Pure Substances, Mixtures, and Solutions



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Pure Substances, Mixtures, and Solutions

Mixtures, elements, compounds Scientists like to classify things. One way that scientists classify matter is by its composition. Ultimately, all matter can be classified as mixtures, elements and compounds.

Why isn t it a good idea to classify matter by its phases? Because one kind of substance can exist in more than one phase such as H20. And matter changes phases rather easily.

Why isn t matter classified according to its physical characteristics, such as color? Scientists wouldn t find it very useful to group gold, sunflowers, and the sun together.

Scientists ask themselves these questions? Is the matter uniform throughout? Can it be separated by physical means? Can it be separated by chemical means?

By asking these questions scientists can classify matter into: Mixtures two or more substances that are not chemically combined with each other and can be separated by physical means. The substances in a mixture retain their individual properties. Solutions a special kind of mixture where one substance dissolves in another. Elements simplest form of pure substance. They cannot be broken into anything else by physical or chemical means. Compounds pure substances that are the unions of two or more elements. They can be broken into simpler substances by chemical means.

Pure substance: matter that has a fixed (constant) composition and unique properties. Contains only 1 type element or compound; homogeneous Mixture: Contains at least 2 PHYSICALLY combined compounds; can be homogeneous or heterogeneous

Examples: Sand water, oil and water, milk, sulfur and iron, granite, blood... heterogeneous mixtures Heterogeneous mixture : the components are not evenly distributed among each other. An heterogeneous mixture has two or more distinct phases that are usually detectable. This type of mixture does NOT have uniform properties. Heterogeneous mixtures that look like solutions can be distinguished because they scatter light (Tyndall effect).

Heterogeneous matter Means different throughout Always a MIXTURE (solutions are mixtures that are NOT heterogeneous) 2 or more PHYSICALLY combined substances (elements/compounds) ex: blood, air, muddy water

Is it uniform throughout? If the answer is no, the matter is a heterogeneous mixture. Considered the least mixed. Does not appear to be the same throughout. Particles are large enough to be seen and to be separated from the mixture.

Examples of heterogeneous mixtures Sand and pebbles Oil and water Powdered iron and powdered sulfur

Granite is a heterogeneous mixture.

Homogeneous Substances Means same throughout 1) element: only 1 type of atom 2) compound: 2 or more CHEMICALLY combined elements (not easily separated from each other) ex: water, CO 2 3) Solution: a special kind of mixture 2 phases/parts (SOLUTE dissolves & SOLVENT does the dissolving) ex: moist air (H 2 O in Air); sterling silver (Cu in Ag called an alloy)

Homogeneus mixtures Homogeneous mixtures : is a mixture in which the components are evenly distributed among each other. You can t see the component parts. Homo means the same throughout. It has a constant composition throughout. Homogenous mixtures are also called SOLUTIONS Examples: Salt dissolved in water, sugar dissolved in water, apple juice, tea, copper (II) sulfate solution in water, alloys...

Matter can also be classified according to its composition. Mixtures can be homogeneous or heterogeneous. Mixtures can be separated into pure substances, and pure substances can be either compounds or elements.

MATTER No Is it uniform throughout? Yes Heterogeneous mixture Homogeneous No Can it be separated by physical means? yes No Element Pure Substance Can it be decomposed into other substance by a chemical process? yes Compound Homogeneous Mixture (solution)

Is it uniform throughout? If the answer is yes, the matter is homogeneous (looks the same throughout). That leads us to another question.

Can it be separated by physical means? If the answer is yes, the matter is a homogeneous mixture or solution.

Homogeneous Mixtures A mixture that appears to be the same throughout. It is well mixed. The particles that make up the mixture are very small and not easily recognizable.

Examples of homogeneous mixtures Milk, toothpaste, and mayonnaise are homogeneous mixtures. They are also colloids.

3 classes of MIXTURES Solution Colloid Suspension Examples Particle Type Particle Size Scatter Light? (TYNDALL EFFECT) Settle while standing? Separate by filtration? salt water, air Soot, fog, mayonnaise Muddy water, Italian dressing ions, atoms Small Clusters Large Clusters small medium large No No No yes No No yes yes yes

Colloids Colloids non transparent, non uniform, large particles, cloudy (milky) but stable system

100 80 60 40 20 0 1st Qtr North 2nd 3rd Qtr East West Qtr 4th Qtr Colloids In a colloid the particles are mixed together but not dissolved. The particles are relatively large and are kept permanently suspended.

Colloids A colloid will not separate upon standing. The particles are constantly colliding, and this allows a colloid to scatter light thus colloids often seem cloudy.

[A colloid can be separated by filtration?] A. True B. False

[Which of the following is a colloid] A. [milk] B. [NaCl in water] C. [sand and water] D. [raisin bread]

Solutions Well-mixed (uniform) single phase homogeneous transparent cannot be separated by filter do not separate on standing

States of matter in solution Example of solutions gas in gas gas in liquid liquid in liquid solid in liquid gas in solid liquid in solid solid in solid air ( N 2, O 2, Ar, CO 2, other gases) soda pop (CO 2 in water) gasoline (a mixture of hydrocarbon compounds) Filtrated sea water ( NaCl and other salts in water) H 2 in platinum or palladium dental amalgams (mercury in silver) alloys ( brass, (Cu/Zn), sol-der (Sn/Pb), Steel (Fe/C ))

[After passing through a muddy pond, the water in a stream contains dirt particles. Which of the following describes the stream?] A. [solution] B. [suspension] C. [pure substance] D. [colloid]

Suspensions A suspension of liquid droplets or fine solid particles in a gas is called an aerosol. In the atmosphere these consist of fine dust and soot particles, and cloud droplets. suspension: system does not stays stable and settle Examples of Suspensions Mud or muddy water, is where soil, clay, or silt particles are suspended in water. Flour suspended in water, as pictured to the right. Paint Chalk powder suspended in water. Dust particles suspended in air. Algae in water Milk of Magnesia

Suspensions like coffee are easily filtered to take out the tiny solid clumps floating in the liquid. In colloids and many homogeneous mixtures have clumps that are so small they pass through most filters.

Colloids Tyndall effect: You can see the light passes through a colloid or suspension. (particles scatter light.) emulsion: a mixture of immiscible substances (liquid-liquid). like milk and mayonnaise

[Which of the following will show the Tyndall Effect] A. [water] B. [sugar water] C. [oxygen gas] D. [fog]