3-D Printing Artificial Reservoir Rocks to Test Their Petrophysical Properties*



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3-D Printing Artificial Reservoir Rocks to Test Their Petrophysical Properties* Sergey Ishutov 1 and Franciszek Hasiuk 1 Search and Discovery Article #41427 (2014) Posted August 29, 2014 *Adapted from oral presentation given at 2014 AAPG Annual Convention and Exhibition, Houston, Texas, April 6-9, 2014 **AAPG 2014 Serial rights given by author. For all other rights contact author directly. 1 Geological and Atmospheric Sciences, Iowa State University, Ames, Iowa (Ishutov_s@mail.ru) Abstract At present, pore-scale imaging and modeling are becoming routine geoscience techniques of reservoir simulation in the oil and gas industry. The foundation of these techniques is the development of sophisticated three-dimensional models that can represent both the multiphase flow dynamics and the geometry of the rock's pore system. Three-dimensional printing may facilitate the transformation of pore-space imaging into rock models, which can be tested using traditional laboratory methods to provide data that is easily comparable to literature data. Although current methodologies for rapid rock modeling and printing obscure many details of rock geometry, computed tomography data is one route to refine pore networks and experimentally test hypotheses related to rock properties, such as porosity and permeability. This study uses three-dimensional printing as a novel way of interacting with (a) x-ray computed tomography data from reservoir rocks, and (b) mathematical models of pore systems in coarse-grained sandstones and limestones. These artificial rocks will be used as a proxy to better understand the contributions of various pore system characteristics at various scales to petrophysical properties in oil and gas reservoirs. Pore sizes of typical reservoir sandstone range from 0.1 to 100s of microns. The resolution of three-dimensional digital printing used in the study varied from 16 to 300 microns, therefore, the threedimensional imaging and especially printing might have lost information on pore geometry. The increase in scale of the pore systems (e.g. from 1 micron in reality to 50 microns in a three-dimensional model) will be a key factor for a precise determination of porosity-permeability relationships as they can be verified against core-scale measurements. The long-term

goal of this study is to focus on testing of petrophysical hypotheses by manipulating digital rock models to determine the resulting changes in artificial rock properties that affect fluid flow. If the pore system models could include tools for adequate measurements of petrophysical properties in manufactured rocks in the laboratory conditions, the accuracy of reservoir flow simulations would be increased. Three-dimensional printing offers a great potential to improve our approach to reservoir simulation, facilitating more efficient oil and gas recovery.

The Use of Computed Tomography and 3D Printing Technology to Replicate Reservoir Pore Systems Advisor: Dr. Franek Hasiuk Sergey Ishutov, PhD student Collaborators: Dr. Chris Harding and Dr. Joe Gray April 7, 2014

AGENDA Introduction Definition of Pores in Reservoir Rocks Importance Challenges of Pore Network Modeling Hypothesis and objectives CT scanning Complexities in Porosity-Permeability Scanning Modeling Reconstruction of CT volume Network Extraction 3D printing Resolution and positioning accuracy Artificial core plugs Petrophysical Measurements Porosity-permeability of natural and artificial rocks

PORES? pore Modified from www.globalccsinstitute.com www.threadless.com

IMPORTANCE Reservoir core plugs Replication of solid materials and pore systems Slicing - scale matters! Demonstration... research c B 0 400 ~m elements, 500 11m pores 400 \lm elements, 375 11m pores GeoFabLab, Iowa State University International Petroleum Technology Conference, Qatar, January 2014

Nelson, 2009 Printing Limit (Positioning Precision) 2.5 µm Scanning Limit (Voxel Dimension) 6 µm Not Scanable Not Printable Scanable Printable

WHAT and WHY? Hypothesis: Textural and petrophysical properties of porous reservoir rocks can be replicated with computed tomography (CT) and three-dimensional (3D) printing technology. Objectives: 1. Test the extent to which CT and 3D printing technologies can reproduce pore geometries and connectivity of natural porous rocks; 2. Conduct experiments on pore systems of natural and artificial rocks to identify what matters to flow at various scales. Samples: core plugs Type Sandstone Carbonates Sample Formation Porosity, % Permeability, md Idaho gray Idaho 29 2200 Castlegate Mesaverde 28 750 Berea Kipton 19 60 Racine Dolomite Racine 11 2 Edwards Brown Edwards Plateau 40 90 Guelph Dolomite Niagara 17 10 Indiana Limestone Bedford 14 9 Austin Chalk Edwards Plateau 25 3 Data from Kocurek Industries(20 13) and Rovey, 1997

Permeability (md) WORKFLOW 1) CT Imaging 2) Modeling 3) Network Extraction 10000 1000 100 5) Rock properties Artificial vs. Natural Rocks Berea Sandstone Idaho Gray Sandstone Porosity (%) Castlegate Sandstone Edwards Brown Limestone 10 Indiana Guelph Austin Limestone Dolomite Chalk 1 0% 10% 20% 30% 40% 4) Production

1) Imaging CT Scanning X-ray source D Detector Specifications: Resolution of CT system - 6 µm Rock Sample Magnification =D/a a=distance between source and sample Samples: core plugs Size of sample: 1x2 Exposures: 2º, 5 sec. Source: Kevex PSX10-16W Set energy: 130 kev Set current: 100 micro-amps Spot size: approx. 16 µm Detector: Varian PaxScan 3024I Resolution: 2816x3584 pixels Pixel Pitch: 83 µm Center for Nondestructive Evaluation, Iowa State University

1) Imaging Racine Dolomite Idaho Gray Sandstone Porosity: 11% Porosity: 22% Permeability: 2 md Permeability: 2200 md Diameter: 1.75 inches Diameter: 1 inch Data from Kocurek Industries(2013) and Rovey, 1997

1) Imaging 2) Modeling Reconstruction of Idaho Gray Sandstone Dimensions: pixels, microns, voxels Core plug 2D image of CT Slice 3D volume Modified from Grandin and Gray, 2014

1) Imaging 2) Modeling 3) Network Extraction!!! Upscaling? Original size of 3D model: 51x63x52 (mm) Porosity Extraction Isosurface Porosity Threshold Connected Pores within Idaho Gray Sandstone 10x magnification

1) Imaging 2) Modeling 3) Network Extraction!!! Upscaling? Original size of 3D model: 51x63x52 (mm) Porosity Extraction Isosurface Porosity Threshold Connected Pores within Idaho Gray Sandstone 10x magnification

1) Imaging 2) Modeling 3) Network Extraction 4) Production 3D PRINTING Makerbot Replicator 2X 2 Print heads Fused Deposition Modeling Filament: Acrylonitrile butadiene styrene (ABS) 10x magnification 5x magnification

1) Imaging 2) Modeling 3) Network Extraction 4) Production 230 C A. Minimum XY element dimensions are controlled by aperture of extruder nozzle Extruder Nozzle Stock 100 C Important parameters of 3D printers B. Element thickness is controlled by positional accuracy of Z stepper motor C. Pore Z-dimension is controlled by positional accuracy of Z stepper motor D. Pore XY-dimension is controlled by positional accuracy of XY stepper motors Printer A. XY Resolution (Nozzle diameter) B/C. Z Resolution (Layer Thickness) D. XY Positioning Accuracy µm µm µm Replicator 2X 400 100 2.5 Objet30 Pro 42 28 30 Objet260 Connex 42 16 30

1) Imaging 2) Modeling 3) Network Extraction 4) Production 5) Rock properties Permeability (md) Petrophysical Measurements Pore size distribution Nuclear Magnetic Resonance Petrography SEM mosaic Porosity, permeability, and pore throat size Helium Porosimetry High-Pressure Mercury Injection Comparison of petrophysical properties between data collected from artificial and natural rocks. Manipulation of properties in 3D models? 10000 1000 100 10 Indiana Limestone Artificial vs. Natural Reservoir Rocks Berea Sandstone Idaho Gray Sandstone Guelph Dolomite Castlegate Sandstone Edwards Brown Limestone Austin 1 Chalk 0% 10% 20% 30% 40% Porosity (%)

Acknowledgements Dr. J. Gray, Center for Nondestructive Evaluation, Iowa State University R. Grandin, PhD Candidate, Center for Nondestructive Evaluation, Iowa State University Dr. C. Harding, GE-AT / Human-Computer Interaction, Iowa State University References Global CCS Institute, 2014, Seal capacity: http://www.globalccsinstitute.com/ publications/caprock-systems-co2-geological-storage/online/100501 (accessed March 2014). Grandin, R., and Gray, J.N., 2013, Implementation of automated 3D defect detection for low signal-to-noise features in NDE data: Center for Nondestructive Evaluation, Iowa State University. Kocurek Industries, 2013, Hard rock division: http://www.kocurekindustries.com (accessed March 2014). Nelson, P.H., 2009. Pore-throat sizes in sandstones, tight sandstones, and shales. AAPG Bulletin, 93(3): 329 340. Rovey II, C.W., 1997, Proposed reference sections and correlation of Upper Silurian and Devonian strata, Eastern Wisconsin: Geoscience Wisconsin, v.16, p. 37-46. Threadless, 2014, Spongebob: www.threadless.com (accessed March 2014).