L - o n L-on Secondary Battery Lthum-on Rechargeable Battery LITHIUM-ION RECHARGEABLE BATTERY Notes for Desgners Select the correct type of battery to match the operatng condtons such as load current, etc. The nformaton n ths secton s for lthum-on cells only. Maxell offers these cells (excludng CLB) n battery pack format only. These nclude electronc crcuts to prevent overcharge, overdscharge and so on. These battery packs are custom-developed and produced accordng to specal requrements regardng operatng condtons and specfcatons. As a result, a mnmum number of unts may apply to such customzed orders from customers purchasng battery packs. For detals, consult your nearest Maxell dealer or dstrbutor. Charge condtons To get the most out of lthum-on batteres and use them safely, please read the followng requrements carefully: Charge mode Charge voltage Max. charge current Charge temperature Charge control flowchart (sample) Refer to the followng flowchart when desgnng constant current and constant voltage battery chargers. Start charge Check battery connecton Check battery temperature Check battery voltage Passed Constant current, constant voltage charge Current montorng Temperature montorng Tme montorng Passed Charge completon Constant current, constant voltage charge (CCCV) 4.20±0.05V / cell, 4.40±0.05V / cell 1I ta 0 to +45 deg. C Faled Prelmnary charge Faled Abnormal charge stop Safety Instructons Improper use of the battery may cause heat, fre, exploson, damage or reduced battery capacty. Please read and follow the handlng nstructons for the battery before and durng usage. The followngs are general cautons and gudelnes only and as such may not nclude every possble usage scenaro. The manufacturer wll not be lable for actons taken or accdents caused. Danger Do not dp or wet the battery n water, seawater, or other lqud. Otherwse the battery may be shorted, whch may generate heat or cause damage. Do not put the battery nto a fre. Otherwse, the electrolyte may burn or cause an exploson. Do not heat the battery. Otherwse the electrolyte may bol and resn parts may melt, causng leakage, exploson or fre. The battery has a predetermned polarty. If the battery wll not connect well to the charger or equpment, do not try to connect the battery forcefully. Check the polarty frst. If the battery s connected n reverse, t wll be charged n reverse and may cause leakage, heat generaton, exploson or fre due to an abnormal chemcal reacton. Do not connect the battery n reverse relaton to the postve (+) and negatve ( ) termnals n the charger or equpment. If the battery s connected n reverse, t wll be charged n reverse, dscharge excessve current and may cause heat generaton, exploson or fre due to an abnormal chemcal reacton. Do not let the battery termnals (+ and ) come nto contact wth a wre or any metal (lke a metal necklace or a harpn) wth whch t s carred or stored. In such a case, the battery wll be shorted and dscharge excessve current, whch may result n heat generaton, exploson or fre. Do not apply any heavy mpact to the battery, throw or drop t. Otherwse the battery may be shorted and result n heat generaton, exploson or fre. 3
LITHIUM-ION RECHARGEABLE BATTERY Do not drve a nal nto, hammer or stamp on the battery. Otherwse the battery may be shorted and result n heat generaton, exploson or fre. Do not solder the battery drectly. Heat appled durng solderng may melt resn parts such as separator or gasket, and result n leakage, heat generaton, exploson or fre. Do not dsassemble or alter the battery. Otherwse the battery may be shorted and result n heat generaton or fre. Do not use or leave the battery near fre, heaters, nsde an automoble n hot weather or under strong sunshne. Such condtons of hgh temperature may damage the separator, and the battery may be shorted and result n heat generaton, exploson or fre. When chargng the battery, do not use any battery charger not specfed by the manufacturer. Always follow the charge condtons specfed by the manufacturer. If the battery s charged under other condtons (a hgh temperature, a hgh voltage/current or an altered charger) not specfed by the manufacturer, the battery may cause heat generaton, exploson or fre due to abnormal chemcal reactons. Do not connect the battery drectly to an electrc outlet or cgarette lghter socket n a car. Applyng a hgh voltage may generate an excessve current and cause an electrc shock. In such a case, the battery may leak electrolyte, overheat, explode or cause fre. Warnngs Do not put the battery n a mcrowave oven or a pressure cooker. Sudden heat may damage the seal of the battery and may cause heat generaton, exploson or fre. Do not use the battery together wth a prmary battery such as a dry battery or other battery of a dfferent capacty, type and/or brand. In such a case, over-dscharge durng use or over-charge durng chargng may occur and abnormal chemcal reactons may cause heat generaton, exploson or fre from the battery. Cauton If the battery leaks and ts electrolyte comes nto contact wth skn or clothes, wash the contact area well wth tap water or other clean water rght away. Otherwse skn may break out n a rash. When the battery s expected not to be used for a long tme, take the battery out of the equpment or devce and store t n a less humd area. After long perods of storage wthout beng used, the battery should be charged before t s used. Charge the battery every 6 months to the level specfed by the manufacturer, even f the battery s not used. Do not leave the battery pack connected to the charger. It may cause the degradaton of battery performance, such as a shortenng of battery lfe. Turn off your equpment or devce power swtch after use. Do not use the battery n other than the followng temperature ranges: Charge Dscharge Storage (less than 30 days) Storage (less than 90 days) Notes for treatng used batteres 0 deg. C to +45 deg. C -20 deg. C to +60 deg. C -20 deg. C to +50 deg. C -20 deg. C to +35 deg. C Insulate (+) and ( ) termnals wth tape. Do not remove coatng. Do not expose to ran or water. Do not dsassemble. Do not leave under strong sunshne. Store n rugged receptacle and cover wth a ld. L - o n If you notce any unusual odor, heat, dscoloraton, deformaton or any other characterstc apart from what you are used to whle usng, chargng or storng the battery, then take t out of the equpment or charger, and avod usng t. Usng t n such state may result n heat generaton, exploson or fre. If the battery leaks or emts an unusual odor, remove t from the vcnty of any fre mmedately. The electrolyte may catch fre, whch may cause heat generaton or exploson. Do not let leaked electrolyte come nto contact wth the eyes. In the event of such contact, flush the eyes wth plenty of water mmedately and consult a doctor. Otherwse prolonged contact may cause serous njury. 4
L-on Secondary Battery Prsmatc Lthum-on Rechargeable Battery L - o n Features Thn battery wth hgh capacty Maxell s orgnal technologes, such as electrode technology, have realzed thn batteres wth hgh capacty that can be used n compact hgh-performance moble devces. Cell Structure Gas release vent Negatve termnal Laser seal Stable dscharge under varous temperature condtons Lthum-on batteres provde stable dscharge wthn a wde range of temperatures, between 20 deg. C and 60 deg. C. Separators Postve electrode Excellent cost performance Superor rechargng propertes ensure a servce lfe of about 500 charge/dscharge cycles under normal usage condtons. The superor cost/performance rato ensures that lthum-on batteres are ultmately more economcal than prmary batteres. Postve can Negatve electrode Hgher energy densty and an operatng voltage of over 3.7V A lthum-on battery delvers and mantans a stable operatng voltage of over 3.7V untl fnal dscharge three tmes as much voltage as an N-Cd or N-MH battery provdes. Therefore, t takes only one-thrd as many lthum-on batteres to provde the equvalent amount of voltage as N-Cd or N-MH batteres provde. Ths means that portable devces can be made much smaller and lghter. Applcatons Moble phones, Smartphones Portable game devces Electronc books Electronc dctonares Dgtal stll cameras Dgtal audo players, etc. Characterstcs (ICP515161HR) Charge characterstcs Dscharge temperature characterstcs Charge capacty (%) 100 80 60 40 20 Charge current (ma) 2500 2000 1500 1000 500 Charge current Charge capacty Cell voltage Charge: 2100mA (1ItA)/4.35V (CCCV)/2.5h Temperature: 25 deg. C 5.0 4.5 4.0 3.5 3.0 Cell voltage (V) Cell voltage (V) 4.5 4.0 3.5 3.0 60 deg. C 0 deg. C 10 deg. C Charge: 2100mA (1ItA)/4.35V (CCCV)/2.5h/25 deg. C Dscharge: 420mA (0.2ItA) (E.V. = 2.75V) 20 deg. C 25 deg. C 0 0 2.5 0 30 60 90 120 150 180 Tme (mn) 2.5 0 500 1000 1500 2000 2500 Capacty (mah) Dscharge load characterstcs 4.5 Cycle lfe characterstcs 2500 Cell voltage (V) 4.0 3.5 0.2I ta (420mA) 1I ta (2100mA) Capacty (mah) 2000 1500 1000 3.0 Charge: 2100mA (1ItA)/4.35V (CCCV)/2.5h 500 Charge: 2100mA (1ItA)/4.35V (CCCV)/2.5h Dscharge: 0.2ItA, 1ItA (E.V. = 2.75V) Dscharge: 2100mA (1ItA) (E.V. = 3.0V) Temperature: 25 deg. C Temperature: 25 deg. C 2.5 0 0 500 1000 1500 2000 2500 0 100 200 300 400 500 Cycle number (cycle) Capacty (mah) 5
LITHIUM-ION RECHARGEABLE BATTERY Products Model *1 ICP382230AQS ICP404251XR ICP446584AHR ICP463450AR ICP494261SRU Dmensons (mm) *2 Thckness 3.65±0.15 3.9±0.2 4.15±0.15 4.4±0.2 4.7±0.2 Wdth 21.9±0.15 41.8±0.2 64.8±0.2 33.8±0.2 41.8±0.2 Heght 30.0+0/ 0.4 50.8+0/ 0.5 83.5+0/ 0.5 49.6+0/ 0.5 61.0+0/ 0.5 *5 Weght (g) *3 6 19 54 18 29 Charge (CCCV) Dscharge (CC) Max. voltage (V) 4.35 4.20 4.35 4.20 4.20 Max. current (A) 0.40 1.02 3.20 0.92 1.50 End voltage (V) 2.75 2.75 2.75 2.75 2.75 Max. current (A) 0.50 1.53 4.80 1.38 2.25 Nomnal voltage (V) 3.8 3.7 3.8 3.7 3.7 Mnmum capacty (mah) *4 250 1020 3200 920 1500 L - o n Model *1 ICP515161HR ICP535154WR ICP653450AR ICP704546HRU ICP103444AHRU Dmensons (mm) *2 Thckness 4.9±0.3 5.0±0.25 6.2±0.3 6.7±0.3 9.7±0.3 Wdth 50.3±0.2 50.85±0.2 33.8±0.2 44.6±0.2 33.6±0.2 Heght 60.5+0/ 0.5 54.1+0/ 0.5 49.6+0/ 0.5 46.5+0/ 0.5 44.0+0/ 0.5 Weght (g) *3 36 33 24 35 32 Charge (CCCV) Dscharge (CC) Max. voltage (V) 4.35 4.40 4.20 4.35 4.35 Max. current (A) 2.10 2.00 1.20 1.96 1.85 End voltage (V) 2.75 2.75 2.75 2.75 2.75 Max. current (A) 3.15 3.00 1.80 2.94 2.78 Nomnal voltage (V) 3.8 3.85 3.7 3.8 3.8 Mnmum capacty (mah) *4 2100 2000 1200 1960 1850 *1 "U" ndcates that the cell has an upper postve termnal. *2 Dmensons of fresh cell wthout tube *3 Approxmate values *4 Measured under the followng condtons: Charge CCCV: 1ItA/4.20V-4.40V/3h, Dscharge CC: 0.2ItA/E.V. = 2.75V, Temperature: 25 deg. C *5 No postve termnal plate on the cell bottom Characterstcs lsted n ths catalog are standard measured examples. Maxell does not guarantee these data. Specfcatons are subject to change wthout notce. Ths data s for lthum-on cells only. Maxell offers these cells n battery pack format only. These nclude electronc crcuts to prevent overcharge, over dscharge and so on. These battery packs are custom-developed and produced accordng to specal requrements regardng operatng condtons and specfcatons. As a result, a mnmum number of unts may apply to such customzed orders from customers purchasng battery packs. For further detals, please contact your nearest Maxell dealer or dstrbutor. Vst our webste for more nformaton http://bz.maxell.com/en/ Go to: Products > Rechargeable Batteres > Prsmatc Lthum-on Rechargeable Battery 6
Dangerous Goods Transportaton Regulatons for Lthum Cells and Batteres Some transportaton regulatons have been recently revsed and wll come nto effect after Jan. 1, 2015. The summary s shown n the followng table. Please use updated Dangerous Goods Regulatons lsted n Normatve Reference to confrm detals. The major revsons for ar transport of lthum cells and batteres (1) Lthum metal cells and batteres transported as cargo wll be restrcted to cargo arcraft only. Note. The prohbton does not apply to lthum metal batteres packed wth equpment (PI 969) or contaned n equpment (PI 970). (2) Gross mass wll change to net quantty for both lthum on cells and batteres (PI 965 Secton IB) and lthum metal cells and batteres (PI 968 Secton IB) Techncal nstructons for lthum metal batteres (PI 968) Secton Secton II Secton IB Secton IA Lthum Metal Content Cell: 0.3 g Battery: 0.3 g Cell: 1.0 g Battery: 2.0 g Cell: 1.0 g Battery: 2.0 g Cell: > 1.0 g Battery: > 2.0 g Package Lmts Quantty Net Weght Cargo arcraft only 2.5 kg 2 batteres or 8 cells Cargo arcraft only > 2 batteres or > 8 cells Cargo arcraft only 2.5 kg Classfcaton Exempted Class 9 Packagng Strong outer packagng 1.2 M drop test Cargo arcraft only 35 kg UN performance packagng Labels Note 1) Note 2) Note 3) Documents Invoce (ar waybll)* Addtonal documents*** Declaraton for DG Ar waybll** Addtonal documents*** Declaraton for DG Ar waybll** Tranng Adequate nstructons DG tranng Note 1): Handlng label Note 2): Cargo arcraft only label (necessary for lthum metal cells and batteres) Note 3): Class 9 hazardous label * The words "lthum metal batteres, n complance wth Secton II of PI 968" and "Cargo Arcraft Only" or "CAO" must appear on the ar waybll, when an ar waybll s used. Ths descrpton should appear n the "Nature and Quantty of Goods" box. ** The words "Dangerous Goods as per attached Shpper's Declaraton" and "Cargo Arcraft Only" or "CAO" must appear n the ar waybll's "Handlng Informaton" column. *** Addtonal documents must ndcate: The package contans lthum metal cells or batteres; The package must be handled wth care and that a flammablty hazard exsts f the package s damaged; Specal procedures should be followed n the event the package s damaged, to nclude nspecton and repackng f necessary; and A telephone number for addtonal nformaton. Ths nformaton can be wrtten n the Declaraton for DG's "Addtonal Handlng Informaton" column or on the ar waybll. 40
Techncal nstructons for lthum-on batteres (PI 965) Secton Secton II Secton IB Secton IA Watt hour Cell: 2.7 Wh Battery: 2.7 Wh Cell: 20 Wh Battery: 100 Wh Cell: 20 Wh Battery: 100 Wh Cell: > 20 Wh Battery: > 100 Wh Package Lmts Quantty Net Weght 2.5 kg 2 batteres or 8 cells > 2 batteres or > 8 cells 10 kg Passenger and cargo arcraft 5 kg: Passenger arcraft 35 kg: Cargo arcraft Classfcaton Exempted Class 9 Packagng Strong outer packagng 1.2 M drop test UN performance packagng Labels Documents Invoce (ar waybll)* Addtonal documents*** Declaraton for DG Ar waybll** Addtonal documents*** Tranng Adequate nstructons DG tranng Declaraton for DG Ar waybll** * The words "Lthum on batteres n complance wth secton II of PI 965" must appear n the ar waybll's "Nature and Quantty of Goods" box, when an ar waybll s used. The words "Cargo Arcraft Only" or "CAO" must appear on the ar waybll, when transported by cargo. ** The words "Dangerous Goods as per attached Shpper's Declaraton" must appear n the ar waybll's "Handlng Informaton" column. The words "Cargo Arcraft Only" or "CAO" must appear on the ar waybll, when transported by cargo. *** Addtonal documents must ndcate: The package contans lthum on cells or batteres; The package must be handled wth care and that a flammablty hazard exsts f the package s damaged; Specal procedures should be followed n the event the package s damaged, to nclude nspecton and repackng f necessary; and A telephone number for addtonal nformaton. Ths nformaton can be wrtten n the Declaraton for DG's "Addtonal Handlng Informaton" column or on the ar waybll. 41
The major revsons for UN Model Regulatons 18th Revsed Edton (1) Damaged or defectve cells or batteres shall be transported as "Class 9" hazardous goods accordng to Specal Provson 376 and Packng Instructon P908 or LP904. (2) Cells and batteres transported for dsposal or recyclng shall be transported as "Class 9" hazardous goods accordng to Specal Provson 377 and Packng Instructon P909. The IMDG Code 2014 edton wll contan the descrptons of these UN recommendatons. The voluntary complance date s Jan. 1, 2015. Complance becomes mandatory on Jan. 1, 2016. Although these revsons wll be reflected n each country's regulatons, some dstrcts, countres or arlnes may establsh ther own specal requrements. Therefore the shpper shall confrm wth the forwarder n advance. Reference Except for ar transportaton, the necessary requrements to transport lthum metal batteres or lthum-on batteres as exempted from regulaton (non-restrcted goods) are as follows; 1. The mnmum requrements to transport lthum metal batteres as non-restrcted goods are as follows; a) Cells and batteres shall be manufactured under a qualty management program. b) For a lthum metal or a lthum alloy cell, the lthum content must not be more than 1 g. For a lthum metal or lthum alloy battery, the aggregate lthum content must not be more than 2 g. c) Each cell or battery must be of the type proven to meet the requrements of each test n the UN Manual of Tests and Crtera, 5th revsed edton, Part III, sub-secton 38.3. d) A battery handlng label must be dsplayed on each package. A telephone number must be prnted on the label for addtonal nformaton. e) Each consgnment must be accompaned by a document for transport wth an ndcaton that: the package contans lthum metal cells or batteres; the package must be handled wth care and that a flammablty hazard exsts f the package s damaged; specal procedures should be followed n the event that the package s damaged, to nclude nspecton and repackagng f necessary; and a telephone number for addtonal nformaton. f) Each package must be capable of wthstandng a 1.2 m drop test. g) Except when batteres are nstalled n or packed wth equpment, packages shall not exceed 30 kg gross mass. 2. The mnmum requrements to transport the lthum-on batteres as non-restrcted goods are as follows; a) Cells and batteres shall be manufactured under a qualty management program. b) For lthum-on cells, the Watt-hour ratng s not more than 20 Wh. For lthum-on batteres, the Watt-hour ratng s not more than 100 Wh. The Watt-hour ratng must be marked on the outsde of the battery case except for those manufactured before Jan. 1, 2009. c) Each cell or battery s of the type proven to meet the requrement of each test n the UN Manual of Tests and Crtera, 5th revsed edton, Part III, sub-secton 38.3. d) A battery handlng label must be dsplayed on each package. A telephone number must be prnted on the label for addtonal nformaton. e) Each consgnment must be accompaned by a document for transport wth an ndcaton that: the package contans lthum-on cells or batteres; the package must be handled wth care and that a flammablty hazard exsts f the package s damaged; specal procedures should be followed n the event the package s damaged, to nclude nspecton and repackagng f necessary; and a telephone number for addtonal nformaton. f) Each package must be capable of wthstandng a 1.2 m drop test. g) Except when batteres are nstalled n or packed wth equpment, packages shall not exceed 30 kg gross mass. Maxell wll provde certfcates for b) and c) as the need arses. Documentaton for d) and e) needs to be prepared by the customer. If our package s used for transport, Maxell wll provde the certfcate for f) as the need arses. However, f the customer s package s used, the customer must confrm the package can wthstand a 1.2 m drop test. Furthermore, even f our package s used for transport, the telephone number prnted on the label must be changed to that of the sender (customer). Major Normatve Reference UN (Unted Natons) Recommendatons (Ar, Marne, Overland transportaton) UN (Unted Natons) Recommendatons on the Transport of Dangerous Goods: Model Regulatons 18th revsed edton UN (Unted Natons) Recommendatons on the Transport of Dangerous Goods: Manual of Test and Crtera 5th revsed edton, Amendment 2 Ar Transportaton Internatonal Cvl Avaton Organzaton (ICAO): Techncal Instructons for Safety Transport of Dangerous Goods by Ar, 2015-2016 edton Internatonal Ar Transport Assocaton (IATA): Dangerous Goods Regulatons, 56th edton 2015 Marne Transportaton Internatonal Martme Organzaton (IMO): Internatonal Martme Dangerous Goods (IMDG) Code, 2012 edton (Ths s applcable untl Dec. 31, 2015) Internatonal Martme Organzaton (IMO): Internatonal Martme Dangerous Goods (IMDG) Code, 2014 edton (Ths s applcable on and after Jan. 1, 2015 and wll be mandatory on and after Jan. 1, 2016) 42
Vst our webste at: bz.maxell.com Maxell s accredted wth nternatonal qualty management standard ISO 9001 and nternatonal envronmental management standard ISO 14001 certfcatons. Catalog contents accurate as of August 2015. Data and dmensons are just reference values. Contents on ths catalog are subject to change wthout notce. Commtted to the hghest qualty assurance management standards as well as responsblty to the envronment. Htach Maxell, Ltd. Energy Dvson Phone: +81-75-957-8119 BATTERIES CATALOG(E) HE022-1508 Prnted n Japan