Biogas to Natural Gas with Highly Selective Membrane Technology
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1 Biogas to Natural Gas with Highly Selective Membrane Technology March 2013 Dipl.-Ing. Anke Schäffer, Eisenmann AG Eisenmann AG / ET / Biogas / Biogasaufbereitung / EN /
2 Index About Eisenmann Eisenmann biogas Motivation biogas upgrading Biogas upgrading with highly selective membrane technology Reference plant Pratteln, Switzerland Operating Data and Advantages 2
3 Index About Eisenmann Eisenmann biogas Motivation biogas upgrading Biogas upgrading with highly selective membrane technology Reference plant Pratteln, Switzerland Operating Data and Advantages 3
4 Fact Sheet No.1 In the world market for paint shops for plastic parts No.1 In the world market for ammunition disposal plants No.2 In the world market for automotive paint shops Mio. Turnover 2011 More than 1,200 Engineers and technicians 3,700 Employees 21 Locations worldwide 4
5 Locations Crystal Lake Puebla Moscow Göttingen (Ruhstrat) Böblingen Holzgerlingen Erftstadt (intec) Stafford Paris Saronno Barcelona Changchun Shanghai Kunshan Fuzhou São Paulo Cruzeiro Thane Pune Chennai Delhi Country with Eisenmann location Country with Eisenmann sales representatives 5
6 Headquarters in Germany Böblingen Eisenmann AG Eisenmann Beteiligungen Eisenmann Service Holzgerlingen Eisenmann Anlagenbau Production: m² Storage: m² Office: m² Assembly 1: m² Assembly 2: m² Piping construction: 500 m² Office: m² 6
7 Range of Products and Services AUTOMOTIVE SYSTEMS Surface Finishing, Body shell conveyor systems, Final assembly lines GENERAL FINISHING Paint shops for metal parts, Paint shops for plastic parts, Paint shops for wooden parts, New materials ENVIRONMENTAL TECHNOLOGY Exhaust air purification, Waste water treatment, Waste disposal, Ammunition disposal, Biogas plants and biogas upgrading plants PROCESS & HIGH TEMPERATURE TECHNOLOGY Pretreatment and coating systems, High-temperature technology, Firing lines for ceramics, Heat treatment, Carbon fiber ovens CONVEYOR SYSTEMS Electric monorail systems, Electric floor-based conveyors, Power & Free conveyors, Peripheral conveyor systems SERVICE Customer service, Spare parts management, Plant renewal, Advisory services, Full service & BOT models 7
8 Index About Eisenmann Eisenmann biogas Motivation biogas upgrading Biogas upgrading with highly selective membrane technology Reference plant Pratteln, Switzerland Operating Data and Advantages 8
9 Eisenmann biogas since 2003 since 2008 since 2012 Agricultural biogas plants Plants in operation: Germany, 55 plants Italy, 22 plants Czech Republic, 1 plant Biowaste biogas plants Plants in operation: Sweden, 1 plant Switzerland, 3 plants Biogas upgrading plants Plants in operation: Switzerland, 1 plant Future development towards biowaste biogas plants. Specifically less gas yield small to medium sized biogas upgrading plants. 9
10 Biogas plants from Eisenmann Substrate pretreatment Plug flow digester Separator Final storage tank CHP/upgrading Biogas upgrading with membrane technology, in conjunction with Eisenmann biogas plants. Eisenmann provides a one-stop solution for the entire process chain. 10
11 Index About Eisenmann Eisenmann biogas Motivation biogas upgrading Biogas upgrading with highly selective membrane technology Reference plant Pratteln, Switzerland Operating Data and Advantages 11
12 Motivation The advantages of biomethane: Local production possible An independent, flexible and storable energy source Allows efficient generation of energy in line with actual demand 2020 goal in Germany Grid injection of 6 billion cubic meters of biomethane annually Currently there are: 107 biogas upgrading plants processing a total 67,000 Nm³/h biomethane We have therefore achieved about 10 % of the 2020 goal so far (Source: Biogaspartner 2012) To meet the 2020 goal, it would be necessary to build an additional 700 plants per year, each processing 200 Nm³/h biogas 12
13 Index About Eisenmann Eisenmann biogas Motivation biogas upgrading Biogas upgrading with highly selective membrane technology Reference plant Pratteln, Switzerland Operating Data and Advantages 13
14 Highly selective membrane technology Gas permeation using selective membranes made from high-performance polymers Design of membrane module Biogas: CH 4 + CO 2 (feed) Biomethane: CH 4 (retentate) Offgas: CH 4 (permeate) Hollow fiber membranes Separation of CO 2 and CH 4 based on differing permeation velocities CH 4 slow CO 2 fast Function of the highly selective membrane 14
15 Flow diagram Biogas Pre-treatment: cooling and desulferization Compressor Purification: fine treatment Biogas production Membrane Stage I Membrane Stage II Biomethane > 98 % CH 4 Pre-treatment Compression Purification Gas separation Offgas treatment Membrane Stage III option TO, KO, RO Offgas CO 2 < 0.5 % CH 4 Purified gas 0.0 % CH 4 15
16 Container 10 m 3 m Machine room compressor (Ex-II), membrane room gas separation (Ex-II), gas analysis room, switch cabinet Compact and modular design. Pre-assembly and test operation by Eisenmann. Turn-key solution. 16
17 Gas separation with highly selective membranes Compressor Membrane Stage I Membrane Stage II Biomethane > 98 % CH 4 Membrane Stage III Offgas CO 2 < 0.5 % CH 4 Two-stage biomethane upgrading. Third membrane stage to minimize methane leakage. Low recirculation rate to minimize load on the compressor. Highly selective membrane technology enables a methane yield greater than 99.5 %. 17
18 Process control and visualization Process control Siemens S7 Remote access Monitoring and operation over the Internet. Text-message alerts in the event of faults. Visualization Touchscreen Visualization of biogas upgrading process Automated operation and process control. Walk-in switch cabinet. 18
19 Index About Eisenmann Eisenmann biogas Motivation biogas upgrading Biogas upgrading with highly selective membrane technology Reference plant Pratteln, Switzerland Operating Data and Advantages 19
20 Site Pratteln Site location: Biopower Nordwestschweiz AG, Pratteln, Schweiz 20
21 Facts and figures Year of construction: 2012 Biogas plant type: high-solids digestion of biowaste Upgraded biogas use: grid injection and fuel Biogas flow rate: 210 Nm³/h Biomethane flow rate: 125 Nm³/h Biomethane concentration: > 98 vol. % Membrane room. Biogas upgrading plant in Pratteln. 21
22 Index About Eisenmann Eisenmann biogas Motivation biogas upgrading Biogas upgrading with highly selective membrane technology Reference plant Pratteln, Switzerland Operating Data and Advantages 22
23 Key operating metrics and advantages Specific energy consumption without peripherals Compressor 0.20 kwh/nm³ biogas Specific energy consumption with peripherals Compressor Blower, cooling and air conditioning 0.29 kwh/nm³ biogas Operation Rapid start-up and shut-down Easy-to-control process No heating required No need for additives/consumables User-friendly operation 23
24 Advantages Eisenmann biogas upgrading plants For small gas quantities greater than 150 Nm³/h Compact and modular design Commissioning and test operation by Eisenmann Turnkey solution Injection into the natural gas grid without further compression Biomethane > 98 % CH 4 Low methane leakage < 0.5 CH 4 High biomethane yield > 99.5 % CH 4 High energy efficiency 24
25 Contact Dipl.-Ing. Anke Schäffer Sales Biogas Environmental Technology Phone: Tübinger Straße 81, Böblingen, Germany 25
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