Page 1 of 24 (TEST RAPORU) Anadolu Kimya San. Ve Tic. Ltd. Şti. One sample of SP 234 Glitter paste (SP 234 Sim Patı numunesi)

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1 TEST REORT age 1 of 24 (TEST RAORU) (Sayfa 1 / 24) REORT NUMBER : (RAOR NUMARASI) TURA ALICANT NAME : (MÜŞTERİ ADI ) ADDRESS : (ADRESİ ) Anadolu Kimya San. Ve Tic. Ltd. Şti. Akçaburgaz mahallesi 120.Cadde 109.Sokak No/10 Esenyurt-İstanbul Tel : Fax : Attention : Gürkan Kaya (gurkan.kaya@anadolukimya.com) (İlgili kişi) SAMLE DESCRITION : (NUMUNE TANIMI ) One sample of S 234 Glitter paste (S 234 Sim atı numunesi) DATE IN : 06 September, 2012 (GİRİŞ TARİHİ ) (06 Eylül, 2012 ) DATE OUT : 17 October, 2012 (ÇIKIŞ TARİHİ ) (17 Ekim, 2012) RESULTS : (SONUÇLAR ) See attachment (Ektedir) Füsun Karaoglu Zeynep Akın Assistant Chemical Laboratory Manager (Kimyasal Laboratuvarı Müdür Yardımcısı) Neslihan Sözer Chemical Laboratory Manager (Kimya Laboratuvar Müdürü) Merkez Mahallesi Sanayi Cad. No: 23 Altındağ laza Yenibosna ISTANBUL / TURKEY * * ssenturk

2 R E S U L T S age 2 of 24 (SONUÇLAR) (Sayfa 2 of 24) RESULT TEST Test Method (Sonuç) (Test Metodu) (Sınır Değer) ASS (GEÇTİ) AEO Test AL : ppm Free Formaldehyde JIS L 1041 Method 2 A : (baby) Af Determination of Free BS EN ISO : Formaldehyde Test ppm Azo Dyestuff EN : 2012 <20 ppm Carcinogenous Dyestuff IHTM AL.2.091:2011 refer to DIN 54231:2005 IHTM AL.2.090:2011 & Allergenic Disperse AL.2.178:2011 refer to Dyestuff DIN 54231:2005 Heavy Metal Analysis Migration of Toxic Elements Determination of Chlorobenzenes and Chlorotoluenes Determination of short chained paraffins (C10-C13) Determination of medium chained parrafins (C14- C17) Flame Retardants test Determination of Dimethylfumarate Determination of olychlorophenols AL : 2012 refer to ISO 105 E-04 BS EN 71-3:1995 : AL : 2012 refer to DIN AL : 2008 AL : 2008 In House Method Solvent Extraction followed by LC-MS-MS & GC/MS AL : 2010 Extraction with KOH, derivatization with acetic anhydride and analysing with GC/MS Antimony Arsenic Cadmium Chromium Chromium + 6 (Cr + 6) Cobalt Cupper Lead Mercury Nickel Antimony Arsenic Barium Cadmium Chromium Lead Mercury Selenium (Sb) (As) (Cd) (Cr) (Co) (Cu) (b) (Hg) (Ni) (Sb) (As) (Ba) (Cd) (Cr) (b) (Hg) (Se) 5 ppm 0.2 ppm 0.1 ppm 1 ppm Under Detection Limit 1 ppm 25 ppm 0.2 ppm 0,02 ppm 1 ppm ppm 1000 ppm entachlorophenol (C) Tetrachlorophenol (TeC) Orthophenylphonol (O) 0,1 ppm 50 ppm

3 R E S U L T S age 3 of 24 (SONUÇLAR) (Sayfa 3 of 24) TEST olyvinly Chloride (VC) with FTIR olycyclic Aromatic Hydrocarbons (AHs) Analysis Organo Tin Compounds FOS & FOA esticides Residue hthalate Content olychlorinated Biphenyls Lead in paint and other similar surface coating Determination of Cadmium Content Triclosan Content Test Method (Test Metodu) AL.2.024: 2011 AL : 2012 based on ZEK AL : 2010 refer to ISO 17353:2004 AL.2.123:2012 AL : 2008 AL : 2011 based on EN : 2004 AL : 2012 refer to DIN Extraction with organic solvent and analysis with GC-MS CSC-CH-E Method followed by IC- OES BS EN 1122:2001 (Method B) and IHTM AL : 2012 using microwave digestion AL : 2010 (Sınır Değer) TESTED COMONENT OF SUBMITTED SAMLE DOES NOT CONTAIN OLYVINYL CHLORIDE (VC) Category 2 Total 18 AH : 10 mg/kg Benzo(a)pyrene : 1 mg/kg Monobutyltin (MBT) Dibutyltin (DBT) 1 ppm* Tributyltin (TBT) 0.5 ppm* Tetrabutyltin (TeBT) Monooctyltin (MOT) Dioctyltin (DOT) 1 ppm* Tricyclohexyltin (TcHT) Tripentyltin (ThT) FOS FOA 0.5 ppm* 1.0 µg/m² 0.25 mg/kg TOTAL 0.5 ppm TOTAL : 500 ppm RESULT (Sonuç) ASS (GEÇTİ) 90 ppm 40 ppm

4 R E S U L T S age 4 of 24 (SONUÇLAR) (Sayfa 4 of 24) AEO Test AL : 2010 In-House Test Method by Gas Chromotographic-Mass Spectrometric (GC-MS) and Liquid Chromotographic-Mass Spectrometric (LC-MS-MS) Analysis Alkylphenols (ppm) Nonylphenol (N) Octylphenol (O) Alkylphenol Ethoxylates Nonylphenolethoxylates (NEO) 100 ppm Octylphenolethoxylates (OEO) ppm = mg/kg reporting limit for N & O = 30 ppm ND = (<30 ppm) ppm = mg/kg reporting limit for NEO & OEO = 10 ppm ND = (<10 ppm) Remark : N&NEO Content in Annex XVII Item 46 of the Reach Regulation (EC) No: 1907/2006 Estimated Total Uncertainty = (Alkylphenols:±4%, Alkylphenol Ethoxylates = ±3%)

5 R E S U L T S age 5 of 24 (SONUÇLAR) (Sayfa 5 of 24) Free Formaldehyde JIS L 1041 Method 2 A : 2011 A A Af < Af* Detection Limit =10 ppm < Less Than * Eco Testing Standard for Textiles Estimated Total uncertainty=(±6%) Note: Sample was received sealed Determination of Free Formaldehyde Test BS EN ISO : 2011 Free and Hydrolized Formaldehyde by UV VIS Analysis <10 ppm 13 ppm ppm (part per million) =mg / kg Detection Limit =10 ppm < Less Than Estimated Total uncertainty=(±6%) Note: Sample was received sealed

6 R E S U L T S age 6 of 24 (SONUÇLAR) (Sayfa 6 of 24) Azo Dyestuff EN : 2012 Determination of Certain Aromatic Amines derived from Azo Colorants followed by GC-MS Analysis Transparent dye <20 ppm INTERRETATION OF AZO-DYES TEST RESULTS : FORBIDDEN AMINE CAS NO FORBIDDEN AMINE CAS NO 4-AMINOBIHENYL ,3 -DİMETHYL-4,4 DIAMINOBIHENYLMETHANE BENZIDINE CRESIDINE CHLORO-O-4-CHLOR-O-TOLUIDINE ,4 -METHYLENE-BIS- ((2 CHLOROANILINE)) NAHTHYLAMINE ,4 -OXYDIANILINE *O-AMINOAZOTOLUENE ,4 -THIODIANILINE *2-AMINO-4-NITROTOLUENE O-TOLUIDINE CHLOROANILINE ,4-TOLUENDIAMINE ,4-DIAMINOANISOLE ,4,5-TRIMETHYLANILINE ,4 -DIAMINOBIHENYLMETHANE O-ANISIDINE ,3 -DICHLOROBENZIDINE **-Aminoazobenzene ,3 -DIMETHOXYBENZIDINE ,4 XYLIDINE ,3 -DIMETHYLBENZIDINE ,6 XYLIDINE NOTE: *The amines o-amino-azotoluene and 2-amino-4-nitrotoluene are detected by its splitted product o-toluidine and 2,4- toluylenediamine. **Azo colorants that are able to form 4-aminoazobenzene, generate under the condition of this method aniline and 1,4- phenylendiamine. The presence of these colorants can not be reliably ascertained without additional information, e.g. chemical structure of the colorant used. Remark: ACCORDING TO THE OFFICIAL METHOD EN 14362, IF 4-AMINODIHENYL OR 2-NATHYLAMINE OR 2,4-DIAMINOANISOLE IS FOUND EXCEEDING 30 M, THE USE OF FORBIDDEN AZO DYESTUFF CANNOT BE ASCERTAINED WITHOUT ADDITIONAL INFORMATION eg. THE CHEMICAL STRUCTURE OF THE DYESTUFF USED. ppm : part per million (mg/kg) < = Less Than Detection Limit: 5 ppm Estimated Total Uncertainity = (±10%)

7 R E S U L T S age 7 of 24 (SONUÇLAR) (Sayfa 7 of 24) Carcinogenous Dyestuff IHTM AL.2.091:2011 refer to DIN 54231:2005 By High erformance Liquid Chromatography & Mass Spectroscopy (LC-MS-MS) & HLC-DAD Analysis COMOUND RESULT (ppm) ACID RED 26 * BASIC RED 9 BASIC VIOLET 14 DIRECT BLACK 38 DIRECT BLUE 6 DIRECT RED 28 DISERSE BLUE 1 DISERSE ORANGE 11 DISERSE YELLOW 3 ppm (part per million) =mg / kg Detection Limit =7.5 ppm n.d = < =Less Than Estimated Total Uncertainty=±8% *Eco Testing Standard for Textiles

8 R E S U L T S age 8 of 24 (SONUÇLAR) (Sayfa 8 of 24) Allergenic Disperse Dyestuff IHTM AL.2.090:2012 & AL.2.178:2011 refer to DIN 54231:2005 By High erformance Liquid Chromatography&Mass Spectroscopy (LC-MS-MS) & HLC - DAD Analysis C.I Generic Name C.I. Disperse Blue 1: C.I. Disperse Blue 3: C.I. Disperse Blue 7: C.I. Disperse Blue 26: C.I. Disperse Blue 35: C.I. Disperse Blue 102: C.I. Disperse Blue 106: C.I. Disperse Blue 124: C.I. Disperse Brown 1: C.I. Disperse Orange 1: C.I. Disperse Orange 3: C.I. Disperse Orange 37/76: C.I. Disperse Orange 149: C.I. Disperse Red 1: C.I. Disperse Red 11: C.I. Disperse Red 17: C.I. Disperse Yellow 1: C.I. Disperse Yellow 3: C.I. Disperse Yellow 9: C.I. Disperse Yellow 23: C.I. Disperse Yellow 39: C.I. Disperse Yellow 49: ppm (part per million) =mg / kg n.d = Detection Limit =3 ppm < =Less Than Estimated Total Uncertainty=±9%

9 R E S U L T S age 9 of 24 (SONUÇLAR) (Sayfa 9 of 24) (*)Heavy Metal Analysis AL : 2012 refer to ISO 105 E-04 Extractable with artificial perspiration solution Antimony (Sb) <0.1 ppm 5 ppm Arsenic (As) <0.1 ppm 0.2 ppm Cadmium (Cd) <0.1 ppm 0.1 ppm Chromium (Cr) <0.1 ppm 1 ppm Chromium + 6 (Cr + 6) Under Detection limit Under Detection Limit Cobalt (Co) <0.1 ppm 1 ppm Cupper (Cu) <0.1 ppm 25 ppm Lead (b) <0.1 ppm 0.2 ppm Mercury (Hg) <0.01 ppm 0.02 ppm Nickel (Ni) <0.1 ppm 1 ppm ppm :part per million (mg/kg) < =Less Than

10 R E S U L T S age 10 of 24 (SONUÇLAR) (Sayfa 10 of 24) Migration of Toxic Elements BS EN 71-3:1995 Acid extraction method was used and toxic elements content were determined by Inductively Coupled lasma- IC_OES. RESULT IN ppm ASS/FAIL (ppm) Antimony (Sb) <2 ppm ASS 60 Arsenic (As) <2 ppm ASS 25 Barium (Ba) <2 ppm ASS 1000 Cadmium (Cd) <2 ppm ASS 75 Chromium (Cr) <5 ppm ASS 60 Lead (b) <5 ppm ASS 90 Mercury (Hg) <2 ppm ASS 60 Selenium (Se) <2 ppm ASS 500 ppm (part per million) =mg / kg < =Less Than Estimated Total Uncertainty = (s quoted have been corrected for uncertainty.)

11 R E S U L T S age 11 of 24 (SONUÇLAR) (Sayfa 11 of 24) Determination of Chlorobenzenes and Chlorotoluenes AL : 2012 refer to DIN By Solvent Extraction GC-MS Determination, Confirmation by GC-ECD COMOUND RESULT (ppm) Dichlorobenzenes 1 ppm* Trichlorobenzenes entachlorobenzenes Tetrachlorobenzenes Hexachlorobenzenes Clorotoluenes Diclorotoluenes Triclorotoluenes Tetraclorotoluenes entaclorotoluenes ppm (part per million) =mg / kg Detection Limit =0.05 ppm < =Less Than ND = * Eco Testing Standard for Textiles Estimated Total Uncertainty= ±8%

12 R E S U L T S age 12 of 24 (SONUÇLAR) (Sayfa 12 of 24) (*)Determination of Short Chained araffins (C10-C13) AL : 2008 By Solvent Extraction and Gas Chromotographic Analysis using Mass Spectrometry (GC-MS) ppm : part per million (mg/kg) Detection Limit = 0.01% < = Less Than Estimated Total Uncertainty= ±5% (*)Determination of Medium Chained arrafins C14- C17 AL : 2008 By Solvent Extraction and Chromatographic Analysis using Mass Spectrometry (GC-MS) 1000 ppm ppm (part per million) =mg / kg Detection Limit =0.01% < =Less Than (Total uncertainty=±5 %)

13 R E S U L T S age 13 of 24 (SONUÇLAR) (Sayfa 13 of 24) (*)Flame Retardants Test Test Method : In House Method Solvent Extraction followed by LC-MS-MS & GC/MS Flame Retardants CAS - Nr (ppm) Tris- (2,3 Dibromopropyl) phosphate (TRIS) olybrominatedbiphenyl (BB) Tris-aziridinyl phosphine oxide (TEA) entabromo diphenyl ether (entabde) Octabromo diphenyl ether (OctaBDE) Hexabromocyclododecane (HBCDD) Decabromodiphenyl Ether (DecaDBE ) Tris(2-chloroethyl)hosphate (TCE) * ppm (part per million) = mg/kg Detection Limit =1 ppm *= Eco Testing Standard for Textiles

14 R E S U L T S age 14 of 24 (SONUÇLAR) (Sayfa 14 of 24) Determination of Dimethylfumarate AL : 2010 By Solvent Extraction and Chromatographic Analysis using Mass Spectrometry (GC-MS) 0,1 ppm ppm (part per million) Detection Limit =mg / kg =0.1 ppm Estimated Total Uncertainty= ±10% Determination of olychlorophenols Extraction with KOH, derivatization with acetic anhydride and analysing with GC/MS entachlorophenol (C) Tetrachlorophenol (TeC) Orthophenylphonol (O) 50 ppm ppm (part per million) =mg / kg Detection Limit =0.05 ppm < =Less Than ND = Estimated Total Uncertainty=± 9 %

15 R E S U L T S age 15 of 24 (SONUÇLAR) (Sayfa 15 of 24) olyvinly Chloride (VC) with FTIR AL.2.024: 2011 Detection of olyvinyl Chloride by FTIR VC WAS NOT DETECTED TESTED COMONENT OF SUBMITTED SAMLE DOES NOT CONTAIN OLYVINYL CHLORIDE (VC)

16 R E S U L T S age 16 of 24 (SONUÇLAR) (Sayfa 16 of 24) olycyclic Aromatic Hydrocarbons (AHs) Analysis AL : 2012 based on ZEK Harmonisierte Methode zur Bestimmung von polycyclischen aromatischen Kohlenwasserstoffen (AK) in Kunststoffproben ZEK AS SOLVENT EXTRACTION AND FOLLOWED BY GAS CHROMATOGRAHY MASS SECTROMETRIC (GC/MS) ANALYSIS RESULT (ppm) NAHTHALENE Category 2 ACENAHTHYLENE Total 18 AH : 10 mg/kg ACENAHTHEN Benzo(a)pyrene : 1 mg/kg FLUORENE HENANTHRENE ANTHRACENE FLUORANTHENE YRENE BENZO (a) ANTHRACENE CHRYSENE BENZO (b) FLUORANTHENE BENZO (k) FLUORANTHENE BENZO (a) YRENE INDENO (1,2,3-cd) YRENE DIBENZO (a,h) ANTHRACENE BENZO (ghi) ERYLENE BENZO(i)FLUORANTHENE BENZO(e)YRENE ---- SUM (18 AH): ppm (part per million) =mg / kg Detection Limit = 0.1 ppm n.d. = Estimated Total Uncertainty= ±3%

17 R E S U L T S age 17 of 24 (SONUÇLAR) (Sayfa 17 of 24) Organo Tin Compounds AL : 2010 refer to ISO 17353:2004 Ethanol extraction, derivatisation and analysis by Gas Chromatography-Mass Spectrophotometry Analysis (GC-MS) Monobutyltin (MBT) Dibutyltin (DBT) 1 ppm* Tributyltin (TBT) 0.5 ppm* Tetrabutyltin (TeBT) Monooctyltin (MOT) Dioctyltin (DOT) 1 ppm* Tricyclohexyltin (TcHT) Tripentyltin (ThT) 0.5 ppm* ppm (part per million) =mg/kg Detection Limit =0.05 ppm *= Eco Testing Standard for Textiles Estimated Total Uncertainty = (±7%)

18 R E S U L T S age 18 of 24 (SONUÇLAR) (Sayfa 18 of 24) FOS (ERFLUOROOCTANE SULFONATES) & FOA (ERFLUOROOCTANOIC ACID) AL.2.123:2012 Solvent Extraction Followed By Liquid Chromotographic- Mass Spectrometric(LS-MS-MS) Analysis * FOS (erfluorooctane Sulfonates) Not detected 1.0 µg/m² FOA (erfluorooctanoic Acid) Not detected 0.25 mg/kg * = FOS : 1 µg/m² in textiles or coated materials according to 2006/122/EC FOA: 0.25 mg/kg according to Eco Testing Standard for Textiles Detection Limit ND =0.25 ppb /0.5 µg/m² (<0,25 ppb / <0.5 µg/m²) Estimated Total Uncertainty = ±4%

19 R E S U L T S age 19 of 24 (SONUÇLAR) (Sayfa 19 of 24) (*)esticides Residue AL : 2008 COMOUND RESULT REQUIREMENT* 2,4,5-T TOTAL 0.5 ppm 2,4-D Azinophosmethyl Azinophosethyl Aldrine Bromophos-ethyl Captafol Carbaryl Chlordane Chlordimeform Chlorfenvinphos Coumaphos Cyfluthrin Cyhalothrin Cypermethrin DEF Deltamethrin DDD DDE DDT Diazinon Dichlorprop Dicrotophos Dieldrine Dimethoate Dinoseb and salts Endosulfan, ALFA Endosulfan, BETA Endrine Esfenvalerate Fenvalerate Heptachlor Heptachloroepoxide Hexachlorobenzene Hexachlorocyclohexane, ALFA Hexachlorocyclohexane, BETA Hexachlorocyclohexane, GAMA Isodrine Kelevane Kepone Lindane Malathion MCA

20 R E S U L T S age 20 of 24 (SONUÇLAR) (Sayfa 20 of 24) (*)esticides Residue AL : 2008 COMOUND RESULT REQUIREMENT* MCB TOTAL 0.5 ppm Mecoprop Metamidophos Methoxychlor Mirex Monocrotophos arathion arathion-methyl erthane hosdrin/mevinphos ropethamphos rofenophos Quinalphos Strobane Telodrine Toxaphene Trifluralin ppm (part per million) =mg / kg Detection Limit =0.1 ppm ND = * Eco Testing Standard for Textiles

21 R E S U L T S age 21 of 24 (SONUÇLAR) (Sayfa 21 of 24) Total hthalate Content AL : 2011 based on EN : 2004 Method By Gas Chromotographic- Mass Spectrometric (GC- MS ) Analysis RESULT (ppm) DIBUTYL HTHALATE (DB) <10 ppm TOTAL : 500 ppm DIETHYL HEXYL HTHALATE (DEH) <10 ppm BENZYL BUTYL HTHALATE (BB) <10 ppm DI-ISO-NONYL HTHALATE (DIN) <10 ppm DI-N-OCTYL HTHALATE (DNO) <10 ppm DI-ISO-DECYL HTHALATE (DID) <10 ppm DI-ISO-BUTYL HTHALATE (DIB) <10 ppm BIS(2-METHOXYETHYL) HTHALATE (BME) <10 ppm DI (C6-C8 ALKYL) HTHALATE (DIH) <10 ppm DI (C7-C11 ALKYL) HTHALATE (DHNU) <10 ppm DI-N-ENTYL HTHALATE (Dn) <10 ppm DI-ISO-ENTYL HTHALATE (Di) <10 ppm REMARK =The Limit of 0.1% by weight was quoted according to Annex XVII Items 51&52 of the REACH Regulation (EC) No.1907/2006 (Formerly known as Directive 2005/84/EC) for hthalate Content. ppm (part per million) =mg / kg Detection Limit =10 ppm < =Less Than * =EXCEEDED LIMIT Estimated Total uncertainty = (±5%)

22 R E S U L T S age 22 of 24 (SONUÇLAR) (Sayfa 22 of 24) olychlorinated Biphenyls AL : 2012 refer to DIN Extraction with organic solvent and analysis with GC-MS olychlorinated Biphenyls (CBs) CAS-Nr. 2,4,4 -Trichlorobiphenyl (CB 28) ,2,5,5 - Tetrachlorobiphenyl (CB 52) ,2,4,5,5 - entachlorobiphenyl (CB 101) ,2,3,4,4,5 - Hexachlorobiphenyl (CB 138) ,2,4,4,5,5 - Hexachlorobiphenyl (CB 153) ,2,3,4,4,5,5 - Heptachlorobiphenyl (CB 180) Total CBs ppm (part per million) =mg / kg ND = Estimated Total Uncertainty =±5%

23 R E S U L T S age 23 of 24 (SONUÇLAR) (Sayfa 23 of 24) Lead in aint and Other Similar Surface Coating CSC-CH-E Method followed by IC-OES 90 ppm ppm (part per million) =mg / kg < Less Than Detection Limit =2 ppm Estimated Total Uncertainty = ±3%

24 R E S U L T S age 24 of 24 (SONUÇLAR) (Sayfa 24 of 24) Determination of Cadmium Content BS EN 1122:2012 (Method B) and IHTM AL : 2012 using Microwave Digestion <2 ppm 40 ppm ppm (part per million) =mg / kg Detection Limit =2 ppm < =Less Than % =ercentage based on dry weight of sample REMARK : As per Cadmium Content in Annex XVII item 23 of the REACH Regulation (EC) No: 1907/2006 amended by 494/2011 (Formerly Known as Directive 91/338/EEC), MicrowaveDigestion Method was used Total Cadmium Content was determined by IC-OES Estimated Total Uncertainty = ±4% Triclosan Content AL : 2010 Triclosan ( ) Detection Limit ppm ND =0.05 ppm = mg/kg = Estimated Total Uncertainty = ± 9% ## END OF TEST REORT ##