IMAPs La Rochelle. Indium Corporation. Indium Thermal Materials. Feb 2 nd 2012

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Indium Corporation Feb 2 nd 2012 IMAPs La Rochelle Graham Wilson Applications Engineer Tel: +44 (0)1908 580400 Mobile: +44 (0)7825 189554 E-mail: gwilson@indium.com Web: www.indium.com

Agenda Indium Corporation Market Sectors Focus on TIMs HeatSpring Data 2 INDIUM Information CORPORATION Property CONFIDENTIAL of Indium Corp.

Indium Corporation Worldwide: Manufacturing and Sales Offices 4 INDIUM Information CORPORATION Property CONFIDENTIAL of Indium Corp.

Markets Solder & Energy Business Unit PCB Assembly Solder Materials Engineered Solder Materials Semiconductor Packaging Solder Materials Thermal Interface Materials Alternative Energy (PV) materials NanoFoil and NanoBond

Thermal...we want it cool! Our Goal is providing High Quality Materials that give Extended Reliability to Applications both in Operation and in Service

Metal Thermal Interface Materials Forms Solder Paste Preforms Wire Types of Solder Indium Indium Containing Alloys Gold Tin, or Gold containing Lead Containing and Lead Free 10

General Review of Indium TIMs Solder TIMs means the TIM reflowed intermetallic is formed, stims SMA-TIMs, soft metal alloy, or compressible TIMs Flat Foil Compressible Surface Altered Foil, Heat-Spring Not Reflowed Phase Change TIMs applied as a solid and the heat-source changes the physical state of the TIM to a liquid metal. Liquid TIMs Liquid at room temp and in operation 11

Compressible Metal Thermal Materials SMA-TIM, soft metal alloy thermal interface material Pure Indium Preforms Indium Containing Alloy Preforms Pure Gold Pure Tin Pure Silver Indium with diffusion barrier TIMs for Burn-in 12 Heat-Spring or surface altered TIMs Heat spring pattern D (HSD) min 76micron after full compression Compensates up to 76micron nonplanarity

Compressible Metal Thermal Materials High thermal conductivity Low bulk resistance insensitive to BLT Heat spreading Metal to Metal Conformability Plastic deformation provides low contact resistance path, especially after time zero (burn-in period) Inherent gap filling for co-planarity issues: +/- 76um Complies with CTE mismatch Stability No bake-out or pump-out issues 13

Heat-Spring : What is it? Material Description Made from Indium or Indium Tin as standard alloys We alter the surface so contact resistance is reduced We use high conductive metal 86w/mk We custom package for your application We standard pack in Tape and Reel It s a green TIM 14

Temperature Profiles- Indium Foil Vs HSD Both 76um Th At 70-75psi a flat foil has about 33% contact. This contact is not consistent. When the Indium is altered with the HSD process We have distributed the 33% contact across the entire area Giving consistent contact and lower contact resistance. 15

Thermal Resistance (cm 2 - o C/W) Indium Thermal Materials Material Comparison: Grease, Foil, Heat-Spring 0.20 0.18 0.16 0.14 Bulk Thermal Resistance Thermal Grease #1 (250um mil) Thermal Grease #2 (250um mil) 76um 3 mil Indium Foil 76um 3 mil HEAT-SPRING 0.12 0.10 0.08 0.06 0.04 0.02 0.00 16 0 13.8 20 27.5 40 41 60 80 55 100 69 120 83 140 96.5 160 110 180 124 138 200 Pressure N/Cm2 (psi)

Heat Spring vs. Graphite Foil Grafoil 127um HSD004 ind1e 100um HSD003 ind 4 76um HSD004 ind 4 100um 17 0 35 69 103 138 172 207 N/Cm2

PCM (solid) vs. PCM (liquid) vs. Heat Spring At high pressures, contact resistance on the HSD yields thermal resistance equivalent to liquid metal or a solder. Indalloy 19 Solid 76um Indalloy 19 Liquid 76um HSD 004 ind 4 100um Indalloy 19 (51In, 32.5Bi, 16.5Sn Indalloy 4 (100 In) 18 0 35 69 103 138 172 207 N/Cm2

Reliability Testing 19

Time Zero for HeatSpring (HSD) vs. Grease; Heat-Spring is running cooler at time zero HSD 76um Baseline Grease 88-90 86-88 84-86 82-84 80-82 78-80 76-78 74-76 72-74 70-72 68-70 66-68 64-66 62-64 60-62 Time 0 Time 0 20

TTV Comparison Bake 1500hrs HSD 76um Baseline Grease 1561 Hr. @90C 88-90 86-88 84-86 82-84 80-82 78-80 76-78 74-76 72-74 70-72 68-70 66-68 64-66 62-64 60-62 Degrees C 1597 Hr. @90C 21

TTV Comparison Bake 3000hrs HSD 76um Baseline Grease 3108 Hr. @90C 88-90 86-88 84-86 82-84 80-82 78-80 76-78 74-76 72-74 70-72 68-70 66-68 64-66 62-64 60-62 Degrees C 3056 Hr. @90C 22

TTV Power Cycling Baseline Thermal Grease shows Pump-out Indium Thermal Materials Time 0 1000 Power-On Cycles 0-50 watts 3 minutes power on, then 2 minutes power off 88-90 86-88 84-86 82-84 80-82 78-80 76-78 74-76 72-74 70-72 68-70 66-68 64-66 62-64 60-62 Degrees C 23

TTV Power Cycling HSD 76um Heat-Spring performs better after multiple cycles Time 0 1000 Power-On Cycles same test as previous slide HSD 76um 88-90 86-88 84-86 82-84 80-82 78-80 76-78 74-76 72-74 70-72 68-70 66-68 64-66 62-64 60-62 Degrees C 24

Time zero vs. 1000 cycles: Thermal Grease 88-90 86-88 84-86 82-84 80-82 78-80 76-78 74-76 72-74 70-72 68-70 66-68 64-66 62-64 60-62 Time zero vs. 1000 cycles: HSD 25 88-90 86-88 84-86 82-84 80-82 78-80 76-78 74-76 72-74 70-72 68-70 66-68 64-66 62-64 60-62 HSD 76um

Thermal Resistance- Grease Vs Heat-Spring Vs Polymer PCM PCM material S-E Grease (G751) HSD 004 ind 4 100um 26

Thickness (mm) Indium Thermal Materials Resistance ( o C cm 2 /W) 85/85 Hast Testing- Heat Spring 0.140 Ind4 SMA TIM Thickness & Resistance vs Time (85 o C / 85% RH) Thickness (Ave): Resistance (Ave): 0.200 0.180 0.120 0.160 0.100 0.140 0.080 0.120 0.100 0.060 0.080 0.040 0.060 0.040 0.020 0.020 0.000 0 50 100 200 400 600 800 1000 Time (hrs) 0.000 27

Temperature Difference, T J-A ( o C) Indium Thermal Materials ISTA Laptop Vibration Testing ISTA Shock and Vibration Testing 53.0 52.0 51.0 Time 0 After ISTA Vibe After Vibe and Drop 50.0 49.0 48.0 47.0 46.0 Core 0 Core 1 ACPI 28

Temperature Difference, T J-A ( o C) Indium Thermal Materials Laptop Random Frequency Vibration Testing Random Component Vibration Testing 54.0 53.0 Time 0 After Random Vibration 52.0 51.0 50.0 49.0 48.0 Core 0 Core 1 ACPI 29

Heat-Spring Benefits. Re-workable Pick and Place-able Clean Application, no residue Passes Shock and Vibe Passes Thermal Cycling Passes Bake Test Passes Power Cycling High Volume Tape and Reel Packaging Foil TIM can be placed and moved before clamping force is applied Indium Corporation Thermal Lab can do additional required testing if needed 30

Heat-Spring Availability minimum thickness of 76um max thickness of 6mm Max width on a Heat-Spring is ~203mm. Can be laid side by side. Sample Bundles (20-100pc) are available in the following: 12.7mm, 25.4mm, 38.1mm and 50.8mm squares 100um thick Ind4 (99.99In) and ind1e (52In48Sn) Over 2000 dies available in house Custom dies available 31

Graham Wilson Applications Engineer Tel: +44 (0)1908 580400 Mobile: +44 (0)7825 189554 E-mail: gwilson@indium.com Web: www.indium.com Thank you Coffee Break!!!

Some Typical Applications for Indium TIMs 33

CPU s and GPU s TIM1: Indium Solder Preforms TIM1.5: Heat-Spring, Liquid Metal TIM2: Heat-Spring, Liquid Metal CPU examples Intel Celeron ~50 watts Intel Sandy Bridge ~130 watts GPU example nvidia Tesla 180 watts 34

Liquid Metal on Desktop for TIM2 http://forums.macrumors.com/showthread.php?t=297084 35

Hi Power LED s Die Attach: Gold Tin Module Attach: BiSn or PbFree Paste, wire High Power LED Heat- Sinking: Heat-Spring 36 Applications range from automotive through to advertising and building lighting

Luminus Devices Application Note: 37

IGBT Power Modules Die and Diode Attach: Paste and preforms (High Sn or AuSn) DBC Substrate attach: Ribbon, Preforms and possible Paste Base Plate Heat-Sinking: Heat-Spring 38

Infineon PrimePack App Note. 39

Power RF Die attach = AuSn or SAC alloy Hermetic Sealing = AuSn Lead Attach = SAC Paste or SAC Flux coated preform Power Amp Heat-Sinking with Solder attach or Heat-Spring 40

Burn-in: Ideal for multi height packages Single Clamping Force Subject High Spot Subject Low Spot HEAT-SPRING TIM Base surface 41