Chemistry/Science. Unit C1: Chemistry in Our World

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Write your name here Surname Other names Pearson Edexcel GCSE Centre Number Chemistry/Science Unit C1: Chemistry in Our World Candidate Number Thursday 15 May 2014 Morning Time: 1 hour You must have: Calculator, ruler Foundation Tier Paper Reference 5CH1F/01 Total Marks Instructions Use black ink or ball-point pen. Fill in the boxes at the top of this page with your name, centre number and candidate number. Answer all questions. Answer the questions in the spaces provided there may be more space than you need. Information The total mark for this paper is 60. The marks for each question are shown in brackets use this as a guide as to how much time to spend on each question. Questions labelled with an asterisk (*) are ones where the quality of your written communication will be assessed you should take particular care with your spelling, punctuation and grammar, as well as the clarity of expression, on these questions. Advice Read each question carefully before you start to answer it. Keep an eye on the time. Try to answer every question. Check your answers if you have time at the end. Turn over P43426RA 2014 Pearson Education Ltd. 1/1/1/1/1/ *P43426RA0120*

The Periodic Table of the Elements 1 2 3 4 5 6 7 0 Key 1 H hydrogen 1 4 He helium 2 7 Li lithium 3 9 Be beryllium 4 relative atomic mass atomic symbol name atomic (proton) number 11 B boron 5 12 C carbon 6 14 N nitrogen 7 16 O oxygen 8 19 F fluorine 9 20 Ne neon 10 23 Na sodium 11 24 Mg magnesium 12 27 Al aluminium 13 28 Si silicon 14 31 P phosphorus 15 32 S sulfur 16 35.5 Cl chlorine 17 40 Ar argon 18 39 K potassium 19 40 Ca calcium 20 45 Sc scandium 21 48 Ti titanium 22 51 V vanadium 23 52 Cr chromium 24 55 Mn manganese 25 56 Fe iron 26 59 Co cobalt 27 59 Ni nickel 28 63.5 Cu copper 29 65 Zn zinc 30 70 Ga gallium 31 73 Ge germanium 32 75 As arsenic 33 79 Se selenium 34 80 Br bromine 35 84 Kr krypton 36 85 Rb rubidium 37 88 Sr strontium 38 89 Y yttrium 39 91 Zr zirconium 40 93 Nb niobium 41 96 Mo molybdenum 42 [98] Tc technetium 43 101 Ru ruthenium 44 103 Rh rhodium 45 106 Pd palladium 46 108 Ag silver 47 112 Cd cadmium 48 115 In indium 49 119 Sn tin 50 122 Sb antimony 51 128 Te tellurium 52 127 I iodine 53 131 Xe xenon 54 133 Cs caesium 55 137 Ba barium 56 139 La* lanthanum 57 178 Hf hafnium 72 181 Ta tantalum 73 184 W tungsten 74 186 Re rhenium 75 190 Os osmium 76 192 Ir iridium 77 195 Pt platinum 78 197 Au gold 79 201 Hg mercury 80 204 Tl thallium 81 207 Pb lead 82 209 Bi bismuth 83 [209] Po polonium 84 [210] At astatine 85 [222] Rn radon 86 [223] Fr francium 87 [226] Ra radium 88 [227] Ac* actinium 89 [261] Rf rutherfordium 104 [262] Db dubnium 105 [266] Sg seaborgium 106 [264] Bh bohrium 107 [277] Hs hassium 108 [268] Mt meitnerium 109 [271] Ds darmstadtium 110 [272] Rg roentgenium 111 Elements with atomic numbers 112-116 have been reported but not fully authenticated * The lanthanoids (atomic numbers 58-71) and the actinoids (atomic numbers 90-103) have been omitted. The relative atomic masses of copper and chlorine have not been rounded to the nearest whole number. 2 *P43426RA0220*

BLANK PAGE Questions begin on next page. *P43426RA0320* 3 Turn over

Answer ALL questions. Some questions must be answered with a cross in a box. If you change your mind about an answer, put a line through the box and then mark your new answer with a cross. Changes in the atmosphere 1 (a) The Earth s earliest atmosphere was very different from the Earth s atmosphere today. Complete the sentence by putting a cross ( ) in the box next to your answer. The Earth s earliest atmosphere was formed by A animals breathing B C D global warming plants decaying volcanic activity (b) Use words from the box to complete the sentences. Each word may be used once, more than once, or not at all. argon carbon dioxide carbonates neon nitrogen (3) (i) The Earth s earliest atmosphere is thought to have contained mainly... (ii) Over the years, carbon dioxide dissolved in the oceans and was absorbed by marine organisms. The marine organisms eventually formed rocks which are... (iii) The Earth s atmosphere today contains approximately 79% of... 4 *P43426RA0420*

(c) There is much less water vapour in the Earth s atmosphere today than in the Earth s earliest atmosphere. Explain how the amount of water vapour decreased. (d) When plants first started to grow on the Earth they caused the composition of the atmosphere to change. Describe how the composition of the atmosphere changed as a result of plants growing. (Total for Question 1 = 8 marks) *P43426RA0520* 5 Turn over

Metals 2 (a) Metals are extracted from rocks found in the Earth s crust. Complete the sentence by putting a cross ( ) in the box next to your answer. Rocks from which metals are extracted are called A alloys B C D elements ores polymers (b) Copper is used as the wire in electric cables. copper wire plastic coating State two reasons why copper is used as the wire in electric cables. 6 *P43426RA0620*

(c) Iron is formed by heating a mixture of iron oxide and carbon. (i) Complete the word equation for this reaction. iron oxide + carbon... +... (ii) In this reaction iron oxide is reduced to iron. Describe what is meant by the term reduced. (d) Metals in waste products are often recycled. Describe the benefits of recycling metals. (Total for Question 2 = 8 marks) *P43426RA0720* 7 Turn over

Hydrochloric acid and chlorine 3 Hydrochloric acid can be electrolysed to form two gases, using the apparatus shown in the diagram. chlorine gas X hydrochloric acid + 6 V d.c. supply (a) Chlorine is one of the gases formed. Give the name of gas X. (b) (i) Write the formula for a molecule of chlorine gas. (ii) Complete the sentence by putting a cross ( ) in the box next to your answer. Chlorine is used on a large scale to A neutralise soil acidity B C D neutralise acidic gases in power stations manufacture bleach manufacture poly(ethene) 8 *P43426RA0820*

(iii) Describe a test to show a gas is chlorine. (c) Hydrochloric acid is present in the stomach. Describe what hydrochloric acid does in the stomach. (d) Magnesium carbonate reacts with dilute hydrochloric acid. Complete the word equation for this reaction......... magnesium hydrochloric + carbonate acid + +......... (3) (Total for Question 3 = 10 marks) *P43426RA0920* 9 Turn over

Crude oil fractions 4 Crude oil can be separated into useful products. (a) Crude oil is non-renewable. State what is meant by the term non-renewable. (b) Crude oil is separated into fractions by fractional distillation. The diagram shows a fractional distillation column and the fractions produced. fractions gases petrol kerosene diesel oil heated crude oil fuel oil bitumen (i) Draw one straight line from each fraction to a use of that fraction. fraction kerosene fuel oil bitumen use of fraction surfacing roads fuel for large ships fuel for planes fuel for trains 10 *P43426RA01020*

(ii) The petrol fraction and the diesel oil fraction have different physical properties. Choose one property, describing the difference between the fractions. (c) The petrol fraction contains octane, C 8 H 18. Octane is a hydrocarbon. Describe what is meant by the term hydrocarbon. (d) The oil industry uses a process to break down longer chain hydrocarbon molecules into shorter chain hydrocarbon molecules. (i) Complete the sentence by putting a cross ( This process is called ) in the box next to your answer. A B C D cracking extraction polymerisation recycling *P43426RA01120* 11 Turn over

(ii) The shorter chain hydrocarbon molecules produced are alkanes and alkenes. Bromine can be used to distinguish between alkanes and alkenes. Describe what is seen when bromine water, which is orange-coloured, is shaken with an alkane and with an alkene. (Total for Question 4 = 10 marks) 12 *P43426RA01220*

Fuels 5 (a) Petrol is a flammable liquid. Which hazard symbol is used on containers to show that the liquid in the container is flammable? Put a cross ( ) in the box to show your answer. A B C D (b) Some people suggest that hydrogen, rather than petrol, should be used as a fuel in cars but there are disadvantages in the widespread use of hydrogen. Describe the disadvantages of hydrogen, rather than petrol, being used as a fuel in cars. (3) *P43426RA01320* 13 Turn over

(c) Sulfur is an impurity in many fuels. When fuels containing sulfur impurities are burnt, sulfur dioxide is released into the atmosphere. Describe some problems this sulfur dioxide can cause. *(d) Experiments were carried out to measure the heat energy given out when three liquid fuels, A, B and C, were burned. In each experiment the same mass of fuel was used to heat the same volume of water, using the apparatus shown. thermometer clamped beaker containing 100 g of water spirit burner liquid fuel 14 *P43426RA01420*

Here are the results, together with the cost of the mass of fuel burnt in each experiment. fuel initial temperature of water ( C) final temperature of water ( C) cost of fuel burnt (pence) A 15 51 3.0 B 16 21 0.5 C 15 39 2.0 observations of the way the fuel burns burns with a blue flame no smoke burns with a yellow flame black smoke burns with a yellow flame no smoke A student considered these results and decided that fuel B was the best fuel. Considering all the evidence for the fuels, A, B, and C, explain whether this is a good choice or not. (6) (Total for Question 5 = 12 marks) *P43426RA01520* 15 Turn over

Limestone 6 (a) Limestone occurs naturally as calcium carbonate. When calcium carbonate, CaCO 3, is heated strongly, calcium oxide and carbon dioxide, CO 2, are formed. (i) State the formula of calcium oxide. (ii) What type of reaction is this? Put a cross ( ) in the box to show your answer. A incomplete combustion B C D oxidation precipitation thermal decomposition (iii) Write the word equation for this reaction. (b) Limestone is a sedimentary rock. Describe how sedimentary rocks are formed. 16 *P43426RA01620*

*(c) The photograph shows a limestone quarry. There is a proposal to open a limestone quarry near a village in a popular tourist area. Evaluate the advantages and disadvantages to the local area of opening this quarry. (6) (Total for Question 6 = 12 marks) TOTAL FOR PAPER = 60 MARKS *P43426RA01720* 17

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