Nano-Spectroscopy. Solutions AFM-Raman, TERS, NSOM Chemical imaging at the nanoscale



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Nano-Spectroscopy Solutions AFM-Raman, TERS, NSOM Chemical imaging at the nanoscale

Since its introduction in the early 80 s, Scanning Probe Microscopy (SPM) has quickly made nanoscale imaging an affordable reality. The technique provides a continuously growing variety of surface analysis methods for the physical characterization of materials, yet label-free chemical sensitivity is still challenging. On the other hand, optical spectroscopy has provided a unique way to determine the structure and chemical composition of molecules for decades and is a method of choice for the analysis of nano-materials despite its diffractionlimited spatial resolution. The two techniques together make up an attractive and unique tool, yet integrating such different instrumention is challenging. Today, with over a decade of experience in this exciting field, we have refined the technique to its utmost with uncompromised performance to bring you a tool that is not only extremely powerful and versatile, but is also so easy to use, fast and reliable that generating outstanding data is virtually effortless. Raman-AFM and TERS Made Easy! Reliable Results Fully automated cantilever alignment insuring reproducible optimization of the AFM parameters from one tip to the next and from one user to another. (1) (5) Reliable repositioning of the probe on the sample within seconds. (1) (8) Drift compensated sample scanner with high resonance frequency brings reproducible images over long periods of time thanks to low vibration sensitivity. (5) Raman laser alignment by piezo-driven closed-loop objective scanner: shortest distance to the focus point for minimum drift. (6) Visual confirmation of the Raman laser alignment with independent video imaging, SPM detection and Raman mapping. (8) Versatile Numerous SPM modes including AFM, STM, tuning fork, NSOM. Full range of Raman excitation lasers, including red and NIR, without interferences, thanks to a 1300 nm AFM feedback diode. (1) Up to 3 spectroscopic detectors and 20 SPM channels. High resolution sample scanner from nanometers to full scan range. (5) Top down and oblique Raman detection for optimum resolution and throughput in both co-localized and Tip-Enhanced measurement modes. (2) Full control through one workstation, or, SPM and spectrometer can be operated independently. 3 7 1 5 2 6 4 8

Powerful 1 1300 nm AFM laser feedback High numerical aperture objectives from both top and side for best co-localized spatial resolution and best TERS collection efficiency. High-throughput optics and spectrometer. High spectral resolution with the LabRAM HR spectrograph. Broad range of detection wavelengths, from deep UV to Infrared. Simultaneous SPM and spectroscopic measurements. Powerful processing software suite for both SPM and spectroscopic data, including Multivariate Analysis and spectral database lookup. 4 2 3 High efficiency top down and side coupling Dual optical scheme, easy switching 5 Compact holder for easy probe exchange 7 6 High performance without active vibration isolation High resonance scanner, auto tip-alignment and tuning Simple and Fast Closed-loop, short path-length Raman laser alignment for long-term stability 8 One-click cantilever alignment, frequency tuning and optimization, requiring no manual adjustments. Easy cantilever exchange without affecting the sample. Fast and intuitive Raman laser to AFM tip alignment. Ultra-fast simultaneous SPM and Raman measurements. Visual confirmation of Raman laser alignment in all modes

The Ultimate Tool for Physical and Chemical Characterization Raman-AFM Full range of SPM modes and simultaneous spectroscopy AFM Optical Image 100 % Main Applications Biological structures Carbon nanotubes Nanowires Polymers SERS substrates Semiconductors Raman Silicon AFM Contact Potential Difference TERS Label-free chemical characterization with nanoscale resolution Composite Raman image AFM Topography SWCNT STM Image Raman with Defects AFM Capacitance CLS Spectra SWCNT TERS Image G Band Raman Single Layer Raman 2-layer Raman 3-layer Raman Amorphous Carbon AFM Phase AFM Friction Data courtesy of Prof. Hiroshi Ujii of K.U. Leuven

Integrated Software Seamless system control and data acquisition, and the most advanced data analysis and processing suite Integrated Multivariate Analysis module. High level analysis at a touch of a button. PCA MCR HCA DCA. Powerful data acquisition and system control interface with scripting and methods definition capabilities. λ = (325 nm - 1064 nm) P 500 mw VISIBLE AND OR INVISIBLE LASER RADIATION AVOID EXPOSURE TO BEAM CLASS 3B LASER PRODUCT KnowItAll HORIBA Edition. Fast chemical identification with HORIBA spectral database (>1750 spectra). * Laser safety classifications depend on individual systems and options info.sci@horiba.com www.horiba.com/scientific USA: +1 732 494 8660 France: +33 (0)1 69 74 72 00 Germany: +49 (0)89 4623 17-0 UK: +44 (0)20 8204 8142 Italy: +39 2 5760 3050 Japan: +81 (0)3 6206 4721 China: +86 (0)21 6289 6060 Brazil: +55 (0)11 5545 1500 Other: +33 (0)1 69 74 72 00 This document is not contractually binding under any circumstances - Printed in France - HORIBA Jobin Yvon 08/2013