: Sorbitol Special Sorbitol Sorbitan Solution, NF;

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1 Sorbitol Special Sorbitol Sorbitan Solution Date of issue: 05/01/2015 Version: 1.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Trade name : Sorbitol Special Sorbitol Sorbitan Solution Synonyms : Sorbitol Special Sorbitol Sorbitan Solution, NF; Sorbitol Special Sorbitol Liquid, partially dehydrated Ph. Eur.; Sorbitol Special GC Sorbitol Sorbitan Solution, NF Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture 1.3. Details of the supplier of the safety data sheet SPI Pharma Inc. Rockwood Office Park 503 Carr Road Wilmington, Delaware (302) Emergency telephone number Emergency number SECTION 2: Hazards identification 2.1. Classification of the substance or mixture GHS-US classification Not classified : Pharmaceutical ingredient : Chemtrec (800) ; Chemtrec (Outside USA) (24 hours; 7 days/week) 2.2. Label elements GHS-US labelling No labelling applicable 2.3. Other hazards 2.4. Unknown acute toxicity (GHS-US) No data available SECTION 3: Composition/information on ingredients 3.1. Substance Name : SORBITOL SPECIAL Sorbitol Sorbitan Solution NF and/or NF/EP (All Grades) Name Product identifier % GHS-US classification Sorbitol (CAS No) Not classified Water (CAS No) Not classified 1,4-Sorbitol (CAS No) Not classified Mannitol (CAS No) Not classified SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : Assure fresh air breathing. Allow the victim to rest. In all cases of doubt, or when symptoms persist, seek medical advice. : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. Seek medical attention if irritation develops. 05/01/2015 EN (English) Page 1

2 First-aid measures after eye contact First-aid measures after ingestion : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. : Rinse mouth. Do NOT induce vomiting. If a large quantity has been ingested : Obtain emergency medical attention Most important symptoms and effects, both acute and delayed Symptoms/injuries : Not expected to present a significant hazard under anticipated conditions of normal use. Symptoms/injuries after inhalation : Overexposure to dusts may produce slight irritation of the respiratory system. Symptoms/injuries after eye contact : May cause slight irritation to eyes. Symptoms/injuries after ingestion : On ingestion in large quantities : may cause gastrointestinal disturbance Indication of any immediate medical attention and special treatment needed None known. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream Special hazards arising from the substance or mixture Explosion hazard : Product is an aqueous solution which will not burn. Reactivity : Stable Advice for firefighters Firefighting instructions Protective equipment for firefighters : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment Emergency procedures : Evacuate unnecessary personnel. : Equip cleanup crew with proper protection. : Ventilate area Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters Methods and material for containment and cleaning up For containment Methods for cleaning up 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling 7.2. Conditions for safe storage, including any incompatibilities Storage conditions Incompatible products Incompatible materials 7.3. Specific end use(s) : Contain the discharged material using dust suppressant. : On land, sweep or shovel into suitable containers. Minimize generation of dust. Store away from other materials. : Provide adequate ventilation. Avoid contact with eyes. Avoid generation of dust. Remove all sources of ignition. Use only non-sparking tools. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. : Store at room temperature. Keep container tightly closed. : Strong bases. Strong acids. Strong oxidizing agents. : Sources of ignition. Direct sunlight. 05/01/2015 EN (English) 2/6

3 SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Appropriate engineering controls Personal protective equipment : Provide local exhaust or general room ventilation to minimize exposure to dust. Exposures should be minimized in accordance with good industrial hygiene practices. : Avoid all unnecessary exposure. Protective goggles. Gloves. Hand protection Eye protection Respiratory protection : Wear protective gloves. : Chemical goggles or safety glasses. : In case of insufficient ventilation, wear suitable respiratory equipment. : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Clear colorless viscous liquid Color : Clear Odor : None Odor threshold ph : Neutral Relative evaporation rate (butyl acetate=1) Melting point Freezing point Boiling point : > 212 F (100 C) Flash point Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure : Not applicable Relative vapour density at 20 C Relative density Density Solubility Log Pow Log Kow Viscosity, kinematic : Not applicable Viscosity, dynamic : About C Explosive properties Oxidising properties Explosive limits 9.2. SECTION 10: Stability and reactivity Reactivity Stable Chemical stability Stable. 05/01/2015 EN (English) 3/6

4 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur Conditions to avoid None Incompatible materials This product may react with strong oxidizing agents Hazardous decomposition products Fume. Carbon monoxide. Carbon dioxide. Low molecular weight hydrocarbons. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity Sorbitol ( ) LD50 oral rat Water ( ) LD50 oral rat Mannitol ( ) LD50 oral rat Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Potential Adverse human health effects and symptoms Symptoms/injuries after inhalation Symptoms/injuries after eye contact Symptoms/injuries after ingestion mg/kg >90 ml/kg mg/kg : Based on available data, the classification criteria are not met. : Overexposure to dusts may produce slight irritation of the respiratory system. : May cause slight irritation to eyes. : On ingestion in large quantities : may cause gastrointestinal disturbance. SECTION 12: Ecological information Toxicity Persistence and degradability Sorbitol Special Sorbitol Sorbitan Solution Persistence and degradability Not established Bioaccumulative potential Sorbitol Special Sorbitol Sorbitan Solution Bioaccumulative potential Not established. 05/01/2015 EN (English) 4/6

5 12.4. Mobility in soil Other adverse effects Effect on ozone layer Effect on the global warming : : No known ecological damage caused by this product. : Avoid release to the environment. SECTION 13: Disposal considerations Waste treatment methods Waste disposal recommendations Ecology - waste materials : Dispose in a safe manner in accordance with local/national regulations. Empty containers should be rinsed and discarded in a waste container or offered for recycling if possible. Do not re-use empty containers except for storage and shipment of original product. : Avoid release to the environment. SECTION 14: Transport information In accordance with DOT Not regulated for transport Additional information : No supplementary information available. ADR Transport document description : Transport by sea Air transport SECTION 15: Regulatory information US Federal regulations International regulations CANADA EU-Regulations Classification according to Regulation (EC) No. 1272/2008 [CLP] Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] National regulations US State regulations No supplementary information available SECTION 16: Abbreviations and acronyms Date of SDS preparation : 05/01/2015 : ATE - acute toxicity estimate. CAS - Chemical Abstracts Service. HCS - Hazard Communication Standard. HMIS - Hazardous Materials Identification System. GHS - Globally Harmonised System. OSHA - Occupational Safety and Health Administration. SDS -. : None. 05/01/2015 EN (English) 5/6

6 NFPA health hazard NFPA fire hazard NFPA reactivity : 0 - Exposure under fire conditions would offer no hazard beyond that of ordinary combustible materials. : 1 - Must be preheated before ignition can occur. : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water. HMIS III Rating Health Flammability Physical Personal Protection : 0 Minimal Hazard - No significant risk to health : 1 Slight Hazard : 0 Minimal Hazard : Safety glasses with side shields SDS US (GHS HazCom 2012) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 05/01/2015 EN (English) 6/6

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