Opportunities for ORC Technology in Oil and Gas Fields. Clotilde Rossi di Schio Dallas, May

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Opportunities for ORC Technology in Oil and Gas Fields Clotilde Rossi di Schio Dallas, 19-20 May Doc.: SMU_Turboden_Mitsubishi Update: 18/05/2015

Turboden ORC fields of application Biomass Heat recovery Waste to energy Geothermal electricity heat Turboden designs, develops and maintains turbogenerators based on the Organic Rankine Cycle (ORC), a technology for the combined generation of electric power and heat from various renewable sources, particularly suitable for distributed generation. Solar Turboden solutions from 200 kw to 15 MW electric per single unit 2

35 Years of Experience 2013 - MHI acquires the majority of Turboden. Italian shareholders stay in charge of management 1998 First ORC biomass plant in Switzerland (300 kw) 1980 - Founded by Mario Gaia, professor at Politecnico di Milano Today - Over 300 plants in the world, 240 in operation, 200 employees, 100 M turnover (2012) 2000 s - ORC biomass plants in Europe 1990 s First ORC projects in solar, geothermal and heat recovery applications 2009 - United Technologies Corp. (UTC) acquires the majority of Turboden s quotas. PW Power Systems supports Turboden in new markets beyond Europe. 100 plants sold 3

Organic Rankine Cycle: concept The principle is based on a turbogenerator working as a normal steam turbine to transform thermal energy into mechanical energy and finally into electric energy through an electric generator. Instead of the water steam, the ORC system vaporizes an organic fluid, characterized by a molecular mass higher than water, which leads to a slower rotation of the turbine and to lower pressure and erosion of the metallic parts and blades. Efficiency: 98% of incoming thermal power is transformed into electric power (around 20%) and heat (78%), with extremely limited thermal leaks, only 2% due to thermal isolation, radiance and losses in the generator. The electric efficiency obtained in non-cogeneration cases is much higher (more than 24% of the thermal input). 4

Organic Rankine Cycle: Thermodynamics Turbine Temperature Entropy Heat carrier Evaporator Pump Electric Energy Generator Pre-heater Cooling medium Condenser 5

Water vs High Molecular Mass - Working Fluid Water Small, fast moving molecules Metal parts and blade erosion Multistage turbine and high speed with mechanical stress High molecular mass fluid Large flow rate Larger diameter turbine with high efficiency of the turbine (85-90%) No wear of blades and metal parts Slow rotation speed and few stages (2-6) 6

Traditional Rankine Cycle vs. Organic Rankine Cycle Steam Rankine Cycle Organic RankineCycle (ORC) Temperature Temperature Thermodynamic features and consequences Operation and maintenance costs High enthalpy drop Superheating needed Risk of blade erosion Entropy Water treatment required Highly skilled personnel needed High pressures and temperatures in the cycle Small enthalpy drop No need to superheat No supercritical pressure No risk of blade erosion Entropy Non-oxidizing working fluid with no corrosion issues Minimum personnel and O&M Completely automatic Other features Convenient for large plants and high temperatures Low flexibility with significantly lower performances at partial load High flexibility and good performances at partial load High availability (average >98%) Possibility to work at low temperatures (90+ C) 7

ORC performance at partial load 9

Turboden references Application Size Plants in operation (*) MW no. MW Heat carrier Wood biomass 0.2-8 218 245.8 Thermal oil Geothermal 1.0-6.0 6 19.2 Hot water Combined cycle (bottoming of gas turbines or reciprocating engines) Industrial heat recovery (cement, glass, steel, etc.) 0.5-4.5 9 10.5 0.5-7.0 7 16.5 Waste to energy 0.5-6.0 7 14.3 Total Turboden plants 247 306.3 Thermal oil (7) Direct heat exchange (2) Thermal oil (5) Saturated steam (1) Direct heat exchange (1) Thermal oil (6) Hot water (1) (*) Other 58 plants are under construction Last update: April 2015 10

ORC finds several applications in the Oil&Gas sector A. Hot water from exhausted oil wells B. Gas turbines exhaust gas Gas compressor stations, natural gas liquefaction, gas storage, etc. C. Associated Petroleum Gas (APG) D. Refinery hot streams Distillation columns, Oil/Gasoline/Kerosene production, etc. 16

Oil&Gas applications A Hot water from exhausted oil wells Geothermal water in oil fields Associated hot water 100-180 C (212 356 F) Electric power Cooling towers Water cooled condensers Air cooled condensers Organic Rankine Cycle Efficiency up to 16% Turboden references 31 MW in 9 geothermal plants 25

References Geothermal 6 references in operation, 19 MW installed Sauerlach Customer: SWM - StadtWerke München (Munich multi-utility) Site: Sauerlach, Germany ORC size: 5.6 MWe + 4 MWth to district heating Start up: January 2013 Scope of supply: Complete ORC supply, air condenser includes Dürrnhaar Customer: Hochtief Energy Management GmbH Site: Dürrnhaar (München), Germany ORC size: 5.6 MWe Start up: December 2012 Scope of supply: full EPC for ORC, air condenser and BOP Kirchstockach Customer: Hochtief Energy Management GmbH Site: Kirchstockach (München), Germany ORC size: 5 MWe Start up: January 2013 Scope of supply: full EPC for ORC, air condenser and BOP Key factors: Close to the Munich urban area (<10 km) Coupled with urban district heating network Possibility to work on island mode (Sauerlach) Medium enthalpy: 140 C (284 F) Non-flammable working fluid Small area covered due to houses in the nearby Turboden supply all the components except geothermal pump an circuit 37

References Low temperature water Waste to energy Mirom, Belgium Heat recovery from pressurized water boiler in waste incinerator Customer: MIROM Location: Roeselare, Belgium Source: hot water at 180C 356F (back at 140C 284F) Cooling source: air coolers ORC electric power: 3 MW Electrical efficiency: 16.5% Availability: >98% Start up: Q2 2008 Waste to energy Séché, France Heat recovery from pressurized water boiler in waste incinerator Customer: Séché Environnement Usine - Alcea Location: Nantes, France Source: hot water at 200C 392F (back at 130C 266F) Cooling source: air coolers ORC electric power: 2.4 MW Electrical efficiency: 16.5% Start up: Q3 2014 38

Oil&Gas applications B Gas turbines exhaust gas Gas turbines Gas compressor stations Gas storage GTs Oil pumping stations Sea water injection systems Internal combustion engines Mechanical/ electric power Cooling towers Water cooled condensers Air cooled condensers Heat exchanger Direct exchange Thermal oil (1) Percent of the prime mover nominal power Organic Rankine Cycle 25 35% additional power (1) Turboden References TransGas Canada GT power: 3.5 MWe ORC power: 1 MWe Thermal oil circuit Start up: Q4 2011 Polympex Russia GT power: 25 MWe ORC power: 3 MWe CHP th. power: 15 MWth Direct Exchange Start up: Q4 2014 17

Turboden reference APG exploitation C Associated Petroleum Gas (APG) Site: Perm, Russia Customer/End user: LabNT/LUKoil Status: started up in June 2012 Heat source: flare gas burning (boiler designed to burn gas with a minimum lower calorific value of 4,500 kcal/nm3 Heat source temperature: thermal oil at 300 C Inlet/Outlet water temperature: 65/95 C (149/203 F) Electric power: 1.8 MW Net electric efficiency: 18% Project description Flare gas from oil extraction wells is burned to heat up thermal oil which is used to feed up an ORC CHP unit. The electricity produced reduces the plant consumptions, whereas the hot water produced is exploited in oil refinery processes including warming up of refined products to be pumped. 27

Oil&Gas applications D Refinery hot streams Electric power Hot stream used for treatment and then dissipated Thermal oil used in Oil&Gas processes Cooling towers Water cooled condensers Air cooled condensers Organic Rankine Cycle Efficiency up to 25+% (1) Turboden case study Thermal oil power: 53 MWth ORC electric power: 10 MW (1) Heat carrier temperature above 300 C 29

Thank you! For further information: clotilde.rossi@turboden.it www.turboden.eu 17