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Technical Social Political Economic 3.003 Problem Definition Figure of Merit System Design Constraints, Tradeoffs Statistics of Variation Tolerance, Capability Principles of Engineering Practice Research Methodology (10min) The Ethical Engineer (30min) Light-Matter Interactions (10min) Lionel C. Kimerling

Laboratory Methodology The Complete Engineer s Skill Set Technical Social Political--Economic Problem Definition Constraints Options Analysis Solution

3.003 Technology Problems The Complete Engineer s Skill Set Technical Social Political--Economic Add the following to your lab report. Problem Definition What problem is the team solving? Experiment Design What are the constraints that the team faces? Solution Justify the experimental design?

3.003 Technology Problems The Complete Engineer s Skill Set Technical Social Political--Economic Problem Definition Attributes, Specifications Design Constraints Options Analysis Solution Results Figure of Merit: Tradeoffs Statistics of Variation: Tolerance, Capability

Figure of Merit materials selection Materials Design Property relation to Performance Example: problem and constraint load bearing with lightest weight Volume = LxA P = load (1/m) max = Performance Materials Properties tensile strength = σ = P/A=load/area m = density x volume = ρal 1/m = σ/ρ x 1/PL FOM =1/m= σ/ρ =tensile strength/density

Ethical Practice

An Ethical Engineer? Conflicting motivations divergence between commerce and engineering? is the data sufficient? Ethical action most good for most people? absolute right and wrong? Dealing at the boundaries

Laboratory Methodology The Complete Engineer s Skill Set Technical Social Political--Economic Problem Definition Constraints Options Analysis Solution

Ethics Basics Absolute of Judgment? Rationale: good world or self? Truth = fuel of the mind science of variation Can sustainability be built on fiction? Ethics is not an act, but a lifetime; it is the definition of self

The Puzzle of Moral Judgment Kant Right is principles that everyone can follow. Mill Right is the greatest good for the greatest number of people. Right before good or good before right?

Ethics: Private vs. Public Your purpose in life Your methods of achieving that purpose

Ethics: Private vs. Public HYPOTHESIS OR FACT? The way that you live has consequences for the lives of others.

Light and Matter

Light is an Electromagnetic Wave Courtesy of the Opensource Handbook of Nanoscience and Nanotechnology.

Observables Electromagnetic Field Photonic Materials voltage current dielectric constant, ε/ε 0 index of refraction, n absorption, α wavelength, λ group velocity, v g = c o /N; N = group index power, P

c material = c 0 /n r n r = (ε/ε 0 ) 1/2 (static) n (υ) Si 11.7 3.5 Ge 16 4 LiNbO 3 43 2.27 BaTiO 3 3600 2.46 c=speed of light; n r =refractive index; ε= electric permittivity ε/ε 0 =dielectric constant

Materials Design by Property Maps Metal CN = 8 Index of refraction Dielectric constant Melting point Lattice parameter Average principal quantum number metallicity CN = 4 (ZB) CN = 4 (W) Hybridization energy Electronegativity difference CN = 6 ionicity hardness Insulator Energy gap Carrier mobility Figure by MIT OpenCourseWare.

Lab #1 Appendix 1 Water Vapor and AR Coatings

Optical absorption of water Courtesy of Martin Chaplin. Used with permission.

Solar spectrum From Haug, Franz-Josef. "Irradiation Spectrum." Solar Cells: Generating Electricity from Light. Used with permission.

Refractive indices Material Refractive index Air 1.0 Water 1.33 SiO 2 1.5 Si 3 N 4 2.0 Si 3.5

Anti-reflection (AR) coatings Elimination of reflection on surfaces: Solar cells Photodetectors Photolithography Quarter wave film

SiO 2 -on-si Color Chart Film thickness, microns Color and comment Film thickness, microns Color and comment 0.05 Tan 0.68 "Bluish" 0.07 0.10 Brown Dark violet to red-violet 0.72 0.77 Blue-green to green (quite broad) "Yellowish" 0.12 Royal blue 0.80 Orange (rather broad for orange) 0.15 Light blue to metallic blue 0.82 Salmon 0.17 Metallic to very light yellow-green 0.85 Dull, light red-violet 0.20 Light gold to yellow - slightly metallic 0.86 Violet 0.22 Gold with slight yellow-orange 0.87 Blue-violet 0.25 Orange to melon 0.89 Blue 0.27 Red-violet 0.92 Blue-green 0.30 Blue to violet-blue 0.95 Dull yellow-green 0.31 Blue 0.97 Yellow to "yellowish" 0.32 0.34 Blue to blue green Light green 0.99 1.00 Orange Carnation pink 0.35 Green to yellow-green 1.02 Violet-red 0.36 Yellow-green 1.05 Red-violet 0.37 Green-yellow 1.06 Violet 0.39 Yellow 1.07 Blue-violet 0.41 Light orange 1.10 Green 0.42 Carnation pink 1.11 Yellow-green 0.44 Violet-red 1.12 Green 0.46 Red-violet 1.18 Violet 0.47 Violet 1.19 Red-violet 0.48 Blue-violet 1.21 Violet-red 0.49 Blue 1.24 Carnation pink to salmon 0.50 Blue-green 1.25 Orange 0.52 Green (broad) 1.28 "Yellowish" 0.54 Yellow-green 1.32 Sky blue to green-blue 0.56 Green-yellow 1.40 Orange 0.57 Yellow to "yellowish" 1.45 Violet 0.58 Light-orange or yellow to pink borderline 1.46 Blue-violet 0.60 Carnation pink 1.50 Blue 0.63 Violet-red 1.54 Dull yellow-green Figure by MIT OpenCourseWare.

MIT OpenCourseWare http://ocw.mit.edu 3.003 Principles of Engineering Practice Spring 2010 For information about citing these materials or our Terms of Use, visit: http://ocw.mit.edu/terms.