CHAPTER 7. Empirical Formulas


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1 CHAPTER 7 Empirical Formulas Suppose you analyze an unknown compound that is a white powder and find that it is composed of 36.5% sodium, 38.1% oxygen, and 25.4% sulfur. You can use those percentages to determine the mole ratios among sodium, sulfur, and oxygen and write a formula for the compound. To begin, the mass percentages of each element can be interpreted as grams of element per 100 grams of compound. To make things simpler, you can assume you have a 100 g sample of the unknown compound. The unknown compound contains 36.5% sodium by mass. Therefore g of the compound would contain 36.5 g of sodium. You already know how to convert mass of a substance into number of moles, so you can calculate the number of moles of sodium in 36.5 g. After you find the number of moles of each element, you can look for a simple ratio among the elements and use this ratio of elements to write a formula for the compound. The chemical formula obtained from the mass percentages is in the simplest form for that compound. The mole ratios for each element, which you determined from the analytical data given, are reduced to the smallest whole numbers. This simplest formula is also called the empirical formula. The actual formula for the compound could be a multiple of the empirical formula. For instance, suppose you analyze a compound and find that it is composed of 40.0% carbon, 6.7% hydrogen, and 53.3% oxygen. If you determine the formula for this compound based only on the analytical data, you will determine the formula to be CH 2 O. There are, however, other possibilities for the formula. It could be C 2 H 4 O 2 and still have the same percentage composition. In fact, it could be any multiple of CH 2 O. It is possible to convert from the empirical formula to the actual chemical formula for the compound as long as the molar mass of the compound is known. Look again at the CH 2 O example. If the true compound were CH 2 O, it would have a molar mass of g/mol. If you do more tests on the unknown compound and find that its molar mass is 60.06, you know that CH 2 O cannot be its true identity. The molar mass is twice the molar mass of CH 2 O. Therefore, you know that the true chemical formula must be twice the empirical formula, (CH 2 O) 2, or C 2 H 4 O 2. Any correct molecular formula can be determined from an empirical formula and a molar mass in this same way. 1 of 11
2 General Plan for Determining Empirical Formulas and Molecular Formulas 1 Percentage of element expressed as grams of element per 100 g unknown Convert using the molar mass of each element. 2 Amount of each element per 100 g of unknown Use the amount of the leastabundant element to calculate the simplest wholenumber ratio among the elements. 4 Empirical formula of the compound Convert using the experimental molar mass of the unknown and the molar mass of the simplest formula. The calculated ratio is the simplest formula. 3 Calculated wholenumber ratio among the elements 5 Molecular formula of the compound SAMPLE PROBLEM 1 Determine the empirical formula for an unknown compound composed of 36.5% sodium, 38.1% oxygen, and 25.4% sulfur by mass. SOLUTION 1. ANALYZE What is given in the problem? What are you asked to find? the percentage composition of the compound the empirical formula for the compound 2 of 11
3 Items The percentage composition of the unknown substance 2. PLAN What steps are needed to calculate the amount in moles of each element per g of unknown? What steps are needed to determine the wholenumber mole ratio of the elements in the unknown (the simplest formula)? Data 36.5% sodium 38.1% oxygen 25.4% sulfur The molar mass of each element* g Na/mol Na g O/mol O g S/mol S Amount of each element per g of the unknown? mol Simplest mole ratio of elements in the unknown? * determined from the periodic table State the percentage of the element in grams and multiply by the inverse of the molar mass of the element. Divide the amount of each element by the amount of the leastabundant element. If necessary, multiply the ratio by a small integer that will produce a wholenumber ratio. 1 Mass of Na per multiply by the inverse of the molar mass of Na 2 Amount Na in mol per percent of Na stated as grams 1 Na per 100 g unknown molar mass Na 36.5 g Na 1 mol Na mol Na g Na Repeat this step for the remaining elements. 2 Amount of Na in mol per divide by the amount of the leastabundant element 4 Empirical formula 3 Wholenumber ratio among the elements 3 of 11
4 3. COMPUTE 36.5 g Na 38.1 g O 25.4 g S Divide the amount of each element by the amount of the leastabundant element, which in this example is S. This can be accomplished by multiplying the amount of each element by the inverse of the amount of the least abundant element mol Na 2.38 mol O mol S 1 mol Na g Na 1 mol S g S mol S mol S mol S 1.59 mol Na 1 mol O g O 2.38 mol O mol S From the calculations, the simplest mole ratio is 2 mol Na:3 mol O:1 mol S. The simplest formula is therefore Na 2 O 3 S. Seeing the ratio 3 mol O:1 mol S, you can use your knowledge of chemistry to suggest that this possibly represents a sulfite group, SO 3 and propose the formula Na 2 SO mol Na 1 mol S 3.01 mol O 1 mol S 1.00 mol S 1 mol S 4. EVALUATE Are the units correct? Is the number of significant figures correct? Is the answer reasonable? Yes; units canceled throughout the calculation, so it is reasonable to assume that the resulting ratio is accurate. Yes; ratios were calculated to three significant figures because percentages were given to three significant figures. Yes; the formula, Na 2 SO 3 is plausible, given the mole ratios and considering that the sulfite ion has a 2 charge and the sodium ion has a 1 charge. 4 of 11
5 PRACTICE 1. Determine the empirical formula for compounds that have the following analyses: a. 28.4% copper, 71.6% bromine ans: CuBr 2 b. 39.0% potassium, 12.0% carbon, ans: KHCO % hydrogen, and 47.9% oxygen c. 77.3% silver, 7.4% phosphorus, 15.3% oxygen ans: Ag 3 PO 4 d. 0.57% hydrogen, 72.1% iodine, 27.3% oxygen ans: HIO 3 SAMPLE PROBLEM 2 Determine the empirical formula for an unknown compound composed of 38.4% potassium, 36.3% oxygen, 23.7% carbon, and 1.66% hydrogen. 2. PLAN What steps are needed to State the percentage of the element calculate the amount in in grams and multiply by the inverse moles of each element per of the molar mass of the element g of unknown? What steps are needed to Divide the amount of each element determine the wholenumber by the amount of the leastabundant mole ratio of the elements in element. If necessary, multiply the the unknown (the simplest ratio by a small integer to produce formula)? a wholenumber ratio. 1 Mass of K in g per multiply by the inverse of the molar mass of K 2 Amount of K in mol per divide by the amount of the leastabundant element, and multiply by an integer that will produce a wholenumber ratio 4 Empirical formula 3 Wholenumber ratio among the elements 5 of 11
6 3. COMPUTE 38.4 g K 1 mol K g K mol K Proceed to find the amount in moles per g of unknown for the elements carbon, oxygen, and hydrogen, as in Sample Problem 1. When determining the formula of a compound having more than two elements, it is usually advisable to put the data and results in a table. Amount in Mass per mol per g g Element of unknown Molar mass of unknown Potassium 38.4 g K g/mol mol K Carbon 23.7 g C g/mol 1.97 mol C Oxygen 36.3 g O g/mol 2.27 mol O Hydrogen 1.66 g H 1.01 g/mol 1.64 mol Again, as in Sample Problem 1, divide each result by the amount in moles of the leastabundant element, which in this example is K. You should get the following results: Amount in mol of element Amount in mol per g of element Element of unknown per mol of potassium Potassium mol K 1.00 mol K Carbon 1.97 mol C 2.01 mol C Oxygen 2.27 mol O 2.31 mol O Hydrogen 1.64 mol 1.67 mol H In contrast to Sample Problem 1, this calculation does not give a simple wholenumber ratio among the elements. To solve this problem, multiply by a small integer that will result in a wholenumber ratio. You can pick an integer that you think might work, or you can convert the number of moles to an equivalent fractional number. At this point, you should keep in mind that analytical data is never perfect, so change the number of moles to the fraction that is closest to the decimal number. Then, choose the appropriate integer factor to use. In this case, the fractions are in thirds so a factor of 3 will change the fractions into whole numbers. 6 of 11
7 Amount in mol of Fraction element nearest the per mole decimal Integer Wholenumber of potassium value factor mole ratio 1.00 mol K 1 mol K 3 3 mol K 2.01 mol C 2 mol C 3 6 mol C 2.31 mol O 2 1/3 mol O 3 7 mol O 1.67 mol H 1 2/3 mol H 3 5 mol H Thus, the simplest formula for the compound is K 3 C 6 H 5 O 7, which happens to be the formula for potassium citrate. 4. EVALUATE Is the answer reasonable? Yes; the formula, K 3 C 6 H 5 O 7 is plausible, considering that the potassium ion has a 1 charge and the citrate polyatomic ion has a 3 charge. PRACTICE 1. Determine the simplest formula for compounds that have the following analyses. The data may not be exact. a. 36.2% aluminum and 63.8% sulfur ans: Al 2 S 3 b. 93.5% niobium and 6.50% oxygen ans: Nb 5 O 2 c. 57.6% strontium, 13.8% phosphorus, and ans: Sr 3 P 2 O 8 or 28.6% oxygen Sr 3 (PO 4 ) 2 d. 28.5% iron, 48.6% oxygen, and 22.9% ans: Fe 2 S 3 O 12 or sulfur Fe 2 (SO 4 ) 3 SAMPLE PROBLEM 3 A compound is analyzed and found to have the empirical formula CH 2 O. The molar mass of the compound is found to be 153 g/mol. What is the compound s molecular formula? SOLUTION 1. ANALYZE What is given in the problem? What are you asked to find? the empirical formula, and the experimental molar mass the molecular formula of the compound 7 of 11
8 Items Data Empirical formula of unknown CH 2 O Experimental molar mass of unknown 153 g/ mol Molar mass of empirical formula g/mol Molecular formula of the compound? 2. PLAN What steps are needed to determine the molecular formula of the unknown compound? Multiply the experimental molar mass by the inverse of the molar mass of the empirical formula. The subscripts of the empirical formula are multiplied by the wholenumber factor obtained. 4 Empirical formula of unknown multiply the experimental molar mass by the inverse of the molar mass of the empirical formula, and multiply each subscript in the empirical formula by the resulting factor 5 Molecular formula of unknown 3. COMPUTE given 153 g 1 mol unknown 1 molar mass of empirical formula 1 mol CH 2 O g 153 g 1 mol unknown 1 mol CH 2O g factor that shows the number of times the empirical formula must be multiplied to get the molecular formula mol CH 2 O 1 mol unknown 5.09 mol CH 2O 1 mol unknown Allowing for a little experimental error, the molecular formula must be five times the empirical formula. Molecular formula (CH 2 O) 5 C 5 H 10 O 5 4. EVALUATE Is the answer reasonable? Yes; the calculated molar mass of C 5 H 10 O 5 is , which is close to the experimental molar mass of the unknown. Reference books show that there are several different compounds with the formula C 5 H 10 O 5. 8 of 11
9 PRACTICE 1. Determine the molecular formula of each of the following unknown substances: a. empirical formula CH 2 ans: C 2 H 4 experimental molar mass 28 g/mol b. empirical formula B 2 H 5 ans: B 4 H 10 experimental molar mass 54 g/mol c. empirical formula C 2 HCl ans: C 6 H 3 Cl 3 experimental molar mass 179 g/mol d. empirical formula C 6 H 8 O ans: C 18 H 24 O 3 experimental molar mass 290 g/mol e. empirical formula C 3 H 2 O ans: C 12 H 8 O 4 experimental molar mass 216 g/mol ADDITIONAL PROBLEMS 1. Determine the empirical formula for compounds that have the following analyses: a. 66.0% barium and 34.0% chlorine b % bismuth, 18.46% oxygen, and 1.16% hydrogen c % aluminum, 19.73% nitrogen, and 67.60% oxygen d % zinc, 26.18% carbon, 34.88% oxygen, and 3.30% hydrogen e. 2.8% hydrogen, 9.8% nitrogen, 20.5% nickel, 44.5% oxygen, and 22.4% sulfur f. 8.09% carbon, 0.34% hydrogen, 10.78% oxygen, and 80.78% bromine 2. Sometimes, instead of percentage composition, you will have the composition of a sample by mass. Use the same method shown in Sample Problem 1, but use the actual mass of the sample instead of assuming a 100 g sample. Determine the empirical formula for compounds that have the following analyses: a. a g sample of an unknown substance is composed of g of copper and g of fluorine b. a g sample of an unknown substance is composed of 9.48 g of barium, 1.66 g of carbon, and 1.93 g of nitrogen c. a g sample of an unknown substance is composed of g manganese, g oxygen, and g sulfur 9 of 11
10 3. Determine the empirical formula for compounds that have the following analyses: a. a g sample contains g of nickel and g of iodine b. a g sample contains g of manganese, g of nitrogen, and g of oxygen c. a g sample contains g of magnesium, g of sulfur, and g of oxygen d. a g sample contains g of potassium, 9.06 g of oxygen, and g of tin 4. Determine the empirical formula for compounds that have the following analyses: a. 60.9% As and 39.1% S b % Re and 23.12% O c. 5.04% H, 35.00% N, and 59.96% O d. 24.3% Fe, 33.9% Cr, and 41.8% O e % C, 37.81% N, and 8.16% H f % C, 3.90% H, 29.43% F, and 10.85% N 5. Determine the molecular formulas for compounds having the following empirical formulas and molar masses: a. C 2 H 4 S; experimental molar mass 179 b. C 2 H 4 O; experimental molar mass 176 c. C 2 H 3 O 2 ; experimental molar mass 119 d. C 2 H 2 O, experimental molar mass Use the experimental molar mass to determine the molecular formula for compounds having the following analyses: a % carbon, 3.47% hydrogen, and 55.14% oxygen; experimental molar mass b % carbon, 9.15% hydrogen, and 36.32% oxygen; experimental molar mass 88 c % carbon, 7.19% hydrogen, and 28.54% oxygen; experimental molar mass A g sample of a white powder contains g of potassium, g of sulfur, and g of oxygen. What is the empirical formula for the compound? 8. A g sample of a lead compound is analyzed and found to be made up of 9.65 g of lead and 0.99 g of oxygen. Determine the empirical formula for this compound. 10 of 11
11 9. A 2.65 g sample of a salmoncolored powder contains 0.70 g of chromium, 0.65 g of sulfur, and 1.30 g of oxygen. The molar mass is What is the formula of the compound? 10. Ninhydrin is a compound that reacts with amino acids and proteins to produce a darkcolored complex. It is used by forensic chemists and detectives to see fingerprints that might otherwise be invisible. Ninhydrin s composition is 60.68% carbon, 3.40% hydrogen, and 35.92% oxygen. What is the empirical formula for ninhydrin? 11. Histamine is a substance that is released by cells in response to injury, infection, stings, and materials that cause allergic responses, such as pollen. Histamine causes dilation of blood vessels and swelling due to accumulation of fluid in the tissues. People sometimes take antihistamine drugs to counteract the effects of histamine. A sample of histamine having a mass of 385 mg is composed of 208 mg of carbon, 31 mg of hydrogen, and 146 mg of nitrogen. The molar mass of histamine is 111 g/mol. What is the molecular formula for histamine? 12. You analyze two substances in the laboratory and discover that each has the empirical formula CH 2 O. You can easily see that they are different substances because one is a liquid with a sharp, biting odor and the other is an odorless, crystalline solid. How can you account for the fact that both have the same empirical formula? 11 of 11
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