Shaping the Wave Front of Light
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1 Shaping the Wave Front of Light Industrial Light Guiding with Bayfol HX November 4 th, 2013 / Dr. Friedrich-Karl Bruder
2 Agenda Introduction Bayfol HX Self-Developing Photopolymer Film Applications in Light Guiding Conclusions
3 Analysis of the Wave Front of Light An object is perceived by a human by the shape of the wave front of light that reaches the eye. A stationary fringe pattern forms by interference with a reference wave. This fringe pattern contains all information of the object wave front. Page 3 Bayer Science For A Be Better Life Symposium November 2013
4 Recording the Wave Front of Light The fringe pattern is stored throughout the recording medium as a local modulation of its optical properties. This is called a volume hologram. TEM image of the recorded fringe pattern Page 4 Bayer Science For A Be Better Life Symposium November 2013
5 Reconstructing the Wave Front The local modulation of the optical properties in the recording medium diffracts the reconstruction wave in such a way that the object wave forms again. Page 5 Bayer Science For A Be Better Life Symposium November 2013
6 Agenda Introduction Bayfol HX Self-Developing Photopolymer Film Applications in Light Guiding Conclusions
7 Bayfol HX Self-Developing Photopolymer Film Characteristics of Bayfol HX Film? Thin polyurethane based photopolymer film on a clear thermoplastic substrate. True color and high photosensitivity! Available up to 1600 mm web width. Customization by substrate, photopolymer formulation and film thickness (joint development). Page 7 Bayer Science For A Be Better Life Symposium November 2013
8 How Bayfol HX Film Works Hologram Recording Mechanisms High index monomers dissolved in a PUR matrix. Photo-initiation by holographic exposure UV Polymerization Light induced rearrangement of monomers forms a refractive index pattern. Fixing & bleaching by UV light flood cure Diffusion of residual monomers Page 8 Bayer Science For A Be Better Life Symposium November 2013
9 Bayfol HX Self-Developing Photopolymer Film Ph Ph H N H N O O O O 1 2 O O O O How Did We Develop Bayfol HX Film? Engineering of the photopolymer for high dynamic range and film formation Photo-Initiation Mechanism for Visible Light. Molecular Modeling of Components and Network-Topology. Polymerization Kinetics of Urethane-Acrylates. Physical Model of the Recording Mechanism. Development of High Quality 2K Film Coating Technology. Page 9 BMS 16:9 Template 2010 September 2012
10 Photo-Initiation for Visible Light Successful development of type 2 photo-initiator systems with high sensitivity and effectiveness Prof. Xavier Allonas Ibrahim, Ley, Allonas, Berneth, Bruder, Fäcke, Rölle, Weiser, Proceedings fisphoton Page 10 Bayer Science For A Be Better Life Symposium November 2013
11 Modeling of Key Components Identification of promising sensitizer candidates by quantum mechanical calculation. Dr. Christian Diedrich Page 11 Bayer Science For A Be Better Life Symposium November 2013
12 Polymerization Kinetics of Urethane-Acrylates Extraordinary fast polymerizing urethane-acrylates found and implemented into photopolymer formulation. Prof. Christopher Barner - Kowollik Acrylate log A E A [kj mol -1 ] k 25 C [L mol -1 s -1 ] Ph-Et-urethane-acrylate Ph-Pr-urethane-acrylate Literature Data Butylacrylate Butylmethacrylate Rölle, Berneth, Hönel, Fäcke, Weiser, Bruder, Macromol. Rapid Commun. 2010, 31, F92 Barner-Kowollik, Junkers, Bennet, Schneider-Baumann, Voll, Bruder, Fäcke, Rölle, Weiser Polym. Chem. 2010, 1, Bennet, Rölle, Faecke, Weiser, Bruder, Barner-Kowollik, Junkers, Macromolecular Chemistry and Physics 2013, 214, Page 12 Bayer Science For A Be Better Life Symposium November 2013
13 Physical Model of the Recording Mechanism Full detailed reaction diffusion model developed which enables identification of suitable hologram recording conditions. Prof. John Sheridan Gleeson, Sheridan, Bruder, Rölle, Berneth, Fäcke, Optics Express 2011, 19, Page 13 Bayer Science For A Be Better Life Symposium November 2013
14 Agenda Introduction Bayfol HX Self-Developing Photopolymer Film Applications in Light Guiding Conclusions
15 Application Example Printed Transparent Directional Diffusor Screen Page 16 Bayer Science For A Be Better Life Symposium November 2013
16 Holographic Light Guiding with Bayfol HX Self-Developing Photopolymer Film Application Areas of Volume HOEs in Bayfol HX Automotive Mobile devices Display Page 17 Bayer Science For A Be Better Life Symposium November 2013
17 Applications in 3D Display as Light Guiding Film Prof. Eon-Soo Kim 3D Auto-Stereoscopic Display Full functional demonstrator based on a slim back light unit was developed! Full screen resolution retained by time multiplexing! No Moiré! Large viewing zone! Page 18 Bayer Science For A Be Better Life Symposium November 2013
18 Agenda Introduction Bayfol HX Self-Developing Photopolymer Film Applications in Light Guiding Conclusions
19 Conclusions To Remember New holographic recording media for slim, lightweight and highly integrated optics. Material development was done with partners in an open innovation network. Extensive material and application intellectual property was created. Unique market opportunities in consumer electronics, automotive and security segments. Development collaborations with several Fortune Global 500 companies initiated. Page 20 Bayer Science For A Be Better Life Symposium November 2013
20 Acknowledgements Many Thanks To The team members of the Functional Films organization. Our partners in the external cooperations. And to you for your attention! Page 21 Bayer Science For A Be Better Life Symposium November 2013
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