First experiences from large scale co- gasification tests with refined biomass fuels

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First experiences from large scale co- gasification tests with refined biomass fuels Presentation at Central European Biomass Conference International workshop: Torrefaction of biomass 17th January 2014, Graz, Austria Nader Padban, Vattenfall R&D Date: 17 th January 2014 1

SECTOR - Production of Solid Sustainable Energy Carriers from Biomass by Means of Torrefaction A European R&D Project funded within the Seventh Framework Programme by the European Commission Task 7.3 (Co-) gasification in entrained-flow gasifiers (-UmU-, Vattenfall, ECN) [Vattenfall will carry out the co-gasification tests in the Buggenum Power Plant that is owned and operated by N.V. Nuon Energy (Nuon) which is a third party to Vattenfall.] 1,5,6: ECN; 2-4 Jasper Lensselink The research leading to these results has received funding from the European Union Seventh Framework Programme FP7/2007-2013 under grant 1 agreement n 282826

Plant Willem Alexander Centrale Buggenum A 253 MW (el) power plant, entered service in 1993 as a coal gasification demonstration plant Hard coal as main fuel but continuous co- gasification of saw dust up to 15% (wt. Co- gasification of thermally treated wood was tested at the plant: - Torrefaction product: ~1500 tons - Steam explosion product: ~5000 tons The plant closed down at April 1st 2013. 3

Process Scheme WAC Buggenum (a) (c) a) Fuel handling/ preparation b) Gasification/ gas cleaning c) Steam and Electricity generation (b)

Process Scheme WAC Buggenum

Test campaign Test protocol for new fuels Fuel sample (~50 kg) Fuel analysis Lab-testing Test panel Logistics test (~40 tons) Small scale test (~300 tons) Large scale test (>1000 tons)

Excution Approximately 1200 tons of torrefied fuel was co- gasified together with hard coal in a ~24 hrs test campaign. The mixing rate was ~70% on energy basis. Logistics Milling Off gas treatment of Coal Mill Dry installation Sluicing Nitrogen usage 7

Mill capacities and plant output

Temperature and gas composition

Main issue: dust formation

Dust formation- Lab scale 100 90 Extended durability test: formation of fines (<250 micron) Accumulated fraction (kg/ ton fuel) 80 70 60 50 40 30 20 10 0 0 50 100 150 200 250 Particle size (micron) Torref pellets -3 Torref pellets -2 SE-pellets 1 Torref pellets -1 Torref pellets -4 ref-coal SE-pellets 2 SE-pellets 3 Ref- white pellets

Product quality: state of the art Imitate physical properties of hard coal Determine relevant parameters and related risks possible performance upstream downstream limitations/mitigations A supply-chain balanced fuel specification Aim Challenges Outcome Status Dust Water resistance Smell Milling capacity LHV (MJ/kg) Steam explosion / / / / Open storage not accepted close to residential Derating at high load 18.5-20 Torrefaction / /? / /? /?/? -/ /? 20-22.5 Note: Size of sign indicate size of test: lab/demo/full-scale Steam explosion fuel proven today, at relevant co-firing rate, with minor downstream modifications If dust problems solved for torrefaction, properties probably superior compared to steam explosion BUT at the cost of higher feedstock losses

Main conclusions Tested torrefied pellets had a lower mechanical durability than normal wood pellets resulting in a high dust formation during handling. The minimum ignition energy (MIE) for the dust from torrefied fuel was too low. Long term outdoor storage of torrefied material requires an improvement in weather and water resistance of the pellets. No big technical challenges were observed during conveying, sluicing and milling of the 70% mixture. It was estimated to be possible to achieve 90% of the plant nominal capacity without major modification in fuel feeding system. A higher heating value in the pellets was connected to better milling property but a less advantageous dust formation behavior. 13

Thank you for your attention! Contact: nader.padban@vattenfall.com