Energy Storage Solutions Panorama for Telecom Stand-By applications

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Energy Storage Solutions Panorama for Telecom Stand-By applications ETSI 2015 Energy Workshop By Claude Campion 3C Projects 1

Energy Storage Solutions Panorama for Telecom Stand-By applications 3C Projects founded in 2011 by Claude Campion coming from large battery industry, is a unipersonal independent company located in Clichy nearby Paris Main Activities are : Technical support : Test lab or field investigation, storage energy solutions selection analysis, training course, test or maintenance procedure update, battery monitoring specifications Marketing support : Promotion of R&D license for use in industry, Specific Technology and Market development surveys Main References are : Orange; EDF (French Utility) ; SNCF (French Railways) ; Electrabel (Belgium); BAE (Germany); ForseePower(France); Albioma(France) More information at www.3cprojects.eu ETSI June 4 th 2015 -Claude Campion 2

Batteries & Energy Storage Solutions Long Storage (day to year) Medium Storage (sec to week) Short Storage (µs to min) Telecom ETSI June 4 th 2015 -Claude Campion 3

Batteries & Energy Storage Solutions Electrical Energy Storage Mechanical Electro- Magnetic Chemical Electro-Chemical Thermal Pump Hydro Supercapacitor Hydrogen Flow Batteries Sensible Heat Compressed Air SMES DSMES SNG Rechargeable Batteries Latent Heat Flywheels Long Storage (day to year) Medium Storage (sec to week) Short Storage (µs to min) Telecom PHES Classification according IEC ESS WP 12/2011 ETSI June 4 th 2015 -Claude Campion 4

Lead Acid Batteries Flooded Weaknesses Mature Technology - Cell Cost of 80-150 /kwh Good extreme temperature acceptance - Convenient cycling performance for tubular variant Limited cycle life for flat plate variant - Water topping up Efficiency of 80-85% Large global production capacities Large capacities range from 10Ah to 4000 Ah Competition with Li-Ion PbSb(flat or tubular) ; PbCa(Flat) ; Plante ; PbC Telecom -Large central office back-up -Wireless outdoor and Off-Grid BTS (PbSb Tubular) - Starting Engine (PbSb or PbCa flat) - Microwave Antenna ETSI June 4 th 2015 -Claude Campion 5

Lead Acid Batteries AGM Weaknesses Mature Technology - Cell Cost of 100-130 /kwh Good Power Performances - Balancing and Maintenance free Limited cycle life Reduced life operation at high temperature Large global production capacities Standard format Competition with Li-Ion PbCa(flat thin / thick) ; Pure Lead Telecom -UPS Data Center -Large or district office back-up -Wireless outdoor or indoor BTS -Starting Engine -Microwave Antenna PABX -DSL ETSI June 4 th 2015 -Claude Campion 6

Lead Acid Batteries Gel Weaknesses Mature Technology - Cell Cost of 120-180 /kwh - Good cycling ability Balancing and Maintenance free Poor Power Performance Life time affected at high temperature operation Large global production capacities High reliability and safety reputation Competition with Li-Ion PbCa(flat or tubular) Telecom -Large or district central office back-up -Wireless outdoor, indoor and off-grid BTS -Microwave Antenna PABX -DSL ETSI June 4 th 2015 -Claude Campion 7

Lead Acid Batteries Summary Large Differences in Term of Battery Choice kwh Cost varies from 1 to 3 according types Life operation can be from 3 years to 25 years according type and temperature operation Cycling performances are quite different from type to type Today Lead Acid battery is the largest player for stand-by applications IEC/EN 60896-1 & 2 ruled the type test performances (float & cycling) IEC/EN 61427 provides recommendations for PV applications ETSI June 4 th 2015 -Claude Campion 8

NiCd Batteries Weaknesses Mature Technology - Extreme low temperature performances Robust reliability - Good energy density Cost around 400 /kwh Recycling process of Cadmium Engine starting at low temperature On board rail application & extreme temperature PV applications Competition with Li-Ion - Cadmium ban Pocket plates (flooded or sealed) & Sintered plates Telecom - Wireless outdoor and off-grid BTS - Microwave Antenna - Engine starting ETSI June 4 th 2015 -Claude Campion 9

NiMH Batteries Weaknesses Mature Technology - Extreme low temperature performances Robust reliability - Good energy density - Cost around 450 /kwh Hybrid Vehicle (Toyota Prius) Portable applications Competition with Li-Ion Flat or Cylindrical Telecom - Handy terminal -PABX ETSI June 4 th 2015 -Claude Campion 10

NiZn Batteries Cycling performance - Wide temperature range operation - Weaknesses No electronic balancing - Recyclability - Energy density No long field experience feed back Abondance of material New jocker for extreme temperature cycling operation Competition with Li-Ion & Lead Acid SCPS License or Powergenix License Telecom - Wireless outdoor and off-grid BTS - Microwave antenna - Engine starting ETSI June 4 th 2015 -Claude Campion 11

NiFe Batteries Weaknesses Mature technology - Very long life operation up to 25 years No electronic balancing - Recyclability High maintenance cost due to high rate of water consumption Abondance of material Competition with Li-Ion & Lead Acid Edison type Telecom - Wireless outdoor and off-grid BTS - Microwave Antenna ETSI June 4 th 2015 -Claude Campion 12

Nickel based Batteries Summary Niche Applications and New Players Nickel Cadmium keeps strong positions on railways and cold starting engine due to safety maturity NiMH keeps market shares in HEV and portable tools due to its safety operation, maturity, as well as good energy density NiZnis a new player and can afford right opportunities for cycling operations at extreme temperature operations with expected reasonable cost NiFe is coming back and field experiences are looking with great attention Competition with lithium based batteries is tough (Battle is lost for portable except for power-tool) IEC/EN 61434, 60623, 62259, 60622, 61951 provides major information for type test performances IEC/EN 61427 is the reference for PV applications ETSI June 4 th 2015 -Claude Campion 13

Lithium LiFePo4 Batteries High Cycling Performances - Partial State of Charge Capability Weaknesses Good safety operation Cell cost about 320 /kwh & Pack cost around 450 /kwh Need electronic pack balancing - Low & High temp. operation Renewable energy storage applications Bus & Commercial EV Competition with Li-Ion Titanate anode batteries & Flow batteries Cylindrical, Pouch (Polymer), Large prismatic Telecom - Wireless outdoor and off-grid BTS - Microwave antenna ETSI June 4 th 2015 -Claude Campion 14

Lithium Ion Batteries (LCO, LMO, NCA, NMC) High Cycling Performance - Partial State of Charge Capability High Energy & Power Density Weaknesses Cell cost from 250 /kwh to 600 /kwh Need electronic pack balancing - Limited low & high temp. operation Portable equipment - EV Batteries Grid support Limited supply in Lithium Cylindrical Prismatic Pouch (Polymer) Telecom - Terminal (Phone, Tablets, Laptop...) - NCA, NMC, LMO can play for offgrid applications, Antenna and BTS equipment ETSI June 4 th 2015 -Claude Campion 15

Lithium Ion Batteries ( LTO anode) Weaknesses Very High Cycling operation > 10 000 Cycles Good safety operation and good charging suitability at low temp. Cell cost over 450 /kwh - Lower energy density Need electronic balancing - Limited high temp. operation Renewable energy storage Grid support - UPS short backup Limited supply in Lithium Few suppliers Prismatic & Pouch Telecom - Wireless outdoor and off-grid BTS - UPS Short Backup ETSI June 4 th 2015 -Claude Campion 16

Lithium Metal Polymer Batteries (LMP) Very High Cycling Performance > 5 000 Cycles Weaknesses Can work at extreme temperature Pack cost over 700 /kwh - lower effeciency Need electronic cell balancing and thermal management Renewable energy storage EV batteries Limited supply in Lithium Limited supplier Prismatic Pack Telecom -Wireless outdoor and off-grid Antenna or BTS ETSI June 4 th 2015 -Claude Campion 17

Lithium based Batteries Summary Large difference in term of battery choice Cycling performances vary from 1 to 30 according, shape, size, cathode and anode material as well as supplier manufacturing process. Example of announced performances : (Here below extract from Lishendatasheets) P/N Cathode Capacity Life Cycles Shape (mah) LR1865BI NMC 1500 300/75% Cyl. LR1865LA NMC 2000 300/75% Cyl. LR1865SK LCO/NCM 2600 300/80% Cyl. LR1865SA LCO 2800 300/80% Cyl. LR1865SC LCO 3000 300/80% Cyl. LR1015AB LCO 60 500/80% Cyl. LR1865SD LCO/NCM 2200 1000/80% Cyl. LR1865EC LFP 1350 1000/80% Cyl. LP2714897 LFP 20000 2000/80% Prism. Up to now very few long period field experiences, project sizing and economics are mainly based on data-sheet Standards for safety are fixed, concerning stand-by type test the standard processes are on going. ETSI June 4 th 2015 -Claude Campion 18

Sodium Batteries (NaNiCl- NaS) Very High Cycling Performances 5 000-10 000 Cycles Can work at extreme temperature Weaknesses Pack cost over 700 /kwh Need thermal management - Thermal losses - Low efficiency Renewable energy storage Grid support Fiamm, GE for NaNiCl& NGK for NaS Telecom Lack of safety confidence - Competition with lithium Wireless outdoor and off-grid BTS at extreme temperature with NaNiCl Standards No specific type test standard up to now ETSI June 4 th 2015 -Claude Campion 19

Redox-Flow Batteries Energy and Power are Independenly scalable Cyclic lifetime > 10 000 Cycles Weaknesses Low efficiency of 60-74 % Lack of long field experience. Cost still at about 500 / kwh at scale Expiration of patent protection Cheap raw materials are available Only few manufacturers Wrong field experiments results VFRB (Vanadium) ZnBr FeCr H 2 Br Telecom Large central office connected to Renewable Energy supply source and operating at extreme temperature ETSI June 4 th 2015 -Claude Campion 20

TES Thermal Energy Storage (Hot or Cold) Scalable Size. Mature Cyclic lifetime > 10 000 Cycles Weaknesses Low efficiency of 60-70 % Not adapted for electricity recovery Extreme temperature operation micro-grid systems Not considered as inovative Telecom As an improvement of renewable energy integration Cold TES can be part of energy efficiency approach for systems and Hot TES with associated applications can be explore. ETSI June 4 th 2015 -Claude Campion 21

Hydrogen and Regenerative Fuel Cell (RFC) Weaknesses Autonomous concept Excellent cycling performance Scalable Low efficiency arround 50 % total Lack of long field experience. CAPEX Cost 600-1000 /kwh Seasonal storage for Renewable Energy Combination with EV propulsion Safety regulation Electrolyser and fuel cell membrane reliability Technologies ElectrolyserPEM + Fuel Cell + Solid, Liquid or Compressed Hydrogen Storage Telecom Seasonal storage for antenna or off-grid BTS ETSI June 4 th 2015 -Claude Campion 22

Conclusions Energy storage solutions are multiple Operation conditions have to be well set to ensure the right choice LCOE (Life Cost of Energy) linked to CAPEX, OPEX and service life is a good approach to set the cost effective choice Dual or Hybrid solutions are more and more considered : Power + Energy or Cycling + Floating Lithium + Lead Lithium NMC + Lithium LTO Supercapacitor + lead Supercapacitor + lithium Electrochemical + Thermal Electrochemical + Chemical New developments are on the way : LiS: Lithium Sulfur Metal Air : Zn-Air, Li-Air, ETSI June 4 th 2015 -Claude Campion 23

Conclusion No one energy storage solution is predominant each one has its adapted fitment Thank You ETSI June 4 th 2015 -Claude Campion 24