Vitreous Materials Lab. LaMaV DEMa - UFSCar lamav.weebly.com

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1 Vitreous Materials Lab. LaMaV DEMa - UFSCar lamav.weebly.com..

2 Desafios... Adversidades despertam capacidades que, em outras circunstâncias, teriam ficado adormecidas... Estranhamente o Homem somente progride perante um ambiente desafiador. Se consegue, passo a passo, superar seus desafios, fica feliz e com mais energia e vontade de tentar novas soluções e novos projetos. Fica divertido!

3 Edgar Dutra Zanotto Center For Research, Technology and Education in Vitreous Materials CeRTEV s activities will focus on multidisciplinary, relevant glass science, useful technology and efficient education and outreach!

4 SCOPE CeRTEV will research and develop or improve glasses and glass-ceramics presenting application-relevant functionalities, such as high mechanical strength and electrical conductivity, biological, optical or catalytic activity, and/or combinations of these properties. A fundamental understanding of these properties will be sought on the basis of the structural organization of these materials on different length scales. We will apply state-of-the art NMR, EPR, EXAFS and vibrational spectroscopy to characterize the local and medium-range order, as well as the full resolution range of optical and electron microscopies, XRD and microanalyses for elucidating nano- and microstructures. This comprehensive experimental approach will be complemented by molecular dynamics simulations. Using this experimental modeling strategy, we will further seek a fundamental understanding of glass sintering and crystallization in terms of the mechanisms, thermodynamics and kinetics of viscous flow, as well as crystal nucleation and growth, enabling us to exercise control of these processes by developing appropriate formation and thermal treatment protocols. In a concerted effort, the participating laboratories will jointly investigate a number of important benchmark systems, which are deemed particularly promising for applications either as structural materials (e.g., dental and armor glass-ceramics), bio active glasses and glass-ceramics, glass-ceramics for architecture and construction, optical materials (e.g., laser glasses), materials for electrochemical energy storage devices (electrolytes, high-temperature seals), and catalytically active systems.

5 6 7 1

6 Glass-ceramics Dental Construction Gratings

7 Coordinador Tech & Innovation Director Coordinator Education and Outreach Manager 2 secretaries 1 informatics Vice-director 14 professors FQV ~30 collaborators ~60 students One of the largest academic glass R & D of this planet!

8 The Team 14 Leandro Innocentini L. de Faria, Manager, Scientometry STRUCTURE Hellmut Eckert Structure, NMR José Fabián Schneider Structure, NMR Claudio José Magon EPR Jose Pedro Donoso Gonzalez EPR Valmor Roberto Mastelaro EXAFS, XRD and laser crystallization Paulo Sergio Pizani Raman spectroscopy José Pedro Rino Molecular dynamics simulation CRYSTALLIZATION + Thermal, Mechanical, Bio and Electrical properties Edgar Dutra Zanotto Nucleation, growth, crystallization, glass-ceramics Marcello Rubens Barsi Andreeta Laser crystallization, crystal growth techniques Ana Cândida Martins Rodrigues Electrical properties, ionic conducting glass & GC Oscar Peitl Bio active glasses and glass-ceramics Eduardo Bellini Ferreira Nucleation, growth, crystallization, glass-ceramics OPTICAL Properties Andrea S. S. de Camargo Alvarez Bernardez Optical properties Marcelo Nalin Optical and chemical properties

9 Ranking in the world (2013) A June 2013 search on the SCOPUS database for the number of published articles with relevant keywords indicates that some of CeRTEV s faculty rank: first in the world with the keywords glass* and NMR*, first with glass* and nucleation, second with glass* and crystal growth, fourth with glass* and crystallization, 26 th with bio* and glass-ceramic*, 28 th with glass* and sinter*, 31 th with glass-ceramic*, 43 th with glass* and EXAFS.

10 Scientific papers - Ranking Russian Academy of Sciences(1,111 glass papers) Kyoto University(849) CeRTEV = USP(370)+ UNESP-(225)+ UFSCar (181) = 776 Shanghai Institute of Optics and Fine Mechanics (759) CNRS Centre National de la Recherche Scientifique(735) Tokyo Institute of Technology(624) University of Cambridge(574) University of Tokyo(553) Osaka University(550) The State Scientific-Research Institute of Glass(550) Friedrich Schiller Universität Jena(479) Universite Pierre et Marie Curie(471) Chinese Academy of Sciences(457) Corning Incorporated(445) Alcatel-Lucent Bell Labs(432) Pennsylvania State University(426) Argonne National Laboratory(423) Massachusetts Institute of Technology(412) S.I. Vavilov State Optical Institute(393) National Institute of Advanced Industrial Science and Technology(383) Universite de Rennes 1(375) 22th USP(370) Consiglio Nazionale delle Ricerche(366) Universite Montpellier 2 Sciences et Techniques(363) Indian Institute of Science(361) Hokkaido University(358) University of Sheffield(351) Alfred University(343) Kyushu University(341) SCOPUS search glass*+ vitreous+ amorphous+ non-crystalline - ( metal* and polymer*)

11 Ranking Shanghai Institute of Optics and Fine Mechanics CAS(201) Russian Academy of Sciences(177) CeRTEV = USP(67)+UFSCar(48)+UNESP(43) = 158 Ningbo University(152) Graduate University of Chinese Academy of Sciences(142) CNRS Centre National de la Recherche Scientifique(137) South China University of Technology(107) Wuhan University of Technology(104) Chinese Academy of Sciences(101) Universite de Rennes 1(96) University of Tokyo(94) Friedrich Schiller Universität Jena(93) Harbin Institute of Technology(91) Sri Venkateswara University(85) Universite Pierre et Marie Curie(82) Kyoto University(82) Tongji University(82) National Research Center, Cairo(79) University of Pardubice(78) Sichuan University(77) Consiglio Nazionale delle Ricerche(75) Tohoku University(72) Osaka University(72) East China University of Science and Technology(71) Pacific Northwest National Laboratory(71) Tokyo Institute of Technology(71) Universität Erlangen-Nürnberg(69) Shanghai Institute of Ceramics Chinese Academy of Sciences(69) Tsinghua University(68) 30th Universidade de Sao Paulo(67) Corning Incorporated(62) glass*+ vitreous+ amorphous+ non-crystalline - (metal* and polymer*)

12 Budget ~US$ 20 million from Fapesp for equipament, travel, materials and supplies spread over 11 years (excluding salaries and students grants) But Fapesp expects us to get complementary funding from other government agencies and industries...

13 International Advisory Board GOMD meeting, San Diego, June 2013 Fran Serbena, Dick Brow, Bruce Aitken and Ed Zanotto. Credit ACerS

14 ICG, Prague, July 2013

15 Our philosophy To pursue relevant research topics with well defined objectives. To carry out long term basic research. To reach and expand the frontiers of knowledge in each one of the chosen subjects. Maximize planning, calculation, simulation, literature search and study to optimize experimentation. To publish original, accurate articles that push the frontiers of knowledge. Quality, and not quantity, is our goal. Technological research via industrial interest that may lead to patents and eventually innovation

16 New glass research center in Brazil 2 universities, 14 profs, 11 years, $20 M one big impact! Published on July 8th, 2013 by Eileen De Guire The American Ceramic Society

17 Jena 1982 Russel Grenoble 1984 Souquet IVSO Inst Fokin Univ. Rostock 2001 Schmelzer Erlangen 2003 Boccaccini TC7 (1984) IMI (2004) LaMaV s International NETWORK Bio glass and GC ~15 institutions L. Hench, Boccacini J. Mauro Corning J. Du Univ. Texas Starting in 2014 Rocherullè & Rouxel Rennes J. Lumeau Fresnel CeRTEV 2012

18 Selected papers published in 2013 Structure of vitreous materials Ren, J., Eckert, H., Anion distribution in superionic Ag3PO4-AgI glasses revealed by dipolar solid-state NMR, Journal of Physical Chemistry C 117 (47), pp , Schneider, J., Tsuchida, J., Eckert, H., Cation size effects in mixed-ion metaphosphate glasses: Structural characterization by multinuclear solid state NMR spectroscopy, Physical Chemistry Chemical Physics 15 (34), pp ,2013. DQ-DRENAR: a New NMR Technique to Measure Site-Resolved Magnetic Dipole-Dipole Interactions in Multispin-1/2 Systems. Theory and Applications to Phosphate Materials, Ren,J.; Eckert, H. J. Chem. Phys. 138, /1-16 (2013). Sol-Gel preparation and structural characterization of mesoporous Al 2 O 3 -SiO 2 glasses, Ren, J.; Zhang, L.; Eckert, H. Sol Gel Sci Technol. 2014, in press. Medium range order in sol-gel prepared Al 2 O 3 -SiO 2 glasses: New results from solid State NMR, Ren, J.; Zhang, L; Eckert, H. J. Phys. Chem. C 2014, in press. Pontes, D.S.L.; Pontes, F.M.; da Silva, L.F.; Chiquito, A.J.; Pizani, P.S.; Longo, E. Influence of a cosubstituted A-site on structural characteristics and ferroelectricity of (Pb, Ba, Ca)TiO3 complex perovskites: analysis of local-, medium- and long-range order. Journal of Sol-Gel Sci Technology, pp

19 Crystal Nucleation, Growth and Overall Crystallization Fokin, V.M.; Reis, R.M.C.V.; Abyzov, A.S.; Chinaglia, C.R.; Zanotto, E.D. Nonstoichiometric crystallization of lithium metasilicate-calcium metasilicate glasses. Part 1 - Crystal nucleation and growth rates. Journal of Non-Crystalline Solids 362 (1), pp Fokin, V.M.; Reis, R.M.C.V.; Abyzov, A.S.; Chinaglia, C.R.; Schmelzer, J.W.P.; Zanotto, E.D. Nonstoichiometric crystallization of lithium metasilicate-calcium metasilicate glasses. Part 2 - Effect of the residual liquid. Journal of Non-Crystalline Solids 379, pp Cabral, A.A.; Ferreira, E.B.; Villas-Boas, M.O.C.; Zanotto, E.D. On the determination of the concentration of crystal nuclei in glasses by DSC. Journal of the American Ceramic Society 96 (9), pp Dyamant, I.; Abyzov, A.S.; Fokin, V.M.; Zanotto, E.D.; Lumeau, J.; Glebova, L.N.; Glebov, L.B. Crystal nucleation and growth kinetics of NaF in photo-thermo-refractive glass. Journal of Non- Crystalline Solids 378, pp Zanotto, E.D. Glass Crystallization Research - A 36-Year Retrospective. Part I, Fundamental Studies. International Journal of Applied Glass Science 4 (2), pp Rodrigues, A.M.; Narváez-Semanate, J.L.; Cabral, A.A.; Rodrigues, A.C.M. Determination of crystallization kinetics parameters of a Li1.5Al0.5Ge1.5(PO4)3 (LAGP) glass by differential scanning calorimetry. Materials Research 16 (4) Jasinevicius, R.G.; Duduch, J.G.; Pizani, P.S. Evidence of crystallographic orientation dependence upon cyclic microindentation-induced recrystallization within amorphous surface layer. Materials Letters 94, pp Almeida, J.M.P., Tribuzi, V., Fonseca, R.D., Otuka, A.J.G., Ferreira, P.H.D., Mastelaro, V.R., Brajato, P., Hernandes, A.C., Dev, A., Voss, T., Correa, D.S., Mendonca, C.R., Femtosecond laser processing of glassy and polymeric matrices containing metals and semiconductor nanostructures, Optical Materials 35 (12), pp , 2013.

20 Bioactive glasses and glass-ceramics Souza, M.T.; Crovace, M.C.; Schröder, C.; Eckert, H.; Peitl, O.; Zanotto, E.D. Effect of magnesium ion incorporation on the thermal stability, dissolution behavior and bioactivity in Bioglass-derived glasses. Journal of Non-Crystalline Solids 382, pp Renno, A.C.M.; Bossini, P.S.; Crovace, M.C.; Rodrigues, A.C.M.; Zanotto, E.D.; Parizotto, N.A. Characterization and in vivo biological performance of biosilicate. BioMed Research International 2013, art. no Renno, A.C.M.; Nejadnik, M.R.; Van De Watering, F.C.J.; Crovace, M.C.; Zanotto, E.D.; Hoefnagels, J.P.M.; Wolke, J.G.C.; Jansen, J.A.; Van Den Beucken, J.J.J.P. Incorporation of bioactive glass in calcium phosphate cement: Material characterization and in vitro degradation. Journal of Biomedical Materials Research - Part A 101 A (8), pp Desimone, D.; Li, W.; Roether, J.A.; Schubert, D.W.; Crovace, M.C.; Rodrigues, A.C.M.; Zanotto, E.D.; Boccaccini, A.R. Biosilicate -gelatine bone scaffolds by the foam replica technique: Development and characterization. Science and Technology of Advanced Materials 14 (4), art. no Pinto, K.N.Z.; Tim, C.R.; Crovace, M.C.; Matsumoto, M.A.; Parizotto, N.A.; Zanotto, E.D.; Peitl, O.; Rennó, A.C.M. Effects of biosilicate scaffolds and low-level laser therapy on the process of bone healing. Photomedicine and Laser Surgery 31 (6), pp Renno, A.C.M.; Van De Watering, F.C.J.; Nejadnik, M.R.; Crovace, M.C.; Zanotto, E.D.; Wolke, J.G.C.; Jansen, J.A.; Van Den Beucken, J.J.J.P. Incorporation of bioactive glass in calcium phosphate cement: An evaluation. Acta Biomaterialia 9 (3), pp Kido, H.W.; Oliveira, P.; Parizotto, N.A.; Crovace, M.C.; Zanotto, E.D.; Peitl-Filho, O.; Fernandes, K.P.S.; Mesquita- Ferrari, R.A.; Ribeiro, D.A.; Renno, A.C.M. Histopathological, cytotoxicity and genotoxicity evaluation of Biosilicate glassceramic scaffolds. Journal of Biomedical Materials Research - Part A 101 A (3), pp Siqueira, R.L.; Zanotto, E.D. The influence of phosphorus precursors on the synthesis and bioactivity of SiO2-CaO-P2O5 sol-gel glasses and glass-ceramics. Journal of Materials Science: Materials in Medicine 24 (2), pp Daguano, J.K.M.F., Rogero, S.O.,Crovace, M.C., Peitl, O., Strecker, K.,Dos Santos, C., Bioactivity and cytotoxicity of glass and glass-ceramics based on the 3CaO P2O5-SiO2-MgO system, ournal of Materials Science: Materials in Medicine 24 (9), pp , Brandão, S.M., Schellini, S.A.,Padovani, C.R., Peitl, O., Hashimoto, E., Análise da biocompatibilidade de cones de biovidro e biovitrocerâmico (Biosilicato ) em cavidade eviscerada de coelho [Biocompatibility analisys of Bioglass 45S5

21 Other types of glass-ceramics Zanotto, E.D. Glass Crystallization Research - A 36-Year Retrospective. Part II, Methods of Study and Glass- Ceramics. International Journal of Applied Glass Science 4 (2), pp Soares, V.O.; Peitl, O.; Zanotto, E.D. New sintered Li2O - Al2O3- SiO2 ultra-low expansion glass-ceramic. Journal of the American Ceramic Society 96 (4), pp Kjeldsen, J.; Yue, Y.; Bragatto, C.B.; Rodrigues, A.C.M. Electronic conductivity of vanadium-tellurite glassceramics. Journal of Non-Crystalline Solids 378, pp

22 Optical Properties De Queiroz, T.B., Botelho, M.B.S., De Boni, L., Eckert, H., De Camargo, A.S.S., Strategies for reducing dye aggregation in luminescent host-guest systems: Rhodamine 6G incorporated in new mesoporous sol-gel hosts, Journal of Applied Physics 113 (11), art. no , De Queiroz, T.B., Botelho, M.B.S., Fernández-Hernández, J.M., Eckert, H., Albuquerque, R.Q., De Camargo, A.S.S., New luminescent hostguest system based on an iridium(iii) complex: Design, synthesis, and theoretical-experimental spectroscopic characterization, Journal of Physical Chemistry C 117 (6), pp , Santos, W.Q., De Camargo, A.S.S.,Wu, D., Silva, W.F., Zhang, L., Jacinto, C., Cooperative upconversion, radiation trapping, and selfquenching effects in highly Yb3+-doped oxyfluoride glasses, Science of Advanced Materials 5 (12), pp , 2013.

23 Optical Properties Manzani, D.; Almeida, J.M.P.; Napoli, M.; De Boni, L.; Nalin, M.; Afonso, C.R.M.; Ribeiro, S.J.L.; Mendonça, C.R. Nonlinear optical properties of tungsten lead-pyrophosphate glasses containing metallic copper Nanoparticles. Plasmonics 8 (4), pp Valle, P.S.; Montesso, M.; Nalin, M.; Donoso, J.P.; Silva, I.D.A.; Magon, C.J. Influence of silver precursors on growth of metallic nanoparticles in heavy metal oxide glasses. Quimica Nova 36 (7), pp , Avila, L.F.; Almeida, J.M.P.; Gonçalves, M.S.; Valle, P.S.; Nalin, M.; Mendonça, C.R.; Cescato, L. Design and fabrication of two-dimensional hexagonal photonic crystals with a linear waveguide in erbium doped GeO2-Bi2O 3-PbO-TiO2 glasses. Proceedings of SPIE - The International Society for Optical Engineering 8776, art. no L, Avila, L.F.; Nalin, M.; Cescato, L. Self diffraction holographic techniques for investigation of photosensitive materials. Proceedings of SPIE - The International Society for Optical Engineering 8776, art. no G, 2013.

24 Book Chapters Glasses on the Nanoscale, Eckert, H. Ribeiro, S.J.L.; Santagneli, S. H.; Nalin, M.; Poirier, G.; Messaddeq,Y. Handbook of Nanomaterials, R. Vajtai, ed. Springer- Verlag Berlin, (2013). Advanced NMR Spectroscopy of Glasses (Review), Eckert, H. to be published in Modern Glass Characterization, M. Affatigato, ed., John Wiley and Sons Bioactive Glass-Ceramics for Load-Bearing Applications - Oscar Peitl, Edgar D Zanotto, Francisco C Serbena and Larry L Hench) - An Introduction to Bioceramics, 2nd Edition Edited by: L. L. Hench, ed., World Scientific (2013) Zanotto E.D. et al- DSC techniques for the study of glass crystallization, in Glassy, Amorphous and Nano-Crystalline Materials ed. J. Sestak, J. Mares, P. Hubik, Springer (2013) Nucleation, Growth and Overall Crystallization, Zanotto, E.D et al., to be published in Glass Encyclopedia, P. Richet, ed., John Wiley and Sons 2014 Stress-induced Pore Formation and Phase Selection in a Crystallizing Stretched Glass, Fokin V.M., Karamanov A., Abyzov A.S, Schmelzer J. W.P., Zanotto E.D, Chapt.8 to be published in Glass: Selected Properties and Crystallization, J. Schmelzer, ed., De Gruyter 2014

25 Planned books Crystals in glass Wiley, Oct Experimental techniques for characterization glass structure and crystallization - start 2014 (CeRTEV team) Fundamentals of glass crystallization start 2014 (Zanotto, Fokin & Schmelzer)

26 Internationalization Visiting professors in 2013 Vladimir Fokin St. Petersburg, Russia, one year Jean Louis Souquet- Grenoble, France, 6 months Juern Schmelzer, Rostok, Germany, 1 week Alexander Priven, Korea, 1 week Post-docs and students 2 undergrads from the USA 2 MSc students from Colombia 1PhD student from Iran (sanduiche) 2 post-docs from India

27 Organization of Congresses, etc... Internal workshops yearly starting 2013 Invention & Innovation Sept Sol-gel workshop Oct Rede BioNetec Meetings yearly starting Nov X Brazilian Symposium on Glass Oct São Paulo School on Glasses and CG Feb Education and Outreach about glass 2015 Flow and Fracture in Glass 2016 (?) XI Brazilian Symposium on Glass 2017 Glass frontiers jointly with the World Congress of Ceramics, Iguassu Falls

28 Invited talks 2013 Hellmut Eckert A homonuclear version of REDOR for recoupling dipolar interactions in multi-spin systems: Applications to inorganic phosphorus clusters and networks, International Symposium of Magnetic Resonance (ISMAR), Rio de Janeiro, May 2013.(Invited) Introduction into Solid State NMR Spectroscopy, workshop, SBQ meeting, Aguas Lindoias, May (Invited) Modern Solid State NMR Strategies for Studying Structural Transformations in Non-Siliceous Sol-Gel Glass Systems, SBPMAT, Campos de Jordão, September 2013.(Invited) Ed Zanotto Iron Phosphate Glasses and Melts - A US-Brazil Research Collaboration on Novel Materials for Nuclear Waste Remediation - 37th International Conference & Exposition on Advanced Ceramics & Composites, Daytona Beach, USA, Jan , 2013 (delivered by R.K. Brow) (Invited) The relationship between molecular structure and nucleation mechanism in glass, ICG 2013, Prague Czech Republic, July (Invited) LaMaV/ UFSCar - 36 anos de ensino, ciência e inovação - II Workshop UEPG, Ponta Grossa, PR, August 13-14, 2013 (Opening Talk) LaMaV UFSCar / 36 anos interagindo com empresas, 22 Encontro Técnico da ABIVIDRO, São Paulo, Oct. 2, 2013 (Invited) Advances in glass crystallization and glass-ceramics- 19th Larson Workshop on Crystallization Technology, Indianapolis, USA, October 5-10, 2013 (Invited) 36 years of science, technology and art - Magna lecture - Admiral Álvaro Alberto Award cerimony - CNPq, Brasília, October 23, 2013 (Invited) Vitrocerâmicas - passado, presente e futuro - Workshop CEFET, São Luiz, MA, 3 Nov (Invited) LaMaV - 3,5 décadas de invenções. Aprendendo com os erros - I EEAEM, UFSCar, 28 Nov (Invited) J. P. Rino

29 Editorship of periodicals -Solid State Nuclear Magnetic Resonance Hellmut Eckert Editor -Journal of Non-Crystalline Solids Edgar D. Zanotto - Editor -Int. Journal of Applied Glass Science, USA- IAB -Materials Research, Brazil - IAB -Ceramica y Vidrio, Spain - IAB -Cerâmica, Brazil IAB -The Open Crystallography Journal Marcello R. Barsi Andreeta - Associate Editor

30 Technology Coordinator Prof. Eduardo B. Ferreira, EESC- USP

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32 O-I TAB meeting, Perrysburg, USA, March 2014 Review and make recommendations on O-I s technology portfoglio EDZ s talk about CeRTEV

33 Glassman South America, March h30 Opening Show: Glassman South America Lucien Belmonte / Greg Morris Abividro 9h40 Cleanfire GC Edson E. Basilio Air Products 10h Heat Recovery Fabio Guastini Area Impianti 10h20 New cost efficient solution for glass moulds Sergio Simones Hoganas 10h40 Hot Bottom Repair Cristina Sanches Fosbel 11h New Material for Glass Melting Eletrodes Elisio Ferreira Neto Plansee 11h20 Defeitos no vidro vs. refratários Marcelo Guerra SEFPRO 1h20 An introduction to the FleXinspect Michael G. Rentschler Buch Emhart Glass 1h40 Glass Sand Manoel J. B. Cordova Mineração Jundu 2h Inovation on glass packaging Daniel Amaral OI 2h20 Soda-ash Tarcisio Neves /Walter Shultz (ANSAC) 2h40 Brazilian Climate Changes Stefan David Abividro 3h Oxygen Enhanced Nox Reduction Abilio Tasca Praxair White 3h20 Quality Control of Cullet Marcos Gibim Verallia CETEV h40 Made in Germany for Glass People K. Rudolph GPS - Verallia 10h Speedline - Evolution in IS machines Rainer Heidemann Heye International 10h20 Brazilian Law on Wastes Ana Paula Bernardes Abividro 10h40 CeRTEV- Center for Research, Technology and Education in Vitreous Materials Edgar Zanotto CeRTEV/UFSCar

34 Corning Inc. Research Summit, Corning, USA June 2014 EDZ talk

35 Vitrovita & DMC, Brazil biog and CG CTA, Brazil Armor GC AGY, USA special fibers LaMaV industry net Optigrate, USA PTRG NSG, Japan viscous flow Corning, USA GR Status & trends Ivoclar? Dental GC Neogres? sintered G & GC Saxon Glass? chem. tough

36 Current projects with companies Ongoing GC Armors, CTA, Brazil Bioactive GC for dental and medical use Vitrovita / DMC, Brazil Photo-thermo-crystallization PTRG OptiGrate, USA Viscous flow and crystal growth in glasses, NSG, Japan Special glass fibers, AGY, USA Glass containers, O-I, USA In negociation Dental GC - Ivoclar, Liechtenstein (NDA signed) LGLT GC Phillips, Netherlands (testing) Chemically toughened glass- Saxon Glass, USA (neg.) Sintered GC / GC tiles - UNIGRES, Brazil (negociation)

37 Example - Bio G and GC technologies being developed Pós Grânulos Prótese Ocular Implantes Recobertos Manta Flexível Prótese de Ouvido Médio Scaffolds

38 Recent CeRTEV Patents Leo et al Armor transparent GC (2013) Marina et al New bioactive fiberizable GC (2013) Clever et al Bioactive coating for Ti (2014)- deposited Marina et al Fiber drawing machine (2014) - Zanotto et al.- REFORMIX Glass - Software for formulation of glass compositions having combined properties (2014) EDZ - The best putter in the world (2014)!

39 Education and Outreach Discussion group / Brazilian glass researchers and engineers active Kit for demonstration of optical phenomena for undergraduate or high school students - ready Colored glass kits - ready Web-site with educational videos - ready Virtual museum of glass (under construction)

40 EDUCATION AND OUTREACH Creation of the first technical course in South America Being aware of the lack of professional training course dedicated to the glass industry, with the partnership of Paula Souza Center, we proposed to create a technical course to provide trained professionals for the glass industry.

41 EDUCATION AND OUTREACH What we have done so far: First meeting: presentation of our project CeRTEV and Education and outreach project to ABIVIDRO Second Meeting: Joint meeting with ABIVIDRO and Paula Souza Center - ABIVIDRO confirmed to Paula Souza Center the urgent need for professional qualification, specially at technical level, to the glass industry. Paula Souza Center asked to describe all technical positions (cargos técnicos) Third meeting: we described the technical positions for the glass (flat and hollow ) fabrication, glass transformation, and also glass specification for construction Next step: a memorandum of agreement between ABIVIDRO, Paula Souza Center and CeRTEV, aiming the consolidation of this new technical course must be prepared and signed

42 EDUCATION AND OUTREACH Already done: -ACIEPE: Engineers and Scientists of the Future - UFSCar program aiming to demonstrate to elementary school students of São Carlos the basis of scientific thinking, aiming to attract them to the field of engineering and hard sciences. -Meeting and agreement with the Secretary of Science and Technology of São Carlos: participation in the program Science at School Same program with Araraquara -School visits to LaMaV glass melting, short talks and video demonstrations to hundreds of high school students from all over the State of São Paulo (UFSCar open day and more )

43 Plans for Offer the first class of the Paula Souza Center technical course in Produce a video-course for architects about the fundamentals of glasses and its specifications for architectural building. -Create a collection of demonstrational functional glasses such as: electrically conducting glass, fotosensitive (PTRG) glass, invisible gass, optical fiber, thermal strain in glass, metallic glass, sugar glass How to use these functional glasses outside our classroom? Physical Museum planed for 2015 São Paulo (International) School of Structure, Crystallization and Properties of Glasses planed for 2015

44 Aknowledgements São Paulo Research Foundation FAPESP Grant # 2013/

45 LaMaV 37 years of equilibrium between science & technology Edgar D. Zanotto

46 LaMaV s mission TO EDUCATE excellent engineers and researchers via good research and teaching TO EXPAND the frontiers of knowledge / via basic research / excellent publications! TO ASSIST companies beyond their expectations / consulting + applied research by TO INNOVATE in the field of glass and related materials / via technological research

47 Sheffield 1979 P. James* Jena 1982 C. Russel Grenoble 1984 J. L. Souquet TC 7 / ICG 1985 Arizona 1987 M. Weinberg* Florida 1994 L. Hench Mastelaro/ Sneid, IFSC/ USP P. C. Soares, UFPR A. A. Cabral, CEFET, MA E.B. Ferreira, EESC J. Daguano- UFABC F. Serbena e V.Soares - UEPG La MaV NETWORK Bio glass and GC ~15 instituições Optigrade, NSG, AGY, Vitrovita,Saxon, CT Cyted/ CNPq, 1998 ICV - A. Duran U. Medellin C. Paucar IVSO Institute 1996, V. M. Fokin CNEA, 1998 M. Prado BAM, 1999 R. Muller Bulg. Acad. Sci. I. Avramov 2001 Univ. Rostock J. Schmelzer 200 ADEMAT, 2003 IC - A. Boccaccini Max Plank A. Pyzalla IMI 2004 Clausthal J. Deubener 2005 CREOL/ UCF L. Glebov 2005 UMR R. Brow 2005 Douhausie J. Zwanziger 2005

48 Bio glass and GC ~15 institutions Daguano UFABC LaMaV s Brazilian NETWORK H.E., Mastelaro & Schneider, Magon IFSC Ferreira EESC Soares PUC-PR Cabral CEFET Serbena & Oliveira UEPG e UEMA CeRTEV 2012

49 TEAM ANNUAL BUDGET Permanent E.D. Zanotto / Crystallization & thermo-mechanical properties O. Peitl - Bio glasses/ Chemical and thermo-mechanical properties A.C.M. Rodrigues / Electrical properties 1 technician (Zé) US$ 430,000 Temporary 4 post docs 9 PhD students 2 MSc students 10 Internship students 1 secretary ,000 Materials & Supplies ,000 US$ 1,030, TOTAL NORMALIZED by PPP (1.0147/0.5336) ~2,000,000

50 Muito obrigado! Thank you very much! Vielen Dank! Dziękuję! Hjärtligt tack! Muchas gracias! Merci beaucoup! Grazie mille!

51 University Ranking glass*+vitreous+amorphous+non-crystalline > Tohoku University (1,660) + Tohoku University(1,287 ) Inoue s > Kyoto University(1,265) > CeRTEV: USP (476) + UNESP (278) + UFSCar (275) = 1029 > Osaka University(938) > Tokyo Institute of Technology(901) > University of Cambridge(855) > University of Tokyo(736) > Massachusetts Institute of Technology(686) > Friedrich Schiller Universität Jena(601) > Pennsylvania State University(600) > Universite Pierre et Marie Curie(572) > Tsinghua University(571) > University of Sheffield(525) > Stanford University(516) > California Institute of Technology(488) > MoskovskijGosudarstvennyjUniversitet(483) > Universite de Rennes 1(480) > USP (476) > Imperial College London(473) > Kyushu University(460) > Universite Montpellier 2 Sciences et Techniques(441) > Hokkaido University(433) > Nagoya University(430) > University of Science and Technology Beijing(403) > Wuhan University of Technology(403) > Alfred University(401)