[AMI] Multi-residue method, by LC-MSMS, for the quantification of amitraz and its metabolites in fruit, vegetables, cereals and cereal products

Transcription

1 Multi-residue methods: all the mentioned substances will be searched for. The general reporting limit (RL) (mg/kg) is mentioned on the right side of each pesticide. The limit of quantification may vary depending on the matrix The abbreviated method name as used by the laboratory is mentioned in [brackets]. This certificate may only be used in correlation with this laboratory method code as mentioned on an analysis-report. New pesticides or updates of the certificate are indicated in green For an up to date list of the accredited analyses or the current version of this document: check our website: [AMI] Multi-residue method, by LC-MSMS, for the quantification of amitraz and its metabolites in fruit, vegetables, cereals and cereal products amitraz ,4-dimethylphenylformamide (DMF) 0.01 N-2,4-dimethylphenyl-N-methylformamidine (DMFP) 0.01 [CL1B] 1 Multi-residue method for the determination of captan & folpet in fruit and vegetables captan folpet [CL2] Multi-residue method for the determination of organochlorine pesticides in milk and milk products aldrin chlordane (cis+trans+oxy-) pp'-dde pp'-ddd (TDE) pp'-ddt op-ddt DDT (sum) dieldrin α-endosulfan endrin 1 (sum) HCB HCH (sum) alfa-hch beta-hch heptachlor 1 (sum) lindane (gamma HCH) nitrofen pentachloraniline (PCA) quintozene (PCNB) quintozene (sum) [CS] Multi-residue method for the determination of dithiocarbamates in leafy vegetables, endive, leek (determined as CS 2 ) RL of CS 2 : 0.5 mg/kg Ferbam mancozeb maneb metiram propineb thiram zineb other dithiocarbamates [CS2] Multi-residue method for the determination of dithiocarbamates in fruit, vegetables (other than in [CS]-method), cereals and tobacco (determined as CS 2 ) RL of CS 2 : 0.05 mg/kg [RL tobacco: 0.5 mg/kg] Ferbam mancozeb maneb metiram propineb thiram zineb other dithiocarbamates 1/12

2 [GIB] 1 Multi-residue method, by LC-MSMS, for the quantification of Gibberellic acid in cereals and cereal products gibberellic acid A gibberellic acid A gibberellic acid A [GLY1] Multi-residue method, by LC-MSMS, for the quantification of glyphosate, AMPA and glufosinate in fruit, vegetables and cereals AMPA glufosinate glyphosate [GMS] Multi-residue method by GC-MSMS for 200 compounds, isomers and degradation products - quantification of pesticides in fruit, vegetables, potatoes, soil and water (for cereals and cereal products use GMS4, R.L. for tobacco between [ ], other commodities on request) 1,2-dibromo-3-chloropropane [0.2] acetochlor 0.01 [0.02] aclonifen 0.01 [0.04] acrinathrin [0.02] alachlor 0.01 [0.02] benalaxyl (including benalaxyl-m) [0.02] benfluralin 0.01 [0.02] benzoylprop-ethyl 0.01 [0.02] bifenazate [0.1] bifenox 0.01 [0.1] bifenthrin [0.02] biphenyl 0.1 [0.2] bromophos (-methyl) [0.04] bromophos-ethyl [0.02] bromopropylate [0.02] butachlor 0.01 [0.02] butafenacil 0.01 [0.02] butralin [0.02] butylate 0.01 [0.02] cadusafos [0.02] carbophenothion [0.04] chinomethionat 0.02 [0.04] chlorbenside 0.01 [0.02] chlordane (sum of cis- + trans-) [0.02] chlordimeform [0.1] chlorfenapyr [**] chlorfenson 0.01 [0.02] chlormephos 0.01 [0.02] chlorobenzilate [0.02] chloroneb 0.01 [0.02] chlorothalonil [0.02] chlorpropham 1 (chlorpropham & 3-chloroaniline 1 ) 0.01 [0.02] chlorpyrifos (-ethyl) [0.01] chlorpyrifos-methyl [0.02] chlorthal-dimethyl (DCPA) [0.02] chlozolinate [0.02] coumaphos 0.01 [0.02] crimidine 0.01 [0.02] cycloate 0.01 [0.02] cyflufenamid 0.01 [0.02] cyfluthrin (sum of isomers) [0.02] cyhalofop-butyl [0.02] cyhalothrin (lambda-) [0.02] cyanofenphos 0.01 [0.02] cypermethrin (sum of isomers) [0.02] DDD 1 (o,p ) [0.02] DDE 1 (o,p ) [0.02] DDT 1 (sum of p,p -DDT, o,p -DDT, p-p -DDE and p,p -TDE (DDD) expressed as DDT) [0.02] DEET [0.04] deltamethrin [0.02] desmetryn 0.01 [0.02] diazinon [0.02] dichlobenil 0.01 [0.02] dichlofenthion 0.01 [0.02] dichlofluanid [0.1] diclofop-methyl 0.01 [0.02] dichlormid 0.01 [0.02] dichlorvos [0.02] dicloran [0.02] dicofol 1 (sum of isomers) [0.02] dieldrin (sum of aldrin + dieldrin) [0.02] dimethachlor 0.01 [0.02] diphenylamine [0.1] ditalimfos [0.02] 2/12

3 edifenphos 0.01 [0.02] endosulfan (sum alpha- + beta- + -sulphate) [0.02] endrin [0.1] EPN [0.02] EPTC 0.01 [0.02] ethalfluralin 0.01 [0.02] ethion [0.02] ethofumesate (sum of ethofumesate + ethofumesate-2-keto, expressed as ethofumesate) [0.02] ethoprophos [0.016] ethoxyquin [0.02] etofenprox [0.02] etridiazole 0.05 [0.1] etrimfos [0.02] famoxadone [0.04] fenchlorphos [0.02] fenitrothion [0.02] fenpropathrin [0.02] fenpropimorph [0.02] fenson 0.01 [0.02] fenvalerate (sum of isomers) [0.02] fipronil (sum fipronil + sulfone metabolite, expressed as fipronil) [0.02] flucythrinate (sum of isomers) [0.02] fludioxonil [0.02] flumetralin [0.02] fluthiacet-methyl [0.1] fluvalinate-tau (sum of isomers) [0.04] formothion [0.02] HCH (sum of alpha- + beta- + delta- + epsilon-) [0.02] heptachlor (sum of heptachlor and heptachlor epoxide expressed as heptachlor) 0.01 [0.02] hexachlorobenzene (HCB) [0.006] imazamethabenz (-methyl) [0.02] ipconazole [0.1] iprodione [0.04] isocarbophos [0.02] isofenphos(-ethyl) [0.02] isofenphos-methyl [0.02] isoprocarb 0.01 [0.02] isoxadifen-ethyl 0.01 [0.02] lindane (gamma HCH) [0.02] malathion (sum of malathion + malaoxon) [0.02] mecarbam [**] mepronil [0.02] methacrifos [0.02] methidathion [0.02] methoprene 0.01 [0.02] methoxychlor 0.01 [0.02] metrafenone [0.02] metribuzin [0.02] mevinphos (sum of isomers) [0.02] mirex [0.04] nitralin 0.01 [0.02] nitrofen [0.02] nitrothal-isopropyl [0.02] oxadiargyl 0.01 [0.02] oxadiazon [0.02] oxychlordane [0.02] oxyfluorfen 0.01 [0.02] paraoxon-ethyl [0.1] parathion (-ethyl) [0.02] parathion-methyl 1 (sum of parathion-methyl + paraoxonmethyl 1 ) [0.02] pebulate 0.01 [0.02] pendimethalin [0.02] pentachloroanisol [0.02] permethrin (sum of isomers) [0.02] phenothrin 0.02 [0.04] phenylphenol (ortho-) [0.1] phorate [0.02] phosalone [0.02] phosmet 1 (phosmet and phosmet-oxon 1, expressed as phosmet) [**] phoxim [0.04] piperonyl butoxide [0.02] pirimiphos-ethyl [0.02] pirimiphos-methyl [0.02] pretilachlor 0.01 [0.02] procymidone [0.02] profluralin [0.02] prometryn [0.02] propanil 0.05 [0.1] propargite [**] prothiofos [0.02] pyrazophos [0.02] pyridaben [0.02] pyriproxyfen [0.02] pyroquilon 0.01 [0.02] quinalphos [0.02] quintozene PCNB (sum of quintozene + pentachloro-aniline) [0.02] S [0.04] silthiofam [0.02] spirodiclofen [0.02] spiromesifen [**] sulfotep [0.02] sulprofos 0.01 [0.02] TCMTB 0.02 [0.04] tecnazene [0.02] tefluthrin [0.02] terbacil 0.01 [0.02] terbuthylazine [0.02] terbutryn 0.01 [0.02] tetrachlorvinphos [0.02] tetradifon [0.02] tiocarbazil 0.05 [0.1] tolclofos-methyl [0.02] tolfenpyrad 0.01 [0.02] tolylfluanid 1 (sum of tolylfluanid 1 + DMST) [0.1] transfluthrin 0.02 [0.04] triallate 0.01 [0.02] trifluralin [0.02] vinclozolin [0.02 3/12

4 **: not in tobacco [GMS2] 1 Multi-residue method for the quantification of pesticides by GC-MSMS in vegetable oil (complementary to GMS3) aclonifen 0.02 alachlor 0.01 benalaxyl (including benalaxyl-m) bifenazate 0.05 bifenox 0.05 biphenyl 0.1 bromophos-ethyl bromopropylate cadusafos 0.01 chinomethionate 0.01 chlordane (sum of cis + trans) 0.01 chlorfenson 0.01 chlorobenzilate 0.01 chlorothalonil chlorpropham (chlorpropham + 3-chloroaniline) chlorpyriphos-ethyl chlorpyriphos-methyl chlorthal-dimethyl (DCPA) chlozolinate cyhalofop-butyl 0.01 DDD (o,p ) DDE (o,p ) DDT (sum of p,p -DDT, o,p -DDT, p-p -DDE and p,p -TDE (DDD) expressed as DDT) diazinon dichlofluanid dichlorvos dicloran dicofol (total) dieldrin (sum of dieldrin + aldrin) diphenylamine ditalimfos 0.01 endosulfan (sum of alfa +beta + -sulfate) endrin EPN ethion ethofumesate ethoprophos ethoxyquin etofenprox 0.01 etrimfos famoxadone 0.02 fenchlorphos fenitrothion fludioxonil formothion HCH (sum of alfa + beta + delta + epsilon) hexachlorobenzene iprodione isocarbophos isofenphos(-ethyl) isofenphos-methyl lindane malathion (malathion + malaoxon) mecarbam mepronil methacrifos 0.01 methidathion metrafenone 0.01 metribuzin 0.01 mevinphos (sum of isomers) mirex nitrofen oxadiazon 0.01 oxyfluorfen 0.01 paraoxon-ethyl parathion-ethyl parathion-methyl (sum of parathion-methyl + paraoxonmethyl) pendimethalin pentachloranisol 0.01 phenylphenol (ortho-) phosalone phosmet phoxim 0.02 piperonyl butoxide pirimiphos-ethyl pirimiphos-methyl procymidone prometryn prothiofos 0.01 pyrazophos pyriproxyfen quinalphos 0.01 quintozene PCNB (sum of quintozene + pentachloroaniline) silthiofam 0.01 spirodiclofen 0.01 spiromesifen 0.01 sulfotep tecnazene terbuthylazine 0.01 tetrachlorvinphos tetradifon tolclofos-methyl tolylfluanid (sum of tolyfluanid + DMST) vinclozolin /12

5 [GMS3] 1 Multi-residue method for the quantification of pesticides (mainly pyrethroids) by GC-MSMS in fatty products like oils, cacao, babyfood, meat, milk,... (complementary to GMS2) acrinathrin benfluralin 0.01 bifenthrin butralin carbophenothion 0.02 chlorfenapyr 0.01 cyfluthrin total cyhalothrin (lambda) cypermethrin (sum of isomers) deltamethrin fenpropathrin fenvalerate (sum of isomers) flucythrinate (sum of isomers) flumetralin fluvalinate-tau total nitrothal isopropyl oxychlordane permethrin (sum cis+trans) phorate profluralin 0.01 propargite pyridaben tefluthrin trifluralin [GMS4] Multi-residue method by GC-MSMS for 195 compounds, isomers and degradation products - quantification of pesticides in cereals and cereal products (other commodities on request) 1,2-dibromo-3-chloropropane acetochlor 0.01 aclonifen 0.01 acrinathrin alachlor 0.01 benalaxyl (including benalaxyl-m) benfluralin 0.01 benzoylprop-ethyl 0.01 bifenazate bifenox 0.01 bifenthrin biphenyl 0.1 bromophos (-methyl) [0.04] bromophos-ethyl bromopropylate butachlor 0.01 butafenacil 0.01 butralin butylate 0.01 cadusafos carbophenothion chinomethionat 0.02 chlorbenside 0.01 chlordane (sum of cis- + trans-) chlordimeform chlorfenapyr chlorfenson 0.01 chlormephos 0.01 chlorobenzilate chloroneb 0.01 chlorothalonil chlorpropham 1 (chlorpropham & 3-chloroaniline 1 ) chlorpyrifos (-ethyl) chlorpyrifos-methyl chlorthal-dimethyl (DCPA) chlozolinate coumaphos 0.01 crimidine 0.01 cycloate 0.01 cyflufenamid 0.01 cyfluthrin (sum of isomers) cyhalofop-butyl cyhalothrin (lambda-) cyanofenphos 0.01 cypermethrin (sum of isomers) DDD 1 (o,p ) DDE 1 (o,p ) DDT 1 (sum of p,p -DDT, o,p -DDT, p-p -DDE and p,p -TDE (DDD) expressed as DDT) DEET [0.04] deltamethrin desmetryn 0.01 diazinon dichlobenil 0.01 dichlofenthion 0.01 diclofop-methyl 0.01 dichlormid 0.01 dichlorvos dicloran dieldrin (sum of dieldrin + aldrin) 0.01 dimethachlor 0.01 diphenylamine ditalimfos edifenphos 0.01 endosulfan (sum alpha- + beta- + -sulphate) endrin 0.01 EPN EPTC /12

6 ethalfluralin 0.01 ethion ethofumesate (sum of ethofumesate + ethofumesate-2-keto, parathion (-ethyl) expressed as ethofumesate) parathion-methyl 1 (sum of parathion-methyl + paraoxonmethyl 1 ) ethoprophos ethoxyquin pebulate 0.01 etofenprox pendimethalin etridiazole pentachloroanisol etrimfos permethrin (sum of isomers) famoxadone 0.01 phenothrin 0.02 fenchlorphos phenylphenol (ortho-) fenitrothion phorate fenpropathrin phosalone fenpropimorph phosmet 1 (phosmet and phosmet-oxon 1, expressed as fenson 0.01 phosmet) fenvalerate (sum of isomers) phoxim fipronil (sum fipronil + sulfone metabolite, expressed as piperonyl butoxide fipronil) pirimiphos-ethyl flucythrinate (sum of isomers) pirimiphos-methyl fludioxonil pretilachlor 0.01 flumetralin procymidone fluvalinate-tau (sum of isomers) profluralin formothion prometryn HCH (sum of alpha- + beta- + delta- + epsilon-) 0.01 propanil 0.05 heptachlor (sum of heptachlor and heptachlor epoxide propargite 0.05 expressed as heptachlor) 0.01 prothiofos hexachlorobenzene (HCB) pyrazophos imazamethabenz (-methyl) pyridaben ipconazole pyriproxyfen iprodione pyroquilon 0.01 isocarbophos quinalphos isofenphos(-ethyl) quintozene PCNB (sum of quintozene + pentachloroaniline) isofenphos-methyl isoprocarb 0.01 S [0.04] isoxadifen-ethyl 0.01 silthiofam lindane (gamma HCH) 0.01 spirodiclofen malathion (malathion + malaoxon) spiromesifen mecarbam sulfotep mepronil sulprofos 0.01 methacrifos TCMTB 0.02 methidathion tecnazene methoprene 0.01 tefluthrin methoxychlor 0.01 terbacil 0.01 metrafenone terbuthylazine metribuzin terbutryn 0.01 mevinphos (sum of isomers) tetrachlorvinphos mirex tetradifon nitralin 0.01 tiocarbazil 0.05 nitrofen tolclofos-methyl nitrothal-isopropyl tolfenpyrad 0.01 oxadiargyl 0.01 transfluthrin 0.02 oxadiazon 0.01 triallate 0.01 oxychlordane trifluralin oxyfluorfen 0.01 vinclozolin paraoxon-ethyl /12

7 [LMS] Multi-residue method by LC-MSMS for 285 compounds, isomers and degradation products - quantification of pesticides in fruit, vegetables, potatoes, cereals, soil and water (R.L. for tobacco between [ ], other commodities on request) 6-benzyladenine 0.01 [0.02] acephate [0.04] acetamiprid [0.02] acibenzolar-s-methyl 1 (sum of acibenzolar acid 1 and acibenzolar-s-methyl) [0.02] aldicarb 1 (sum of aldicarb + -sulfone 1 + -sulfoxide 1 ) [0.02] allethrin 0.01 [**] ametryn 0.01 [0.02] amidosulfuron 0.01 [0.02] amisulbrom 0.01 [0.02] atrazine 0.01 [0.02] azaconazole 0.01 [0.02] azadirachtin [**] azamethiphos [0.02] azimsulfuron [0.02] azinphos-ethyl [0.02] azinphos-methyl [0.02] azoxystrobin [0.02] beflubutamid 0.01 [0.02] bendiocarb 0.01 [0.02] benfuracarb 1 * [0.02] bensulfuron-methyl 0.01 [0.02] benthiavalicarb-isopropyl [0.02] bispyribac-sodium 0.01 [0.02] bitertanol 0.02 [0.04] bixafen 0.01 [0.02] boscalid (nicobifen) [0.02] bromacil 0.02 [0.1] bromfenvinphos-methyl 0.01 [0.02] bromuconazole [0.02] bupirimate 0.01 [0.02] buprofezin 0.01 [0.02] carbaryl [0.1] carbendazim (sum of carbendazim + benomyl) [0.02] carbetamide 0.01 [0.02] carbofuran 1 (sum of carbofuran + 3-hydroxy-carbofuran 1 ) 0.01 [0.02] carbosulfan [0.05] carboxin [0.02] carfentrazone-ethyl [0.02] chlorantraniliprole 0.01 [0.02] chlorbromuron [0.05] chlorfenvinphos 0.01 [0.02] chlorfluazuron [0.02] chloridazon [0.02] chloroxuron [0.02] chlorsulfuron 0.01 [0.02] chlortoluron [0.02] clethodim (sum of sethoxydim + clethodim) 0.01 [0.02] clodinafop 0.01 [0.02] clodinafop-propargyl 0.01 [0.02] clofentezine [0.02] clomazone 0.01 [0.02] cloquintocet-mexyl 0.01 [0.02] cyazofamid [0.02] cyclanilide 0.01 [0.02] cymiazole [0.02] cymoxanil 0.01 [0.02] cyproconazole [0.02] cyprodinil 0.01 [0.02] demeton-s-methyl [0.012] diclobutrazol 0.01 [0.02] dicrotophos [0.02] diethofencarb 0.01 [0.02] difenoconazole [0.02] diflubenzuron [0.05] diflufenican 0.01 [0.02] dikegulac [0.02] dimethenamid 0.01 [0.02] dimethoate (sum of dimethoate & omethoate) [0.02] dimethomorph [0.02] dimoxystrobin [0.02] diniconazole [0.02] dinotefuran 0.01 [0.02] disulfoton 1 (sum of disulfoton 1 + -sulfone 1 + -sulfoxide 1 ) [0.02] diuron [0.02] dodemorph 0.01 [0.02] dodine [0.02] epoxiconazole [0.02] ethametsulfuron-methyl 0.01 [0.02] ethiofencarb (sum of ethiofencarb + -sulfone + -sulfoxide, expressed as ethiofencarb) [0.02] ethirimol [0.02] ethoxysulfuron 0.01 [0.02] etoxazole [0.02] fenamidone [0.02] fenamiphos 1 (sum of fenamiphos 1, -sulfone 1 & -sulfoxide 1 ) [0.02] fenarimol 0.01 [0.02] fenazaquin 0.01 [0.02] fenbuconazole [0.02] fenhexamid [0.05] fenobucarb 0.01 [0.02] fenoxaprop-p 0.01 [0.02] fenoxaprop-p-ethyl 0.01 [0.02] fenoxycarb [0.02] fenpiclonil 0.01 [0.02] fenpropidin 0.01 [0.02] fenpyroximate [0.02] fensulfothion 1 (sum of fensulfothion + -sulfon 1, expressed as fensulfothion) [0.02] 7/12

8 fenthion 1 (sum of fenthion + -sulfone 1 + -sulfoxide 1 ) 0.01 [0.1] fenuron [0.02] flazasulfuron 0.01 [0.02] florasulam 0.01 [0.02] flonicamid [0.02] fluazifop-p-butyl (sum of fluazifop-p-butyl + free acid) 0.01 [0.05] fluazinam [0.02] flubendiamide 0.01 [0.02] flufenacet [0.02] flufenoxuron [0.02] fluopicolide 0.01 [0.02] fluoxastrobin [0.02] fluopyram 0.01 [0.02] flupyrsulfuron-methyl-sodium 0.01 [0.02] fluquinconazole [0.02] flurochloridone 0.01 [0.05] fluroxypyr [0.1] flurtamone 0.01 [0.02] flusilazole [0.02] flutolanil 0.01 [0.02] flutriafol 0.01 [0.02] fonofos 0.01 [0.1] foramsulfuron* 0.01 [0.02] forchlorfenuron [0.02] fosthiazate [0.02] fuberidazole [0.02] furalaxyl 0.01 [0.02] furathiocarb [0.02] haloxyfop-methyl (sum of haloxyfop-methyl + free acid) [0.02] heptenophos 0.01 [0.02] hexaconazole [0.02] hexazinone 0.01 [0.02] hexythiazox [0.02] imazalil (=enilconazole) [0.02] imazamox 1 *** 0.01 [0.02] imazapyr [0.02] imazosulfuron 0.01 [0.02] imidacloprid [0.02] indoxacarb (sum of S & R isomers) [0.02] iodosulfuron-methyl-sodium [0.02] iprobenfos 0.01 [0.02] iprovalicarb [0.02] isonoruron 0.01 [0.02] isoprothiolane 0.01 [0.02] isoproturon [0.02] isoxaben [0.02] kresoxim-methyl 0.01 [0.02] lenacil 0.01 [0.02] linuron [0.02] lufenuron [0.1] mandipropamid 0.01 [0.02] mefenpyr-diethyl 0.01 [0.02] mepanipyrim (sum of mepanipyrim and mepanipyrim-2- hydroxypropyl, expressed as mepanipyrim) 0.01 [0.02] mesosulfuron-methyl 0.01 [0.02] metaflumizone 0.01 [0.02] metalaxyl (sum of metalaxyl & metalaxyl-m) [0.02] metamitron [0.05] metazachlor 0.01 [0.02] metconazole [0.02] methabenzthiazuron [0.02] methamidophos [0.02] methiocarb 1 (sum of methiocarb + -sulfon 1 + -sulfoxide 1 ) [0.02] methomyl (sum of methomyl + thiodicarb) [0.02] methoprotryne 0.01 [0.02] methoxyfenozide [0.02] metobromuron [0.05] metolachlor (including metolachlor-s) [0.02] metosulam 0.01 [0.02] metoxuron [0.02] metsulfuron-methyl [0.02] molinate [0.02] monocrotophos [0.02] monolinuron [0.02] monuron 0.01 [0.02] myclobutanil 0.01 [0.02] naftylacetamide 0.01 [0.02] napropamide 0.01 [0.02] nicosulfuron [0.02] nitenpyram [0.1] novaluron [0.02] nuarimol 0.01 [0.02] ofurace 0.01 [0.02] omethoate [0.02] oxadixyl [0.05] oxamyl [0.02] oxycarboxin 0.01 [0.02] oxydemeton-methyl 1 (oxydemeton-methyl 1 + demeton-s-methylsulfone) [0.02] paclobutrazol [0.02] penconazole 0.01 [0.02] pencycuron 0.01 [0.02] penoxsulam 0.01 [0.02] pethoxamid 0.01 [0.02] phenmedipham [0.02] phenthoate [**] phosphamidon [0.02] picolinafen [0.05] picoxystrobin [0.02] pinoxaden 0.01 [0.02] pirimicarb (sum of pirimicarb + pirimicarb-desmethyl) [0.02] prochloraz [0.02] profenofos 0.01 [0.02] promecarb 0.01 [0.02] propachlor 0.01 [0.02] propaquizafop [0.02] propham 0.01 [0.02] propiconazole [0.02] propoxur 0.01 [0.02] propyzamide 0.01 [0.02] 8/12

9 proquinazid 0.01 [0.02] prosulfocarb [0.02] prosulfuron [0.02] prothioconazole [0.02] prothioconazole-desthio [0.02] pymetrozine 1 * [0.02] pyraclofos 0.01 [0.02] pyraclostrobin 0.01 [0.02] pyraflufen-ethyl 0.01 [0.02] pyrethrins [0.04] pyridaphenthion [0.02] pyrifenox [0.02] pyrimethanil 0.01 [0.02] quinclorac [0.05] quinoxyfen 0.01 [0.02] quizalofop-ethyl 0.01 [0.02] quizalofop 0.01 [0.05] rimsulfuron 0.01 [0.02] rotenone [0.02] sethoxydim 0.01 [0.02] siduron 0.01 [0.02] simazine 0.01 [0.02] spinosad (sum of spinosyn A & D) [0.02] spirotetramat [0.02] spiroxamine [0.02] sulfosulfuron 0.01 [0.02] tebuconazole [0.02] tebufenozide [0.02] tebufenpyrad [0.02] tepraloxydim 0.01 [0.02] terbufos [0.02] tetraconazole [0.02] tetramethrin 0.01 [0.02] thiabendazole [0.02] thiacloprid [0.02] thiamethoxam (sum of thiamethoxam + clothianidin) [0.04] thifensulfuron-methyl [0.02] thiobencarb 0.01 [0.02] thiophanate-methyl [0.05] triadimefon + triadimenol (sum) [0.02] triasulfuron [0.02] triazophos 0.01 [0.02] tribenuron-methyl [0.02] trichlorfon [0.1] tricyclazole 0.01 [0.02] tridemorph [0.02] trifloxystrobin [0.02] triflumizole [0.02] triflumuron 0.01 [0.02] triflusulfuron-methyl 0.01 [0.02] triforine [0.02] trinexapac-ethyl [0.1] triticonazole 0.01 [0.02] vamidothion [0.02] zoxamide [0.02] *: not in acidic matrices **: not in tobacco ***: not in cereals [LMS2] Multi-residue method, by LC-MSMS in negative mode for 22 compounds, isomers and degradation products - quantification of selected pesticides (majority acidic herbicides) in fruit, vegetables, potatoes, cereals, soil and water (R.L. for tobacco between [ ], other commodities on request) 2,4-D [0.02] 2,4-DB [0.02] 4-CPA [0.02] 2,4,5-T [0.02] bentazone [0.02] bromoxynil [0.02] clopyralid 1 (3,6-DCP) [0.4] dicamba [0.02] dichlorophen [0.02] dichlorprop (2,4-DP) [0.02] dinocap [0.2] dithianon * hexaflumuron [0.02] ioxynil [0.02] MCPA [0.02] MCPB [0.02] mecoprop (MCPP) [0.02] picloram [0.1] prohexadione-ca [0.4] sulfentrazone [0.02] teflubenzuron [0.02] triflumuron [0.02] * : only on pear, LOD value 9/12

10 [LMS3] Multi-residue method, by LC-MSMS, for the quantification of diafenthiuron, dazomet and pyridate in fruit and vegetables diafenthiuron 0.01 dazomet 0.01 pyridate (sum of pyridate and pyridafol expressed as pyridate) 0.01 [LMS5] Multi-residue method, by LC-MSMS, for the fast quantification of selected pesticides in fruit, vegetables, potatoes and cereals (other commodities on request) for use in the belgian preharvest controls abamectin 1 B1a&B1b acetamipirid ametoctradin azoxystrobin boscalid carbendazim (sum of carbendazim + benomyl) carbetamide cyproconazole cyprodinil difenoconazole dimethoate 1 (sum of dimethoate 1 & omethoate 1 ) dimethomorph fenamidone fenhexamid formetanate flonicamid imazalil imidacloprid indoxacarb isoxaflutole linuron mandipropamid mepronil mesotrione metalaxyl (sum of metalaxyl & metalaxyl-m) methiocarb (sum of methiocarb + -sulfon + -sulfoxide) methomyl (sum of methomyl + thiodicarb) metobromuron myclobutanil oxadixyl oxamyl pirimicarb (sum of pirimicarb + pirimicarb-desmethyl 1 ) propamocarb propyzamide 0.01 prosulfocarb pymetrozine pyraclostrobin spinosad 1 (sum of spinosyn A 1 & D 1 ) spirotetramat sulcotrione tebuconazole thiabendazole thiacloprid thiophanate-methyl [MEC] 1 Multi-residue method, by LC-MSMS, for the quantification of mectins in fruit, vegetables, cereals and cereal products abamectin (sum abamectin B1a+ B1b) 0.01 emamectin benzoate ( sum emamectin benzoate B1a + B1b) 0.01 ivermectin B1a /12

11 [P2] Multi-residue method for the determination of organophosphorus pesticides in cereals and cereal products - to be used as babyfood ingredient. This method is also applicable (and validated) for seeds. milk, oil, meat, liver,... with matrix-dependant RL s (all in the same order of magnitude of cereals) chlorpyrifos chlorpyrifos-methyl diazinon dichlofenthion dichlorvos ethion ethoprofos etrimfos fenchlorfos fenitrothion heptenofos malathion methidathion mevinphos parathion parathion-methyl pirimiphos-ethyl pirimiphos-methyl sulfotep [PAH] 1 Multi-residue method, by LC-MSMS, for the quantification of polycyclic aromatic hydrocarbons in oils and oilseeds Bena[a]anthracene Benzo[a]pyrene Benzo[b]fluoranthene Benzo[g,h,i]perylene Benzo[k]fluoranthene Chrysene Dibenz[a,h]anthracene Indeno[1,2,3-c,d]pyrene [QAC] Multi-residue method, by LC-MSMS, for the quantification of quaternairy amonium compounds in fruit, vegetables and cereals BAC-C BAC-C BAC-C BAC-C DDAC-C DDAC-C DDAC-C [QU1] Multi-residue method, by LC-MSMS, for the quantification of chlormequat and mepiquat in fruit, vegetables and cereals chlormequat mepiquat [QU2] 1 Multi-residue method, by LC-MSMS, for the quantification of diquat and paraquat in fruit, vegetables and cereals diquat (cereals 0.05) paraquat (cereals 0.05) Specific individual methods for the determination of residues of pesticides in fatty products and tobacco. benzo[a]pyrene /12

12 Specific individual methods for the determination of residues of pesticides in fruit and vegetables asulam bromine [BR] 5 chlorprofam [CIPC] (method applies only to potatoes) ethephon fosetyl-aluminium maleic hydrazide 1 5 (tobacco 20) nicotine 0.01 nitrate [NIT] 50 pentachlorophenol sulfur 1-5 thiram 1 [TMTD] Specific individual methods for the determination of residues of pesticides in soil bromine 1 [BR2]- 0,5 mg/kg Specific individual methods for the determination of residues of pesticides in water bromine 1 [BR2] - 0,5 mg/l nitrate 1 [NIT] - 1 mg/l 1 : not under accreditation 12/12