SAFETY DATA SHEET EVO-STIK SYSTEM G EXPANDING FOAM-GUN APPLIED

Transcription

1 Revision Date Revision 2 SAFETY DATA SHEET EVO-STIK SYSTEM G EXPANDING FOAM-GUN APPLIED 1 / 7 SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1. Product identifier Product name Product No. EVO-STIK SYSTEM G EXPANDING FOAM-GUN APPLIED D Relevant identified uses of the substance or mixture and uses advised against Identified uses Sealant Details of the supplier of the safety data sheet Supplier BOSTIK INDUSTRIES LTD NEWTOWN SWORDS CO.DUBLIN sds.box-irl@bostik.com 1.4. Emergency telephone number SECTION 2: HAZARDS IDENTIFICATION 2.1. Classification of the substance or mixture Classification (1999/45/EEC) Carc. Cat. 3;R40. R42/43. Xi;R36/37/38. F+;R12. N;R51/53. R Label elements Contains Labelling 4,4'-DIPHENYLMETHANE-DIISOCYANATE, ISOMERS + MIXTURES OF THESE Risk Phrases Safety Phrases Harmful Extremely flammable Dangerous for the environment R12 R36/37/38 R40 Extremely flammable. Irritating to eyes, respiratory system and skin. Limited evidence of a carcinogenic effect. R42/43 May cause sensitisation by inhalation and skin contact. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R64 May cause harm to breastfed babies. A1 A2 S2 S9 S13 S16 S23 S25 Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50 C. Do not pierce or burn, even after use. Do not spray on a naked flame or any incandescent material. Keep out of the reach of children. Keep container in a well-ventilated place. Keep away from food, drink and animal feeding stuffs. Keep away from sources of ignition - No smoking. Do not breathe vapour/spray. Avoid contact with eyes. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S29/56 Do not empty into drains, dispose of this material and its container at hazardous or special waste collection point. S36/37 Wear suitable protective clothing and gloves. S38 In case of insufficient ventilation, wear suitable respiratory equipment.

2 2 / 7 EVO-STIK SYSTEM G EXPANDING FOAM-GUN APPLIED S40 To clean the floor and all objects contaminated by this material, use... S45 S61 S63 In case of accident or if you feel unwell, seek medical advice immediately (show label where possible). Avoid release to the environment. Refer to special instructions/safety data sheets. In case of accident by inhalation: remove casualty to fresh air and keep at rest Other hazards SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS 3.2. Mixtures 4,4'-DIPHENYLMETHANE-DIISOCYANATE, ISOMERS + MIXTURES OF THESE 10-30% CAS-No.: EC No.: Classification (EC 1272/2008) Not classified. Classification (67/548/EEC) Xn;R20. Xi;R36/37/38. R42/43. ALKANES, C14-17, CHLORO 1-5% CAS-No.: EC No.: Classification (EC 1272/2008) EUH066 Lact. - H362 Aquatic Acute 1 - H400 Aquatic Chronic 1 - H410 Classification (67/548/EEC) R64 R66 N;R50/53 DIMETHYL ETHER 10-30% CAS-No.: EC No.: Classification (EC 1272/2008) Flam. Gas 1 - H220 Classification (67/548/EEC) F+;R12 The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. SECTION 4: FIRST AID MEASURES 4.1. Description of first aid measures General information Remove affected person from source of contamination. Inhalation Move the exposed person to fresh air at once. Get medical attention if any discomfort continues. Ingestion Get medical attention if any discomfort continues. Skin contact Remove contaminated clothing immediately and wash skin with soap and water. Consult a physician for specific advice. Eye contact Immediately rinse with water. Get medical attention immediately. Continue to rinse Most important symptoms and effects, both acute and delayed

3 3 / Indication of any immediate medical attention and special treatment needed SECTION 5: FIREFIGHTING MEASURES 5.1. Extinguishing media Extinguishing media Extinguish with foam, carbon dioxide, dry powder or water fog. Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire Special hazards arising from the substance or mixture Hazardous combustion products When heated, vapours/gases hazardous to health may be formed. Unusual Fire & Explosion Hazards Aerosol cans may explode in a fire. Specific hazards In case of fire, toxic gases may be formed Advice for firefighters Special Fire Fighting Procedures Use supplied air respirator if product is involved in a fire. Water spray should be used to cool containers. Protective equipment for fire-fighters Use air-supplied respirator during fire fighting. SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions, protective equipment and emergency procedures Wear protective clothing as described in Section 8 of this safety data sheet. Do not smoke, use open fire or other sources of ignition Environmental precautions Not relevant considering the small amounts used Methods and material for containment and cleaning up Extinguish all ignition sources. Avoid sparks, flames, heat and smoking. Ventilate. Collect for reclamation or absorb in vermiculite, dry sand or similar material Reference to other sections SECTION 7: HANDLING AND STORAGE 7.1. Precautions for safe handling Avoid contact with skin and eyes. Eliminate all sources of ignition. Provide good ventilation Conditions for safe storage, including any incompatibilities Keep away from heat, sparks and open flame. Keep upright. Aerosol cans: Must not be exposed to direct sunlight or temperatures above 50 C. Avoid contact with oxidising agents Specific end use(s) SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control parameters Name STD TWA - 8 Hrs STEL - 15 Min Notes DIMETHYL ETHER WEL 400 ppm 766 mg/m3 500 ppm 958 mg/m3 WEL = Workplace Exposure Limit.

4 4 / Exposure controls Protective equipment Respiratory equipment If ventilation is insufficient, suitable respiratory protection must be provided. It is recommended to use respiratory equipment with combination filter, type A2/Р2. Hand protection Use suitable protective gloves if risk of skin contact. Butyl rubber gloves are recommended. Eye protection Wear approved safety goggles. Other Protection Wear appropriate clothing to prevent any possibility of skin contact. Wear long-sleeved clothing. Hygiene measures Promptly remove any clothing that becomes contaminated. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties Appearance Colour Odour Solubility Initial boiling point and boiling range ( C) Relative density Aerosol. Buff. Characteristic. Reacts with water. n/a not determined 9.2. Other information Volatile Organic Compound (VOC) 15-22% SECTION 10: STABILITY AND REACTIVITY Reactivity Chemical stability Stable under normal temperature conditions Possibility of hazardous reactions Conditions to avoid Avoid contact with strong oxidisers. Avoid heat, flames and other sources of ignition Incompatible materials Materials To Avoid Acids, oxidising. Flammable/combustible material Hazardous decomposition products None under normal conditions. SECTION 11: TOXICOLOGICAL INFORMATION Information on toxicological effects Toxicological information No information available.

5 5 / 7 SECTION 12: ECOLOGICAL INFORMATION Toxicity LC 50, 96 Hrs, Fish mg/l not determined EC 50, 48 Hrs, Daphnia, mg/l > Persistence and degradability Bioaccumulative potential Mobility in soil Results of PBT and vpvb assessment Other adverse effects SECTION 13: DISPOSAL CONSIDERATIONS Waste treatment methods Do not puncture or incinerate even when empty. Waste Class Classified as Special Waste. Not permitted for landfill in liquid state. SECTION 14: TRANSPORT INFORMATION UN number UN No. (ADR/RID/ADN) 1950 UN No. (IMDG) 1950 UN No. (ICAO) UN proper shipping name Proper Shipping Name AEROSOLS (ALKANES, C14-17, CHLORO) Transport hazard class(es) ADR/RID/ADN Class 2.1 ADR/RID/ADN Class Class 2: Gases ADR Label No. 2.1 IMDG Class 2.1 ICAO Class/Division 2.1 Transport Labels FLAMMABLE GAS Packing group Not applicable Environmental hazards Environmentally Hazardous Substance/Marine Pollutant

6 6 / Special precautions for user EMS Tunnel Restriction Code F-D, S-U (D) Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code SECTION 15: REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture Chemical Safety Assessment SECTION 16: OTHER INFORMATION General information This product should be used as directed by Bostik Industries Ltd. For further information consult the product data sheet or contact Technical Services. Information Sources This safety data sheet was compiled using current safety information supplied by distributor of raw materials. Revision Date Revision 2 Date Risk Phrases In Full R12 R20 R36/37/38 R40 R64 R42/43 R66 R51/53 R50/53 Hazard Statements In Full H319 H315 H222 H220 H334 H317 H362 H335 EUH066 H351 H411 H410 H400 Extremely flammable. Harmful by inhalation. Irritating to eyes, respiratory system and skin. Limited evidence of a carcinogenic effect. May cause harm to breastfed babies. May cause sensitisation by inhalation and skin contact. Repeated exposure may cause skin dryness or cracking. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Causes serious eye irritation. Causes skin irritation. Extremely flammable aerosol. Extremely flammable gas. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. May cause harm to breast-fed children. May cause respiratory irritation. Repeated exposure may cause skin dryness or cracking. Suspected of causing cancer. Toxic to aquatic life with long lasting effects. Very toxic to aquatic life with long lasting effects. Very toxic to aquatic life.

7 7 / 7 Disclaimer This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.