1 Vitreous Materials Lab. LaMaV DEMa - UFSCar lamav.weebly.com..
2 Desafios... Adversidades despertam capacidades que, em outras circunstâncias, teriam ficado adormecidas... Estranhamente o Homem somente progride perante um ambiente desafiador. Se consegue, passo a passo, superar seus desafios, fica feliz e com mais energia e vontade de tentar novas soluções e novos projetos. Fica divertido!
3 Edgar Dutra Zanotto Center For Research, Technology and Education in Vitreous Materials CeRTEV s activities will focus on multidisciplinary, relevant glass science, useful technology and efficient education and outreach!
4 SCOPE CeRTEV will research and develop or improve glasses and glass-ceramics presenting application-relevant functionalities, such as high mechanical strength and electrical conductivity, biological, optical or catalytic activity, and/or combinations of these properties. A fundamental understanding of these properties will be sought on the basis of the structural organization of these materials on different length scales. We will apply state-of-the art NMR, EPR, EXAFS and vibrational spectroscopy to characterize the local and medium-range order, as well as the full resolution range of optical and electron microscopies, XRD and microanalyses for elucidating nano- and microstructures. This comprehensive experimental approach will be complemented by molecular dynamics simulations. Using this experimental modeling strategy, we will further seek a fundamental understanding of glass sintering and crystallization in terms of the mechanisms, thermodynamics and kinetics of viscous flow, as well as crystal nucleation and growth, enabling us to exercise control of these processes by developing appropriate formation and thermal treatment protocols. In a concerted effort, the participating laboratories will jointly investigate a number of important benchmark systems, which are deemed particularly promising for applications either as structural materials (e.g., dental and armor glass-ceramics), bio active glasses and glass-ceramics, glass-ceramics for architecture and construction, optical materials (e.g., laser glasses), materials for electrochemical energy storage devices (electrolytes, high-temperature seals), and catalytically active systems.
5 6 7 1
6 Glass-ceramics Dental Construction Gratings
7 Coordinador Tech & Innovation Director Coordinator Education and Outreach Manager 2 secretaries 1 informatics Vice-director 14 professors FQV ~30 collaborators ~60 students One of the largest academic glass R & D of this planet!
8 The Team 14 Leandro Innocentini L. de Faria, Manager, Scientometry STRUCTURE Hellmut Eckert Structure, NMR José Fabián Schneider Structure, NMR Claudio José Magon EPR Jose Pedro Donoso Gonzalez EPR Valmor Roberto Mastelaro EXAFS, XRD and laser crystallization Paulo Sergio Pizani Raman spectroscopy José Pedro Rino Molecular dynamics simulation CRYSTALLIZATION + Thermal, Mechanical, Bio and Electrical properties Edgar Dutra Zanotto Nucleation, growth, crystallization, glass-ceramics Marcello Rubens Barsi Andreeta Laser crystallization, crystal growth techniques Ana Cândida Martins Rodrigues Electrical properties, ionic conducting glass & GC Oscar Peitl Bio active glasses and glass-ceramics Eduardo Bellini Ferreira Nucleation, growth, crystallization, glass-ceramics OPTICAL Properties Andrea S. S. de Camargo Alvarez Bernardez Optical properties Marcelo Nalin Optical and chemical properties
9 Ranking in the world (2013) A June 2013 search on the SCOPUS database for the number of published articles with relevant keywords indicates that some of CeRTEV s faculty rank: first in the world with the keywords glass* and NMR*, first with glass* and nucleation, second with glass* and crystal growth, fourth with glass* and crystallization, 26 th with bio* and glass-ceramic*, 28 th with glass* and sinter*, 31 th with glass-ceramic*, 43 th with glass* and EXAFS.
10 Scientific papers - Ranking Russian Academy of Sciences(1,111 glass papers) Kyoto University(849) CeRTEV = USP(370)+ UNESP-(225)+ UFSCar (181) = 776 Shanghai Institute of Optics and Fine Mechanics (759) CNRS Centre National de la Recherche Scientifique(735) Tokyo Institute of Technology(624) University of Cambridge(574) University of Tokyo(553) Osaka University(550) The State Scientific-Research Institute of Glass(550) Friedrich Schiller Universität Jena(479) Universite Pierre et Marie Curie(471) Chinese Academy of Sciences(457) Corning Incorporated(445) Alcatel-Lucent Bell Labs(432) Pennsylvania State University(426) Argonne National Laboratory(423) Massachusetts Institute of Technology(412) S.I. Vavilov State Optical Institute(393) National Institute of Advanced Industrial Science and Technology(383) Universite de Rennes 1(375) 22th USP(370) Consiglio Nazionale delle Ricerche(366) Universite Montpellier 2 Sciences et Techniques(363) Indian Institute of Science(361) Hokkaido University(358) University of Sheffield(351) Alfred University(343) Kyushu University(341) SCOPUS search glass*+ vitreous+ amorphous+ non-crystalline - ( metal* and polymer*)
11 Ranking Shanghai Institute of Optics and Fine Mechanics CAS(201) Russian Academy of Sciences(177) CeRTEV = USP(67)+UFSCar(48)+UNESP(43) = 158 Ningbo University(152) Graduate University of Chinese Academy of Sciences(142) CNRS Centre National de la Recherche Scientifique(137) South China University of Technology(107) Wuhan University of Technology(104) Chinese Academy of Sciences(101) Universite de Rennes 1(96) University of Tokyo(94) Friedrich Schiller Universität Jena(93) Harbin Institute of Technology(91) Sri Venkateswara University(85) Universite Pierre et Marie Curie(82) Kyoto University(82) Tongji University(82) National Research Center, Cairo(79) University of Pardubice(78) Sichuan University(77) Consiglio Nazionale delle Ricerche(75) Tohoku University(72) Osaka University(72) East China University of Science and Technology(71) Pacific Northwest National Laboratory(71) Tokyo Institute of Technology(71) Universität Erlangen-Nürnberg(69) Shanghai Institute of Ceramics Chinese Academy of Sciences(69) Tsinghua University(68) 30th Universidade de Sao Paulo(67) Corning Incorporated(62) glass*+ vitreous+ amorphous+ non-crystalline - (metal* and polymer*)
12 Budget ~US$ 20 million from Fapesp for equipament, travel, materials and supplies spread over 11 years (excluding salaries and students grants) But Fapesp expects us to get complementary funding from other government agencies and industries...
13 International Advisory Board GOMD meeting, San Diego, June 2013 Fran Serbena, Dick Brow, Bruce Aitken and Ed Zanotto. Credit ACerS
14 ICG, Prague, July 2013
15 Our philosophy To pursue relevant research topics with well defined objectives. To carry out long term basic research. To reach and expand the frontiers of knowledge in each one of the chosen subjects. Maximize planning, calculation, simulation, literature search and study to optimize experimentation. To publish original, accurate articles that push the frontiers of knowledge. Quality, and not quantity, is our goal. Technological research via industrial interest that may lead to patents and eventually innovation
16 New glass research center in Brazil 2 universities, 14 profs, 11 years, $20 M one big impact! Published on July 8th, 2013 by Eileen De Guire The American Ceramic Society
17 Jena 1982 Russel Grenoble 1984 Souquet IVSO Inst Fokin Univ. Rostock 2001 Schmelzer Erlangen 2003 Boccaccini TC7 (1984) IMI (2004) LaMaV s International NETWORK Bio glass and GC ~15 institutions L. Hench, Boccacini J. Mauro Corning J. Du Univ. Texas Starting in 2014 Rocherullè & Rouxel Rennes J. Lumeau Fresnel CeRTEV 2012
18 Selected papers published in 2013 Structure of vitreous materials Ren, J., Eckert, H., Anion distribution in superionic Ag3PO4-AgI glasses revealed by dipolar solid-state NMR, Journal of Physical Chemistry C 117 (47), pp , Schneider, J., Tsuchida, J., Eckert, H., Cation size effects in mixed-ion metaphosphate glasses: Structural characterization by multinuclear solid state NMR spectroscopy, Physical Chemistry Chemical Physics 15 (34), pp ,2013. DQ-DRENAR: a New NMR Technique to Measure Site-Resolved Magnetic Dipole-Dipole Interactions in Multispin-1/2 Systems. Theory and Applications to Phosphate Materials, Ren,J.; Eckert, H. J. Chem. Phys. 138, /1-16 (2013). Sol-Gel preparation and structural characterization of mesoporous Al 2 O 3 -SiO 2 glasses, Ren, J.; Zhang, L.; Eckert, H. Sol Gel Sci Technol. 2014, in press. Medium range order in sol-gel prepared Al 2 O 3 -SiO 2 glasses: New results from solid State NMR, Ren, J.; Zhang, L; Eckert, H. J. Phys. Chem. C 2014, in press. Pontes, D.S.L.; Pontes, F.M.; da Silva, L.F.; Chiquito, A.J.; Pizani, P.S.; Longo, E. Influence of a cosubstituted A-site on structural characteristics and ferroelectricity of (Pb, Ba, Ca)TiO3 complex perovskites: analysis of local-, medium- and long-range order. Journal of Sol-Gel Sci Technology, pp
19 Crystal Nucleation, Growth and Overall Crystallization Fokin, V.M.; Reis, R.M.C.V.; Abyzov, A.S.; Chinaglia, C.R.; Zanotto, E.D. Nonstoichiometric crystallization of lithium metasilicate-calcium metasilicate glasses. Part 1 - Crystal nucleation and growth rates. Journal of Non-Crystalline Solids 362 (1), pp Fokin, V.M.; Reis, R.M.C.V.; Abyzov, A.S.; Chinaglia, C.R.; Schmelzer, J.W.P.; Zanotto, E.D. Nonstoichiometric crystallization of lithium metasilicate-calcium metasilicate glasses. Part 2 - Effect of the residual liquid. Journal of Non-Crystalline Solids 379, pp Cabral, A.A.; Ferreira, E.B.; Villas-Boas, M.O.C.; Zanotto, E.D. On the determination of the concentration of crystal nuclei in glasses by DSC. Journal of the American Ceramic Society 96 (9), pp Dyamant, I.; Abyzov, A.S.; Fokin, V.M.; Zanotto, E.D.; Lumeau, J.; Glebova, L.N.; Glebov, L.B. Crystal nucleation and growth kinetics of NaF in photo-thermo-refractive glass. Journal of Non- Crystalline Solids 378, pp Zanotto, E.D. Glass Crystallization Research - A 36-Year Retrospective. Part I, Fundamental Studies. International Journal of Applied Glass Science 4 (2), pp Rodrigues, A.M.; Narváez-Semanate, J.L.; Cabral, A.A.; Rodrigues, A.C.M. Determination of crystallization kinetics parameters of a Li1.5Al0.5Ge1.5(PO4)3 (LAGP) glass by differential scanning calorimetry. Materials Research 16 (4) Jasinevicius, R.G.; Duduch, J.G.; Pizani, P.S. Evidence of crystallographic orientation dependence upon cyclic microindentation-induced recrystallization within amorphous surface layer. Materials Letters 94, pp Almeida, J.M.P., Tribuzi, V., Fonseca, R.D., Otuka, A.J.G., Ferreira, P.H.D., Mastelaro, V.R., Brajato, P., Hernandes, A.C., Dev, A., Voss, T., Correa, D.S., Mendonca, C.R., Femtosecond laser processing of glassy and polymeric matrices containing metals and semiconductor nanostructures, Optical Materials 35 (12), pp , 2013.
20 Bioactive glasses and glass-ceramics Souza, M.T.; Crovace, M.C.; Schröder, C.; Eckert, H.; Peitl, O.; Zanotto, E.D. Effect of magnesium ion incorporation on the thermal stability, dissolution behavior and bioactivity in Bioglass-derived glasses. Journal of Non-Crystalline Solids 382, pp Renno, A.C.M.; Bossini, P.S.; Crovace, M.C.; Rodrigues, A.C.M.; Zanotto, E.D.; Parizotto, N.A. Characterization and in vivo biological performance of biosilicate. BioMed Research International 2013, art. no Renno, A.C.M.; Nejadnik, M.R.; Van De Watering, F.C.J.; Crovace, M.C.; Zanotto, E.D.; Hoefnagels, J.P.M.; Wolke, J.G.C.; Jansen, J.A.; Van Den Beucken, J.J.J.P. Incorporation of bioactive glass in calcium phosphate cement: Material characterization and in vitro degradation. Journal of Biomedical Materials Research - Part A 101 A (8), pp Desimone, D.; Li, W.; Roether, J.A.; Schubert, D.W.; Crovace, M.C.; Rodrigues, A.C.M.; Zanotto, E.D.; Boccaccini, A.R. Biosilicate -gelatine bone scaffolds by the foam replica technique: Development and characterization. Science and Technology of Advanced Materials 14 (4), art. no Pinto, K.N.Z.; Tim, C.R.; Crovace, M.C.; Matsumoto, M.A.; Parizotto, N.A.; Zanotto, E.D.; Peitl, O.; Rennó, A.C.M. Effects of biosilicate scaffolds and low-level laser therapy on the process of bone healing. Photomedicine and Laser Surgery 31 (6), pp Renno, A.C.M.; Van De Watering, F.C.J.; Nejadnik, M.R.; Crovace, M.C.; Zanotto, E.D.; Wolke, J.G.C.; Jansen, J.A.; Van Den Beucken, J.J.J.P. Incorporation of bioactive glass in calcium phosphate cement: An evaluation. Acta Biomaterialia 9 (3), pp Kido, H.W.; Oliveira, P.; Parizotto, N.A.; Crovace, M.C.; Zanotto, E.D.; Peitl-Filho, O.; Fernandes, K.P.S.; Mesquita- Ferrari, R.A.; Ribeiro, D.A.; Renno, A.C.M. Histopathological, cytotoxicity and genotoxicity evaluation of Biosilicate glassceramic scaffolds. Journal of Biomedical Materials Research - Part A 101 A (3), pp Siqueira, R.L.; Zanotto, E.D. The influence of phosphorus precursors on the synthesis and bioactivity of SiO2-CaO-P2O5 sol-gel glasses and glass-ceramics. Journal of Materials Science: Materials in Medicine 24 (2), pp Daguano, J.K.M.F., Rogero, S.O.,Crovace, M.C., Peitl, O., Strecker, K.,Dos Santos, C., Bioactivity and cytotoxicity of glass and glass-ceramics based on the 3CaO P2O5-SiO2-MgO system, ournal of Materials Science: Materials in Medicine 24 (9), pp , Brandão, S.M., Schellini, S.A.,Padovani, C.R., Peitl, O., Hashimoto, E., Análise da biocompatibilidade de cones de biovidro e biovitrocerâmico (Biosilicato ) em cavidade eviscerada de coelho [Biocompatibility analisys of Bioglass 45S5
21 Other types of glass-ceramics Zanotto, E.D. Glass Crystallization Research - A 36-Year Retrospective. Part II, Methods of Study and Glass- Ceramics. International Journal of Applied Glass Science 4 (2), pp Soares, V.O.; Peitl, O.; Zanotto, E.D. New sintered Li2O - Al2O3- SiO2 ultra-low expansion glass-ceramic. Journal of the American Ceramic Society 96 (4), pp Kjeldsen, J.; Yue, Y.; Bragatto, C.B.; Rodrigues, A.C.M. Electronic conductivity of vanadium-tellurite glassceramics. Journal of Non-Crystalline Solids 378, pp
22 Optical Properties De Queiroz, T.B., Botelho, M.B.S., De Boni, L., Eckert, H., De Camargo, A.S.S., Strategies for reducing dye aggregation in luminescent host-guest systems: Rhodamine 6G incorporated in new mesoporous sol-gel hosts, Journal of Applied Physics 113 (11), art. no , De Queiroz, T.B., Botelho, M.B.S., Fernández-Hernández, J.M., Eckert, H., Albuquerque, R.Q., De Camargo, A.S.S., New luminescent hostguest system based on an iridium(iii) complex: Design, synthesis, and theoretical-experimental spectroscopic characterization, Journal of Physical Chemistry C 117 (6), pp , Santos, W.Q., De Camargo, A.S.S.,Wu, D., Silva, W.F., Zhang, L., Jacinto, C., Cooperative upconversion, radiation trapping, and selfquenching effects in highly Yb3+-doped oxyfluoride glasses, Science of Advanced Materials 5 (12), pp , 2013.
23 Optical Properties Manzani, D.; Almeida, J.M.P.; Napoli, M.; De Boni, L.; Nalin, M.; Afonso, C.R.M.; Ribeiro, S.J.L.; Mendonça, C.R. Nonlinear optical properties of tungsten lead-pyrophosphate glasses containing metallic copper Nanoparticles. Plasmonics 8 (4), pp Valle, P.S.; Montesso, M.; Nalin, M.; Donoso, J.P.; Silva, I.D.A.; Magon, C.J. Influence of silver precursors on growth of metallic nanoparticles in heavy metal oxide glasses. Quimica Nova 36 (7), pp , Avila, L.F.; Almeida, J.M.P.; Gonçalves, M.S.; Valle, P.S.; Nalin, M.; Mendonça, C.R.; Cescato, L. Design and fabrication of two-dimensional hexagonal photonic crystals with a linear waveguide in erbium doped GeO2-Bi2O 3-PbO-TiO2 glasses. Proceedings of SPIE - The International Society for Optical Engineering 8776, art. no L, Avila, L.F.; Nalin, M.; Cescato, L. Self diffraction holographic techniques for investigation of photosensitive materials. Proceedings of SPIE - The International Society for Optical Engineering 8776, art. no G, 2013.
24 Book Chapters Glasses on the Nanoscale, Eckert, H. Ribeiro, S.J.L.; Santagneli, S. H.; Nalin, M.; Poirier, G.; Messaddeq,Y. Handbook of Nanomaterials, R. Vajtai, ed. Springer- Verlag Berlin, (2013). Advanced NMR Spectroscopy of Glasses (Review), Eckert, H. to be published in Modern Glass Characterization, M. Affatigato, ed., John Wiley and Sons Bioactive Glass-Ceramics for Load-Bearing Applications - Oscar Peitl, Edgar D Zanotto, Francisco C Serbena and Larry L Hench) - An Introduction to Bioceramics, 2nd Edition Edited by: L. L. Hench, ed., World Scientific (2013) Zanotto E.D. et al- DSC techniques for the study of glass crystallization, in Glassy, Amorphous and Nano-Crystalline Materials ed. J. Sestak, J. Mares, P. Hubik, Springer (2013) Nucleation, Growth and Overall Crystallization, Zanotto, E.D et al., to be published in Glass Encyclopedia, P. Richet, ed., John Wiley and Sons 2014 Stress-induced Pore Formation and Phase Selection in a Crystallizing Stretched Glass, Fokin V.M., Karamanov A., Abyzov A.S, Schmelzer J. W.P., Zanotto E.D, Chapt.8 to be published in Glass: Selected Properties and Crystallization, J. Schmelzer, ed., De Gruyter 2014
25 Planned books Crystals in glass Wiley, Oct Experimental techniques for characterization glass structure and crystallization - start 2014 (CeRTEV team) Fundamentals of glass crystallization start 2014 (Zanotto, Fokin & Schmelzer)
26 Internationalization Visiting professors in 2013 Vladimir Fokin St. Petersburg, Russia, one year Jean Louis Souquet- Grenoble, France, 6 months Juern Schmelzer, Rostok, Germany, 1 week Alexander Priven, Korea, 1 week Post-docs and students 2 undergrads from the USA 2 MSc students from Colombia 1PhD student from Iran (sanduiche) 2 post-docs from India
27 Organization of Congresses, etc... Internal workshops yearly starting 2013 Invention & Innovation Sept Sol-gel workshop Oct Rede BioNetec Meetings yearly starting Nov X Brazilian Symposium on Glass Oct São Paulo School on Glasses and CG Feb Education and Outreach about glass 2015 Flow and Fracture in Glass 2016 (?) XI Brazilian Symposium on Glass 2017 Glass frontiers jointly with the World Congress of Ceramics, Iguassu Falls
28 Invited talks 2013 Hellmut Eckert A homonuclear version of REDOR for recoupling dipolar interactions in multi-spin systems: Applications to inorganic phosphorus clusters and networks, International Symposium of Magnetic Resonance (ISMAR), Rio de Janeiro, May 2013.(Invited) Introduction into Solid State NMR Spectroscopy, workshop, SBQ meeting, Aguas Lindoias, May (Invited) Modern Solid State NMR Strategies for Studying Structural Transformations in Non-Siliceous Sol-Gel Glass Systems, SBPMAT, Campos de Jordão, September 2013.(Invited) Ed Zanotto Iron Phosphate Glasses and Melts - A US-Brazil Research Collaboration on Novel Materials for Nuclear Waste Remediation - 37th International Conference & Exposition on Advanced Ceramics & Composites, Daytona Beach, USA, Jan , 2013 (delivered by R.K. Brow) (Invited) The relationship between molecular structure and nucleation mechanism in glass, ICG 2013, Prague Czech Republic, July (Invited) LaMaV/ UFSCar - 36 anos de ensino, ciência e inovação - II Workshop UEPG, Ponta Grossa, PR, August 13-14, 2013 (Opening Talk) LaMaV UFSCar / 36 anos interagindo com empresas, 22 Encontro Técnico da ABIVIDRO, São Paulo, Oct. 2, 2013 (Invited) Advances in glass crystallization and glass-ceramics- 19th Larson Workshop on Crystallization Technology, Indianapolis, USA, October 5-10, 2013 (Invited) 36 years of science, technology and art - Magna lecture - Admiral Álvaro Alberto Award cerimony - CNPq, Brasília, October 23, 2013 (Invited) Vitrocerâmicas - passado, presente e futuro - Workshop CEFET, São Luiz, MA, 3 Nov (Invited) LaMaV - 3,5 décadas de invenções. Aprendendo com os erros - I EEAEM, UFSCar, 28 Nov (Invited) J. P. Rino
29 Editorship of periodicals -Solid State Nuclear Magnetic Resonance Hellmut Eckert Editor -Journal of Non-Crystalline Solids Edgar D. Zanotto - Editor -Int. Journal of Applied Glass Science, USA- IAB -Materials Research, Brazil - IAB -Ceramica y Vidrio, Spain - IAB -Cerâmica, Brazil IAB -The Open Crystallography Journal Marcello R. Barsi Andreeta - Associate Editor
30 Technology Coordinator Prof. Eduardo B. Ferreira, EESC- USP
32 O-I TAB meeting, Perrysburg, USA, March 2014 Review and make recommendations on O-I s technology portfoglio EDZ s talk about CeRTEV
33 Glassman South America, March h30 Opening Show: Glassman South America Lucien Belmonte / Greg Morris Abividro 9h40 Cleanfire GC Edson E. Basilio Air Products 10h Heat Recovery Fabio Guastini Area Impianti 10h20 New cost efficient solution for glass moulds Sergio Simones Hoganas 10h40 Hot Bottom Repair Cristina Sanches Fosbel 11h New Material for Glass Melting Eletrodes Elisio Ferreira Neto Plansee 11h20 Defeitos no vidro vs. refratários Marcelo Guerra SEFPRO 1h20 An introduction to the FleXinspect Michael G. Rentschler Buch Emhart Glass 1h40 Glass Sand Manoel J. B. Cordova Mineração Jundu 2h Inovation on glass packaging Daniel Amaral OI 2h20 Soda-ash Tarcisio Neves /Walter Shultz (ANSAC) 2h40 Brazilian Climate Changes Stefan David Abividro 3h Oxygen Enhanced Nox Reduction Abilio Tasca Praxair White 3h20 Quality Control of Cullet Marcos Gibim Verallia CETEV h40 Made in Germany for Glass People K. Rudolph GPS - Verallia 10h Speedline - Evolution in IS machines Rainer Heidemann Heye International 10h20 Brazilian Law on Wastes Ana Paula Bernardes Abividro 10h40 CeRTEV- Center for Research, Technology and Education in Vitreous Materials Edgar Zanotto CeRTEV/UFSCar
34 Corning Inc. Research Summit, Corning, USA June 2014 EDZ talk
35 Vitrovita & DMC, Brazil biog and CG CTA, Brazil Armor GC AGY, USA special fibers LaMaV industry net Optigrate, USA PTRG NSG, Japan viscous flow Corning, USA GR Status & trends Ivoclar? Dental GC Neogres? sintered G & GC Saxon Glass? chem. tough
36 Current projects with companies Ongoing GC Armors, CTA, Brazil Bioactive GC for dental and medical use Vitrovita / DMC, Brazil Photo-thermo-crystallization PTRG OptiGrate, USA Viscous flow and crystal growth in glasses, NSG, Japan Special glass fibers, AGY, USA Glass containers, O-I, USA In negociation Dental GC - Ivoclar, Liechtenstein (NDA signed) LGLT GC Phillips, Netherlands (testing) Chemically toughened glass- Saxon Glass, USA (neg.) Sintered GC / GC tiles - UNIGRES, Brazil (negociation)
37 Example - Bio G and GC technologies being developed Pós Grânulos Prótese Ocular Implantes Recobertos Manta Flexível Prótese de Ouvido Médio Scaffolds
38 Recent CeRTEV Patents Leo et al Armor transparent GC (2013) Marina et al New bioactive fiberizable GC (2013) Clever et al Bioactive coating for Ti (2014)- deposited Marina et al Fiber drawing machine (2014) - Zanotto et al.- REFORMIX Glass - Software for formulation of glass compositions having combined properties (2014) EDZ - The best putter in the world (2014)!
39 Education and Outreach Discussion group / Brazilian glass researchers and engineers active Kit for demonstration of optical phenomena for undergraduate or high school students - ready Colored glass kits - ready Web-site with educational videos - ready Virtual museum of glass (under construction)
40 EDUCATION AND OUTREACH Creation of the first technical course in South America Being aware of the lack of professional training course dedicated to the glass industry, with the partnership of Paula Souza Center, we proposed to create a technical course to provide trained professionals for the glass industry.
41 EDUCATION AND OUTREACH What we have done so far: First meeting: presentation of our project CeRTEV and Education and outreach project to ABIVIDRO Second Meeting: Joint meeting with ABIVIDRO and Paula Souza Center - ABIVIDRO confirmed to Paula Souza Center the urgent need for professional qualification, specially at technical level, to the glass industry. Paula Souza Center asked to describe all technical positions (cargos técnicos) Third meeting: we described the technical positions for the glass (flat and hollow ) fabrication, glass transformation, and also glass specification for construction Next step: a memorandum of agreement between ABIVIDRO, Paula Souza Center and CeRTEV, aiming the consolidation of this new technical course must be prepared and signed
42 EDUCATION AND OUTREACH Already done: -ACIEPE: Engineers and Scientists of the Future - UFSCar program aiming to demonstrate to elementary school students of São Carlos the basis of scientific thinking, aiming to attract them to the field of engineering and hard sciences. -Meeting and agreement with the Secretary of Science and Technology of São Carlos: participation in the program Science at School Same program with Araraquara -School visits to LaMaV glass melting, short talks and video demonstrations to hundreds of high school students from all over the State of São Paulo (UFSCar open day and more )
43 Plans for Offer the first class of the Paula Souza Center technical course in Produce a video-course for architects about the fundamentals of glasses and its specifications for architectural building. -Create a collection of demonstrational functional glasses such as: electrically conducting glass, fotosensitive (PTRG) glass, invisible gass, optical fiber, thermal strain in glass, metallic glass, sugar glass How to use these functional glasses outside our classroom? Physical Museum planed for 2015 São Paulo (International) School of Structure, Crystallization and Properties of Glasses planed for 2015
44 Aknowledgements São Paulo Research Foundation FAPESP Grant # 2013/
45 LaMaV 37 years of equilibrium between science & technology Edgar D. Zanotto
46 LaMaV s mission TO EDUCATE excellent engineers and researchers via good research and teaching TO EXPAND the frontiers of knowledge / via basic research / excellent publications! TO ASSIST companies beyond their expectations / consulting + applied research by TO INNOVATE in the field of glass and related materials / via technological research
47 Sheffield 1979 P. James* Jena 1982 C. Russel Grenoble 1984 J. L. Souquet TC 7 / ICG 1985 Arizona 1987 M. Weinberg* Florida 1994 L. Hench Mastelaro/ Sneid, IFSC/ USP P. C. Soares, UFPR A. A. Cabral, CEFET, MA E.B. Ferreira, EESC J. Daguano- UFABC F. Serbena e V.Soares - UEPG La MaV NETWORK Bio glass and GC ~15 instituições Optigrade, NSG, AGY, Vitrovita,Saxon, CT Cyted/ CNPq, 1998 ICV - A. Duran U. Medellin C. Paucar IVSO Institute 1996, V. M. Fokin CNEA, 1998 M. Prado BAM, 1999 R. Muller Bulg. Acad. Sci. I. Avramov 2001 Univ. Rostock J. Schmelzer 200 ADEMAT, 2003 IC - A. Boccaccini Max Plank A. Pyzalla IMI 2004 Clausthal J. Deubener 2005 CREOL/ UCF L. Glebov 2005 UMR R. Brow 2005 Douhausie J. Zwanziger 2005
48 Bio glass and GC ~15 institutions Daguano UFABC LaMaV s Brazilian NETWORK H.E., Mastelaro & Schneider, Magon IFSC Ferreira EESC Soares PUC-PR Cabral CEFET Serbena & Oliveira UEPG e UEMA CeRTEV 2012
49 TEAM ANNUAL BUDGET Permanent E.D. Zanotto / Crystallization & thermo-mechanical properties O. Peitl - Bio glasses/ Chemical and thermo-mechanical properties A.C.M. Rodrigues / Electrical properties 1 technician (Zé) US$ 430,000 Temporary 4 post docs 9 PhD students 2 MSc students 10 Internship students 1 secretary ,000 Materials & Supplies ,000 US$ 1,030, TOTAL NORMALIZED by PPP (1.0147/0.5336) ~2,000,000
50 Muito obrigado! Thank you very much! Vielen Dank! Dziękuję! Hjärtligt tack! Muchas gracias! Merci beaucoup! Grazie mille!
51 University Ranking glass*+vitreous+amorphous+non-crystalline > Tohoku University (1,660) + Tohoku University(1,287 ) Inoue s > Kyoto University(1,265) > CeRTEV: USP (476) + UNESP (278) + UFSCar (275) = 1029 > Osaka University(938) > Tokyo Institute of Technology(901) > University of Cambridge(855) > University of Tokyo(736) > Massachusetts Institute of Technology(686) > Friedrich Schiller Universität Jena(601) > Pennsylvania State University(600) > Universite Pierre et Marie Curie(572) > Tsinghua University(571) > University of Sheffield(525) > Stanford University(516) > California Institute of Technology(488) > MoskovskijGosudarstvennyjUniversitet(483) > Universite de Rennes 1(480) > USP (476) > Imperial College London(473) > Kyushu University(460) > Universite Montpellier 2 Sciences et Techniques(441) > Hokkaido University(433) > Nagoya University(430) > University of Science and Technology Beijing(403) > Wuhan University of Technology(403) > Alfred University(401)
Assoc. Prof. Dr. M. Aylin DELİORMANLI EDUCATION Degree University Department / Program Undergrad Ege University Chemical Engineering 99 99 M.S. Izmir Institute of Tech. Materials Science and Engineering
University of São Paulo School of Economics, Business Administration and Accounting at Ribeirão Preto The University of São Paulo Praça do Relógio - Clock Square Established in January 25th, 1934; Public
Formation of solids from solutions and melts Solids from a liquid phase. 1. The liquid has the same composition as the solid. Formed from the melt without any chemical transformation. Crystallization and
Upcoming APS Summer Schools 9th U.S. National School on Neutron & X-Ray Scattering August 12 25, 2007 Argonne Division of Educational Programs 3rd APS XAFS Summer School July 23 27, 2007 APS XAFS Scientific
Master in Condensed Matter Physics Master académique 2 " A research centered university with a personal atmosphere and multicultural flair " Students at the University of Luxembourg 3 Do it like Einstein,
MATERIALS SCIENCE AND ENGINEERING MASTER S PROGRAMS Program Description The MSE graduate program was designed as an interdisciplinary venture that would attract highly qualified graduate students, considered
Luis M. Liz- Marzán Ikerbasque Research Professor, Centre for Cooperative Research in Biomaterials, CIC. biomagune, 20009, San Sebastián, Spain Current Position: L UIS M. LIZ- MARZÁN Education: Bachelor
CURRICULUM VITAE EDUCATION: Donghyun Shin Department of Mechanical and Aerospace Engineering The University of Texas at Arlington, Arlington, TX 76019 Tel: (817) 272-9336; Email: email@example.com; Fax: (817)
Southern Federal University Master course in Material Science in Nanosystems Field of study: Nanotechnologies and Microsystems Engineering Course Director: Dr. Yury Yuzyuk Faculty of Physics Southern Federal
2 nd Finnish-Brazilian Workshop on Biomass Conversion: Actions in Science, Innovation and Education to Create a Sustainable World An International Master in Biomass and Bioenergy for Sustainable Development
Auburn University 1 Chemical Engineering - CHEN Courses CHEN 2100 PRINCIPLES OF CHEMICAL ENGINEERING (4) LEC. 3. LAB. 3. Pr. (CHEM 1110 or CHEM 1117 or CHEM 1030) and (MATH 1610 or MATH 1613 or MATH 1617
Hannes Jónsson Faculty of Physical Sciences, University of Iceland, 107 Reykjavík, Iceland e-mail: firstname.lastname@example.org http://www.hi.is/ hj April 2014 Education: Employment: Institution: Degree: Dates: University
Double Degree exchange programs taught at Phelma for KTH students Double Degree program for KTH students: In-coming Double Degree KTH students are registered in KTH and in Phelma, but they do not pay registration
Chemical Sciences Major Chemistry is often known as the central science because of the key position it occupies in modern science and engineering. Most phenomena in the biological and Earth sciences can
- 1 - Appendix XIII UNIVERSITY OF KERALA Updated list of standard journals approved by Board of Studies in Optoelectronics kup 1012(5)/2014-15 160 - 2 - Updated list of standard journals approved by Board
IUCLID 5 COMPOSITION AND ANALYSIS GUIDANCE DOCUMENT: IRON ORES, AGGLOMERATES [EINECS NUMBER 265 996 3, CAS NUMBER 65996 65 8] IRON ORE PELLETS INTRODUCTION Each REACH registrant is required to file its
Light management for photovoltaics using surface nanostructures Roberta De Angelis Department of Industrial Engineering and INSTM, University of Rome Tor Vergata New Materials For Optoelectronics webnemo.uniroma2.it
U.S. News Best Global Universities Rankings: An inside look at the latest results and methodology Robert J. Morse, Chief Data Strategist U.S. News & World Report 6th International Conference on World-Class
ISE Satellite Student Regional Symposium - Environmental Electrochemistry Meeting (Semana de Eletroquímica Ambiental (in Portuguese)) Aim The proposal to hold the Environmental Electrochemistry Meeting
Current Address: 607 Charles E. Young Dr. E., Room 4234 Los Angeles, CA 90024 Telephone: +1-(310)-825-7385 E-mail: email@example.com Date/Place of Birth: Citizenship: 07 December 1990 / Corpus Christi,
Contents Contributors Preface xiii xiv 1 Quality control and regulation 1 C.J. MOORES 1.1 Introduction 1 1.2 The quality of medicines 2 1.2.1 The meaning of quality 2 1.2.2 Medicines are special 3 1.2.3
CIRICULUM VITAE 1. PERSONAL Name, Title : Derya ATAÇ, M.Sc. Date of Birth-Place : March 2 nd 1984- Balikesir, Turkey Address Phone E-mail : NanoElectronics Group (NE), MESA+ Institute for Nanotechnology,
Electronic Supplementary Material (ESI) for Energy & Environmental Science. This journal is The Royal Society of Chemistry 2014 Professor John Varcoe (Department of Chemistry, University of Surrey, UK)
Page 1 of 5 JAMIE R. GOMEZ Department of Chemical & Nuclear Engineering, University of New Mexico 1 University Boulevard, Albuquerque, NM 87131 Tel: 505-277-2742 Email: firstname.lastname@example.org Education Florida
www.keithley.com 1 st Edition Nanotechnology Measurement Handbook A Guide to Electrical Measurements for Nanoscience Applications To get a free electronic version of this book, visit Keithley s Knowledge
2013-2014 Engineering and Applied Science Calendar Class of 2016 Second Year Common CORE - 2013-2014 APSC 200 Engineering Design and Practice II F 3-0-1 4 APSC 293 Engineering Communications F.25-0-.75
CURRICULUM VITAE JOANA SETZER EDUCATION Phd (since 2009) LSE London School of Economics and Political Science, London, UK. Mentor: Dr. Michael Mason. Essay: Environmental paradiplomacy: São Paulo s transregional
Mechanical Engineering and Materials Science 1 The George R. Brown School of Engineering Ch a i r Enrique V. Barrera Associate Chair Andrew J. Meade Pr o f e s s o r s Pulickel Ajayan John E. Akin Andrew
TERMS AND CONDITIONS RESEARCH INITIATION FELLOWSHIPS (2 nd Call) IMDEA Materials Institute (Madrid Institute for Advanced Studies of Materials) is a nonprofit independent research organization promoted
VCU CHEMISTRY, BACHELOR OF SCIENCE (B.S.) WITH A CONCENTRATION IN BIOCHEMISTRY The curriculum in chemistry prepares students for graduate study in chemistry and related fields and for admission to schools
Matter, Materials, Crystal Structure and Bonding Chris J. Pickard Why should a theorist care? Where the atoms are determines what they do Where the atoms can be determines what we can do Overview of Structure
Product Information Thermal Properties of Elvax Measured by Differential Scanning Calorimeter (DSC) Summary The melting and freezing points of various Elvax ethylene vinyl acetate (EVA) polymers were measured
CHEM 10113, Quiz 7 December 7, 2011 Name (please print) All equations must be balanced and show phases for full credit. Significant figures count, show charges as appropriate, and please box your answers!
Ultrashort pulse laser processing current industrial applications and beyond Stefan Nolte Institute of Applied Physics, Abbe Center of Photonics, Friedrich Schiller University Jena, Albert-Einstein-Str.
ЖУРНАЛЫ ИЗДАТЕЛЬСТВА ELSEVIER В ОБЛАСТИ НАНОТЕХНОЛОГИЙ Доступ к полнотекстовым статьям из журналов издательства Elsevier для организаций - участников национальной нанотехнологической сети осуществляется
Laser Based Micro and Nanoscale Manufacturing and Materials Processing Faculty: Prof. Xianfan Xu Email: email@example.com Phone: (765) 494-5639 http://widget.ecn.purdue.edu/~xxu Research Areas: Development
And so Scientia Agricola has gone international... 1st Brazil-China Bilateral Meeting on STM Publishing São Paulo, 05/23/14 Luís Reynaldo Ferracciú Alleoni Editor-in-Chief Universidade de São Paulo University
DEVelopment of Infrastructure for Smart Engineering Materials Research /DEVISER/ A Czech structural funds project aimed for building a new public research infrastructure called Laboratory of Functional
International Leader Training Program for Sustainable Use of Water and Resources (SUW Program) The University of Kitakyushu Kitakyushu s Overcoming Pollution International Leader Training Program for Sustainable
The Master s Degree Program in Applied Biomedical Engineering Russell L. McCally The Master s Degree Program in Applied Biomedical Engineering was established in 1993. This article describes its history,
The Samantha Christey Communications Unit - ERC Executive Agency ENRC Meeting Brussels 1st December 2010 ERC at Events across EU 2010 June: ERC - Celebrating 1000 innovative ideas Ludwig-Maximilians-University
Soft lithography for diffractive microfabrications Liliana D Amico PhD Section: Materials Engineering XXVIII Cycle (3 Year) Mauro Casalboni, Fabio De Matteis, Paolo Prosposito, Roberta De Angelis Summary
CHEMISTRY UW-PARKSIDE 2015-17 CATALOG Greenquist 344 262-595-2326 College: Natural and Health Sciences Degree and Programs Offered: Bachelor of Science Major - Chemistry Minor - Chemistry Certificate -
DESIGN, FABRICATION AND ELETRICAL CHARACTERIZATION OF SOI FINFET TRANSISTORS Prof. Dr. João Antonio Martino Professor Titular Departamento de Engenharia de Sistemas Eletrônicos Escola Politécnica da Universidade
Materials Science Forum Vols. 660-661 (2010) pp 176-181 Online available since 2010/Oct/25 at www.scientific.net (2010) Trans Tech Publications, Switzerland doi:10.4028/www.scientific.net/msf.660-661.176
Optica Applicata, Vol. XXXVII, No. 4, 2007 The study of structural and optical properties of TiO 2 :Tb thin films AGNIESZKA BORKOWSKA, JAROSLAW DOMARADZKI, DANUTA KACZMAREK, DAMIAN WOJCIESZAK Faculty of
Engineering Fracture Mechanics International Journal of Hydrogen Energy Materials and Design Mechanics and Industry Physic Letters Technical Langmuir Langmuir Theoretical and Applied Fracture Mechanics
Globalizing Engineering Education in Materials Development for Optics and Photonics (MDOP): a Princeton-São Paulo partnership Craig B. Arnold Princeton Institute for Science and Technology of Materials;
NDSU Department of Physics Graduate Student Handbook Department of Physics North Dakota State University Fargo, ND 58108-6050 History Draft: August 24, 2014 Table of Contents 1. Contact 2 2. Graduate Program
Materials Science Forum Vols. 660-661 (2010) pp 225-228 Online available since 2010/Oct/25 at www.scientific.net (2010) Trans Tech Publications, Switzerland doi:10.4028/www.scientific.net/msf.660-661.225
Graduate Studies and Research (GSR) This information was provided to GSR by the Program Director in parent unit Name of Degrees Offered College Department Ph.D. in Materials Science and Engineering Engineering
InFormation 2016 Mailing List Rental Opportunities MATERIALS RESEARCH SOCIETY Advancing materials. Improving the quality of life. The Materials Research Society (MRS) has come a long way since a visionary
Production of ferrite nanopowders in radiofrequency thermal plasma PhD Theses Loránd Gál Budapest, 2008 HAS Chemical Research Center Institute of Materials and Environmental Chemistry Department of Plasma
Overview of the Research Programs of School of Biomedical Engineering and Med-X Research Institute, Shanghai Jiao Tong University Mission To bridge and integrate engineering technology and medical sciences
XRF and SEM EDS Using the PDF for material identification using elemental data from XRF and SEM EDS. XRF and SEM EDS What? The Powder Diffraction File contains data on pure solid state compounds of well
Handbook of Research on Effective Project Management through the Integration of Knowledge and Innovation George Lealjamil Informagöes em Rede, Brazil Sergio Maravilhas Lopes CETAC.MEDIA - Porto and Aveiro
Pulsed laser deposition of organic materials PhD theses Gabriella Kecskeméti Department of Optics and Quantum Electronics University of Szeged Supervisor: Dr. Béla Hopp senior research fellow Department
E JAPAN PATENT OFFICE STUDY PROGRAM WIPO/IP/HR/TYO/11/INF/4 ORIGINAL:ENGLISH DATE: FEBRUARY 2011 Study Program on Human Resource Development in the Field of Industrial Property organized by the World Intellectual
UNIVERSIDADE DE SÃO PAULO Adnei Melges de Andrade Vice-President, International Relations UNIVERSIDADE DE SÃO PAULO 7 Campi Universidade de São Paulo Some figures about Brazil Total area Population GDP
Solidification, Crystallization & Glass Transition Cooling the Melt solidification Crystallization versus Formation of Glass Parameters related to the formaton of glass Effect of cooling rate Glass transition
Nanostructured Energy Conversion for Low power Energy Harvesting Devices and Beyond for High power Sun to fiber' Solar Devices Michael Oye and Nobuhiko Nobby Kobayashi Advanced Studies Laboratories and
UNR Chemistry Courses Changes to implement the UCCSN Common Course Numbering Initiative Effective beginning with Summer 2003 term Old CHEM courses (2002-2003 catalog) 100 MOLECULES AND LIFE IN THE MODERN
ACTA PHYSICA DEBRECINA XLVI, 133 (2012) GOLD AND CALCIUM ION BEAMS FOR MATERIALS RESEARCH BY THE ATOMKI ECR ION SOURCE R. Rácz 1, 2, S. Biri 1, I. Charnovych 2, S. Kökényesi 2 1 Institute of Nuclear Research
Indian Journal of Chemistry Vol. 48A, October 2009, pp. 1378-1382 Notes Effect of surface area, pore volume and particle size of P25 titania on the phase transformation of anatase to rutile K Joseph Antony
Hanover Center for Optical Technologies - HOT apl. Prof. Dr. Bernhard Roth Bernhard.Roth@hot.uni-hannover.de www.hot.uni-hannover.de Hannover, November 18 th, 2014 Hannoversches Zentrum für Optische Technologien
NANOSYSTEMS: PHYSICS, CHEMISTRY, MATHEMATICS, 2011, 2 (2), P. 76 83 UDC 538.97 MOLECULAR DYNAMICS INVESTIGATION OF DEFORMATION RESPONSE OF THIN-FILM METALLIC NANOSTRUCTURES UNDER HEATING I. S. Konovalenko
Dr. Kevin W. Bieg Senior IP Counsel at Sandia National Laboratories Email: kwbieg[at]sandia.gov Dr. Kevin Bieg is currently Senior IP Counsel at Sandia National Laboratories specializing in technical areas
STUDY AT CONTACT Office for International Students, Zhejiang Normal University Address: 688 Yingbin Avenue, Jinhua City, Zhejiang Province, 321004, P.R. China Tel: +86-579-82283146, 82283155 Fax: +86-579-82280337
Sputtered AlN Thin Films on and Electrodes for MEMS Resonators: Relationship Between Surface Quality Microstructure and Film Properties S. Mishin, D. R. Marx and B. Sylvia, Advanced Modular Sputtering,
Newsletter February 2011 The latest edition of the newsletter provides you with updated results and outcomes generated in the frame of the DIBANET project. The project will reach its half-life soon and
Vol. 93 (1997) A CTA PHYSICA POLONICA A No. 2 Proceedings of the 1st International Symposium on Scanning Probe Spectroscopy and Related Methods, Poznań 1997 NEAR FIELD OPTICAL MICROSCOPY AND SPECTROSCOPY
TOTVS S.A. Corporate Taxpayer s ID (CNPJ/MF) 53.113.791/0001-22 Corporate Registry ID (NIRE) 35.300.153.171 MINUTES OF THE BOARD OF DIRECTORS MEETING HELD ON APRIL 23, 2009 1. - DATE, TIME AND PLACE OF
Differential Scanning Calorimetry theoretical background Galina Kubyshkina Elektromaterial Lendava d.d., Slovenia Crystalline materials Typical features presence of a unit (cell), which is periodically
1. Photon Beam Damage and Charging at Solid Surfaces John H. Thomas III 1. Introduction............................. 2. Electrostatic Charging of Samples in Photoemission Experiments............................