New Bio Solutions. DONG Energy. Pyroneer November 2013. May 2013



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DONG Energy New Bio Solutions Pyroneer November 2013 May 2013 Status of DONG Energy's Pyroneer gasification technology for high alkaline fuels like straw: an efficient and sustainable method to replace fossil fuels in our energy system IEA Bioenergy Task 33, Nov. 19-20, 2013, Gothenburg Martin Møller / Graham Henderson DONG Energy, New Bio Solutions

DONG Energy is one of the leading energy groups in Northern Europe Our business is based on procuring, producing, distributing and trading in energy and related products in Northern Europe. Key figures 2012 results Revenues: 9bn EBITDA: 1.2bn Employees 7000 Ownership The Danish State 81.02% SEAS-NVE Holding 10.88% Others 08.10% Exploration & Production Wind Power Thermal Power Customers & Markets 2

DONG Energy's strategy on power production is to expand in wind and convert from coal to biomass Wind Biomass One of the few storable CO 2 neutral resources 3

Thermal Power is front-runner in biomass-to-energy 1.8 GW converted to biomass by 2017 Expected long term portfolio Expected FID for biomass conversion 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017 Asnaes unit 2 (142MW) Avedoere unit 1 (250 MW) Avedoere unit 2 (543 MW) Esbjerg unit 3 (371 MW) H.C Oersted unit 8 (23 MW) Herning (90 MW) Kyndby (734 MW) Skaerbaek unit 3 (392 MW) Studstrup unit 3 (357 MW) Coal Coal Natural Gas / straw / wood pellets Coal Natural Gas Wood chips and pellets Oil Natural Gas Coal (straw) Gasification/grate Wood pellets Wood chips Wood pellets Source: DONG Energy Thermal Power Commercial 4

Sustainability is crucial when it comes to the use of biomass - but other factors such as CO 2 and local job creation are also important Woody fuels Discussion on CO 2 delay Discussion on deforestation Global fuel; Global economy - limited "local" job creation Short rotation crops / Energy crops Large potential for biomass supply Limited CO 2 discussion Indirect Land Use Change Removing the wood and leaving a dessert is not an option Agri residues No CO 2 discussion Nutrient and carbon discussion Local fuel; Local economy "local" job creation 5

Historical use of straw within the power sector in Denmark Political agreement in 1993 obligated power plants to apply 1.4 million tonnes of biomass (mainly straw) for power production by 2000 Limited national and international experience with straw combustion in1993 Large development program for development and demonstration of straw combustion technologies initiated Typically 100.000 300.000 ton/year per site can be sourced 6

New Bio Solutions An important part of strategy and future growth within DONG Energy Power Inbicon From straw to 2G bioethanol Kalundborg is the worlds biggest 2G demonstration plant Renescience Efficient grading of household waste Succesfull demonstration of presorting of waste at Amager Combustion Pyroneer Gasification of biomass residues from agriculture and forestry Demonstration plant commissioned at ASV 7

The Pyroneer technology as of today - The fuel flexible gasifier = the basic building block for future options Straw Energy Crops Gas: Substitution of coal, wood and HFO at power stations. Later even substitution of gas Industrial leftovers Manure Fibre Ash: With accessible contents of nutrients, especially potassium and phosphorus Sewage sludge Efficiency around 95% 8

Direct replacement of fossils fuels in existing units has a high CO 2 reduction potential 0.2 MW Air, Steam, N 2 and sand Straw 50 MW Baled straw 11.8 t/h Straw receiving and preparation Cuttet straw Pyroneer gasifier 50 MWth Coal 650 o C hot gas 47.7 MW 289 bar 582 o C Condense Mode 47% el. eff. Coal boiler Commissioned in 1997 Power Bio Power 22.4 MW Bio Ash Ash back to the fields 1.8 MW For illustration only 1 GJ straw can replace 0,95 GJ coal, this is very efficient

Milestones in developing the low temperature gasifier 1999 prototype 50 KW gasifier at DTU 2003 Up-scaling 500 KW gasifier at DTU 2007 Several Fuels 100 KW gasifier at DTU DONG Energy Procured the rights to the technology in 2009 Next step was to construct a 6 MW demonstration gasifier

The 6 MW test facility located next to a coal boiler The plant is located next to an existing coal boiler at Asnæs, Kalundborg Gasifier commissioned 2011 6 MW demo plant The gas is combusted in a separate burner The ash is utilised in full scale fertiliser experiments Used in campaign operation, to support 60 MW design 11

Status development of the Pyroneer gasification technology Key figures for the demonstration plant 1800 operation hours with air blower incl. start-up and cold test 1300 tons of straw gasified Results Fuel feed from 5 MW to 7,2 MW Stable and safe operation Automated start-up after trip to full load in less than 10 min Partly automated start-up from cold in less than 24 hours Automated and partly unmanned operation 12

Result from operation of the demonstration plant Gas composition H 2 : ~ 6% CO : ~ 11% CO 2 : ~ 13% N 2 : ~ 34% H 2 O : ~ 29% CH 4 +: ~ 7% Tar compounds are an essential contributor to the LHV of 5.9 MJ/kg Good combustion Good ash quality 13

The ash is low in heavy metals and can be distributed on farmland as a fertiliser Mg/kg PAH Cd Cr Hg Ni Pb Average figures 6,3 <0,09 17 <0,0012 5,6 3,9 Data variation +- 3 +- 0,01 +- 5 +- 0,0003 +- 1,8 +- 2 Limits to be meet for straw ash 1 12 5 100 0,8 60 120 All limits set by regulators can be met with large margin Conclusion: Ash can be distributed on farm land Note 1: Danish legislation "Biomasseaskebekendtgørelsen" 14

The Pyroneer ash is being tested as fertilser at the Bregentved Estate in a 3 year R&D program evaluated by agro institutes Ash produced in 6 MW Demo plant Ash distributed on trial plots in 2012 and 2013 Result after 2013 harverst: The ash works as good as NPK 15

Economic drivers for the Pyroneer technology is to be able to use low cost biomass fuels Cost of Fuel delivered at site, EUR/GJ 16,0 14,0 12,0 10,0 8,0 6,0 4,0 2,0 Fuel cost 2020 CO 2, Penalty@ 22 Euro/ton Typical Pyroneer fuels are high alkaline and high ash fuels, that are difficult to combust in existing boilers. 0,0 Natural Gas Coal HFO Wood Pellets Woodchips Straw Alternative Pyroneer fuels Based on data from the Danish Energy Agency 16

Using Danish straw price, the Pyroneer gas cost is similar to the cost of natural gas Comparable prices for power production fuels, EUR/GJ 14 12 10 8 6 4 2 0 8,2 0,7 1,5 6,0 Pyroneer fuel 4,3 0.7 3,6 Coal 8,4 0,4 8,0 Natural gas 9.4 Wood pellets 13,6 0,6 13,0 HFO The total Pyroneer conversion cost is approximately 2,2 EUR/GJ (incl. CAPEX) Using Danish straw at a price of 5.6 EUR/GJ as input the price of the Pyroneer gas will be around 8,2 EUR/GJ Alternative low cost biomasses will further reduce the cost of the Pyroneer fuel CO2 penalty Fuel cost Converson OPEX Conversion CAPEX Biomass 17

Outlook potential application areas but one step at a time 2012 2013 2014 2015 2016 2018 2020 2022 2025 Demo 6 MW Kalundborg 50 MW full-scale Version 1 Co-firing existing plants Typical scale 50-150 MW Up scale Gasifier Version 2 Industrial & HRSG Typical scale 5-50 MW Filter knowhow Version 2A Gas Engine (New Capacity/retrofit) Typical scale 25-100 MW Tar reforming knowhow Syngas & SNG (new capacity) Pressurerised Pyroneer gasifier Same technology but pressurized Typical scale 100-200 MW Version 3

Thank you for your attention Questions? 19