Spectrométrie d absorption moléculaire UV-visible
|
|
|
- Rolf Curtis
- 8 years ago
- Views:
Transcription
1 Spectrométrie d absorption moléculaire 1
2 faibles quantités échantillon liquide byfiles.storage.live.com/y1php6mrdyehuw8p4jw0... non destructrice bp0.blogger.com/.../m_7spgk78eu/s400/boum_4.png s'applique à un très grand nombre de dosages 2
3 Certaines molécules absorbent certaines longueurs d ondes du spectre : loi de - Étude qualitative structurale par l analyse des spectres d absorption sciexp.ch/images/chimiste.gif 3
4 E = h ν = h C / λ 4
5 d absorption moléculaire en bandes larges peu nombreuses 5
6 Domaine spectral 6
7 dans le visible : couleurs des molécules 7
8 Absorbance ou densité optique 8
9 Loi de 9
10 Loi de 10
11 A λ = ε λ. l. C Les dosages 11
12 des ions permanganate MnO 4 - oxidationsystems.com/.../permanganate.jpg Gamme de dilution ou d étalonnage 12
13 d absorption moléculaire en UVvisible MnO 4-13
14 des ions permanganate MnO 4 - oxidationsystems.com/.../permanganate.jpg Vo en (ml) C = [ MnO 4 - ] en mol/l 14
15 des ions permanganate MnO 4 - oxidationsystems.com/.../permanganate.jpg Vo en (ml) C = [ MnO 4 - ] en mol/l
16 des ions permanganate MnO 4 - oxidationsystems.com/.../permanganate.jpg Mesure de l absorbance des solutions Préalablement à ces mesures, le chimiste a réglé, avec une cuve remplie d'eau, le zéro d'absorbance de l'appareil 16
17 des ions permanganate MnO 4 - Vo en (ml) C = [ MnO 4 - ] en mol/l Absorbance A λ 0,22 0,44 0,66 0,88 1,1 17
18 des ions permanganate MnO 4 - A λ = f (C) pedagogie.ac-montpellier.fr/.../loupe.gif 18
19 Etude spectrophotométrique d une réaction A λ = f (t) 19
20 [C] max mesurée [C] max = A max / (εl) 20
21 O 21
22 Transitions électroniques des composés organiques 22
23 Coefficient d extinction ε 23
24 Chromophore et chromogène Chromophore : groupement d atomes responsables d absorptions caractéristiques Chromogène : squelette d une molécule transparent porteur d un ou de plusieurs chromophores 24
25 Chromophores isolés Chromophore Exemple Transition électronique λ max, nm ε Solvant C=C Ethene π > π* hexane C C 1-Hexyne π > π* hexane C=O Ethanal n > π* hexane π > π* hexane N=O Nitromethane n > π* π > π* ethanol ethanol C-X X=Br X=I Methyl bromide Methyl Iodide n > σ* n > σ* hexane hexane 25
26 Chromophore des systèmes conjugués effet hyperchrome chromophore λmax Log ε C=C (C=C) (C=C) (C=C) effet bathochrome 26
27 Déplacement des bandes d absorption Effet Conséquences Hypsochrome (Blue shift) λ max diminue Bathochrome (Red shift) λ max augmente Hyperchrome I max augmente Hypochrome I I max diminue 27
28 Le spectrophotomètre 28
29 Eléments constituant un spectrophotomètre 29
30 La cuve 30
31 Pour conclure 31
32 Analyse moléculaire 32
33 Spectrométrie d absorption moléculaire bandes d absorbances λ max ε caractéristique à λ donnée de la molécule Analyse quantitative dosages grâce à la loi de - 33
34 Détecteur : la photodiode ou semi-conducteur 34
35 Transitions électroniques des composés organiques 35
36 Techniques séparatives Chromatographiques 36
37 Analyse moléculaire 37
38 Analyse élémentaire chromatographie volumétrie potentiométrie conductimétrie 38
39 Techniques séparatives Chromatographiques La chromatographie : généralités La chromatographie en phase gazeuse CPG La chromatographie ionique La chromatographie d exclusion-diffusion La chromatographie liquide haute pression Techniques couplées (GC-MS) 39
40 Chromophore des systèmes conjugués molecule wavelength of maximum absorption (nm) ethene 171 buta-1,3-diene 217 hexa-1,3,5-triene
41 Woodward-Fieser Rules for Calculating the π > π* λ max of Conjugated Carbonyl Compounds Core Chromophore nm R = H 210 nm R = OR' 195 nm Cyclopentenone 202 nm R = Alkyl 215 Substituent and Influence α- Substituent R- (Alkyl Group) +10 nm Cl- (Chloro Group) +15 Br- (Chloro Group) +25 HO- (Hydroxyl Group) +35 RO- (Alkoxyl Group) +35 RCO 2 - (Acyl Group) +6 β- Substituent R- (Alkyl Group) +12 nm Cl- (Chloro Group) +12 Br- (Chloro Group) +30 HO- (Hydroxyl Group) +30 RO- (Alkoxyl Group) +30 RCO 2 - (Acyl Group) +6 RS- (Sulfide Group) +85 R 2 N- (Amino Group) +95 γ & δ- Substituents R- (Alkyl Group) +18 nm (both γ & δ) HO- (Hydroxyl Group) +50 nm (γ) RO- (Alkoxyl Group) +30 nm (γ) Further π -Conjugation C=C (Double Bond) C 6 H 5 (Phenyl Group) (i) Each exocyclic double bond adds 5 nm. In the example on the right, there are two exo-double bond components: one to ring A and the other to ring B. (ii) Homoannular cyclohexadiene component adds +35 nm (ring atoms must be counted separately as substituents) (iii) Solvent Correction: water = 8; methanol/ethanol = 0; ether = +7; hexane/cyclohexane = λ max (calculated) = Base + Substituent Contributions and Corrections
42 La source Lampe à décharge au deutérium Lampe à filament de tungstène 42
43 Le monochromateur 43
44 Détecteur : Le photomultiplicateur 44
45 Effet du aux solvants : solvatochromie 45
UV-Visible Spectroscopy
UV-Visible Spectroscopy UV-Visible Spectroscopy What is UV-Visible Spectroscopy? Molecular spectroscopy that involves study of the interaction of Ultra violet (UV)-Visible radiation with molecules What
Ultraviolet and visible spectrometry
Ultraviolet and visible spectrometry Theoretical overview Molecular absorption of electromagnetic radiation changes of energy state of the molecule include electronic state E e =150-600 kj/mol (electron
Ultraviolet Spectroscopy
Ultraviolet Spectroscopy The wavelength of UV and visible light are substantially shorter than the wavelength of infrared radiation. The UV spectrum ranges from 100 to 400 nm. A UV-Vis spectrophotometer
Organic Spectroscopy 1
rganic Spectroscopy 1 Lecture 5, 2 nd Year Michaelmas 2010! Dr Rob Paton CRL ffice 11, 1st floor! E-mail: robert.paton@chem.ox.ac.uk http://paton.chem.ox.ac.uk utline of Lectures 5-8 In lectures 5-6 of
SPECTROSCOPY. Light interacting with matter as an analytical tool
SPECTROSCOPY Light interacting with matter as an analytical tool Electronic Excitation by UV/Vis Spectroscopy : X-ray: core electron excitation UV: valance electronic excitation IR: molecular vibrations
13.4 UV/VIS Spectroscopy
13.4 UV/VIS Spectroscopy The spectroscopy which utilizes the ultraviolet (UV) and visible (VIS) range of electromagnetic radiation, is frequently referred to as Electronic Spectroscopy. The term implies
Colorimetry Extinction coefficient (ε) Lambda max (λ max ) Qualitative vs. quantitative analysis
Lab Week 2 - Spectrophotometry Purpose: Introduce students to the use of spectrophotometry for qualitative (what is it) and quantitative (how much is there of it) analysis of biological samples and molecules.
IUPAC System of Nomenclature
IUPAC System of Nomenclature The IUPAC (International Union of Pure and Applied Chemistry) is composed of chemists representing the national chemical societies of several countries. ne committee of the
Personnalisez votre intérieur avec les revêtements imprimés ALYOS design
Plafond tendu à froid ALYOS technology ALYOS technology vous propose un ensemble de solutions techniques pour vos intérieurs. Spécialiste dans le domaine du plafond tendu, nous avons conçu et développé
Austin Peay State University Department of Chemistry Chem 1111. The Use of the Spectrophotometer and Beer's Law
Purpose To become familiar with using a spectrophotometer and gain an understanding of Beer s law and it s relationship to solution concentration. Introduction Scientists use many methods to determine
Determining the Structure of an Organic Compound
Determining the Structure of an Organic Compound The analysis of the outcome of a reaction requires that we know the full structure of the products as well as the reactants In the 19 th and early 20 th
α α λ α = = λ λ α ψ = = α α α λ λ ψ α = + β = > θ θ β > β β θ θ θ β θ β γ θ β = γ θ > β > γ θ β γ = θ β = θ β = θ β = β θ = β β θ = = = β β θ = + α α α α α = = λ λ λ λ λ λ λ = λ λ α α α α λ ψ + α =
for excitation to occur, there must be an exact match between the frequency of the applied radiation and the frequency of the vibration
! = 1 2"c k (m + M) m M wavenumbers! =!/c = 1/" wavelength frequency! units: cm 1 for excitation to occur, there must be an exact match between the frequency of the applied radiation and the frequency
6. 3. Molecular spectroscopy. Unit 6: Physical chemistry of spectroscopy, surfaces and chemical and phase equilibria
6. 3 Molecular spectroscopy Spectroscopy in its various forms is a technique with wide applications across many disciplines. From qualitative analysis in toxicology through to quantitative measurements
Austin Peay State University Department of Chemistry CHEM 1021 TESTING FOR ORGANIC FUNCTIONAL GROUPS
TESTING FOR ORGANIC FUNCTIONAL GROUPS Caution: Chromic acid is hazardous as are many of the organic substances in today s experiment. Treat all unknowns with extreme care. Many organic substances are flammable.
HUMBOLDT-UNIVERSITÄT ZU BERLIN MATHEMATISCH-NATURWISSENSCHAFTLICHE FAKULTÄT I
HUMBOLDT-UNIVERSITÄT ZU BERLIN MATHEMATISCH-NATURWISSENSCHAFTLICHE FAKULTÄT I INSTITUT FÜR PHYSIK Physik von Makromolekülen UV-VIS absorption characterization of (macro)molecular solutions Persons in charge:
Organic Spectroscopy. UV - Ultraviolet-Visible Spectroscopy. !! 200-800 nm. Methods for structure determination of organic compounds:
Organic Spectroscopy Methods for structure determination of organic compounds: X-ray rystallography rystall structures Mass spectroscopy Molecular formula -----------------------------------------------------------------------------
Nucleophilic Substitution and Elimination
Nucleophilic Substitution and Elimination What does the term "nucleophilic substitution" imply? A nucleophile is an the electron rich species that will react with an electron poor species A substitution
Molecular Spectroscopy
Molecular Spectroscopy UV-Vis Spectroscopy Absorption Characteristics of Some Common Chromophores UV-Vis Spectroscopy Absorption Characteristics of Aromatic Compounds UV-Vis Spectroscopy Effect of extended
Problem Set 6 UV-Vis Absorption Spectroscopy. 13-1. Express the following absorbances in terms of percent transmittance:
Problem Set 6 UV-Vis Absorption Spectroscopy 13-1. Express the following absorbances in terms of percent transmittance: a 0.051 b 0.918 c 0.379 d 0.261 e 0.485 f 0.072 A = log P o /P = log1/t = - log T
EXPERIMENT 11 UV/VIS Spectroscopy and Spectrophotometry: Spectrophotometric Analysis of Potassium Permanganate Solutions.
EXPERIMENT 11 UV/VIS Spectroscopy and Spectrophotometry: Spectrophotometric Analysis of Potassium Permanganate Solutions. Outcomes After completing this experiment, the student should be able to: 1. Prepare
Infrared Spectroscopy 紅 外 線 光 譜 儀
Infrared Spectroscopy 紅 外 線 光 譜 儀 Introduction Spectroscopy is an analytical technique which helps determine structure. It destroys little or no sample (nondestructive method). The amount of light absorbed
Bac + 04 Licence en science commerciale, option marketing et communication. Degree in computer science, engineering or equivalent
L un de ces postes vous intéresse? Postulez sur djezzy@talents-network.com Communication Brand senior manager Bac + 04 Licence en science commerciale, option marketing et communication. 05 years minimum
RAMAN SCATTERING INDUCED BY UNDOPED AND DOPED POLYPARAPHENYLENE
RAMAN SCATTERING INDUCED BY UNDOPED AND DOPED POLYPARAPHENYLENE S. Krichene, S. Lefrant, G. Froyer, F. Maurice, Y. Pelous To cite this version: S. Krichene, S. Lefrant, G. Froyer, F. Maurice, Y. Pelous.
RAPPORT FINANCIER ANNUEL PORTANT SUR LES COMPTES 2014
RAPPORT FINANCIER ANNUEL PORTANT SUR LES COMPTES 2014 En application de la loi du Luxembourg du 11 janvier 2008 relative aux obligations de transparence sur les émetteurs de valeurs mobilières. CREDIT
Fundamentals of modern UV-visible spectroscopy. Presentation Materials
Fundamentals of modern UV-visible spectroscopy Presentation Materials The Electromagnetic Spectrum E = hν ν = c / λ 1 Electronic Transitions in Formaldehyde 2 Electronic Transitions and Spectra of Atoms
where h = 6.62 10-34 J s
Electromagnetic Spectrum: Refer to Figure 12.1 Molecular Spectroscopy: Absorption of electromagnetic radiation: The absorptions and emissions of electromagnetic radiation are related molecular-level phenomena
Ces deux analyseurs permettent le contrôle de la qualité de l eau et des effluents.
OptiLIS 201 & 301 Online multi-parameter water analyzers These two standalone analyzers enable you to control continuously both fresh water and effluents quality Ces deux analyseurs permettent le contrôle
electron does not become part of the compound; one electron goes in but two electrons come out.
Characterization Techniques for Organic Compounds. When we run a reaction in the laboratory or when we isolate a compound from nature, one of our first tasks is to identify the compound that we have obtained.
Electrophilic Addition Reactions
Electrophilic Addition Reactions Electrophilic addition reactions are an important class of reactions that allow the interconversion of C=C and C C into a range of important functional groups. Conceptually,
ORGANIC CHEMISTRY. Spectroscopy of Organic Compounds. Prof. Subodh Kumar Dept. of Chemistry Guru Nanak Dev University Amritsar -143005 (26.10.
GANIC CHEMISTY Spectroscopy of rganic Compounds Prof. Subodh Kumar Dept. of Chemistry Guru Nanak Dev University Amritsar -143005 (26.10.2006) CNTENTS Introduction Ultraviolet and Visible Spectroscopy Nature
Q.1 Draw out some suitable structures which fit the molecular formula C 6 H 6
Aromatic compounds GE 1 BENZENE Structure Primary analysis revealed benzene had an... empirical formula of and a molecular formula of 6 6 Q.1 Draw out some suitable structures which fit the molecular formula
Basic UV-Vis Theory, Concepts and Applications
Introduction Ultraviolet and visible spectrometers have been in general use for the last 35 years and over this period have become the most important analytical instrument in the modern day laboratory.
Remote Method Invocation
1 / 22 Remote Method Invocation Jean-Michel Richer jean-michel.richer@univ-angers.fr http://www.info.univ-angers.fr/pub/richer M2 Informatique 2010-2011 2 / 22 Plan Plan 1 Introduction 2 RMI en détails
Reaction Stoichiometry and the Formation of a Metal Ion Complex
Reaction Stoichiometry and the Formation of a Metal Ion Complex Objectives The objectives of this laboratory are as follows: To use the method of continuous variation to determine the reaction stoichiometry
Solvent Effects on the UV/ Visible Absorption Spectra of Some Aminoazobenzene Dyes
Chem Sci Trans., 212, 1(1), 1-8 Chemical Science Transactions DOI:1.7598/cst212.118 ISS: 2278-3458 RESEARCH ARTICLE Solvent Effects on the UV/ Visible Absorption Spectra of Some Aminoazobenzene Dyes M.
MOLECULAR REPRESENTATIONS AND INFRARED SPECTROSCOPY
MLEULAR REPRESENTATINS AND INFRARED SPETRSPY A STUDENT SULD BE ABLE T: 1. Given a Lewis (dash or dot), condensed, bond-line, or wedge formula of a compound draw the other representations. 2. Give examples
2. Illustration of the Nikkei 225 option data
1. Introduction 2. Illustration of the Nikkei 225 option data 2.1 A brief outline of the Nikkei 225 options market τ 2.2 Estimation of the theoretical price τ = + ε ε = = + ε + = + + + = + ε + ε + ε =
Chapter 5 Classification of Organic Compounds by Solubility
Chapter 5 Classification of Organic Compounds by Solubility Deductions based upon interpretation of simple solubility tests can be extremely useful in organic structure determination. Both solubility and
Copyright 1999 2010 by Mark Brandt, Ph.D. 12
Introduction to Absorbance Spectroscopy A single beam spectrophotometer is comprised of a light source, a monochromator, a sample holder, and a detector. An ideal instrument has a light source that emits
Chapter 22 Carbonyl Alpha-Substitution Reactions
John E. McMurry www.cengage.com/chemistry/mcmurry Chapter 22 Carbonyl Alpha-Substitution Reactions The α Position The carbon next to the carbonyl group is designated as being in the α position Electrophilic
Chapter 12 Organic Compounds with Oxygen and Sulfur
Chapter 12 Organic Compounds with Oxygen and Sulfur 1 Alcohols An alcohol contains a hydroxyl group ( OH) that replaces a hydrogen atom in a hydrocarbon. A phenol contains a hydroxyl group ( OH) attached
Spectrophotometry and the Beer-Lambert Law: An Important Analytical Technique in Chemistry
Spectrophotometry and the Beer-Lambert Law: An Important Analytical Technique in Chemistry Jon H. Hardesty, PhD and Bassam Attili, PhD Collin College Department of Chemistry Introduction: In the last lab
The foundation of the new sewage plant at le Havre An alternative solution with a preloading embankment
Titre The foundation of the new sewage plant at le Havre An alternative solution with a preloading embankment F. Baguelin & Seng Y Ung (FONDASOL) F. Gaillard & J.P. Commun (RAZEL) Journée franco-britannique
UV/VIS Spectroscopy. Summary. Contents
Summary UV/VIS Spectroscopy Many chemical compounds have a characteristic colour. For example, quinone is yellow; chlorophyll is green; the 2,4-dinitrophenylhydrazone derivatives of aldehydes and ketones
Unit Vocabulary: o Organic Acid o Alcohol. o Ester o Ether. o Amine o Aldehyde
Unit Vocabulary: Addition rxn Esterification Polymer Alcohol Ether Polymerization Aldehyde Fermentation Primary Alkane Functional group Saponification Alkene Halide (halocarbon) Saturated hydrocarbon Alkyne
GSAC CONSIGNE DE NAVIGABILITE définie par la DIRECTION GENERALE DE L AVIATION CIVILE Les examens ou modifications décrits ci-dessous sont impératifs. La non application des exigences contenues dans cette
Unrealized Gains in Stocks from the Viewpoint of Investment Risk Management
Unrealized Gains in Stocks from the Viewpoint of Investment Risk Management Naoki Matsuyama Investment Administration Department, The Neiji Mutual Life Insurance Company, 1-1 Marunouchi, 2-chome, Chiyoda-ku,
Note concernant votre accord de souscription au service «Trusted Certificate Service» (TCS)
Note concernant votre accord de souscription au service «Trusted Certificate Service» (TCS) Veuillez vérifier les éléments suivants avant de nous soumettre votre accord : 1. Vous avez bien lu et paraphé
Chemistry 118 Laboratory University of Massachusetts Boston Beer s Law
Name: LEARNING GOALS: Chemistry 118 Laboratory University of Massachusetts Boston Beer s Law 1. Become familiar with the concept of concentration and molarity. 2. Become familiar with making dilutions
Molecular Formula Determination
Molecular Formula Determination Classical Approach Qualitative elemental analysis Quantitative elemental analysis Determination of empirical formula Molecular weight determination Molecular formula determination
University of Maryland Fraternity & Sorority Life Spring 2015 Academic Report
University of Maryland Fraternity & Sorority Life Academic Report Academic and Population Statistics Population: # of Students: # of New Members: Avg. Size: Avg. GPA: % of the Undergraduate Population
Régression logistique : introduction
Chapitre 16 Introduction à la statistique avec R Régression logistique : introduction Une variable à expliquer binaire Expliquer un risque suicidaire élevé en prison par La durée de la peine L existence
Troncatures dans les modèles linéaires simples et à effets mixtes sous R
Troncatures dans les modèles linéaires simples et à effets mixtes sous R Lyon, 27 et 28 juin 2013 D.Thiam, J.C Thalabard, G.Nuel Université Paris Descartes MAP5 UMR CNRS 8145 IRD UMR 216 2èmes Rencontres
Ch17_PT MULTIPLE CHOICE. Choose the one alternative that best completes the statement or answers the question.
Ch17_PT MULTIPLE CHOICE. Choose the one alternative that best completes the statement or answers the question. 1) Which molecule is a carboxylic acid? A) 1) B) C) D) E) CH3 CH2 CH2 NH2 2) Which molecule
4. Molecular spectroscopy. Basel, 2008
4. Molecular spectroscopy Basel, 2008 4. Molecular spectroscopy Contents: 1. Introduction 2. Schema of a spectrometer 3. Quantification of molecules mouvements 4. UV-VIS spectroscopy 5. IR spectroscopy
STAGE YOGA & RANDONNEES à MADERE
STAGE YOGA & RANDONNEES à MADERE Du dimanche 10 au dimanche 17 juillet 2016 Animé par Naomi NAKASHIMA et Sylvain BRUNIER L île aux fleurs, paradis des randonneurs et amoureux de la nature Au cours de ce
RNA) - - - = 1 1 = 1 EU
Colorimetric Methods for Determining Protein Concentration. Goals: 1. Learn how to use colorimetric (Lowry, BCA, and Bradford) methods to determine protein concentration in mg/ml. 2. Use intrinsic biomolecular
Langages Orientés Objet Java
Langages Orientés Objet Java Exceptions Arnaud LANOIX Université Nancy 2 24 octobre 2006 Arnaud LANOIX (Université Nancy 2) Langages Orientés Objet Java 24 octobre 2006 1 / 32 Exemple public class Example
Benzene Benzene is best represented as a resonance hybrid:
Electrophilic Aromatic Substitution (EAS) is a substitution reaction usually involving the benzene ring; more specifically it is a reaction in which the hydrogen atom of an aromatic ring is replaced as
Thursday, February 7, 2013. DOM via PHP
DOM via PHP Plan PHP DOM PHP : Hypertext Preprocessor Langage de script pour création de pages Web dynamiques Un ficher PHP est un ficher HTML avec du code PHP
«Object-Oriented Multi-Methods in Cecil» Craig Chambers (Cours IFT6310, H08)
«Object-Oriented Multi-Methods in Cecil» Craig Chambers (Cours IFT6310, H08) Mathieu Lemoine 2008/02/25 Craig Chambers : Professeur à l Université de Washington au département de Computer Science and Engineering,
Experiment C-31 Color Absorption
1 Experiment C-31 Color Absorption Objectives To understand the concepts of light waves and color. To investigate how red, green and blue liquids absorb light of different wavelengths. To learn about colorimeter
Lecture 1: Basic Concepts on Absorption and Fluorescence
Lecture 1: Basic Concepts on Absorption and Fluorescence Nicholas G. James Cell and Molecular Biology University of Hawaii at Manoa, Honolulu The Goal The emission of light after absorption of an outside
5.33 Lecture Notes: Introduction to Spectroscopy
5.33 Lecture Notes: ntroduction to Spectroscopy What is spectroscopy? Studying the properties of matter through its interaction with different frequency components of the electromagnetic spectrum. Latin:
Upon completion of this lab, the student will be able to:
1 Learning Outcomes EXPERIMENT B4: CHEMICAL EQUILIBRIUM Upon completion of this lab, the student will be able to: 1) Analyze the absorbance spectrum of a sample. 2) Calculate the equilibrium constant for
STUDENT APPLICATION FORM (Dossier d Inscription) ACADEMIC YEAR 2010-2011 (Année Scolaire 2010-2011)
Institut d Administration des Entreprises SOCRATES/ERASMUS APPLICATION DEADLINE : 20th November 2010 OTHER (Autre) STUDENT APPLICATION FORM (Dossier d Inscription) ACADEMIC YEAR 2010-2011 (Année Scolaire
2 Spectrophotometry and the Analysis of Riboflavin
2 Spectrophotometry and the Analysis of Riboflavin Objectives: A) To become familiar with operating the Platereader; B) to learn how to use the Platereader in determining the absorption spectrum of a compound
Chapter 13 Spectroscopy NMR, IR, MS, UV-Vis
Chapter 13 Spectroscopy NMR, IR, MS, UV-Vis Main points of the chapter 1. Hydrogen Nuclear Magnetic Resonance a. Splitting or coupling (what s next to what) b. Chemical shifts (what type is it) c. Integration
The dipolar nature of acids
I. Introduction arboxylic Acid Structure and hemistry: Part 1 Jack Deuiter arboxylic acids are hydrocarbon derivatives containing a carboxyl () moiety. ecall that carbon has four valence electrons and
Absorption by atmospheric gases in the IR, visible and UV spectral regions.
Lecture 6. Absorption by atmospheric gases in the IR, visible and UV spectral regions. Objectives: 1. Gaseous absorption in thermal IR. 2. Gaseous absorption in the visible and near infrared. 3. Gaseous
The wolf who wanted to change his color Week 1. Day 0. Day 1. Day 2. Day 3. - Lecture de l album
The wolf who wanted to change his color Week 1. Day 0. Day 1. Day 2. Day 3. - Lecture de l album - Lecture simplifiée de l album - Découverte des affiches des - Exercice de reconnaissance de - Découverte
Alkanes. Chapter 1.1
Alkanes Chapter 1.1 Organic Chemistry The study of carbon-containing compounds and their properties What s so special about carbon? Carbon has 4 bonding electrons. Thus, it can form 4 strong covalent bonds
CHM220 Addition lab. Experiment: Reactions of alkanes, alkenes, and cycloalkenes*
CM220 Addition lab Experiment: Reactions of alkanes, alkenes, and cycloalkenes* Purpose: To investigate the physical properties, solubility, and density of some hydrocarbon. To compare the chemical reactivity
13C NMR Spectroscopy
13 C NMR Spectroscopy Introduction Nuclear magnetic resonance spectroscopy (NMR) is the most powerful tool available for structural determination. A nucleus with an odd number of protons, an odd number
Spécifications techniques
www.farpi.com FARPI-FRANCE 06/2015 V1.20 Spécifications techniques - Petit Tonnage de J35AD à J180AD All Electric Servo Drive Injecon Molding Machine FARPI-FRANCE Z.I. le Chanay -BP 3-69720 SAINT BONNET
CAMÉRAS EMCCD POUR LA QUANTIFICATION DE FLUORESCENCE IN VIVO
CAMÉRAS EMCCD POUR LA QUANTIFICATION DE FLUORESCENCE IN VIVO Yoann Gosselin, B.Ing., M.Sc.A. Ingénieur en application 2 3 3 TECHNOLOGIE BREVETÉE POUR LA CAMÉRA LA PLUS SENSIBLE 6 TECHNOLOGIE BREVETÉE
Calculating the Degrees of Unsaturation From a Compound s Molecular Formula
Calculating the Degrees of Unsaturation From a Compound s Molecular Formula Alkanes have the molecular formula C n. Alkanes are saturated hydrocarbons because each member of the family has the maximum
Certificat de fusion. Certificate of Amalgamation. Canada Business Corporations Act. Loi canadienne sur les sociétés par actions
Industry Canada Industrie Canada Certificate of Amalgamation Canada Business Corporations Act Certificat de fusion Loi canadienne sur les sociétés par actions Franco-Nevada Corporation 445771-4 Name of
AD511 Active Iridium Antenna User Manual Mar 12 V4.0
AD511 Active Iridium Antenna User Manual Mar 12 V4.0 AD511 Active Iridium Transmitter/Receiver Antenna with up to 160 metres of coaxial down-lead and DC Power Break-In Box for Iridium Satellite Systems
CHEM 322 Organic Chemistry II - Professor Kathleen V. Kilway
CHEM 322 Organic Chemistry II - Professor Kathleen V. Kilway "Organic Chemistry" by Maitland Jones, 4th edition Chapter 12 Homework: 1, 2, 4, 5, 6, 7, 15, 16, 17, 19, 21, 24, 26, 28, 29, 30, 38, 39, 44,
A Beer s Law Experiment
A Beer s Law Experiment Introduction There are many ways to determine concentrations of a substance in solution. So far, the only experiences you may have are acid-base titrations or possibly determining
Lab #11: Determination of a Chemical Equilibrium Constant
Lab #11: Determination of a Chemical Equilibrium Constant Objectives: 1. Determine the equilibrium constant of the formation of the thiocyanatoiron (III) ions. 2. Understand the application of using a
Formation à l ED STIC ED STIC Doctoral education. Hanna Klaudel
Formation à l ED STIC ED STIC Doctoral education Hanna Klaudel Texte de référence / Text of low L arrêté de 7 août 2006 : «Les écoles doctorales proposent aux doctorants les formations utiles à leur projet
IR Summary - All numerical values in the tables below are given in wavenumbers, cm -1
Spectroscopy Data Tables Infrared Tables (short summary of common absorption frequencies) The values given in the tables that follow are typical values. Specific bands may fall over a range of wavenumbers,
NMR SPECTROSCOPY A N I N T R O D U C T I O N T O... Self-study booklet NUCLEAR MAGNETIC RESONANCE. 4 3 2 1 0 δ PUBLISHING
A N I N T R O D U T I O N T O... NMR SPETROSOPY NULEAR MAGNETI RESONANE 4 3 1 0 δ Self-study booklet PUBLISING NMR Spectroscopy NULEAR MAGNETI RESONANE SPETROSOPY Origin of Spectra Theory All nuclei possess
UV-Vis spectroscopy Basic theory
UV-Vis spectroscopy Basic theory Dr. Davide Ferri Empa, Lab. for Solid State Chemistry and Catalysis 044 823 46 09 davide.ferri@empa.ch Importance of UV-Vis in catalysis IR Raman NMR XAFS UV-Vis EPR 0
Chapter 5 Organic Spectrometry
Chapter 5 Organic Spectrometry from Organic Chemistry by Robert C. Neuman, Jr. Professor of Chemistry, emeritus University of California, Riverside orgchembyneuman@yahoo.com
Sample exam questions for First exam CHM 2211
Sample exam questions for First exam CM 2211 1. The IR absorption due to the stretching of which of these carbon-hydrogen bonds occurs at the highest frequency? I II III E) V IV V 2. ow many signals would
Reaction of Blue Food Dye with Bleach
Exercise 2 Reaction of Blue Food Dye with Bleach 2 Introduction In the experiment, you will study the rate of the reaction of FD&C Blue #1 (Blue #1 is denoted by E number E133 in food stuff) with sodium
Sur 1 Bit bit n 4 bit n 3 bit n 2 bit n 1 bit n 4 bit n 3 bit n 2 bit n 1 bit n 4 bit n 3 bit n 2 bit n 1
Si on a 1 QUARTET Si on a 2 QUARTETS QUARTET Faible Poids QUARTET Fort Poids QUARTET Faible Poids Sur 1 Bit bit n 4 bit n 3 bit n 2 bit n 1 bit n 4 bit n 3 bit n 2 bit n 1 bit n 4 bit n 3 bit n 2 bit n
IDENTIFICATION OF ALCOHOLS
IDENTIFICATION OF ALCOHOLS Alcohols are organic compounds that which considered as derivatives of water. One of the hydrogen atoms of water molecule (H-O-H) has been replaced by an alkyl or substituted
"Internationalization vs. Localization: The Translation of Videogame Advertising"
Article "Internationalization vs. Localization: The Translation of Videogame Advertising" Raquel de Pedro Ricoy Meta : journal des traducteurs / Meta: Translators' Journal, vol. 52, n 2, 2007, p. 260-275.
Hierarchical Classification of the Photovoltaic Materials by Data Analysis Method
Rev. Energ. Ren. Vol.5 (00) 3-3 Hierarchical Classification of the Photovoltaic Materials by Data Analysis Method M. Benosman, A. Zerga and B. Benyoucef Laboratoire de Matériaux et des Energies Renouvelables
INTERNATIONAL OLIVE COUNCIL
INTERNATIONAL OLIVE COUNCIL COI/T.20/Doc. No 19/Rev. 3 February 2015 ENGLISH Original: ENGLISH Príncipe de Vergara, 154 28002 Madrid España Telef.: +34 915 903 638 Fax: +34 915 631 263 - e-mail: iooc@internationaloliveoil.org
IR Applied to Isomer Analysis
DiscovIR-LC TM Application Note 025 April 2008 Deposition and Detection System IR Applied to Isomer Analysis Infrared spectra provide valuable information about local configurations of atoms in molecules.
Office of the Auditor General / Bureau du vérificateur général FOLLOW-UP TO THE 2010 AUDIT OF COMPRESSED WORK WEEK AGREEMENTS 2012 SUIVI DE LA
Office of the Auditor General / Bureau du vérificateur général FOLLOW-UP TO THE 2010 AUDIT OF COMPRESSED WORK WEEK AGREEMENTS 2012 SUIVI DE LA VÉRIFICATION DES ENTENTES DE SEMAINE DE TRAVAIL COMPRIMÉE
Typical Infrared Absorption Frequencies. Functional Class Range (nm) Intensity Assignment Range (nm) Intensity Assignment
Typical Infrared Absorption Frequencies Functional Class Range (nm) Intensity Assignment Range (nm) Intensity Assignment Alkanes 2850-3000 CH 3, CH 2 & CH 2 or 3 bands Alkenes 3020-3100 1630-1680 1900-2000
Future Entreprise. Jean-Dominique Meunier NEM Executive Director www.nem-initiative.org. Nov. 23, 2009 FIA Stockholm
Future Entreprise Jean-Dominique Meunier NEM Executive Director www.nem-initiative.org Nov. 23, 2009 FIA Stockholm 1 Nov. 23, 2009 FIA Stockholm Source : @JDM 2 Nov. 23, 2009 FIA Stockholm Source : @JDM