Materials Engineering at the ZMNS: From Nanostructures to Optoelectronic Devices



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Materials Engineering at the ZMNS: From Nanostructures to Optoelectronic Devices Gottfried Strasser Institut für Festkörperelektronik Zentrum für Mikro- und Nanostrukturen Fakultät für Elektrotechnik und Informationstechnik Technische Universität Wien October 25 2011 IV EU-RUSSIAN OPEN DAYS

Center for Micro- and Nanostructures http://zmns.tuwien.ac.at/ October 25 2011 IV EU-RUSSIAN OPEN DAYS

Cleanroom area 500m 2 (class 100 and 10000) Solid State Electronics Microelectronics Photonics Sensor and Actuator Systems Microwave and Circuit Engineering Physics Materials Engineering

ZMNS EE Institut für Festkörperelektronik (solid state electronics) Institut für Mikroelektronik (microelectronics) Institut für Photonik (photonics) Institut für Sensor- & Aktuatorsysteme (sensor and actuators) Institut für elekt. Mess- & Schaltungstechnik (circuit design) TU Vienna Atominstitut (atomic institute) Institut für Allgemeine Physik (general physics) Institut für Festkörperphysik (solid state physics) Institut für Anorganische Chemie (inorganic chemistry) External User

Molecular Beam Epitaxy Veeco (Intevac) mod GenII : Ga, Al, In, As // Si, C Riber P32: Ga, Al, In, N, Sb, As //Si XRD (Philips Expert)

Lithography - Contact lithography (2x SUSS MJB3, 1 EVG) - Mask production (GCA 3600)

EBL Electron Beam Lithography Laser interferometer stage 100 mm by 100 mm travel range 2 nm resolution piezo-positioning Minimum line width < 20 nm Stitching accuracy 40 nm Overlay accuracy 40 nm 18.2 nm

Plasma Systems: Etching & Coating Plasma-enhanced CVD processing dielectrics Reactive Ion Etching

RIE ICP Etching of Si & GaAs/AlGaAs/InGaAs & GaN trench 8µm, ridge 20µm, depth 40µm GaAs ICP etching Silicon ICP etching etch rates : 1µm/min trench 8µm, ridge 4µm, depth 40µm

Thin Film Technology Evaporators thermal e-beam Sputter RF-magnetron DC low rate

Coating and Bonding - Spray coating - Wafer bonding - Double sided aligning

Analysis - Focused Ion Beam - Electron Beam Microscope - AFM - Dektak - Ellipsometry

Research Topics: Project Name Funding Project Name CoQuS Euro Graphene HipoSwitch HiTGaN ICARUS Ionenstrahlinduzierte Nanodrahtsynthese IRON II: III-V based IR nanodevices IRON II: IR response of nanostructures IRON II: Electronic transport in nanostructures PLATON THz Photonics PLATON III-V Nanostructures Plasmonic IR Devices RTN: Novel Materials Funding FWF FWF EU-ICT EU-ICT EU-IP FWF FWF SFB FWF SFB FWF SFB FFG FFG EC EU Microdisc Laser WWTF Microstructured Bioelectronic Interfaces Monolithische Integration FWF von Nanodrähten MORGAN EU-NME Nanonoise FWF NILdirect_stamp FFG NSI - NanoScapel FFG Scanning FWF Electroluminescence Microscopy on Nanostructures Spectrosmart FFG......... plus projects funded by companies

High-k Materials high-k nano wire transistors Y 2 O 3 and ZrO 2 MOS-Structures vertically integrated nanowire field effect transistor Single crystalline Si-NW AG E. Bertagnolli

Advanced Lithography Imprint Lithography large area fabrication of nanopatterned surfaces Maskless Lithography direct-writing with focused e-beams AG E. Bertagnolli

Integrated Sensor Systems Physical chemosensors, biochips, microfluidics, MEMS sensors 3D fluidic lens Lorentz-force viscosity sensor Technology: Silicon MEMS, glass, ceramics, SU-8, microstereolitho, 2-photon structuring 2-photon lens AG M. Vellekoop

from nanostructures C C E E B B to optoelectronic devices

Motivation intersubband transitions Electronics Terahertzgap Photonics 10 9 Hz 10 10 Hz 10 11 Hz 10 12 Hz 10 13 Hz 10 14 Hz 10 15 Hz 10 15 Hz Frequency Radiowellen MM MW FIR MIR NIR VIS UV X-Rays 30 cm 3 cm 3 mm 300 µm 30 µm 3 µm 300 nm 30 nm Wavelength intraband laser Applications Spectroscopy @ 3.4-25 µm Fingerprint region Continuous pollutant analysis, trace monitoring optical communication (wireless LAN) in the atmospheric windows medicine applications / scanners (security) / counter measures Basic science new material combinations & concepts telecom wavelength sources & detectors room temperature THz sources

Semiconductor heterostructures conduction band quantum well AlGaAs GaAs AlGaAs energy growth direction growth direction valence band 2D electron gases, phemts (FETs), tunneling diodes (RTDs), quantum wells (MQWs), superlattices (SLs), hot electron transistors, light emitting diodes (LEDs), semiconductor laser, QW laser, VCSELs, QCLs, THz laser, detectors (QWIPs), Bragg reflectors,

Optoelectronic devices interband laser QW Laser intraband laser QC Laser ћω E gap = 1.5 ev ћω = 0.01-0.15 ev CB VB

Quantum Cascade Laser (QCL) e injector injector active region radiative transition An electron streams down a staircase and emits a photon at each step. Cascade: one electron can emit as many photons as cascades.

Device Fabrication for QCLs Design growth of nanostructures waveguide design distance (µm) 0 5 10 15 spacer active spacer substrate mode intensity n+ n+ Fabry-Perot DFB micro-cavity

Nanostructured Devices processing DFB Coupled Cavity Bragg mirror Y-coupled QCL Surface emitter MIR Disks & Rings Lateral & Ring DFBs THz Disks & Rings PBG QCs

Design & Fabrication Mix & Match processing radial grating with e-beam lithography 200 µm ridges, insulations, contacts with standard UV-lithography 40 µm Extended contact Insulation Au-grating 10 µm

MIR Ring-CSEL vs. FP ring-csel FP narrow circular beam (~1.5 ) ring shaped pattern (interference pattern) high beam divergence ~30 (10µm ridge)

Spectra Signal (norm.) 0.4 0.2 Wavelength (µm) 4.1 4.05 4 3.95 3.9 3.85 1.0 0.8 a) FP ring-csel Λ= 1.235 µm 100 khz/20 ns 78 K 10 ka/cm 2 0.6 0.0 2425 2450 2475 2500 2525 2550 2575 2600 Wavenumbers (cm -1 ) Signal (norm.) 1.0 0.8 0.6 0.4 0.2 Wavelength (µm) 8.15 8.1 8.05 8 7.95 7.9 7.85 b) FP ring-csel Λ= 2.521 µm 100 khz/20 ns 293 K 6 ka/cm 2 0.0 1220 1230 1240 1250 1260 1270 1280 Wavenumbers (cm -1 ) Signal (norm.) Frequency (THz) 2.4 2.6 2.8 3.0 3.2 3.4 3.6 3.8 1.0 0.8 0.6 0.4 0.2 Wavelength (µm) 120 110 100 90 80 c) FP ring-csel Λ= 25.43 µm 50 khz/1 µs 10 K 1.8 ka/cm 2 80 90 100 110 120 130 Wavenumbers (cm -1 ) λ~4 µm λ~8 µm λ~93 µm (3.24 THz) side mode suppression ratio (SMSR) higher than 25 db Signal (norm.) 10-1 10-2 10-3 Wavelength (µm) 4.05 4 3.95 3.9 10 0 a) Λ= 1.235 µm 100 khz/20 ns 78 K 10 ka/cm 2 10-4 2460 2490 2520 2550 2580 Wavenumbers (cm -1 ) Signal (norm.) Frequency (THz) 2.8 3.0 3.2 3.4 3.6 Wavelength (µm) 110105 100 95 90 85 80 10 0 c) Λ= 25.43 µm 50 khz/1 µs 10 K 1.8 ka/cm 2 10-1 10-2 10-3 90 95 100 105110 115120 125 Wavenumbers (cm -1 )

Broadband Array Widely spectral tunable array λ 1 λ 2 16-ring-CSEL broadband array 1mm λ n-1 λ n + =

Spectra linear spectral tuning tuning range ~180 cm -1 SMSR ~25 db

Spectral Dependency threshold current density is not influenced by the cavity (grating design, since no facets are present) power and threshold variations given by gain profile ITQW 2011, Sardinia

Outlook coherent coupling coherent high power array λ 1 widely spectral tunable array λ 1 λ 2 2D beam steering λ n-1 λ n

Thanks to and thank you for your attention!

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