Page 1 of 8 DAIHAN INK CO., LTD. 899 Eoyeon-ri,Cheongbuk-myeon Pyeongteak-si,Gyeonggi-do Korea The following sample(s) was/were submitted and identified by/on behalf of the client as:- SGS File No. Product Name Item No./Part No. : AYAA16-08310 : SOLFREE MAGENTA_SOLFREE YELLOW(HF)_SOLFREE CYAN_SOLFREE BLACK_SOLFREE WHITE : N/A Received Date : 2016. 02. 03 Test Period : 2016. 02. 03 to 2016. 02. 11 Test Results : For further details, please refer to following page(s) SGS Korea Co., Ltd. Jeff Jang / Chemical Lab Mgr t +82 (0)31 4608 000 f +82 (0)31 4608 09 http://www.sgsgroup.kr
Page 2 of 8 Sample No. : AYAA16-08310.001 Sample Description : SOLFREE MAGENTA_SOLFREE YELLOW(HF)_SOLFREE CYAN_SOLFREE BLACK_SOLFREE WHITE Item No./Part No. : N/A Materials : LIQUID Heavy Metals Test Items Unit Test Method MDL Results Cadmium (Cd) Lead (Pb) Mercury (Hg) Hexavalent Chromium (Cr VI) Antimony (Sb) Flame Retardants-PBBs/PBDEs With reference to IEC 62321-:2013 (Determination of Cadmium by ICP-OES) With reference to IEC 62321-:2013 (Determination of Lead by ICP-OES) With reference to IEC 62321-4:2013 (Determination of Mercury by ICP-OES) With reference to IEC 62321:2008 (Determination of Hexavalent Chromium by spot test/colorimetric Method using UV-Vis) With reference to EPA 302(1996), US EPA 6010B(1996), ICP Test Items Unit Test Method MDL Results Monobromobiphenyl Dibromobiphenyl Tribromobiphenyl Tetrabromobiphenyl Pentabromobiphenyl Hexabromobiphenyl Heptabromobiphenyl Octabromobiphenyl Nonabromobiphenyl Decabromobiphenyl Monobromodiphenyl ether Dibromodiphenyl ether Tribromodiphenyl ether With reference to IEC 62321-6:201 With reference to IEC 62321-6:201 With reference to IEC 62321-6:201 With reference to IEC 62321-6:201 With reference to IEC 62321-6:201 With reference to IEC 62321-6:201 With reference to IEC 62321-6:201 With reference to IEC 62321-6:201 With reference to IEC 62321-6:201 With reference to IEC 62321-6:201 With reference to IEC 62321-6:201 With reference to IEC 62321-6:201 With reference to IEC 62321-6:201 0. t +82 (0)31 4608 000 f +82 (0)31 4608 09 http://www.sgsgroup.kr 2 1 10
Page 3 of 8 Sample No. : AYAA16-08310.001 Sample Description : SOLFREE MAGENTA_SOLFREE YELLOW(HF)_SOLFREE CYAN_SOLFREE BLACK_SOLFREE WHITE Item No./Part No. : N/A Materials : LIQUID Flame Retardants-PBBs/PBDEs Test Items Unit Test Method MDL Results Tetrabromodiphenyl ether Pentabromodiphenyl ether Hexabromodiphenyl ether Heptabromodiphenyl ether Octabromodiphenyl ether Nonabromodiphenyl ether Decabromodiphenyl ether Halogen Content With reference to IEC 62321-6:201 With reference to IEC 62321-6:201 With reference to IEC 62321-6:201 With reference to IEC 62321-6:201 With reference to IEC 62321-6:201 With reference to IEC 62321-6:201 With reference to IEC 62321-6:201 Test Items Unit Test Method MDL Results Bromine(Br) With reference to EN 1482, IC Chlorine(Cl) With reference to EN 1482, IC 30 14 30 NOTE: (1) = Not detected.(<mdl) (2) = ppm (3) MDL = Method Detection Limit (4) - = No regulation () Negative = Undetectable / Positive = Detectable (6) ** = Qualitative analysis (No Unit) (7) * = a. The sample is positive for CrVI if the CrVI concentration is greater than 0.13 ug/cm2. The sample coating is considered to contain CrVI. b. The sample is negative for CrVI if CrVI is n.d. (concentration less than 0.10 ug/cm2). The coating is considered a non-crvi based coating. c. The result between 0.10 ug/cm2 and 0.13 ug/cm2 is considered to be inconclusive - unavoidable coating variations may influence the determination. t +82 (0)31 4608 000 f +82 (0)31 4608 09 http://www.sgsgroup.kr
Page 4 of 8 Picture of Sample as Received: t +82 (0)31 4608 000 f +82 (0)31 4608 09 http://www.sgsgroup.kr
Page of 8 Testing Flow Chart for RoHS:Cd/Pb/Hg/Cr 6+ /PBBs&PBDEs Testing Cd/Pb/Hg PBBs/PBDEs Cr 6+ Acid Digestion with Microwave/Hotplate Filtration Residue Total Digestion ICP-AES/AAS/MS DATA Solvent Extraction of the Sample Screen Analysis Concentration/Dilution of Extraction Solution Filtration GC/MS DATA Nonmetallic Material Adding Extraction Solution Heating to 90~9 C for Extraction Filtration and ph Adjustment Adding 1,-Diphenylcarbazide for Color Development UV-Vis DATA The samples were dissolved totally by pre-conditioning method according to above flow chart for Cd,Pb,Hg. Section Chief : Gilsae Yi t +82 (0)31 4608 000 f +82 (0)31 4608 09 http://www.sgsgroup.kr
Cr6+ Page 6 of 8 Metallic Material Boiling water extraction (0 ± ) cm2 0 ml DI water Remove sample after boiling for 10 min Filter the solution by 0.4 µm if necessary 1 ml orthophosphoric acid 2 ml as sample blank 2 ml as sample 1 ml diphenylcarbazide aci UV-VIS Absorbance Value <0.1 µg/cm2 0.1 µg/cm2 Absorbance Value 0.13 µg/cm2 Absorbance Value >0.13 µg/cm2 Negative result Inconclusive Positive result t +82 (0)31 4608 000 f +82 (0)31 4608 09 http://www.sgsgroup.kr
Page 7 of 8 Flow Chart for Inorganic Elements Testing Inorganic Elements Acid Digestion with Microwave/Hotplate Filtration Residue Total Digestion ICP-AES DATA Major Inorganic Heavy Metals Antimony(Sb), Beryllium(Be), Phosphorus(P), Arsenic(As) etc. t +82 (0)31 4608 000 f +82 (0)31 4608 09 http://www.sgsgroup.kr
Page 8 of 8 Flow Chart for Halogen Test Sample screening using XRF. Liquid containing water(>80%) Yes No Weigh the samples into the combustion boat. Add absorption solution into the bomb or tube. Admit O2 gas or O2 +Ar2 gas and start the combustion. Allow during absorption of the burnt gas. Dilute the solution (EPA300) Analyze absorbed solution using Ion Chromatography. Data *** End of Report *** t +82 (0)31 4608 000 f +82 (0)31 4608 09 http://www.sgsgroup.kr