Introduction to Shape Memory Alloys (SMAs) (Micro)structural aspects of martensitic transformations (MT) Thermodynamic issues of MT Self-accomodation

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1 Introduction to Shape Memory Alloys (SMAs) (Micro)structural aspects of martensitic transformations (MT) Thermodynamic issues of MT Self-accomodation modes Detwinning One-way shape memory effect Superelasticity Two-way shape memory effect Superelasticity Pseudoelasticity Nitinol alloys Applications

2 (Micro)structural aspects Thermally induced martensitic transformation BAIN STRAIN SMAs

3 (Micro)structural aspects SMAs

4 (Micro)structural aspects austenite martensite SMAs

5 (Micro)structural aspects AUSTENITE: Cubic (B2) high simmetry MARTENSITE: Monoclinic (B19) low simmetry SMAs

6 (Micro)structural aspects SMAs

7 Thermodynamic issues M s M f M s A s A f

8 Thermodynamic issues M f M s A s A f Main features of the MT: First order Athermic Non diffusive Reversible

9 Thermodynamic issues

10 Thermodynamic issues

11 Thermodynamic issues

12 Thermodynamic issues

13 Thermodynamic issues s M s s s A s M s

14 Thermodynamic issues

15 Thermodynamic issues

16 Thermodynamic issues

17 Thermodynamic issues % di fase austenitica riscaldamento raffreddamento Temperatura

18 Thermodynamic issues % di fase trasformata Temperatura ( C) % di fase martensitica % di fase austenitica

19 Thermodynamic issues

20 Self accommodation modes

21 Self accommodation modes INVARIANT SHEAR STRAIN: Mechanisms for accommodating shape and/or volume changes SLIP

22 Self accommodation modes INVARIANT SHEAR STRAIN: Mechanisms for accommodating shape and/or volume changes TWINNING

23 Self accommodation modes

24 Self accommodation modes TWINNING: Thermally reversible strain! Some features of twins: Low energy High mobility No break of chemical bonds

25 Self accommodation modes SEVERAL VARIANTS... i.e., ORIENTATIONS

26 Self accommodation modes

27 Self accommodation modes

28 Self accommodation modes About thermal hysteresis: a comparison between transformation nature THERMOELASTIC (Au-Cd) Fully MARTENSITIC, i.e., no THERMOELASTIC (Fe-Ni) Au-Cd: A->M - nucleation/growth M->A - inversion Fe-Ni: A->M & M->A nucleation/growth

29 Self accommodation modes Result of self accommodation: the shape is preserved.

30 Detwinning DETWINNING

31 Detwinning MACRO & MICROSCOPIC ASPECTS of DETWINNING

32 Detwinning

33 Detwinning T<M f

34 Detwinning T<M f

35 Detwinning Tension Compression Tension Compression

36 Detwinning

37 Detwinning Compression 4% Tension 4%

38 One-way shape memory effect 1) 3) 2) 1) austenite->martensite (thermally induced) 2) deformation of martensite 3) martensite->austenite (thermally induced) SHAPE RECOVERY!

39 One-way shape memory effect

40 One-way shape memory effect Requirements for shape recovery: Twinning as accommodation mode of Martensite; Very small or nil volume changes involved in the A<->M transformation (<<1%).

41 One-way shape memory effect FIRST CICLE A M M A SECOND CICLE A M Shape change occurs just once: One Way Shape Memory Effect (OWSME) Leghe a memoria di forma

42 One-way shape memory effect

43 Superelasticity Mechanically induced martensitic tranformation OWSME

44 Superelasticity

45 Superelasticity T>A f

46 Superelasticity

47 Superelasticity SUPERELASTICY: elevated strains (8%)... Fully recoverable (reversible)

48 Superelasticity dσ dt = ΔH M >A ΔV def T t

49 Superelasticity

50 Superelasticity

51 Superelasticity Superelastic range Sistema Isteresi Ms Range NiTi C -60/60 C NiTiCu 5-10 C 30 C/50 C AgCd 15 C -80 C CuZnAl 10 C -20/50 C CuAlNi 35 C 80/130 C NiTiNb C -20/-50 C Leghe a memoria di forma

52 Superelasticity

53 Superelasticity One-way shape memory effect

54 Superelasticity One-way shape memory effect

55 Superelasticity - Pseudoelasticity T<M f T>A f T M d T>M d

56 Superelasticity - Pseudoelasticity T<M f T>M d

57 Superelasticity - Pseudoelasticity

58 Superelasticity - Pseudoelasticity

59 Superelasticity - Pseudoelasticity 1.2% T<M f 4% 6% 0% Leghe a memoria di forma

60 Two-way shape memory effect: phenomenology One-Way SME A M M A Two-Way SME A M A...

61 Two-way shape memory effect: training High strain of martensite One-way shape memory cycles Superelastic (mechanical) cycles

62 Two-way shape memory effect: training Two Way Shape Memory Effect (TWSME) A M A...

63 Two-way shape memory effect: training

64 Two-way shape memory effect: decay of the effect Allungamento % Num ero cicli termici Sforzo (MPa) Allungamento % Allungamento % Num ero cicli termici

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