Biomass gasification for CHP applications

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Biomass gasification for CHP applications C.M. van der Meijden July 2014 ECN-L--14-038

Biomass gasification for CHP applications CHP & RENEWABLE ENERGY CONFERENCE London, May 22nd 2014 Christiaan van der Meijden vandermeijden@ecn.nl +31 653 292 766 www.ecn.nl

Overall Bio-CHP system based on fluidized bed gasification Biomass To flare OLGA Collector OLGA Tar removal OLGA Absorber Combustion in steam boiler Fresh sand OLGA ESP Micro Gas Turbine Bottom ashes CFB Gasifier Primairy Product Gas Cooler Cyclone Aqueous Condenser & Scrubber Gas Engine Gasification air fan Pressure Fan Bottom Ashes Heat Coarse solids Heat Fine solids Heavy tar Light tar Condensate water Inorganic impurities (NH3 HCl etc)

MILENA Indirect Gasification Fluidized bed gasification Temperature level: 850 C Product gas contains methane, ethylene, benzene and tars. Heating value > 12 MJ/nm3. Very little nitrogen in producer gas Complete conversion of the fuel No carbon in the ash High efficiency Heat transfer through bed material One single vessel: compact design Fuel flexible

Comparison MILENA CFB/BFB Downdraft Conversion 100% / white ash ~90% / black ash ~90% / black ash Cold Gas Efficiency ~80% ~70% ~70% Temperature control Temperature versus Efficiency Fuel flexibility Gas Good control, no char accumulation lower temperature = higher efficiency waste, agricultural residues any size 12-15 MJ/Nm 3 essentially N 2 -free Lower control ability due to char hold-up lower temperature = lower conversion less freedom any size 5-6 MJ/Nm 3 ~50% N 2 Very heterogeneous lower temperature = lower conversion woody only large chunks 5-6 MJ/Nm 3 ~50% N 2 Scale Scalable (>100 MW) Scalable (>100 MW) Max. 1 MW

Markets for MILENA gasifier Co-firing in coal boilers or gas turbines Clean gas feeding to boiler or turbine With Milena lower grade biomass or waste can be used, rather than the clean wood pellets needed for direct cofiring in boilers Combined heat and power On-site conversion of waste to energy In combination with gas engine or small gas turbine Milena produces medium calorific gas, not diluted with nitrogen Substitute Natural Gas production High methane content of producer gas makes Milena very suitable for SNG production (Bio-Methane / Bio-LNG) (Co-)Production of fuels or chemicals FT, Ethylene, BTX

Efficiency LHV basis [%] Gas Engine system efficiency MILENA CHP configuration 80 70 Thermal Efficiency Electrical Efficiency 60 50 40 30 20 GE GE + ORC GE + ORC + Dryer Typical scale: several MWe. 6

ECN Experience with MILENA gasification technology

Milena Technology test facilities at ECN 25 kw (~ 5 kg/h) 0.8 MW (~150 kg/h) Extensive gas analyses

800 kw th MILENA + OLGA pilot plant MILENA gasifier in operation since 2008 Typical input 150 kg/h Realistic fuel particles sizes. Refractory lined vessel. Runs in campaigns Connected to OLGA tar removal system OLGA pilot plant also tested in combination with CFB gasifier, gas engine and small gas turbine.

Tested feedstocks Clean Wood Demolition Wood Straw Soya stalk High-ash coals (> 50 wt% ash) Lignite RDF Sunflower husks

Results 500 hour test of 1 MW Milena + OLGA tar removal system Availability Milena 96% Downstream downtime : in OLGA tar removal system

Gas composition 2012 duration test Fluidisation gas is air

Gas cleaning

The tar problem Tar starts to condense <400 C Fouling coolers, blowers, inlet gas engines Water pollution Catalyst deactivation 14

ECN OLGA gas cleaning

Tondela, Portugal Tar dew point < 10 C No water pollution with tars!

MILENA and OLGA commercialisation with Royal Dahlman

Project in Development in Alkmaar, The Netherlands Project has changed several times over past years. 4 MW MILENA - OLGA Methanation producing Bio- Methane Royal Dahlman will build the plant Main subsidy granted, waits for final investment decision by Province of North Holland.

RDF gasification demo-project by ETI in UK 7 MW e combined cycle using gas turbine MILENA OLGA technology Dahlman leads consortium Phase 1 commissioned and funded by the Energy Technologies Institute (ETI). Three technologies / consortia compete in phase 1. Phase 1: Pilot scale testing + engineering in 2013 After execution of phase 1 ETI will select one of the three competitors for the waste gasification demonstration.

Thermax Soya Residue 1 MWe Soya residue gasification demo. Construction ongoing Commissioning starts after summer 2014

Thank you for your attention! Questions? For more information: www.milenatechnology.com Contact: Christiaan van der Meijden +31 224 564582 vandermeijden@ecn.nl 21

ECN Westerduinweg 3 P.O. Box 1 1755 LE Petten 1755 LG Petten The Netherlands The Netherlands T +31 88 515 4949 F +31 88 515 8338 info@ ecn.nl www.ecn.nl 8