: Glucose oxidase/catalase Mixture (eukaryote) E-GOXCA

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1 Date of issue: 05/06/2013 Revision date: 25/11/2015 Supersedes: 28/05/2013 Version: 1.2 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Powder Name : Glucose oxidase/catalase Mixture (eukaryote) 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Industrial/Professional use spec Use of the substance/mixture : Industrial For professional use only : Use as laboratory reagent Uses advised against 1.3. Details of the supplier of the safety data sheet Megazyme International Ireland Bray Business Park Bray - Ireland T F Emergency telephone number Emergency number : Country Official advisory body Address Emergency number IRELAND (REPUBLIC OF) UNITED KINGDOM SECTION 2: Hazards identification National Poisons Information Centre Beaumont Hospital National Poisons Information Service (Birmingham Centre) City Hospital 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Resp. Sens. 1 H334 Full text of H-phrases: see section 16 Beaumont Hospital Beaumont Road 9 Dublin Dudley Road B18 7QH Birmingham : (UK only) Classification according to Directive 67/548/EEC or 1999/45/EC Xn; R42 Full text of R-phrases: see section 16 Adverse physicochemical, human health and environmental effects 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] Hazard pictograms (CLP) : Signal word (CLP) Hazardous ingredients Hazard statements (CLP) Precautionary statements (CLP) : Danger GHS08 : glucose oxidase : H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled : P261 - Avoid breathing dust P285 - In case of inadequate ventilation wear respiratory protection P304+P341 - IF INHALED: If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing P342+P311 - If experiencing respiratory symptoms: Call a POISON CENTRE or doctor/physician P501A - Dispose of this material and its container at hazardous or special waste collection point 05/06/2013 EN (English) 1/6

2 2.3. Other hazards SECTION 3: Composition/information on ingredients 3.1. Substances 3.2. Mixture Name Product identifier % Classification according to Directive 67/548/EEC glucose oxidase (CAS No) (EC no) Xn; R42 Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] glucose oxidase (CAS No) (EC no) Full text of R-, H- and EUH-phrases: see section Resp. Sens. 1, H334 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing. If experiencing respiratory symptoms: Call a POISON CENTRE or doctor/physician. : Remove affected clothing and wash all exposed skin area with mild soap and water, followed by warm water rinse. : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness persist. : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention Most important symptoms and effects, both acute and delayed Symptoms/injuries after inhalation : May cause allergy or asthma symptoms or breathing difficulties if inhaled Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream Special hazards arising from the substance or mixture 5.3. Advice for firefighters Firefighting instructions Protection during firefighting : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Avoid fire-fighting water enteing the environment. : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Emergency procedures For emergency responders Protective equipment Emergency procedures : Evacuate unnecessary personnel. : Equip cleanup crew with proper protection. : Ventilate area Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters Methods and material for containment and cleaning up Methods for cleaning up : On land, sweep or shovel into suitable containers. Minimize generation of dust. Store aways from other materials. 05/06/2013 EN (English) 2/6

3 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling 7.2. Conditions for safe storage, including any incompatibilities Storage conditions Incompatible materials 7.3. Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. Avoid breathing dust/fume/gas/mist/vapours/spray. : Keep only in the original container in a cool, well ventilated place away from : Keep container closed when not in use. : Sources of ignition. Direct sunlight Exposure controls Personal protective equipment Hand protection Eye protection Respiratory protection : Avoid all unnecessary exposure. : Wear protective gloves. : Chemical goggles or safety glasses. : In case of inadequate ventilation wear respiratory protection. : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Solid Colour : Colourless. Odour : characteristic. Odour threshold ph Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point Flash point Self ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Solubility Log Pow Log Kow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits /06/2013 EN (English) 3/6

4 SECTION 10: Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Direct sunlight. Extremely high or low temperatures Incompatible materials Strong bases Hazardous decomposition products fume. Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard Potential Adverse human health effects and symptoms : May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause allergy or asthma symptoms or breathing difficulties if inhaled :. SECTION 12: Ecological information Toxicity Persistence and degradability K- LACTUL Bottle 2 Persistence and degradability glucose oxidase ( ) Persistence and degradability Readily biodegradable in water Bioaccumulative potential K- LACTUL Bottle 2 Bioaccumulative potential glucose oxidase ( ) Bioaccumulative potential 05/06/2013 EN (English) 4/6

5 12.4. Mobility in soil Results of PBT and vpvb assessment Other adverse effects : Avoid release to the environment. SECTION 13: Disposal considerations Waste treatment methods Waste disposal recommendations Ecology - waste materials SECTION 14: Transport information In accordance with ADR / RID / ADNR / IMDG / ICAO / IATA UN number No dangerous good in sense of transport regulations UN proper shipping name Transport hazard class(es) Packing group : Dispose in a safe manner in accordance with local/national regulations. Dispose of contents/container to... : Avoid release to the environment Environmental hazards : No supplementary information available Special precautions for user Overland transport Transport by sea Air transport Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code SECTION 15: Regulatory information Safety, health and environmental regulations/legislation specific for the substance or mixture EU-Regulations No REACH Annex XVII restrictions Contains no REACH candidate substance National regulations Chemical safety assessment No chemical safety assessment has been carried out SECTION 16: Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. : None. Full text of R-, H- and EUH-phrases:: 05/06/2013 EN (English) 5/6

6 Resp. Sens. 1 Sensitisation Respiratory, category 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled R42 Xn May cause sensitization by inhalation Harmful SDS EU (REACH Annex II) This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product 05/06/2013 EN (English) 6/6

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