ORG CHEM II LAB(MAJOR S) IR Problem Set 1 ANSWER KEY
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1 ORG CHEM II LAB(MAJOR S) KELLY IR Problem Set 1 ANSWER KEY 1. K Allyl alcohol The allyl alcohol OH stretch is indicated by the large, broad absorption between cm -1. The double bond is indicated by the C-H stretch in the region just to the left of 3,000 cm -1. This can be differentiated from benzyl alcohol by the small C=C stretch at about 1650 cm -1. Note that the C-O stretch absorption at about 1025 cm -1 indicates a 1 alcohol. C-C stretch Olefinic C-H stretch CH 2 bend Aliphatic C-H stretch C-H OOP 2. N. Cyclooctene Cyclooctene has an ir spectrum very similar to 1-heptene, but can be differentiated from it by close examination of the spectrum. Both cyclooctene and 1-heptene have very simple spectra, with olefinic C-H stretch absorptions above 3,000 cm -1. Both also have very small C=C stretch absorptions about 1650 cm -1. Cyclohexene has a fairly strong CH 2 scissoring bend at about 1470cm -1. It does not, however, have a CH 3 symmetric umbrella bend at 1375cm -1. There is a weak absorption (probably part of the fingerprint) at about 1350cm -1, but this is too low to be the CH 3 bend. C-C stretch CH 2 bend Olefinic C-H stretch C-H OOP Aliphatic C-H stretch
2 3. D Heptaldehyde The intense carbonyl C=O stretch peak at ~1725 cm -1 suggests either an aldehyde, or possibly a ketone (although it is a little higher frequency than a standard ketone). The aldehyde is indicated by the two aldehyde C-H stretch absorptions which appear at 2750 & 2850 cm -1. Note that the peak at 2850 cm -1 appears as a shoulder on the much more intense absorption corresponding to the symmetric CH 2 stretching vibration. Aldehyde C-H Stretch CH 2 Bending Aldehyde C=O stretch Aliphatic C-H stretching 4. M Benzyl Alcohol Note the broad absorption and the olefinic C-H stretch absorptions. This spectrum can be differentiated from that for allyl alcohol by observing the combination and overtone bands from cm -1, which are indicative of a monosubstituted benzene. In addition the C=C ring stretch at about cm -1 indicate that it is an aromatic ring. C-C stretch Aromatic ring breath Aromatic C-H stretch C-H OOP
3 5 L Butyl acetate Note the presence of a C=O stretch at about cm -1. This would tend to indicate the possibility of an ester functional group, or possibly a strained ring ketone. The broad and intense C-O stretch absorption at about 1250cm -1 is a strong indicator of an ester group. This band is the C-O stretch corresponding to the bond of the ester oxygen and the carbonyl carbon. In addition, the C-O stretch at about 1050cm -1 is due to the other C-O stretch to a 1 carbon. C-O stretch 1 Aliphatic C-H stretch C-O stretch to carbonyl carbon C=O stretch 6 B 3-Pentanone Note the presence of a C=O stretch at about cm -1. This would tend to indicate the possibility of an ketone, aldehyde, or possibly a conjugated ester. There are no absorptions at 2850 and 2750cm -1 which would correspond to the aldehyde C-H stretch, thus it is not likely to be an aldehyde. There are no olefinic C-H stretch absorption bands above 3000cm -1, nor are there any C=C stretch absorptions around 1600 to 1650cm -1. Thus it is not likely a conjugated ester (also note the lack of strong C-O stretch absorptions at 1250cm -1 in the ester). The compound is likely a ketone. C=O stretch
4 7. F Propanoic Acid The broad O-H absorption from 2400 to 3400cm -1 is a dead giveaway for a carboxylic acid. Note also the relatively broad C=O at about 1710cm -1 and the C-O stretch at 1250cm -1. Broad of acid dimer C-H stretch C-O stretch C=O stretch 8 H 1-Butanol Note the broad alcohol at cm -1. More importantly, note the 1 alcohol C- O stretch at ~1050cm I Cyclohexane Note the simplicity of the spectra, only C-H stretch and bend absorptions. The most important aspect of this spectrum is what is NOT present. Note the absence of a CH 3 bend at 1375 cm- 1. This would suggest a ring structure. NO CH 3 SYMMETRIC BEND CH 2 Scissoring bend C-H stretch
5 10. E 2-Butanol Note the broad alcohol at cm -1. More importantly, note the 2 alcohol C-O stretch at ~1100cm -1. C-O Stretch (2 ) 11. C 1-Hexene 1-Hexene has an ir spectrum very similar to cyclooctene, but can be differentiated from it by close examination of the spectrum. 1-Hexene has a CH 3 symmetric umbrella bend at 1375cm -1. Also note if you will, that the unsymmetric double bond C=C stretch of 1-heptene is more intense than the symmetric C=C stretch in cyclooctene. C=C stretch CH 3 bend Olefinic C-H stretch 12. J 2-Methyl-2-butanol Note the broad alcohol at cm -1. More importantly, note the 3 alcohol C-O stretch at ~1150cm -1. C-O Stretch (3 )
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