Material Safety Data Sheet

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1 Material Safety Data Sheet Regulation (EC) No 1907/2006 Version 3.0 Revision Date 01/09/2014 Date IDENTIFICATION OF THE MIXTURE AND COMPANY IDENTIFICATION 1.1 Product Tags Product Name: MetZyme Ligno Item number: 936 REACH Pre-registration: WN CLP Number: Identification of the substance or mixture Relevant identified uses and uses advised against Identified uses: Use the industrial production of textiles, biofuel- or Pulp and paper industry as an excipient. 1.3 Material Safety Data Sheet supplier details seller / producer: MetGen Ltd Rakentajantie 26, Kaarina, Finland Phone +358 (0) Your address will 1.4 Emergency telephone number Emergency telephone number: Poison Information Centre HAZARDS IDENTIFICATION 2.1 Identification of the substance or mixture Classification with Regulation (EC) No 1272/2008 [EU-GHS / CLP]. Respiratory sensitization (Category 1) EU Directives 67/548 / EEC or 1999/45 / EC Classification Inhalation may cause sensitization. 2.2 Label elements The labeling of the regulation (EC) No 1272/2008 [CLP]. Warning sign Word Danger Hazard statement (s) H334 May cause allergy or asthma symptoms or difficulty in breathing. Precautionary statement (s) P261 Avoid breathing dust / fume / gas / mist / vapors / spray P285 Wear respiratory protection if ventilation is inadequate. P304 + P341. IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. P342 + P311 If experiencing respiratory symptoms: Call POISON CENTER or physician.

2 P501 Dispose of contents / container to hazardous waste Directive 67/548 / EEC and as amended. Indication of danger / Xn / Harmful R-phrases R42 May cause sensitization by inhalation.phrases S23 Do not breathe gas / fumes / vapor / spray. 2.3 Other hazards - no other risk factors for non-pbt or vpvb 3 COMPOSITION AND INGREDIENTS 3.1 Substances Component Concentration enzyme protein CAS-No EC-No Index-No FIRST AID MEASURES 4.1 Description of first aid measures Special instructions Consult a physician. Show this safety data sheet to the doctor in attendance. Inhalation If breathed in, move person to fresh air. If not breathing, give artificial respiration. If the patient is allergic symptoms consult doctor. Skin contact Wash off with soap and plenty of water. Remove contaminated clothing and wash. Eye contact Flush eyes with water for at least 15 minutes, may not be chemically neutralize, if irritation persists, consult a doctor. After ingestion The patient is given plenty of water to an unconscious person or convulsions Never give anything by mouth and immediately consult a physician. 4.2 Most important symptoms and effects, both acute and delayed The substance is irritating to the respiratory tract, excessive exposure may lead to sensitization and allergic symptoms such as henkitysvaikeuksia especially lung diseases and allergy sufferers. 4.3 Indication of any immediate medical attention and special treatment needed If breathing is difficult patient to fresh air breathing guarantee a position to rest. If hengityoireet persist / worsen should contact a POISON CENTER or physician.

3 5. FIRE-FIGHTING MEASURES 5.1 Extinguishing media foam, powder or carbon dioxide ABC 5.2 Special hazards arising from substance or mixture The carbon and nitrogen fire decomposition products are harmful to the environment. 5.3 Advice for firefighters Wear a self-contained breathing apparatus (NIOSH / MSHA), and protective equipment for fire fighting. Packages can be cool with water. 6. ACCIDENTAL RELEASE MEASURES IN 6.1 Personal precautions, protective equipment and emergency procedures Isolate the accident in the area and use the personal protective equipment. Avoid dust formation. Avoid breathing vapors / fumes / gas inhalation. Ensure adequate ventilation. Evacuate personnel to the area. Wash or abandoned polluted clothes. 6.2 Environmental precautions Remove mechanically, it is recommended for downloading (note: the HEPA filter) The solid is collected in appropriate containers for disposal. Small amounts may be diluted with plenty of water while preventing aerosol formation and to flush a suitable drain. 6.3 Clean-up methods Remove mechanically, it is recommended for downloading (note: the HEPA filter). The solid is collected in appropriate containers for disposal. Small amounts may be diluted with plenty of water while preventing aerosol formation and to flush a suitable drain. Contaminated materials stored in closed containers for disposal. 7. HANDLING AND STORAGE 7.1 Precautions for safe handling Keep away from acids, bases, combustible organic substances or other easily oxidizable materials. Do not freeze, keep away from open flames and heat sources. 7.2 Conditions for safe storage, including any incompatibilities Keep in a cool place. Keep container tightly closed in a dry state. 7.3 Specific end use

4 8. EXPOSURE AND PERSONAL SAFETY 8.1 Control parameters Contains no substances with limit values. 8.2 Exposure controls Appropriate engineering controls The substance must be handled in well ventilated areas, with good industrial hygiene and safety practice. Wash hands before breaks and after work Personal protective equipment Eye and face protection Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166 (EU) with appropriate protective equipment. Skin and body protection Wear protective gloves when handling. (EN 374) neoprene or polyvinyl alcohol Body protection Wear long-sleeved Uniforms. Type of protective equipment must be selected at the specific workplace of the dangerous substance according to the concentration and amount. Respiratory protection Normal dust protection, use type P95 (US) or type P1 (EU EN 143) a better level of protection of use type OV / AG / P99 (US) or type ABEK-P2 (EU EN 143) respirator Environmental exposure controls Eye removed immediately and prevent aerosol formation. 9. PHYSICAL AND CHEMICAL PROPERTIES 9.1 The basic physical and chemical characteristics of the product a state: Brown liquid b Odor: Sweet, earth like c Odor threshold: Not specified d ph 7 +/- 0.5 e Not specified f Not specified g Not specified h Not specified i Not specified j Not specified k Not specified l Not specified m Relative density: Fixed Solubility: Soluble in water, also in other solvents n Not specified p Not specified q Not specified r Not specified s Not specified t Not specified

5 9.2 Other safety instructions 10. STABILITY AND REACTIVITY 10.1 Reactivity No data available 10.2 Chemical stability Stable 10.3 Possibility of hazardous reactions Not observed; not hazardous reactions 10.4 Conditions to avoid Not found 10.5 Incompatible materials No known 10.6 Hazardous decomposition products There is none 11. TOXICOLOGICAL INFORMATION 11.1 Information on toxicological effects Acute toxicity The product is not toxic Skin corrosion / irritation The product is not a primary skin irritant, but prolonged contact with the skin should be avoided. Serious eye damage / eye irritation Exposure to the substance causes irritation. Respiratory or skin sensitization Inhalation may cause sensitization and / or an allergic reaction in susceptible people. Does not cause skin symptoms. Germ cell mutagenicity Carcinogenicity This product is no ingredient which is at least 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. Reproductive toxicity Specific target organ toxicity single exposure

6 Specific target organ toxicity - repeated exposure Aspiration May cause allergy or asthma symptoms or breathing difficulties sensitized 12. ECOLOGICAL INFORMATION 12.1 Toxicity data are not available, however, the enzymes are not known to be particularly dangerous to the environment 12.2 Persistence and degradability data are not available, however, the product is an enzyme and the enzyme is known to be soluble in water and is unlikely to permanent. In addition, the enzymes are 100% biodegradable 12.3 Bioaccumulative data are not available, however, the product is completely soluble in water, therefore, is not likely to bioaccumulate, in addition to the enzymes are 100% biodegradable Mobility in the soil 12.5 Results of PBT and vpvb assessment 12.6 Other adverse effects 13. DISPOSAL CONSIDERATIONS 13.1 Waste treatment methods The product and its surplus is not classified as hazardous waste EU Directive 91/689 / EC. Contaminated packaging should be rinsed before disposal. 14. TRANSPORT INFORMATION 14.1 UN number ADR / RID: - IMDG: - IATA: shipping name ADR / RID: Not dangerous goods IMDG: Not dangerous goods IATA: Not dangerous goods 14.3 Transport hazard class ADR / RID: - IMDG: - IATA: -

7 14.4 Packaging class ADR / RID: - IMDG: - IATA: Environmental hazards ADR / RID: no IMDG Marine pollutant: no IATA: no 14.6 Special precautions for user 15. REGULATORY INFORMATION This Material Safety Data Sheet Conforms to Regulation (EC) No 1907/ specific for the substance or mixture Safety, health and environmental codes or legislation Conforms to EU Directives 67/548 / EEC and 1999/45 / EC requirements when used in the textile, biofuel- or paper and pulp industry Chemical Safety Assessment Information not yet available 16. OTHER INFORMATION More information Copyright 2011 MetGen Ltd. Unlimited copying of internal use, The above information is correct to the best of the current knowledge, but they should be used only as a guide. Metgen Ltd is not responsible for any kind of damage caused by the handling or from contact with the substance.

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