David B. Wallace MicroFab Technologies, Inc. Plano, Texas dwallace@microfab.com www.microfab.com

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Ink-Jet Applications, Physics, and Modeling - an Industrial / Applied Research View David B. Wallace Plano, Texas dwallace@microfab.com www.microfab.com

Ink-Jet Microdispensing Advantages Direct-write of materials data-driven (flexible no masks, low cost) additive (environmentally friendly, low cost) non-contact Piezoelectric Ink-Jet Technology single jets and arrays wide operating temperature range (0-370C) wide range of materials biological, metals, polymers, fluxes wide range of resolutions 10-120um drops + N drops per spot wide range of rates 1Hz - 1MHz

Solder Jet Data-Driven Driven

Ink-Jet Microdispensing Applications Electronics manufacturing interconnects, passives, conductors, dielectrics, adhesives Photonics lens arrays, display materials, waveguides, NLO materials Medical Diagnostics immuno and DNA diagnostics, genomics, proteomics, drug discovery Medical Procedures olfaction, laser surgery, drug delivery, tissue engineering Other pest control, ink-jet printing, combi-chem

Electronics Manufacturing Applications Demand Mode Solder Jet Drop Size Modulation: 60 & 100µm drops from same device using different waveforms

Solder Jet 1440 pad microprocessor test vehicle, 60µm bumps

Solder Jet Print-on on-the-fly, 100µm bumps, 250µm centers, 400/sec.

Solder Jet Model This! Poulikakos, Megaridis, Wadvogel

Printed Solder Interconnects MEMS Applications Modeling Challenges Printed Solder Columns Dielectric Layer Copper Conductor 60µm towers 3-D D structure, 60µm m feature size 24µm towers

Electronics Manufacturing Applications Embedded Passives Conductive Polymer Resistors, <200?/sq, ~1mm long

Photonics Manufacturing Applications Simulated GRIN lenslet: how is this possible? 90µm spots and line of phosphor particles 100µm waveguides / splitter light emitting polymer 250µm hemi-elliptical lenses

Photonics Manufacturing Applications 300µm simulated AGRIN lens Simulated 300 micron agrin lenslet Multidrop / multiple fluid sphere formation with axial (only) gradient. Model this!

Photonics Manufacturing Applications Solder & microlens on VCSEL: 125µm square pad (solder) 17 µm emitter Portion of 19,000 300um lenses printed on glass wafer, for coupling to matching GaAs micro lasers & photodetectors Array of 80um spot of optical epoxy doped with fluorescing probe, printed onto 480:m fiber bundle.

Medical Applications Genetics, Proteomics,, Diagnostics 10 fluid ink-jet printhead and printing results (200 µm spacings) anti-cytochrome C spots, 40µm in diameter. printhead detail (140um grooves) 100um spots of DNA on 200um centers

Proteomic Analysis 2-D D Gel In-Situ Digestion /Analysis on Membrane matrix Laser water trypsin, etc. + + + + + + detector To MALDI To archive Proteome System Ltd. s Chemical Printer for peptide mass fingerprinting

Olfaction Diagnostics Olfactometer Research into early onset of neurodegenerative diseases (e.g. Alzheimer's) 1000 THRESHOLD DEFICIENT Detected 100 Not Detected # of Drops 10 NORMAL Detected Not Detected THRESHOLD 1 0 5 10 15 20 25 Test #

Combinatorial Odor Synthesis Internet Ready

Ink-Jet Printing real time drop volume modulation results 120 channel printhead with onboard drive electronics microfabricated structures 170um pitch polymer orifice array, 170um pitch printhead in operation

Modeling Ink-Jet Systems Difficulties in Systems Models Multiple types of mathematical regimes Elliptical, parabolic, and hyperbolic equation sets Moving boundaries, phase change, fluid / structure interaction Wide range of time scales in different regimes Sub-microsecond to seconds Properties at physical and temporal microscale Dynamic surface tension in microsecond regime Viscosity at MHz shear rates; micron scale particles/cells Microscale piezoelectric properties / uniformity Mass removal / separation Array systems Cross-talk effects, location of computational boundaries

Modeling Ink-Jet Systems Drive Electronics (elec. circuits) Piezoelectric Structure (electrostatics, piezoelectrics, solid mechanics) Fluid Delivery System (Low Re flow) Acoustic Energy Transfer Zone (fluid acoustics) Acoustic Energy Transport (fluid acoustics) Drop Impact (Low Re flow, + ) Drop Formation (Low Re, free surface flow)

Subsystems Modeling Efficient but Hazardous 1.4 1.4 Pressure Energy Droplet Volume Droplet Velocity Droplet Momentum 1.2 1.2 Value Normalized 1 1 0.8 0.8 0.6 0.6 250 300 350 400 Channel Height, um

Goals of Modeling Efforts Levels of Modeling Results Obtain insight into the physics of the system being modeled Determine the effects of specific variables qualitative performance prediction OK Determine optimum configuration parameters qualitative performance prediction OK Manufacturing materials/process selection qualitative performance prediction OK In-process manufacturing test support qualitative performance prediction OK Quantitative performance prediction

11 µs 12 µs 13 µs 14 µs 15 µs 16 µs 17 µs 18 µs 19 µs

Orifice Plate Thickness Effects Maximum Velocity and Frequency 14.0 DROP VELOCITY (M/SEC) 12.0 10.0 8.0 6.0 4.0 2.0 shared wall satellites above 17V for 2 mil thick plate, above 20V for 1 mil thick plate 2kHz, 2mil 3kHz 2mil 4kHz 2mil 5kHz, 2mil 6 khz, 2mil 2kHz, 1mil 3kHz, 1mil 4kHz, 1mil 5kHz, 1mil 6kHz, 1mil 0.0 8.0 12.0 16.0 20.0 24.0 28.0 32.0 36.0 VOLTAGE

Agenda Industrial Application of Ink-Jet Technology Modeling of Ink-Jet Systems Modeling in an Industrial Environment Case Study: Shared Wall / Shear Mode Printhead

Shared Wall / Shear Mode Printhead boundary condition: polymer orifice array, 170um pitch 120 channel printhead with onboard drive electronics 3-D piezoelectric structures (shared wall), 170um pitch drive waveform: simplest = 5 degrees of freedom printhead in operation

Shared Wall / Shear Mode Printhead Basic Structure, Fields, and Motion inactive material Electric Field PZT PZT Electric Field + V - V Metalization & Bond Line fluid channel Poling Directions PZT Electric Field

Model Components Shared Wall / Shear Mode Printhead Structural Motion coupled electric field, piezoelectric, structural static analysis Fluid / Structure Coupling quasi-static assumption change from pressure / wall position system to pressure rise / compliance Fluid Acoustics method of characteristics solution frequency dependent friction Boundary Conditions orifice flow model from steady flow data; SOR manifold pressure from steady flow model Drop Formation Model various Drop Impact Model Spread Factor

Model Block Diagram Structural, Electrical, Piezoelectric Static Solution Pressure Rise per Volt Compliance Waveform (voltage vs. time) Inlet Boundary Condition Method of Characteristic Solution Orifice Flow Model Drop Impact Model Drop Formation Model

Structural Model Elements and Mesh Geometry unpoled PZT cyclical boundary condition cyclical boundary condition PZT metalization & bond line fluid PZT Poling Direction artificial boundary

Structural Model Voltage Distribution and Displacement unpoled PZT metalization & bond line PZT fluid -1 -.777778 -.555556 -.333333 -.111111.111111.333333.555556.777778 1 PZT

Structural Model Electric Field Distribution unpoled PZT metalization & bond line PZT fluid.673e-07.143e-04.285e-04.427e-04.569e-04.712e-04.854e-04.996e-04.114e-03.128e-03 PZT

Method of Characteristics Solution Pressure vs. Time Solution 300 200 Pressure, kpa 100 0-100 -200 0 5 10 15 Distance from Orifice, mm time = 26 us (after voltage fall) Pressure, kpa 300 200 100 0-100 time = 63 us (end of waveform) -200 0 5 10 15

Orifice Flow Model Orifice Flow Model and Data Discharge Coefficient 1 0.8 0.6 0.4 0.2 0 10 100 1000 10000 Reynolds Number data model

Drop Formation and Impact Models 0 Drop formation Method: Adams & Roy Case: solder 0 Droplet impact & solidification Method: Poulikakos et al. solder on Si

Fluid System Model 35.0 30.0 25.0 Array Size & Fluid 0.25", IPA 1" IPA Jet Velocity = 5 m/s Pressure Drop 20.0 15.0 10.0 0.25" ink (4cp) 1" ink (4cp) 5.0 0.0 Orifice Channel Manifold Inlet Line Filter TOTAL