DIMENSIONAL STABILITY AND THERMOPLASTIC POLYOLEFIN (TPO) ROOF MEMBRANES



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DIMENSIONAL STABILITY AND REFLECTIVITY OF FIELD EXPOSED THERMOPLASTIC POLYOLEFIN (TPO) ROOF MEMBRANES Ana H. Delgado 1, Chuck Chapman 2, KC Barnhardt 3, Jim Carlson 4, Randy Ober 5, Dwayne Wacenske 6, Steve Moskowitz 7, Michael Ludwig 4, Stephen Elliott 4, Ralph M. Paroli 1

WSRCA s TPO Task Group Christian Madsen, WSRCA President, and the Last 10 WSRCA Presidents. KC Barnhardt, WSRCA Former President, Task Group Co-Chairman Arlene Lawson, WSRCA Executive Director Randy Ober, Carlisle SynTec Dwayne Wacenske, Firestone Building Products Mark Sansing, American Roofing & Metal Co., San Antonio, Texas Tim Gardner, Snyder Roofing, Seattle, Washington Misty Stoddard & Curt Miller, Rainproof Roofing, Anchorage. Alaska Mark Sansing, American Roofing & Metal Co., San Antonio, Texas Dennis Conway & Ray Snow, Commercial Roofers, Inc., Las Vegas, NV Tim Gardner & Kyle King, Snyder Roofing, Seattle, Washington Ana H. Delgado, Ralph M. Paroli, National Research Council of Canada Stephen Elliot, Michael Ludwig, Bill Collins, Darrell Hunt, Ernie Rosenow, Andy Leonard, and Jim Carlson of BET&R

Issues Reported by Contractors

Montana TPO Roof Cracking Along the Interior Seam Line

Montana TPO Roof Surface Crazing or Micro-cracking and delamination of top coating.

Early Generation TPO Roof in Oregon

Same Early Generation TPO Roof in Oregon Section of Roof Adjacent the Windows

There can be no progress if people have no faith in tomorrow President John F. Kennedy

Program Goal To provide pertinent technical and performance information to the North American roofing industry at large, regarding 60-mil (1.5 mm) TPO roof membrane (over polyiso) attributes, their performance properties and resistance to degradation due to the effects of weathering Inception: 2000

General Installation and Exposure Information Area 1 Area 2 Area 3 Area 4 The Roofs Are Divided Into Four (4) Individual Areas. Each Test Roof Area Is Separated by a Roof Area Divider and Must Drain Individually

Overview of Properties tested Mechanical Properties Thickness, Sheet Overall Thickness of Coating Over Scrim Linear Dimensional Change Water Absorption Tensile Properties Seam Strength Surface Characteristics (Thickness, Reflectivity) Chemical Properties Dynamic mechanical analysis (DMA) Thermogravimetry (TG/DTG) Fourier transform infrared spectroscopy (FTIR)

Anchorage, Alaska Cold and Damp

Las Vegas, Nevada Hot and Dry

Seattle, Washington Moderate and Wet/Dry

San Antonio, Texas Hot and Humid

Las Vegas Roof Area 2 A slight increase in tightening was observed at year ten in multiple locations.

Anchorage Roof Area 4 Weldability Test patches were welded on the existing membrane, then field peel tests were performed.

Las Vegas Roof Area 1 Effect of Hard Creases A photo from original installation of the TPO membrane in 2000. Note how the bucket and roofer s foot are hard-creasing the membrane.

Las Vegas Roof Area 2 Effect of Hard Creases A side lap seam where creasing during installation and sun/heat load have led to cracking of the creases (2011)

A close-up view of an isolated crease crack Las Vegas Roof Area 2 Effect of Hard Creases

Dimensional Stability Change in length or width of membrane due to exposure to elevated temperatures or membrane relaxation Can affect waterproofing integrity Expansion can cause wrinkling Shrinkage can lead to tearing or cracking

Linear Dimensional Change Measured based on ASTM D1204-02 Samples were removed from the oven and reconditioned in the laboratory at 23 ± 2 C (73 ± 4 F) and 50 ± 5% RH for at least 1 h. The linear dimensional change is the change in dimension as a percent of the original dimension. Dimensional Change = (D f - D o )/D o x 100% A positive linear dimensional change indicates expansion while a negative value denotes shrinkage.

1.0 0.6 0.2-0.2-0.6 Area1 Area2 Area3 Area4 ASTM Spec. = ± 1% 0.4 Linear Dimensional Change (MD) Area1 Area2 Area3 Area4 AK(7-yrs) LV(7-yrs) SEA(7-yrs) TX(7-yrs) LV(7-yrs) SEA(7-yrs) TX(7-yrs) AK(7-yrs) -1.0 Location 0.2 0.0-0.2-0.4 Location Change (%) Change (%)

Why is Reflectivity important? Solar reflectance is a key characteristic of a roof membrane in terms of mitigating the urban heat island effect and helping reduce energy demands during warmer months New, white TPO membranes usually have a reflective value greater than 80%, which exceeds the U.S. Environmental Protection Agency s ENERGY STAR performance levels set at 65% when new and 50% after three years exposure.

Reflectivity Testing in the Field

Reflectivity Testing

Reflectivity Testing

Reflectivity Testing

Reflectivity Testing

Reflectivity Testing at Cleaned Area

Reflectivity Test Reading

Pressure Washing

Scrubbing to Clean Surface

Scrubbing to Clean

Reflectivity Testing Cleaned Areas

Solar Reflectivity Testing Anchorage, Alaska WSRCA TPO WEATHERING FARM TEST COMPARISONS FROM REGIONAL LOCATIONS Las Vegas, Nevada San Antonio, Texas Seattle, Washington AGE OF ROOF AREA ROOF AREA ROOF AREA ROOF REA ROOF 1 2 3 4 1 2 3 4 1 2 3 4 1 2 3 4 AVERAGE New - - - - - - - - - - - - - - - - Average: 0.826 Average: 0.826 Average: 0.826 Average: 0.826 0.826 7-Month - - - - - - - - - - - - 0.670 0.657 0.676 0.668 Average: - Average: - Average: - Average:* 0.668 0.668 3-4 Year 0.720 0.595 0.603 0.626 0.693 0.721 0.654 0.701 0.000 0.000 0.000 0.000 0.683 0.605 0.618 0.656 Average: 0.636 Average: 0.692 Average: 0.000 Average: 0.641 0.656 Elapsed Change: - 0.190 Elapsed Change: - 0.125 Elapsed Change: - - Elapsed Change: - 0.186 0.170 * Unofficial test results taken only at Seattle TPO Test Roof CLEANED ROOF AREA TEST COMPARISONS FROM REGIONAL LOCATIONS AGE OF Anchorage, Alaska Las Vegas, Nevada San Antonio, Texas Seattle, Washington ROOF 1 2 3 4 1 2 3 4 1 2 3 4 1 2 3 4 AVERAGE New - - - - - - - - - - - - - - - - Average: 0.826 Average: 0.826 Average: 0.826 Average: 0.826 0.826 3-4 Year 0.774 0.680 0.681 0.723 0.746 0.761 0.742 0.783 0.000 0.000 0.000 0.000 0.713 0.628 0.669 0.732 Average: 0.715 Average: 0.758 Average: 0.000 Average: 0.686 0.719 Elapsed Change: - 0.112 Elapsed Change: - 0.068 Elapsed Change: - Elapsed Change: - 0.141 0.107

Reflectivity Testing WSRCA TPO WEATHERING FARM PROJECT: LAS VEGAS, NEVADA DATE: 6/3/2004 SURFACE TYPE: WHITE TPO ROOF AREA: 4 PURPOSE: REFLECTIVITY / REFLECTANCE TESTING INSTRUMENT: D & S Model SSR-ER (Version 5.0) ON-SITE START END INDUSTRY STANDARD CALIBRATION: AGE OF SURFACE: Approx. 48 MONTHS REFLECTANCE OPERATOR: Ross Robertson METER READER AND DATA ASSEMBLY: Ernie Rosenow CALIBRATION: 0.787 0.787 NBS A92 = 0.787 TEMPERATURE & HUMIDITY: 129 F at 3% REFLECTIVITY TESTS ON EXISTING/UNCLEANED TPO ROOF MEMBRANES ROOF COMPARISON OF ENTIRE TEST EXISTING/EXPOSED ROOF AREA TEST LOCATIONS AVERAGE AREA ROOF AREA AVERAGE ZONE A B C D E 1 0.693 1 0.707 0.712 0.711 0.705 0.671 0.701 2 0.721 2 0.680 0.669 0.672 0.689 0.696 0.681 3 0.654 3 0.714 0.709 0.699 0.713 0.707 0.708 4 0.701 4 0.704 0.696 0.703 0.688 0.678 0.694 ENTIRE ROOF AREA 0.692 5 0.692 0.700 0.679 0.686 0.699 0.691 REFLECTIVITY AVERAGE 6 0.705 0.702 0.707 0.700 0.714 0.706 7 0.694 0.724 0.710 0.709 0.708 0.709 8 0.719 0.710 0.718 0.709 0.705 0.712 9 0.716 0.713 0.709 0.707 0.712 0.711 10 0.689 0.697 0.701 0.688 0.680 0.691 TOTAL ROOF AREA 4 AVERAGE: 0.701 REFLECTIVITY TESTS ON CLEANED TPO ROOF MEMBRANES ON-SITE START END TEMPERATURE & HUMIDITY To Testing * Test Zone Pressure Washed And Dried Prior CALIBRATION: 0.758 0.787 132 F at 2% TEST CLEANED TEST LOCATIONS AVERAGE ^ Test Zone Rinsed/Wetted, Scrubbed With ZONE A B C D E Stiff-Bristle Push Broom, And Dried Prior 4A* 0.768 0.774 0.765 0.761 0.755 0.765 To Testing 4B^ 0.804 0.795 0.808 0.800 0.804 0.802 AVERAGE: 0.783

Reflectivity Laboratory Measurements Experimental procedure Unexposed, three, seven and ten years samples from the WSRCA research project were selected for reflectivity measurements Five specimens 3 cm x 4 cm (1.2 in x 1.6 in) in size were cut from each of the as received (0-, 3- and 7- yrs) samples. Due to time limitation, only two specimens from each of the ten years samples were cut and tested.

Reflectivity Laboratory Measurements A Cary 5E UV-VIS-NIR spectrophotometer equipped with a diffuse reflectance accessory and the Cary WinUV Scan software was used to measure the reflectivity of specimens The top ply surface of the specimen before and after cleaning was measured in the 2500 300 nm range The specimen surface was cleaned by wiping the surface with a damped kimwipes and allowed to dry for at least 20 minutes before re-scanning.

Reflectivity Calculations The E903 Tool Simplified0011 integrator a, which is the newest version of the Spectral Integrator Workshop b was used as calculating tool a b E903 Solar Reflectance, Coded by Ronnen Levinson, Lawrence Berkeley Laboratory. Revised 2008-03-02 to remove display of directnormal ( collimated ) solar reflectance Courtesy of Dr. Hashemn Akbari and Dr. Ronnen Levinson, Heat Island Group, Lawrence Berkeley National Laboratory, USA

Typical Reflectance Graphs from Integrator 1.0 uv vis nir 1.8 AK1e10 bot 1 drity G:sol=0.86,uv=0.14,vis=0.92,nir=0.88 0.9 1.6 AK1e10 bot 1 clean G:sol=0.86,uv=0.14,vis=0.92,nir=0.88 Reflectance 0.8 0.7 0.6 0.5 0.4 0.3 1.4 1.2 1.0 0.8 0.6 Irradiance (W m -2 nm -1 ) AK1e10 bot 2 drity G:sol=0.87,uv=0.15,vis=0.93,nir=0.88 AK1e10 bot 2 clean G:sol=0.85,uv=0.14,vis=0.90,nir=0.87 AK1e10 bot 3 dirty G:sol=0.86,uv=0.14,vis=0.92,nir=0.88 AK1e10 bot 3 clean G:sol=0.87,uv=0.14,vis=0.92,nir=0.88 0.2 0.4 400 nm line 0.1 0.2 700 nm line 0.0 0.0 250 500 750 1000 1250 1500 1750 2000 2250 2500 Wavelength (nm) sol=300-2500 nm; uv=300-400 nm; vis=400-700nm; nir=700-2500 nm (G) AM1.5 Global Tilt Solar Irradiance, ASTM G173-03 (uv=5%,vis=43%,nir=52%)

Laboratory Reflectivity b = before cleaning c = clean 1.0 Reflectivity 0.8 0.6 0.4 Unexp. 3-Yrs. 7-Yrs. 10-Yrs Minimum requirement for new 0.2 0.0 AK1bc AK1c AK2bc AK2c AK3bc AK3c AK4bc AK4c 1.0 0.8 Unexp. 3-yrs. 7-yrs. 10-yrs. Minimum requirement for new Reflectivity 0.6 0.4 0.2 0.0 LV1b LV1c LV2b LV2c LV3b LV3c LV4b LV4c

Laboratory Reflectivity b = before cleaning c = clean 1.0 Reflectivity 0.8 0.6 0.4 Unexp. 3-yrs. 7-yrs. 10-yrs. Minimum requirement for new 0.2 0.0 SEA1b SEA1c SEAb SEA2c SEA3b SEA3c SEA4b SEA4c 1.0 Reflectivity 0.8 0.6 0.4 Unexp. 3-yrs. 7-yrs 10.yrs. Minimum requirement for new 0.2 0.0 TX1b TX1c TX2b TX2c TX3b TX3c TX4b TX4c

Conclusions The linear dimensional change of all seven years samples was within the maximum allowable limit of ±1% as specified in ASTM D6878 for new membranes. After the small changes observed in the first year of exposure, the linear dimensional stability in MD and XD remained almost unchanged up to seven years of service in the field. In general, the reflectivity of the roof membranes increased by less than 10% after cleaning, regardless of the cleaning method with the exception of the Texas field values, which show an increase up to 16% after cleaning.

Reflectivity Reflectivity values for the new samples measured in the laboratory are, in general, similar to those measured in the field. Values for exposed samples show larger differences. Alaska and Las Vegas, the difference between lab and field values range from 0 to 8% and increases to 15% for the Texas samples The reflectivity values for the 3- and 7-year samples before cleaning (2 nd time) range from 61% to 87% and from 69% to 88% after cleaning with a damped cloth. Higher reflectivity values after cleaning. Values after cleaning are above the 50% ENERGY STAR specified limit for exposed membranes

General Conclusions Climate plays a large role in the service life of all roof systems, including TPO materials. In general, all four test areas in all four climatic regions are doing well, with the exception of one area at the Las Vegas site. o Alaska: cold, harsh climate, roof covered with snow for weeks. o Las Vegas: hot, dry, and extremely sunny climate. o San Antonio: hot, humid, and sunny climate with hail. o Seattle: cool and rainy, predominantly cloudy climate.

Las Vegas Roof Area 2 Overview Close-Up View

Conclusions (continued) The widespread rumored TPO craze-cracking, reported by some to be happening on many aging TPO roofs was not experienced with these 60- mil, white TPO roof research and testing project. Crease-cracking was experienced on one roof area in one isolated location in San Antonio at year 7, and in numerous locations on one roof area in Las Vegas at year 10. Those cracks were initiated by creasing of the roof membrane during installation a practice that was discouraged by the Task Group 5 years ago

Conclusions (continued) Micro-cracking adjacent to the outer seam edge was observed at year ten on the Las Vegas roof area that also experienced crease-cracking. Some hand-welded T-joint covers, corner boots, and other hand-welded seam edges experienced some disbonding. But, no robotic-welded seams disbonded during this 10+ year study. The disbonded hand welds and the crazed or cracked membranes were all repairable, and all membranes are serviceable today. No widespread-catastrophic problems were observed. In general, these 3 rd generation white 60-mil TPO membranes are performing successfully.

Recommendations When specifying TPO roof membranes, consider using white, 60 mil (minimum). In hot, sunny, or high-altitude sunny regions, WSRCA also strongly suggests thicker membranes be considered. WSRCA strongly urges ASTM and other standards-setting WSRCA strongly urges ASTM and other standards-setting organizations to develop rating classifications, which could include Types (e.g., Type I, Type II, etc.) and/or grades (e.g., 1, 2, 3, or Commodity-Grade, Commercial-Grade, Premium-Grade, etc.) for all roof system categories, including all single-ply membranes.

Recommendations (continued) As with all roof systems, WSRCA recommends inspecting TPO roofs on a yearly (minimum) basis. Just like regular service extends the life of your car regular roof inspections, maintenance, and repairs extend the life of all roof systems. Regular roof inspection, maintenance, and repair is essential for the longevity of the roof system. Every roof system is different, thus different repair techniques may be required. To thoroughly address TPO repair techniques, WSRCA developed the TPO Maintenance and Repair Guidelines.

In Memory of Terry Simmons

Thank you!