: Henko all weather comp B

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1 Revision date: : Version: SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Chemical type Trade name : Mixture Product code : 7236 : Henko all weather comp B 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Intended for general public Main use category Industrial/Professional use spec. Use of the substance/preparation Function or use category : Industrial use,professional use : Non-dispersive use wide dispersive use : adhesive : Adhesives, binding agents Uses advised against 1.3. Details of the supplier of the safety data sheet Henko A & T B.V. Graafschap Hornelaan HT Weert - Netherlands T F Emergency telephone number Emergency number : SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Directive 67/548/EEC or 1999/45/EC Carc.Cat.3; R40 Xn; R20-48/20 Xi; R36/37/38 R42/43 Full text of R-phrases: see section 16. Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Directive 67/548/EEC or 1999/45/EC Hazard symbols : Hazardous ingredients R-phrases S-phrases Xn - Harmful : Methylenediphenyl diisocyanate : R20 - Harmful by inhalation. R36/37/38 - Irritating to eyes, respiratory system and skin. R40 - Limited evidence of a carcinogenic effect R42/43 - May cause sensitization by inhalation and skin contact. R48/20 - Harmful: danger of serious damage to health by prolonged exposure through inhalation. : S1/2 - Keep locked up and out of the reach of children. S23 - Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer). S36/37 - Wear suitable protective clothing and gloves. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible) Other hazards This substance/mixture does not meet the PBT/vPvB criteria of REACH, annex XIII EN (English) 1/5

2 SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Name Product identifier % Classification according to Directive 67/548/EEC Methylenediphenyl diisocyanate (CAS No.) (EC no) (EC index no) ,2 dimorfolino ditehylether (CAS No.) (EC no) Carc.Cat.3; R40 Xn; R20-48/20 Xi; R36/37/38 R42/ Xi; R36/38 Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] Methylenediphenyl diisocyanate (CAS No.) (EC no) (EC index no) ,2 dimorfolino ditehylether (CAS No.) (EC no) Full text of R-, H- and EUH-phrases: see section Acute Tox. 4 (Inhalation), H332 Skin Irrit. 2, H315 Eye Irrit. 2, H319 Resp. Sens. 1, H334 Skin Sens. 1, H317 Carc. 2, H351 STOT SE 3, H335 STOT RE 2, H Skin Irrit. 2, H315 Eye Irrit. 2, H319 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Remove to fresh air and keep at rest in a position comfortable for breathing. If breathing difficulties persist : Call a physician immediately. : Wash off immediately with soap and plenty of water. Do not apply (chemical) neutralizing agents. If necessary seek medical advice. : Wash immediately with lots of water (15 minutes)/shower. Do not apply (chemical) neutralizing agents. Consult an eye specialist. : Rinse mouth out with water. If swallowed, do NOT induce vomiting. Immediately consult a doctor/medical service Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media 5.2. Special hazards arising from the substance or mixture Fire hazard : Polyvalent foam. carbon dioxide (CO2), powder, hazy water. : On heating/burning: release of carbon monoxide - carbon dioxide. Nitrous fumes. Decomposes on exposure to temperature rise: formation of small quantities of hydrogen cyanide. Reacts violently with hot water: pressure rise and possible bursting of container Advice for firefighters Protection during firefighting Other information : Wear self-contained breathing apparatus when entering area unless atmosphere is proved to be safe. Protective clothing. : Continue water spray from protected position until container stays cool. Do not move the load if exposed to heat. Dilute toxic gases with water spray. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel For emergency responders 6.2. Environmental precautions EN (English) 2/5

3 6.3. Methods and material for containment and cleaning up Methods for cleaning up : Wash contaminated clothes. Acetone Reference to other sections SECTION 7: Handling and storage 7.1. Precautions for safe handling Hygiene measures : Strict hygiene required Conditions for safe storage, including any incompatibilities Storage conditions : Ventilation along the floor. Keep only in the original container in a cool, well-ventilated place. Maximum storage period : 365 days Storage area : Store away from heat. Store in tightly closed containers Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Appropriate engineering controls Hand protection Eye protection Skin and body protection Respiratory protection : Concentration measurement in air. Well-ventilated area. : polyethylene or polypropylene gloves in combination with fabric under-gloves. : Face shield. : Protective equipment. : Wear appropriate breathing apparatus if air renewal not sufficient to maintain dust/vapour under TLV. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Solid Appearance : liquid / paste. Colour Odour Odour threshold ph Melting point Solidification point Boiling point Flash point Relat. evapor. rate comp. to butylacetate Flammability (solid, gas) Explosive limits Vapour pressure Relative vapour density at 20 C Relative density Solubility Log Pow Self ignition temperature Decomposition temperature Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties 9.2. Other information SECTION 10: Stability and reactivity Reactivity EN (English) 3/5

4 10.2. Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products SECTION 11: Toxicological information Information on toxicological effects Acute toxicity : Harmful by inhalation. Irritation Corrosivity Sensitisation Repeated dose toxicity Carcinogenicity Mutagenicity Reproductive toxicity : Irritating to eyes, respiratory system and skin. : May cause sensitization by inhalation and skin contact. : Harmful: danger of serious damage to health by prolonged exposure through inhalation. : Limited evidence of a carcinogenic effect. SECTION 12: Ecological information Toxicity Persistence and degradability Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Henko all weather comp B This substance/mixture does not meet the PBT/vPvB criteria of REACH, annex XIII Other adverse effects SECTION 13: Disposal considerations Waste treatment methods SECTION 14: Transport information No dangerous good in sense of transport regulations. SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations No ingredients included in the REACH Candidate list National regulations Chemical safety assessment EN (English) 4/5

5 SECTION 16: Other information Full text of R-, H- and EUH-phrases: Acute Tox. 4 (Inhalation) Acute toxicity (inhalation) Category Carc. 2 Carcinogenicity Category Eye Irrit. 2 Serious Eye Damage/Irritation Category Resp. Sens. 1 Respiratory sensitization Category Skin Irrit. 2 skin corrosion/irritation Category Skin Sens. 1 Skin sensitization Category STOT RE 2 Specific target organ toxicity (repeated exposure) Category STOT SE 3 Specific target organ toxicity (single exposure) Category H315 Causes skin irritation H317 May cause an allergic skin reaction H319 Causes serious eye irritation H332 Harmful if inhaled H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled H335 May cause respiratory irritation H351 Suspected of causing cancer H373 May cause damage to organs through prolonged or repeated exposure R20 Harmful by inhalation R36/37/38 Irritating to eyes, respiratory system and skin R36/38 Irritating to eyes and skin R40 Limited evidence of a carcinogenic effect R42/43 May cause sensitization by inhalation and skin contact R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation. SDS EU (REACH Annex II) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product EN (English) 5/5

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