California State Polytechnic University, Pomona. Exam Points 1. Nomenclature (1) 30
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1 Chem 316 Final Exam Winter, 2008 Beauchamp ame: Topic Total Points Exam Points 1. omenclature (1) 30 Credit 2. Explanation of elative eactivities of Aromatic 20 Compounds or Carbonyl Compounds 3. eactions Page (10 x 3 = 30) Tautomers (acidic conditions and base conditions) Aromatic Mechanism and Explanation of ubstituent 30 Effects 6. C-14 ynthesis Bio-organic Game (reaction recognition/simplistic 52 mechanisms) 8. Carbonyl Chemistry synthesis and mechanisms 30 Total 245 This is a long exam. It has been designed so that no one question will make or break you. The best strategy is to work steadily, starting with those problems you understand best. Make sure you show all of your work. Draw in any lone pairs of electrons, formal charge and curved arrows to show electron movement. nly write answers on the front of each page. Do your best to show me what you know in the time available. othing in life is to be feared. It is only to be understood. Marie Curie
2 1. Provide an acceptable name for the following structure. (30 pts) 5' 6' 7' C 8Z ' 1' 6' 3' 4' 5' 4' 3' ' 2' 4 2' 8' 1' ' 3' 1 1' 2' 3' 4' 5' 3E 6' 7' (2,6,10,11)--(3-phenylhept-3E-enyl)-2-amino-3-(4-hydroxycyclooct-5E-enyl)-6-(1-ethyl-3-methylbutoxy)- 7,12-dioxo-8-(3-hydroxy-4-mercaptocyclohexyl)-9-formyl-10-cyano-11-benzyldodec-8Z-en-4-ynamide 2. tate whether each of the following aromatic substituents acts as an activating or deactivating group on the aromatic ring. rder the substituents in decreasing order of activating influence on the aromatic ring (1 = most activating). how intermediate structures that will explain your order of reactivity. Write out the reaction conditions for bromination and an expected major product in each case. (20 pts) 3 C 3 C 3 C a b c
3 3. Provide the expected product for each of the following transformations. how regiochemistry and stereochemistry clearly, if relevant. Do T show mechanisms. WK = workup. (30 pts) a. AlCl / 1. Br 2 / hν 2. K + / (C 3 ) 3 C- b. 2 4 // // // c. Cl 1. Li WK 2 4 // (- 2 ) 1. B / d B / 1. LDA, -78 o C 2. Br 3. WK Ts, (- 2 ) e n / Cl 2. a 2 /Cl (T < 5 o C) CuC T > 5 o C 1. C 3 -Li / 2 f. Br 2 / FeBr 3 1. Cr 3 / 2 g. Br 1. Li 2. CuBr 2. WK Zn / Cl h. Cl 2 / hν 1. Ph 3 P 2. nbu-li 3. s 4 i LiAl 4 Cl Cl AlCl / 2 j.
4 Cr 3 / 1. a 2. Br 1. ab / 2
5 4. tarting from benzene, propose a synthesis for each of the following molecules. (25 pts) a. ynthetic targets Propose a synthetic sequence that leads to each molecule. o mechanisms are required here. (4 pts) i. ii. b. Provide mechanisms that show how any necessary electrophiles reacting with the aromatic ring are generated. (6 pts) i. ii.
6 c. Provide a mechanistic explanation that explains the observed regioselectivity (ortho, meta or para) when the second group adds to the aromatic ring in each of your proposed syntheses in part a. (20 pts) i. ii.
7 5. Provide a complete arrow-pushing mechanism for each reaction below. Include curved arrows, lone pairs of electrons and formal charge. If resonance is present, draw at least one additional resonance structure to show you recognize this feature, and one of them should be the best resonance structure. (35 pts base = 15 pts and acid = 20 pts) a.
8 b.
9 6. Propose a synthesis for the following compound using methane, ethane, propane, cyclohexane, benzene, sodium cyanide and/or carbon dioxide. Your only sources of radioactive 14 C carbon are methane, *C4, carbon dioxide, *C2 and sodium cyanide, a*c. You may also use any typical organic reagents. ften the best strategy is to work backwards from the target molecule. The last step of the synthesis should be your first step. how the reagents and reactant for each backwards step until you reach allowable starting molecules. Do not show mechanisms. (30 pts) * Br * *
10 7. From the given bio-organic structure, use our simplistic mechanisms to show how each transformation could occur. If any structures are missing, use the descriptive term to fill in the necessary structures and details. Draw in any additional atoms or structures needed to demonstrate the transformations (e.g. a hydrogen atom or a water molecule, any co-factors, etc.). Use B: if you need a base and B- if you need an acid. Acceptable representations of possible co-factors are provided at the bottom of the last page. (50 pts) a. Carbonyl hydration AD + b keto/enol tautomers to 1,3-dicarbonyl C c. TPP ylid C
11 d. C 2 e. AD P f. tautomerization 2
12 8. a. Provide the necessary starting materials and a complete arrow pushing mechanism to explain formation of the indicated product (show proper curved arrow conventions, lone pairs as two dots and single electrons as one dot). You only need to show the most important resonance structure and ( es.) whenever resonance is present. The necessary starting structures will be supplied for 3 points (12 pts)? b. Provide a detailed mechanism for the next step of the synthesis. You only need to show the most important resonance structure and ( es.) whenever resonance is present. (8 pts) 3 C 3 C
13 c. Provide a detailed mechanism for the next step of the synthesis. You only need to show the most important resonance structure and ( es.) whenever resonance is present. Indicate what products x and y are. (10 pts) + + product x product y
14 9. Propose a complete arrow pushing mechanism for the following reaction from the tetradotoxin synthesis. int: Make a hemi-acetal first, using the acid, and then do the usual Jones Cr3 reaction. (15 pts) Cr 3 / 2 / acid Jones Add in the methyl group at the appropriate position. implified co-factors for the bio-organic game problems, if needed. P ATP AD + equivalent AD equivalent TPP ylid ATP vitamin B-6 (1 o amine version) vitamin B-6 (aldehyde version)
15 o person is free who is not master of himself. Epictetus
16 a. Br 2 FeBr 3 1. Mg 1. PCC Ts, (- 2 ) 3. WK b / ncl 2 Cl Cl c. Et 3 2 Br 2 / FeBr 3 d. AlCl 3 e. I 1. Li 2. CuBr WK Zn / Cl mcpba WK Mg Br Cr 3 2 / 3 + f. 1. a 2 2. Br 3. WK 3 / 2 1. ab 4 2. WK g. h WK p~5 (- 2 ) Br excess LiAl 4 2. WK Br 2 Ts (- 2 ) p~5 (- 2 ) i. 1. Li Ph Ph Ph P j. C 2 2. WK Cr 3 / 2 Cl 2 (C 3 ) 2 Cu Li 3 / 2 4
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