Label elements of the CLP regulation

Transcription

1 Label elements of the CLP regulation The CLP regulation (Classification, Labelling and Packaging of substances and mixtures) institutes new hazard symbols and standard phrases, and new classification rules.

2 Physical hazards 1/2 Explosives Classification Unstable Explosive Division 1.1 Division 1.2 Division 1.3 Division 1.4 Division 1.5 Division 1.6 Warning No signal word H200 Unstable Explosive H201 Explosive; mass explosion hazard H202 Explosive; severe projection hazard H203 Explosive; fire, blast or projection hazard H204 Fire or projection hazard H205 May mass explode in fire No hazard Flammable liquids Category 3 Flammable solids Warning H224 Extremely flammable liquid and vapour H225 Highly flammable liquid and vapour H226 Flammable liquid and vapour H228 Flammable solid H228 Flammable solid Flammable gases Flammable aerosols Oxidising gases Classification Category 1 H220 Extremely flammable gas H221 Flammable gas H222 Extremely H223 Flammable flammable aerosol aerosol H270 May cause or intensify fire; oxidizer Oxidising liquids Category 3 Oxidising solids Category 3 Warning H271 May cause fire or explosion; strong oxidiser H272 May intensify fire; oxidiser H272 May intensify fire; oxidiser Warning H271 May cause fire or explosion; strong oxidiser H272 May intensify fire; oxidiser H272 May intensify fire; oxidiser 1. CLP regulation: regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, according to the last adaptation to technical and scientific progress.

3 Physical hazards 2/2 Self-reactive substances and mixtures Classification Type A Type B Types C and D Types E and F Type G There are no label elements allocated to this hazard category Pyrophoric liquids Classification Category 1 Warning H240 Heating may cause an explosion H241 Heating may cause a fire or explosion H242 Heating may cause a fire H242 Heating may cause a fire H250 Catches fire spontaneously if exposed to air Pyrophoric solids Classification Category 1 Organic peroxides Classification Type A Type B Types C and D Types E and F Type G There are no label elements allocated to this hazard category H250 Catches fire spontaneously if exposed to air Warning H240 Heating may cause an explosion H241 Heating may cause a fire or explosion H242 Heating may cause a fire H242 Heating may cause a fire Substances and mixtures which, in contact with water, emit flammable gases Category 3 Warning H260 In contact with water releases flammable gases which may ignite spontaneously H261 In contact with water releases flammable gases H261 In contact with water releases flammable gases Self-heating substances and mixtures H251 Selfheating: may catch fire H252 Selfheating in large quantities: may catch fire 1. CLP regulation: regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, according to the last adaptation to technical and scientific progress. Substances and mixtures corrosive to metals Classification Category 1 Gases under pressure Classification Compressed gas Liquefied gas Refrigerated liquefied gas Dissolved gas Warning H290 May be corrosive to metals Warning Warning Warning Warning H280 Contains gas under pressure; may explode if heated H280 Contains gas under pressure; may explode if heated H281 Contains refrigerated gas; may cause cryogenic burns or injury H280 Contains gas under pressure; may explode if heated

4 Health hazards 1/2 Acute toxicity Classification Categories 1 and 2 Category 3 Category 4 Specific target organ toxicity after single exposure Category 3 Warning Warning : oral : dermal : inhalation H300 Fatal if swallowed H310 Fatal in contact with skin H330 Fatal if inhaled H301 Toxic if swallowed H311 Toxic in contact with skin H331 Toxic if inhaled H302 Harmful if swallowed H312 Harmful in contact with skin H332 Harmful if inhaled H370 Causes damage to organs (or state all organs affected, if known) (state route of exposure if it is conclusively proven that no other routes of exposure cause H371 May cause damage to organs (or state all organs affected, if known) (state route of exposure if it is conclusively proven that no other routes of exposure cause H335 May cause respiratory irritation or H336 May cause drowsiness or dizziness Skin corrosion/irritation Serious eye damage/eye irritation Classification Categories 1A, 1B and 1C Category 2 H314 Causes severe skin burns and eye damage H315 Causes skin irritation H318 Causes serious eye damage H319 Causes serious eye irritation Classification Respiratory or skin sensitisation Respiratory sensitisation Category 1 and sub-categories 1A and 1B H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled Skin sensitisation Category 1 and sub-categories 1A and 1B H317 May cause an allergic skin reaction Aspiration toxicity Classification Category 1 H304 May be fatal if swallowed and enters airways 1. CLP regulation: regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, according to the last adaptation to technical and scientific progress.

5 Health hazards 2/2 Specific target organ toxicity after repeated exposure Classification Carcinogenicity Categories 1A and 1B Category 2 H372 Causes damage to organs (or state all organs affected, if known) through prolonged or repeated exposure (state route of exposure if it is conclusively proven that no other routes of exposure cause H373 May cause damage to organs (or state all organs affected, if known) through prolonged or repeated exposure (state route of exposure if it is conclusively proven that no other routes of exposure cause H350 May cause cancer (state route of exposure if it is conclusively proven that no other routes of exposure cause H351 Suspected of causing cancer (state route of exposure if it is conclusively proven that no other routes of exposure cause Classification Germ cell mutagenicity Categories 1A and 1B Category 2 Reproductive toxicity Classification Categories 1A and 1B Category 2 Effects on or via lactation H340 May cause genetic defects (state route of exposure if it is conclusively proven that no other routes of exposure cause H341 Suspected of causing genetic defects (state route of exposure if it is conclusively proven that no other routes of exposure cause No signal word H360 May damage fertility or the unborn child (state specific effect if known) (state route of exposure if it is conclusively proven that no other routes of exposure cause H361 Suspected of damaging fertility or the unborn child (state specific effect if known) (state route of exposure if it is conclusively proven that no other routes of exposure cause H362 May cause harm to breast-fed children 1. CLP regulation: regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, according to the last adaptation to technical and scientific progress.

6 Environmental hazards ACUTE ous to the aquatic environment CHRONIC Classification Category 1 Category 1 Category 2 Category 3 Category 4 Warning Warning No signal word H400 Very toxic to aquatic life H410 Very toxic to aquatic life with long lasting effects H411 Toxic to aquatic life with long lasting effects No signal word H412 Harmful to aquatic life with long lasting effects No signal word H413 May cause long lasting harmful effects to aquatic life ous for the Ozone Layer H420 Harms public health and the environment by destroying ozone in the upper atmosphere 1. CLP regulation: regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, according to the last adaptation to technical and scientific progress. OR ous for the Ozone Layer EUH059 ous for the Ozone Layer

7 s for physical hazards Code H200 H201 H202 H203 H204 H205 H220 H221 H222 H223 H224 H225 H226 H228 H240 H241 H242 H250 H251 H252 H260 H261 H270 H271 H272 H280 H281 H290 Unstable explosive. Explosive; mass explosion hazard. Explosive; severe projection hazard. Explosive; fire, blast or projection hazard. Fire or projection hazard. May mass explode in fire. Extremely flammable gas. Flammable gas. Extremely flammable aerosol. Flammable aerosol. Extremely flammable liquid and vapour. Highly flammable liquid and vapour. Flammable liquid and vapour. Flammable solid. Heating may cause an explosion. Heating may cause a fire or explosion. Heating may cause a fire. Catches fire spontaneously if exposed to air. Self-heating: may catch fire. Self-heating in large quantities: may catch fire. In contact with water releases flammable gases which may ignite spontaneously. In contact with water releases flammable gas. May cause or intensify fire; oxidiser. May cause fire or explosion; strong oxidiser. May intensify fire; oxidiser. Contains gas under pressure; may explode if heated. Contains refrigerated gas; may cause cryogenic burns or injury. May be corrosive to metals. 1. CLP legislation: Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, according to the last adaptation to technical and scientific progress.

8 s for health hazards Code H300 * H301 ** H302 *** H304 H310 * H311 ** H312 *** H314 H315 H317 H318 H319 H330 * H331 ** H332 *** H334 H335 H336 H340 H341 H350 H351 H360 H361 H362 H370 H371 H372 H373 Fatal if swallowed. Toxic if swallowed. Harmful if swallowed. May be fatal if swallowed and enters airways. Fatal in contact with skin. Toxic in contact with skin. Harmful in contact with skin. Causes severe skin burns and eye damage. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye damage. Causes serious eye irritation. Fatal if inhaled. Toxic if inhaled. Harmful if inhaled. May cause allergy or asthma symptoms of breathing difficulties if inhaled. May cause respiratory irritation. May cause drowsiness or dizziness. May cause genetic defects (state route of exposure if it is conclusively proven that no other routes of exposure cause. Suspected of causing genetic defects (state route of exposure if it is conclusively proven that no other routes of exposure cause. May cause cancer (state route of exposure if it is conclusively proven that no other routes of exposure cause. Suspected of causing cancer (state route of exposure if it is conclusively proven that no other routes of exposure cause. May damage fertility or the unborn child (state specific effect if known) (state route of exposure if it is conclusively proven that no other routes of exposure cause. Suspected of damaging fertility or the unborn child (state specific effect if known) (state route of exposure if it is conclusively proven that no other routes of exposure cause. May cause harm to breast-fed children. Causes damage to organs (or state all organs affected, if known) (state route of exposure if it is conclusively proven that no other routes of exposure cause. May cause damage to organs (or state all organs affected, if known) (state route of exposure if it is conclusively proven that no other routes of exposure cause. Causes damage to organs (or state all organs affected, if known) through prolonged or repeated exposure (state route of exposure if it is conclusively proven that no other routes of exposure cause. May cause damage to organs (or state all organs affected, if known) through prolonged or repeated exposure (state route of exposure if it is conclusively proven that no other routes of exposure cause. * Combinaton of these hazard s is allowed. ** Combinaton of these hazard s is allowed. *** Combinaton of these hazard s is allowed. 1. CLP legislation: Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, according to the last adaptation to technical and scientific progress.

9 s for environmental hazards Code H400 H410 H411 H412 H413 H420 Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects. Toxic to aquatic life with long lasting effects. Harmful to aquatic life with long lasting effects. May cause long lasting harmful effects to aquatic life. Harms public health and the environment by destroying ozone in the upper atmosphere. Supplemental hazard information Code EUH001 EUH006 EUH014 EUH018 EUH019 EUH029 EUH031 EUH032 EUH044 EUH059 EUH066 EUH070 EUH071 EUH201 EUH201A EUH202 EUH203 EUH204 EUH205 EUH206 EUH207 EUH208 EUH209 EUH209A EUH210 EUH401 Explosive when dry. Explosive with or without contact with air. Reacts violently with water. In use may form flammable/explosive vapour-air mixture. May form explosive peroxides. Contact with water liberates toxic gas. Contact with acids liberates toxic gas. Contact with acids liberates very toxic gas. Risk of explosion if heated under confinement. ous to the ozone layer. Repeated exposure may cause skin dryness or cracking. Toxic by eye contact. Corrosive to the respiratory tract. Contains lead. Should not be used on surfaces liable to be chewed or sucked by children. Warning! Contains lead. Cyanoacrylate.. Bonds skin and eyes in seconds. Keep out of the reach of children. Contains chromium (VI). May produce an allergic reaction. Contains isocyanates. May produce an allergic reaction. Contains epoxy constituents. May produce an allergic reaction. Warning! Do not use together with other products. May release dangerous gases (chlorine). Warning! Contains cadmium. ous fumes are formed during use. See information supplied by the manufacturer. Comply with the safety instructions. Contains (name of sensitising substance). May produce an allergic reaction. Can become highly flammable in use. Can become flammable in use. Safety data sheet available on request. To avoid risks to human health and the environment, comply with the instructions for use. 1. CLP legislation: Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, according to the last adaptation to technical and scientific progress.

10 PRC The Prevention of chemical risk unit is an intramural service of the CNRS Institute of Chemistry. It provides a scientific support to the CNRS and the chemical sector. The unit promotes chemical safety and protection of human health against dangerous chemicals. The activities meet the needs of the scientific community, occupational health and safety managers, public agencies, industry and the general public. Expert appraisal The unit contributes to the expertise work at national and european level for the toxicological and physico-chemical evaluation of chemicals, and responds to requests from government agencies, local authorities and entreprises. Information The multidisciplinary team responds to requests for information related to the hazards of chemicals and their proper conditions of use. It provides scientific support and implements communication activities. Training courses The unit offers training courses in the field of chemical safety. These courses are intended for users of chemicals, security managers and occupational physicians. Several levels are available, from risk awareness to proficiency courses. Training courses may also be designed to map specific needs.