AC SIMDIS Solutions. True Boiling Point Distribution up to C120. Compliance with Global Standard Test Methods

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1 AC SIMDIS Solutions True Boiling Point Distribution up to C120 Compliance with Global Standard Test Methods Unique Solutions include AC 8634 & Crude Oil Analyzer Dedicated Correlations & Calculations ONE WORLD ONE COMPANY ONE TEAM

2 2 Complete Range of Applications AC Analytical Controls (AC), the global SIMDIS market leader, provides solutions that accurately determine true boiling point data from naphtha up to crude oil samples. Full range of SIMDIS applications determine boiling points up to C120 Product range includes several unique solutions: - AC 8634 analyzer for accelerated D 86 data of jet fuel and diesel - Crude Oil analyzer Merges DHA Front End with High Temp SIMDIS Technique - Sulfur and Nitrogen SIMDIS solutions to determine Hydrocarbon, Sulfur and Nitrogen BP distributions in a single run - Wax D 5442 application Dedicated correlations and calculations are available for: - Correlation to Physical Distillation D 86 & D 1160 ( D 2887; IP 406; ISO 3924) - NOACK - DIN MOV - D Conversion to volume % for crude oil - Cutpoints & fractions - Flashpoint ( D 7215) Excellent LIMS connectivity: upload the results directly to your LIMS or manually after approval Solutions comply with, CEN, DIN, IP and ISO SIMDIS methods A broad set of calibration, reference and quality control samples completes each SIMDIS application User group meetings allows users to improve analyzer performance SIMDIS software is compatible with major chromatographic data systems AC software puts the instrument in standby mode after analysis, to save gas and keep the instrument in optimal condition Several features contribute to the analysis precision: - Use of pre-programmed sample types - Automatic blank subtraction, calibration and system validation - Customer selective start and end algorithm Version 6,1,0,0 simdi s IP PM-CF-98 2 Sample name : REF Acquired on : 3/9/01 4:05:16 PM Vial : 103 Processed on : 6/11/01 7:52:35 AM Injection : 1 Data File : HT750A\103F0401.D General Variables Used Blank HT750A\101F0201.D Used BP calibrant HT750A\102F0301.D Used Reference Used Start elution (min) Used End elution (min) Total area New Response factor e-006 Signal Reference Check Recovered Target Values Determined Values mass % BP C dbp C BP C dbp C Maximum Squared Deviation = 43 Found Maximum Squared Squared Deviation Deviation = 43 4 Squared Found Squared test passed Deviation = 4 Squared test passed Retention Time (min) AC High Temp SIMDIS analysis of a reference sample

3 Compliance with Global Standard Test Methods Boiling point data is a major specification in characterizing petroleum streams. SIMDIS uses a gas chromatographic technique to determine the true boiling point (TBP) distribution. By automating the analysis the AC SIMDIS applications provide fast and accurate boiling point results. Our active involvement in worldwide standardization committees resulted in a compliance with all, CEN, DIN, IP and ISO methods and a listing of these methods in current jet fuel and diesel specifications. The AC SIMDIS application meets and exceeds the reproducibility of the worldwide standard test methods. 3 Method Number D 3710 D 7096 D 2887* D 5307 D 7213 D 6352 D 7169 D 7398 D 7500 Maximum Carbon Number reported C 15 C 16 C 44 C 44 C 60 C 90 C 100 C 60 C 110 Sample Range Gasoline Naphtha Gasoline Naphtha Jet Fuel Diesel Crude Oil Lube Oil Base Stocks Lube Oil Base Stocks Residue Crude Oil FAMES (biodiesel, B100) Blends of Diesel and Biodiesel (B1 through B100) Distillates, Base Oils Lubricating Base Stocks Boiling Range Sample FBP < 260 C (500 F) FBP < 280 C (536 F) FBP < 538 C (1000 F) IBP > 100 C (212 F) FBP < 615 C (1138 F) IBP > 174 C (345 F) FBP < 700 C (1292 F) FBP > 720 C (1328 F) FBP < 538 C (1000 F) IBP > 100 C (212 F) FBP < 735 C (1355 F) Overview of SIMDIS methods *includes Accelerated SIMDIS/8634 TM Method Number ISO 3924 IP 406 IP 480 EN DIN IP 507 EN pren IP 545 Maximum Carbon Number reported C 44 C 120 C 120 C 120 Sample Range Jet Fuel Diesel Lube Oil Base Stocks (totally eluting) Residue Crude Oil Boiling Range Sample FBP < 538 C (1000 F) IBP > 100 C (212 F) FBP < 750 C (1382 F) IBP > 100 C (212 F) FBP > 750 C (1382 F) FBP > 750 C (1382 F) Overview of SIMDIS CEN, DIN, IP, ISO methods Signal BP F Recovery Mass Retention Time (min) Accelerated SIMDIS analysis of a reference sample

4 4 Flexible Configuration The AC SIMDIS solutions are based on the new Agilent Technologies 7890 Series or the 6850 gas chromatograph equipped with: Single or dual channel, packed or capillary column(s) for boiling point separation AC proprietary Temperature Programmable Inlet to simplify system maintenance, improve peak identification and prevent column contamination Flame Ionization Detector A 16-shot automatic liquid sampler (150 tray optional) A set of calibration, reference, and quality controls samples dedicated to the method Data System Compatibility The AC SIMDIS application offers you a choice in selecting a chromatographic data system. The AC software allows fully automated analysis processing and operates on the following chromatographic data systems: ChemStation - Agilent Technologies EZChrom Elite - Agilent Technologies Atlas - Thermo Electron SIMDIS report menu offers several plot options for the chromatogram Extensive Report Options The AC SIMDIS applications offer several options to report the true boiling point distribution & analysis parameters and include dedicated correlations & calculations. Reports are fully configurable per sample type. Report Options Chromatogram and boiling point distribution plot List of calculation parameters Quality control report check Report of peak skew and column resolution parameters Tables and graphs of boiling point versus retention time or versus mass% Several correlation reports such as D86 and D1160, Flashpoint (D7215) Output of report to several formats, such as CSV, PDF file, for reviewing the results outside the SIMDIS software, direct import to excel, or direct upload to a LIMS system.

5 Accurate Crude Oil Analysis One unique AC solution is the Crude Oil Analyzer, which combines detailed hydrocarbon analysis (DHA) front end technique with high temperature simulation distillation. Merging the DHA and SIMDIS data of the crude oil analysis improves accuracy. This merging technique is an AC innovation and is standardized as IP 545, D 7169 and pren The dedicated system design of the Crude Oil Analyzer consists of the following: The AC High Temp SIMDIS application that incorporates all, DIN, IP and CEN methods for high temperature simulated distillation The AC DHA Front End application which uses a single capillary column conform IP PM-DL to characterize the C1-nC9 fraction in crude oil Merging principle for DHA & SIMDIS 5 High Temp SIMDIS analysis of a crude oil Conversion to Volume% The AC High Temp SIMDIS Analyzer includes a special report option to convert data from mass% to volume % for crude oils that comply with: FBP > 538 ºC (1000 F) T (50wt%) < 538 ºC (1000 F) Converting Mass % to Volume %

6 6 Jet Fuel and Diesel Analysis D 2887, IP 406 & ISO 3924 To determine the true boiling point (TBP) distribution for jet fuel and diesel AC Analytical Controls offers the SIMDIS D 2887, IP 406 & ISO 3924 application. Jet fuel specifications D 1655 and DEF STAN list D 2887 as an alternative to physical distillation D 86 in determining distillation properties for Jet A & A-1. The AC application reports both the TBP and correlated D 86 data. D 86 Boiling Point To assist refiners in determining D 86 boiling range data, AC developed the AC 8634 application. The AC8634 TM principle is now accepted within several standard methods, such as D Hydrocarbon AC 8634 analysis of a gasoil Sulfur and Nitrogen Boiling Point AC enhanced the SIMDIS application with a dedicated Sulfur and Nitrogen Chemiluminescence Detector to characterize the sulfur and nitrogen specifications. The AC CNS SIMDIS applications report the Hydrocarbon, Nitrogen and Sulfur boiling point distributions. Nitrogen 199 ppm N Carbazole Anilines, Indoles, Quinolines C1-CA C2-CA C3+-CA Sulfur 325 ppm S C1-BDTH C2-BDTH C3-BDTH DiBenzoThiophene BenzoThiophene C1-BDTH C2-BDTH AC Sulfur SIMDIS analysis of a NIST standard Example of a diesel sample on CNS - A single analysis run yields three chromatograms

7 User Group & PMP SIMDIS users may join the AC User Group. Members are invited to attend meetings scheduled periodically and to participate in PAC s Performance Monitoring Program. Regularly AC schedules a worldwide SIMDIS Performance Monitoring Program (PMP), which is an anonymous round robin test. AC reports the statistical values and advices on improving analysis precision. A great number of labs worldwide participate in this PMP. Optimize Analyzer Precision Sample type menu displays the pre-programmed sample types 7 Several features contribute to the analysis precision: Use of pre-programmed sample types Automatic blank subtraction, calibration and system validation Customer selective start and end elution algorithm Automatic validation of the Analyzer through user-configurable reference values checks AC software puts the instrument in standby mode after analysis to save gas and to keep it in optimal condition. One-click access to the blank, calibration and reference analysis for quick validation Each system comes with a broad set of Quality Control samples Special error viewer shows users when the software detects anomalies in the analysis AC SIMDIS reference report AC High Temp SIMDIS 5010 reference sample

8 AMERICAS UNITED STATES PAC Corporate Headquarter 8824 Fallbrook Drive Houston, TX USA Phone: TEST or Fax: EMEAI GERMANY Badstrasse 3-5, P.O. Box 1241 DE Lauda-Königshofen Germany Phone: +49 (0) Fax: +49 (0) FRANCE BP VERSON CARPIQUET Cedex France Phone: +33 (0) Fax: +33 (0) THE NETHERLANDS Innsbruckweg AG Rotterdam The Netherlands Phone: +31 (0) Fax: +31 (0) RUSSIA & CIS Shabolovka street, 34, Bldg , Moscow, Russia Phone: Fax: UAE Villa#8/1, Street#9 Al Karama District P.O.Box Abu Dhabi, United Arab Emirates Phone: Fax: ASIA SINGAPORE 61, Science Park Road #03-09/10 The Galen Singapore Science Park III Singapore Phone: Fax: CHINA Rm.1003, Sunjoy Mansion No.6 RiTan Rd. ChaoYang District, Beijing P.R. China Phone: ext 370/371/372/373/375 Fax: Features and Benefits Full range of SIMDIS applications determines boiling points up to C120 Product range includes several unique solutions: - AC 8634 analyzer for accelerated D 86 data of jet fuel and diesel - Crude Oil analyzer merges DHA Front End with High Temp SIMDIS Technique - Sulfur and Nitrogen SIMDIS solutions to determine sulfur and nitrogen distributions - Wax D 5442 application Solutions comply with, CEN, DIN, IP and ISO SIMDIS methods A broad set of calibration, reference and quality control samples completes each SIMDIS application User group meetings help users network and improve analyzer performance SIMDIS software is compatible with major chromatographic data systems Dedicated correlations and calculations are included for: - Correlation to Physical Distillation D 86 & D 1160 ( D 2887; IP 406; ISO 3924) - NOACK - DIN MOV - D Conversion to volume % for crude oils - Cutpoints & fractions - Flashpoint ( D 7215) Excellent LIMS connectivity: upload the results directly to your LIMS or manually after approval Several features contribute to the analysis precision: - Use of pre-programmed sample types - Automatic blank subtraction, calibration and system validation - Customer selective start and end algorithm The AC SIMDIS is a complete, turnkey system that s completely assembled with all necessary valves, connections, and analyzer columns. It s ready to go, calibrated, tested to certified calibration blends, fine-tuned and delivered to the customer s facility in plug and play condition. A qualified and dedicated Service Engineer will visit at the customer s convenience after delivery to perform installation and training, so that the customer can begin getting the most benefit out of their SIMDIS right away. Plus, PAC s solid guarantee covers all parts and analytical performance during the first year. THAILAND 25 Floor, M. Thai Tower, All seasons place 87 Wireless Road, Lumpini Phatumwan Bangkok Thailand Phone : Fax : SOUTH KOREA World Vision Building # Youido-dong, Youngdeungpoku Seoul Korea Phone: Fax: Copyright 2010 PAC L.P. All rights reserved