/DCI or FD/FI form with the standard EI source a system for simultaneous or alternating recording of ions from two independent ion sources. CI-UDIC Ion source (Module Transfer required). Flange with EI ion source structure, AMD MICS extension, movable CI ionization volume, shut-off and regulation valve for reagent gas, high vacuum lock, special in axis configuration (with transfer ion optics) for simultaneous or alternating recording of ions from CI/DCI and standard EI ion source Analysis & Technology Aktiengesellschaft Königsberger Str. 1 27243 Harpstedt Telefon (04244) 968736 Telefax (04244) 968738 Handelsregister HRB 141560 Amtsgericht Oldenburg Ust-ID Nr. DE238516825 Steuer-Nr. 2357/201/12096 Zoll-Nr.: 6602150

Page 5 AMD QuAS 3 AR Performance Specifications: 1 Analyzer: Magnetic sector analyzer system in double focusing EB configuration for multichannel parallel ion recording 2 Resolution: Point detector at largest magnetic deflection radius: 300-10000 (10 % valley) or 600-20000 (FWHM) Multi channel mode 300-3000 (10 % valley) or 600-6000 (FWHM) 3 Mass range: 1-2,000 Dalton at 6 kv accelerating voltage 2-4,000 Dalton at 3 kv accelerating voltage 4 Scan range: B-scan: full mass range V/E-scan in multi channel mode: 1.2 mass decade selectable (e.g. 50 800 or 100 1600 u) 5 Scan speed: B-scan: 0.5 sec/mass decade (cycle time 0.8 sec) V/E-scan in multi channel mode: 30 msec/1.2 mass decade (cycle time 40 msec) 6 Sensitivity: 5-10 picogram injected on a capillary column result in substance specific mass spectra for standard samples in GC/MS EI-mode (identifiable by library search) and in CI mode (quasi molecular ion) SIM Techniques: Substance quantitation for standard sample concentrations in the range of 2 5 picogram/µl in GC/MS-EICI mode, (femtogram range at low chemical noise level possible) 100 picogram Reserpine in flow injection ESI-mode yield a signal to noise ratio S/N > 100:1 for the protonated molecular ion 7 Accuracy of mass determination: Computer aided accurate mass determination (short range V/E-Scan): 2-5 ppm at R=3000 (10% valley) B-Scan mode: precision and accuracy of masses in the range of 0.5 2.0 mmu, averaging of at least 5 spectra (scan speed: 1,0 sec/dec, R = 3000 (10% valley), mass range 70-600 u (100 ions per peak required) KHM/Revision June 2012 Analysis & Technology Aktiengesellschaft Königsberger Str. 1 27243 Harpstedt Telefon (04244) 968736 Telefax (04244) 968738 Handelsregister HRB 141560 Amtsgericht Oldenburg Ust-ID Nr. DE238516825 Steuer-Nr. 2357/201/12096 Zoll-Nr.: 6602150