3-1 Copyright Richard M. Felder, Lisa G. Bullard, and Michael D. Dickey (2014)
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1 EQUATIONS OF STATE FOR GASES Questions A gas enters a reactor at a rate of 255 SCMH. What does that mean? An orifice meter mounted in a process gas line indicates a flow rate of 24 ft 3 /min. The gas temperature is 195 o F and the pressure is 62 psig. The gas is a mixture containing 70 mole% CO and the balance H 2. What is the mass flow rate of the hydrogen in the gas? A reactor feed stream consists of O 2 flowing at 32 kg/s. The gas is to be compressed from 37 o C and 2.8 atm absolute to 54 o C and 284 atm. What are the volumetric flow rates at the inlet and outlet (needed to rate the compressor)? A pitot tube indicates that the velocity of a stack gas is 5.0 m/s at 175 o C. The stack diameter is 4.0 m. A continuous stack analyzer indicates an SO 2 level of 2500 ppm (2500 moles SO 2 /10 6 moles gas). At what rate in kg/s is SO 2 being discharged into the atmosphere? A 70.0 m 3 tank is rated at 2000 kpa. If 150 kg of helium is charged into the tank, what will the pressure be? How much more helium can be added before the rated pressure is attained? Answers: Need an equation of state: relationship between temperature (T), pressure (P), volume (V), and number of moles (n) of a gas. In Chapter 4, streams on flow charts labeled like this: 100 mol/s mol A/mol mol B/mol In this chapter, stream data just as likely to look like this: o C, 800 mm Hg p A = 420 mm Hg (partial pressure of A) For material balances, however, we still need moles and mole fractions. The job now becomes one of converting volumetric flow rates (or volumes) to molar flow rates (or moles), and (for gases) partial pressures to mole fractions. (Latter is easy: y A = p A /P ) Convert volumes to moles Solids & liquids: use tabulated densities (volume to mass) & molecular weights (mass to moles). Mixtures either look up mixture density data or assume volume additivity & calculate density from Eq. (5.1-1). Gases, can t use tabulated densities. (Why not?) Instead, need an equation of state (EOS) a formula relating V, n, T, and P. Simplest is the ideal gas EOS. Read Section 5.1. We won t lecture on it, but you need to know it. 3-1
2 Ideal Gas Equation of State (Sections 5.2a & 5.2b) PV nrt (batch) or PV nrt (continuous) or PVˆ RT where Vˆ V / n (or V / n ) is the specific molar volume of the gas T and P must be absolute temperature (K, o R) and absolute pressure (not gauge). R is the gas constant values given on inside back cover of text. Convenient applies regardless of what the gas is, & whether the gas has a single component or is a mixture. If you can t assume ideal gas behavior (i.e., if gas is nonideal or real), Approximate greatest validity at low gas densities (high T, low P), when gas molecules are far enough apart for intermolecular forces to be negligible (behave like billiard balls). Usually ok for temperatures at or above 0 o C & pressures at or below 1 atm. Rule of thumb for when to use it given in Eqs. (5.2-3) on p Three will get you four. Given any three of the variables PV, (or V ), T, and n(or n ), calculate the fourth one. Example The volumetric flow rate of a stream of propane at 150 o C and 70.0 atm being fed to a combustion furnace is measured and found to be 29.0 m 3 /h. (a) Determine its molar flow rate in kmol/h. Solution. We are given three of the four gas law variables (,, and ) and so can determine the fourth one ( ). From the inside back cover, R (L atm)/(mol K). 3 kmol C 70.0 atm 29.0 m mol K 3H8 PV n h RT h L atm kmol = 58.5 h (b) Now, suppose an analysis of the combustion chamber products shows that the molar flow rate of the propane was 101 kmol/h. Think of four possible reasons for the discrepancy between the two stated values of the molar flow rate
3 (c) Check the assumption of ideal gas behavior. Solution: RT L atm L, therefore from Eq., P mol K mol ideal gas behavior is a assumption. For another example, work through Problem 5.10 in the workbook. Standard temperature and pressure (STP): 0 o C (273.16K, o R), 1 atm. At STP, 1 mol occupies L, 1 kmol occupies m 3, & 1 lb-mole occupies ft 3. (Memorize) While our text (and many other thermodynamic texts) use 0 o C and 1 atm as STP, there are some other standards. In this course, please use the values on p Suppose you are told that a gas flows at a rate of, say, 1280 SCFH [standard cubic feet per hour, or ft 3 (STP)/h] (a) It does not mean that the gas is at standard temperature and pressure. It does mean that if you brought it from whatever its temperature and pressure really are to 0 o C and 1 atm, its volumetric flow rate would be 1280 ft 3 /h. (See Example ) (b) You can calculate the molar flow rate of the gas as ft (STP) 1 lb-mole lb-mole n h ft (STP) h (c) If you know that the actual temperature of the gas is 120 o C (393K) and atm, you can calculate its actual flow rate as ft (STP) 393 K 1 atm ft V 2300 h 273 K atm h (See Example ) 3-3
4 Ideal Gas Mixtures, Partial Pressures, and Volume Percentages (Section 5.2c) Suppose y A = mole fraction of a component A in a mixture of gases at pressure P and volume V. (Example: A mixture of gases at P = 1000 mm Hg with a volume of 200 liters contains 30 mole% CH 4, 50 mole% C 2 H 6, and 20 mole% C 2 H 4.) Partial pressure of a component of a gas: p A = y A P Example: p mm Hg = 300 mm Hg CH4 The partial pressures of all components of a mixture add up to the total pressure (prove it). Pure component volume and percentage by volume: The pure component volume of A is the volume A would occupy if it were by itself at the mixture temperature and pressure PvA nart Divide va na ya (volume fraction = mole fraction) PV nrt V n The percentage by volume (% v/v) is 100 times the volume fraction. Thus, % v/v = mole% for an ideal gas mixture % v/v has no practical significance for a nonideal gas mixture Three alternative ways of telling you the value of a mole fraction MOLE FRACTIONS y A PARTIAL PRESSURE p A = y A P VOLUME FRACTION % v/v = mole% for an ideal gas mixture From now on, any of these specifications may be given in material balance problems. You should immediately convert the first two to mole fractions when you label the flow chart, and if you label the partial pressure on the flow chart also label the mole fraction and count p A = y A P as another equation in the degree-of-freedom analysis. 3-4
5 Exercise. Liquid acetone (C 3 H 6 O) is fed at a rate of 400 L/min into a heated chamber where it evaporates into a nitrogen stream which enters at 27 o C and 475 mm Hg (gauge). The gas leaving the heater is diluted by another nitrogen stream flowing at a measured rate of 419 m 3 (STP) at 25 o C and 2.5 atm. The combined gases are then compressed to a total pressure P = 6.3 atm (gauge) at a temperature of 325 o C. The partial pressure of acetone in this stream is p a = 501 torr (501 mm Hg). Atmospheric pressure is 763 torr. (a) Write the complete set of equations you would solve to determine the molar composition of the product gas stream and the volumetric flow rate of the nitrogen entering the evaporator. (b) How is it possible for the second nitrogen stream to be at standard temperature and pressure and at 25 o C and 2.5 atm? Solution. Verify that the flow chart is completely labeled. 3 V 1(m / min) n (mol N / min) 1 2 o 27 C, 475 torr 400 L/min C 3 H 6 O (l) n 2 (mol/min) (a) Degree-of-freedom analysis: Evaporator Compressor 419 m 3 /min (STP) N 2 /min n 3(mol N 2/ min) 25 o C, 2.5 atm n 4 (mol/ min) y 4 (mol C 3 H 6 O(v)/mol) (1 y 4 ) (mol N 2 /mol) 325 o C, 6.3 atm (gauge) p a = 501 torr System equations: (b) 3-5
6 Nonideal (Real) Gases (Section 5.3) How would you measure P, V, T relationships in a laboratory? Would the relationships be different for each gas species? When you can t assume behavior (low, high, outside criteria of Eqs ), rather than create massive tables of P, V, T data for each gas species, need to find a universal equation of state that incorporates properties of the gas species. Read p. 5-4 of the workbook. It turns out that different gases behave similarly at the same Section 5.3a. Each gas has a unique value for T c and P c (Table B.1). Let s review supercritical behavior. We will discuss three approaches for non-ideal equations of state: 1. Virial equations of state (Section 5.3b). PVˆ RT BP 1 (see p. 201 for how to calculate B) RT 2. Cubic equations of state and the SRK equation (Section 5.3c). Commonly used for single species (for mixtures, use compressibility factor EOS). The SRK equation of state (Eq ) may be the most commonly used EOS other than the ideal gas equation. Easy or hard to use, depending on which of the three variables ( PV, ˆ, T) is unknown. Procedure: For given species, look up T c, P c, and the Pitzer acentric factor (Table for selected species). Calculate a, b, and m from Eqs , 5.3-9, & If T and V ˆ are known, evaluate T r from Eq and from Eq , solve Eq for P. If T and P are known, enter Eq in Solver, enter all known values, and solve for V ˆ. (Alternatively, use Solver in Excel, as in Example ) If P and ˆ V are known, enter Eqs , for T r, and for into Excel s Solver, enter all known values, and solve for T. 3-6
7 3. Compressibility factor equation of state (Section 5.4): PV = znrt, where z is the compressibility factor (a fudge factor the farther it is from 1, the farther the gas is from ideal). Either you have tables where you can look up z for a given T and P (Section 5.4a, single species only), or you use the law of corresponding states (Section 5.4b) to estimate z. Procedure: Given two of the variables T, P, and V ˆ (or V and n or V and n ) 1. Look up T c and P c (e.g. in Table B.1). Apply Newton s corrections for H 2, He (p. 208). 2. Calculate two of the quantities reduced temperature. T r = T/T c, reduced pressure P r = P/P c, and ˆ ideal ideal reduced volume, ˆ V Vr RTc / Pc known. 3. Look up z on one of the generalized compressibility charts, Figs , depending on which two of the variables T, P, and ˆ V are 4. Substitute known variables and z into the compressibility factor equation of state to determine the unknown variable. Example: Example 5.4-2, p Note: If the gas were anything other than nitrogen, then Z will change because the critical constants are different. For example, Z = 1.4 for hydrogen. Go through Test Yourself on p Kay s rule: PVT calculations for nonideal gas mixtures using compressibility charts (Section 5.4c): Calculate pseudocritical temperature and pseudocritical pressure by weighting T ci and P ci by mole fractions of i th component (Eqs and ), then proceed as for single component. This is the only method we will present in this book for doing PVT calculations on nonideal gas mixtures. 3-7
8 Exercise. A natural gas (85 mole% CH 4, 15% C 2 H 6 ) at 20 o C and 80 atm is burned completely with 30% excess air. V natural gas 285 L/s. The stack gas emerges at 280 o C and 1 atm. What is V stack gas? Solution. (a) Draw and label the flow chart. Furnace CH 4 + 2O 2 CO 2 + 2H 2 O C 2 H O 2 2 2CO 2 + 3H 2 O (b) What equations of state should you use to relate the volumetric flow rates of the fuel and stack gases to their molar flow rates? Fuel gas: Stack gas: (c) Do the degree-of-freedom analysis (use atomic balances). 3-8
9 (d) Write out the seven equations required to solve for the unknowns, letting (T cm, P cm ) and (T ce, P ce ) = critical temperatures of methane and ethane, respectively. (You could find their values in Table B1 but don t bother.) 3-9
10 3-10
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