Siddhi Green Excellence Pvt. Ltd., Ankleshwar

Transcription

1 Photographs of Baseline Monitoring Sampling carried out in 10 km radius of study area around project site of Polyols & Polymers at D-2/CH-266,267,268, Ta. Vagra, Dist. Bharuch, Gujarat, India for EIA for proposed synthetic resin manufacturing unit. (Duration Oct 2014 to Dec 2014) Photographs of AAQM station installations Vav Village - Primary School Padariya Village - Gram Panchayat Koliyad Village - Gram Panchayat Siddhi Green Excellence Pvt. Ltd., Ankleshwar Page 1 of 20

2 Photographs of Baseline Monitoring Sampling carried out in 10 km radius of study area around project site of Polyols & Polymers at D-2/CH-266,267,268, Ta. Vagra, Dist. Bharuch, Gujarat, India for EIA for proposed synthetic resin manufacturing unit. (Duration Oct 2014 to Dec 2014) Galenda Village - Panchayat Office Project Site Jolva Siddhi Green Excellence Office terrace Ambetha Final Pumping Station Security cabin of Sunshine industries - Dahej Siddhi Green Excellence Pvt. Ltd., Ankleshwar Page 2 of 20

3 Photographs of Baseline Monitoring Sampling carried out in 10 km radius of study area around project site of Polyols & Polymers at D-2/CH-266,267,268, Ta. Vagra, Dist. Bharuch, Gujarat, India for EIA for proposed synthetic resin manufacturing unit. (Duration Oct 2014 to Dec 2014) Geo Engineering Survey photographs Plate3.1 and 3.2: Measurement of water level Plate 3.3: Location marking with hand held GPS Plate 3.4: Measurement of curbing length Photographs of water sampling Ambheta Village Pond Siddhi Green Excellence Pvt. Ltd., Ankleshwar Dahej Village Pond Page 3 of 20

4 Photographs of Baseline Monitoring Sampling carried out in 10 km radius of study area around project site of Polyols & Polymers at D-2/CH-266,267,268, Ta. Vagra, Dist. Bharuch, Gujarat, India for EIA for proposed synthetic resin manufacturing unit. (Duration Oct 2014 to Dec 2014) Jolva Village Pond GIDC Reservoir Koliad Village Pond Padariya Village Pond Siddhi Green Excellence Pvt. Ltd., Ankleshwar Page 4 of 20

5 Photographs of Baseline Monitoring Sampling carried out in 10 km radius of study area around project site of Polyols & Polymers at D-2/CH-266,267,268, Ta. Vagra, Dist. Bharuch, Gujarat, India for EIA for proposed synthetic resin manufacturing unit. (Duration Oct 2014 to Dec 2014) Vadadla Village Pond Vav Village Photographs of soil sampling Plate 4.1: soil sampling with the help of spiral auger Siddhi Green Excellence Pvt. Ltd., Ankleshwar Page 5 of 20

6 Photographs of Baseline Monitoring Sampling carried out in 10 km radius of study area around project site of Polyols & Polymers at D-2/CH-266,267,268, Ta. Vagra, Dist. Bharuch, Gujarat, India for EIA for proposed synthetic resin manufacturing unit. (Duration Oct 2014 to Dec 2014) Plate 4.2: Soil sampling with spiral auger Photographs of noise monitoring Ambheta Village - Noise Siddhi Green Excellence Pvt. Ltd., Ankleshwar Page 6 of 20

7 Photographs of Baseline Monitoring Sampling carried out in 10 km radius of study area around project site of Polyols & Polymers at D-2/CH-266,267,268, Ta. Vagra, Dist. Bharuch, Gujarat, India for EIA for proposed synthetic resin manufacturing unit. (Duration Oct 2014 to Dec 2014) Janiyadra Village - Noise Koliad Village Jolva Village- Noise near internal village road Jolva Village- Noise near temple Padariya Noise Project Site Vadadla Village Siddhi Green Excellence Pvt. Ltd., Ankleshwar Page 7 of 20

8 Photographs of Baseline Monitoring Sampling carried out in 10 km radius of study area around project site of Polyols & Polymers at D-2/CH-266,267,268, Ta. Vagra, Dist. Bharuch, Gujarat, India for EIA for proposed synthetic resin manufacturing unit. (Duration Oct 2014 to Dec 2014) Vav Village Photographs of water sampling for aquatic studies Jolva Village Pond GIDC Reservoir Koliad Village Vadadla Village Siddhi Green Excellence Pvt. Ltd., Ankleshwar Page 8 of 20

9 Photographs of Baseline Monitoring Sampling carried out in 10 km radius of study area around project site of Polyols & Polymers at D-2/CH-266,267,268, Ta. Vagra, Dist. Bharuch, Gujarat, India for EIA for proposed synthetic resin manufacturing unit. (Duration Oct 2014 to Dec 2014) Padariya Village Vav Village Photographs of Flora observed Galenda Village Siddhi Green Excellence Pvt. Ltd., Ankleshwar Janiyadra Village Page 9 of 20

10 Photographs of Baseline Monitoring Sampling carried out in 10 km radius of study area around project site of Polyols & Polymers at D-2/CH-266,267,268, Ta. Vagra, Dist. Bharuch, Gujarat, India for EIA for proposed synthetic resin manufacturing unit. (Duration Oct 2014 to Dec 2014) Project Site Water Lily - Jolva Pond Narmada River Bank Photographs of Fauna survey Koliad Village Siddhi Green Excellence Pvt. Ltd., Ankleshwar Indian Flying Fox - Janiyadra Pond Page 10 of 20

11 Photographs of Baseline Monitoring Sampling carried out in 10 km radius of study area around project site of Polyols & Polymers at D-2/CH-266,267,268, Ta. Vagra, Dist. Bharuch, Gujarat, India for EIA for proposed synthetic resin manufacturing unit. (Duration Oct 2014 to Dec 2014) Padariya Village Skittering Frog Dragonfly Guppy Fish Indian Flap Shell turtle Siddhi Green Excellence Pvt. Ltd., Ankleshwar Page 11 of 20

12 Photographs of Baseline Monitoring Sampling carried out in 10 km radius of study area around project site of Polyols & Polymers at D-2/CH-266,267,268, Ta. Vagra, Dist. Bharuch, Gujarat, India for EIA for proposed synthetic resin manufacturing unit. (Duration Oct 2014 to Dec 2014) Eutrophicated Pond - Padariya Village Dragon Fly - in Vav village pond Potter Wasps - Ambheta Village Pond Water Striders - Ambheta Village Pond Stone Chat Siddhi Green Excellence Pvt. Ltd., Ankleshwar Page 12 of 20

13 Photographs of Baseline Monitoring Sampling carried out in 10 km radius of study area around project site of Polyols & Polymers at D-2/CH-266,267,268, Ta. Vagra, Dist. Bharuch, Gujarat, India for EIA for proposed synthetic resin manufacturing unit. (Duration Oct 2014 to Dec 2014) Photographs of Plankton species Balantidium sp - GIDC Reservoir Calanus Sp - GIDC Reservoir Daphnia sp - Koliad Village Rotifer sp - Padariya Village Phytoplankton & debris - Vadadla Village Cyclops sp - Vav Village Siddhi Green Excellence Pvt. Ltd., Ankleshwar Page 13 of 20

14 Photographs of Baseline Monitoring Sampling carried out in 10 km radius of study area around project site of Polyols & Polymers at D-2/CH-266,267,268, Ta. Vagra, Dist. Bharuch, Gujarat, India for EIA for proposed synthetic resin manufacturing unit. (Duration Oct 2014 to Dec 2014) Euglena sp - Vav Village Photographs of sampling of marine water and sediments Siddhi Green Excellence Pvt. Ltd., Ankleshwar Page 14 of 20

15 Photographs of Baseline Monitoring Sampling carried out in 10 km radius of study area around project site of Polyols & Polymers at D-2/CH-266,267,268, Ta. Vagra, Dist. Bharuch, Gujarat, India for EIA for proposed synthetic resin manufacturing unit. (Duration Oct 2014 to Dec 2014) Siddhi Green Excellence Pvt. Ltd., Ankleshwar Page 15 of 20

16 Photographs of Baseline Monitoring Sampling carried out in 10 km radius of study area around project site of Polyols & Polymers at D-2/CH-266,267,268, Ta. Vagra, Dist. Bharuch, Gujarat, India for EIA for proposed synthetic resin manufacturing unit. (Duration Oct 2014 to Dec 2014) Photographs of Benthos Gomphonema sp. Scripsella sp. Thallasiosira sp. Euglena Siddhi Green Excellence Pvt. Ltd., Ankleshwar Page 16 of 20

17 Photographs of Baseline Monitoring Sampling carried out in 10 km radius of study area around project site of Polyols & Polymers at D-2/CH-266,267,268, Ta. Vagra, Dist. Bharuch, Gujarat, India for EIA for proposed synthetic resin manufacturing unit. (Duration Oct 2014 to Dec 2014) Chaetoceros sp. Tetrastrum sp. Photographs of Socio-economic survey Ambheta Village Vadadla Village Vadadla Village Jolva Villaje Siddhi Green Excellence Pvt. Ltd., Ankleshwar Page 17 of 20

18 Photographs of Baseline Monitoring Sampling carried out in 10 km radius of study area around project site of Polyols & Polymers at D-2/CH-266,267,268, Ta. Vagra, Dist. Bharuch, Gujarat, India for EIA for proposed synthetic resin manufacturing unit. (Duration Oct 2014 to Dec 2014) Jolva Village Gram Panchayat & Bank Facility Jolva village Post Office Project Site Galenda Village Siddhi Green Excellence Pvt. Ltd., Ankleshwar Page 18 of 20

19 Photographs of Baseline Monitoring Sampling carried out in 10 km radius of study area around project site of Polyols & Polymers at D-2/CH-266,267,268, Ta. Vagra, Dist. Bharuch, Gujarat, India for EIA for proposed synthetic resin manufacturing unit. (Duration Oct 2014 to Dec 2014) Janiyadra Village Koliad Village Vav Village Siddhi Green Excellence Pvt. Ltd., Ankleshwar Dahej Villaje Page 19 of 20

20 Photographs of Baseline Monitoring Sampling carried out in 10 km radius of study area around project site of Polyols & Polymers at D-2/CH-266,267,268, Ta. Vagra, Dist. Bharuch, Gujarat, India for EIA for proposed synthetic resin manufacturing unit. (Duration Oct 2014 to Dec 2014) Padariya Village Dahej Village Siddhi Green Excellence Pvt. Ltd., Ankleshwar Page 20 of 20

21 Plot Plan: M/s. POLYOLS AND POLYMERS at Plot No. D2/CH-266,267,268, Dahej - II, Tal Vagra, Dist - Bharuch, State Gujarat, India Predominant Wind Direction - SW to NE Affected Area SN 1. Leakage from the 10 KL Tank - Stability Class D (8.33) Damage distances for toxic effect from Evaporating puddle Acrylonitrile- 10 KL (1 Tank of 10 KL at site) Red : 49 meters --- (333 ppm) Orange: 108 meters --- (85 ppm = IDLH)

22 Plot Plan: M/s. POLYOLS AND POLYMERS at Plot No. D2/CH-266,267,268, Dahej - II, Tal Vagra, Dist - Bharuch, State Gujarat, India Predominant Wind Direction - SW to NE Affected Area SN 2. Leakage from the 10 KL Tank - Stability Class F (2.2) Damage distances for toxic effect from Evaporating puddle Acrylonitrile- 10 KL (1 Tank of 10 KL at site) Red : 26 meters --- (333 ppm) Orange: 91 meters --- (85 ppm = IDLH)

23 Plot Plan: M/s. POLYOLS AND POLYMERS at Plot No. D2/CH-266,267,268, Dahej - II, Tal Vagra, Dist - Bharuch, State Gujarat, India Predominant Wind Direction - SW to NE SN 3. Leakage from the 10 KL Tank - Stability Class D (8.33) Damage distances for Thermal Radiation from Pool Fire Acrylonitrile- 10 KL (1 Tank of 10 KL at site) Red : 11 meters (37.5 kw/(sq m)) Orange: 23 meters -----(4.0 kw/(sq m)) Yellow: 31 meters (1.6 kw/(sq m))

24 Plot Plan: M/s. POLYOLS AND POLYMERS at Plot No. D2/CH-266,267,268, Dahej - II, Tal Vagra, Dist - Bharuch, State Gujarat, India Predominant Wind Direction - SW to NE SN 4. Leakage from the 10 KL Tank - Stability Class F (2.2) Damage distances for Thermal Radiation from Pool Fire Acrylonitrile- 10 KL (1 Tank of 10 KL at site) Red : < 10 meters(10.9 yards)(37.5 kw/(sq m)) Orange: 24 meters (4.0 kw/(sq m)) Yellow: 36 meters (1.6 kw/(sq m))

25 Plot Plan: M/s. POLYOLS AND POLYMERS at Plot No. D2/CH-266,267,268, Dahej - II, Tal Vagra, Dist - Bharuch, State Gujarat, India Predominant Wind Direction - SW to NE Affected Area SN 5. Leakage from the 50 KL Tank - Stability Class F (2.2) Damage distances for Toxic Area from Vapor Cloud Yellow: 162 meters --- (20 ppm) Formaldehyde KL (2 nos. 50 KL Tank at site)

26 Plot Plan: M/s. POLYOLS AND POLYMERS at Plot No. D2/CH-266,267,268, Dahej - II, Tal Vagra, Dist - Bharuch, State Gujarat, India Predominant Wind Direction - SW to NE SN 6. Leakage from the 10 KL Tank - Stability Class D (8.33) Damage distances for Thermal Radiation from Pool Fire Methyl Ethyl Ketone - 10 KL (1 Tank of 10 KL at site) Red : 12 meters --- (37.5 kw/(sq m)) Orange: 26 meters --- (4.0 kw/(sq m)) Yellow: 35 meters --- (1.6 kw/(sq m))

27 Plot Plan: M/s. POLYOLS AND POLYMERS at Plot No. D2/CH-266,267,268, Dahej - II, Tal Vagra, Dist - Bharuch, State Gujarat, India Predominant Wind Direction - SW to NE SN 7. Leakage from the 10 KL Tank - Stability Class F (2.2) Damage distances for Thermal Radiation from Pool Fire Methyl Ethyl Ketone - 10 KL (1 Tank of 10 KL at site) Red : <10 meters (10.9 yards) --- (37.5 kw/(sq m)) Orange: 25 meters --- (4.0 kw/(sq m)) Yellow: 39 meters --- (1.6 kw/(sq m))

28 Plot Plan: M/s. POLYOLS AND POLYMERS at Plot No. D2/CH-266,267,268, Dahej - II, Tal Vagra, Dist - Bharuch, State Gujarat, India Predominant Wind Direction - SW to NE SN 8. Catastrophic Failure of Hydrogenation reactor - Stability Class D (8.33) Damage distances for Overpressure (blast force) from vapor cloud explosion Hydrogen - 2 Cylinders bank of 30 cylinders Red : LOC was never exceeded (8.0 psi = destruction of buildings) Orange: LOC was never exceeded (3.5 psi = serious injury likely) Yellow: 24 meters --- (0.5 psi)

29 Plot Plan: M/s. POLYOLS AND POLYMERS at Plot No. D2/CH-266,267,268, Dahej - II, Tal Vagra, Dist - Bharuch, State Gujarat, India Predominant Wind Direction - SW to NE SN 9. Catastrophic Failure of Hydrogenation reactor - Stability Class F (2.2) Damage distances for Overpressure (blast force) from vapor cloud explosion Hydrogen - 2 Cylinders bank of 30 cylinders Red : LOC was never exceeded --- (8.0 psi = destruction of buildings) Orange: LOC was never exceeded --- (3.5 psi = serious injury likely) Yellow: 75 meters --- (0.5 psi)

30 Plot Plan: M/s. POLYOLS AND POLYMERS at Plot No. D2/CH-266,267,268, Dahej - II, Tal Vagra, Dist - Bharuch, State Gujarat, India Predominant Wind Direction - SW to NE SN 10. Leak from hydrogen cylinders through ¾ instrument tubing- Stability Class F (2.2) Damage distances for Overpressure (blast force) from vapor cloud explosion Hydrogen - 2 Cylinders bank of 30 cylinders Red : LOC was never exceeded --- (8.0 psi = destruction of buildings) Orange: LOC was never exceeded --- (3.5 psi = serious injury likely) Yellow: 25 meters --- (0.5 psi)

31 Plot Plan: M/s. POLYOLS AND POLYMERS at Plot No. D2/CH-266,267,268, Dahej - II, Tal Vagra, Dist - Bharuch, State Gujarat, India Predominant Wind Direction - SW to NE SN 11. Leakage from 20 KL storage tank- Stability Class D (8.33) Damage distances for Thermal radiation from pool fire Styrene - 40 MT (20 KL - 2 nos. of tank at site) Red : 15 meters --- (37.5 kw/(sq m)) Orange: 31 meters --- (4.0 kw/(sq m)) Yellow: 42 meters --- (1.6 kw/(sq m))

32 Plot Plan: M/s. POLYOLS AND POLYMERS at Plot No. D2/CH-266,267,268, Dahej - II, Tal Vagra, Dist - Bharuch, State Gujarat, India Predominant Wind Direction - SW to NE SN 12. Leakage from 20 KL storage tank- Stability Class F (2.2) Damage distances for Thermal radiation from pool fire Styrene - 40 MT (20 KL - 2 nos. of tank at site) Red : less than 10 meters(10.9 yards) --- (37.5 kw/(sq m)) Orange: 29 meters --- (4.0 kw/(sq m)) Yellow: 46 meters --- (1.6 kw/(sq m))

33 Plot Plan: M/s. POLYOLS AND POLYMERS at Plot No. D2/CH-266,267,268, Dahej - II, Tal Vagra, Dist - Bharuch, State Gujarat, India Predominant Wind Direction - SW to NE SN 13. Leakage from 20 KL storage tank- Stability Class D (8.33) Damage distances for Thermal radiation from pool fire Xylene- 20 MT (20 KL - 1no. of tank at site) Red : 17 meters --- (37.5 kw/(sq m)) Orange: 35 meters --- (4.0 kw/(sq m)) Yellow: 48 meters --- (1.6 kw/(sq m))

34 Plot Plan: M/s. POLYOLS AND POLYMERS at Plot No. D2/CH-266,267,268, Dahej - II, Tal Vagra, Dist - Bharuch, State Gujarat, India Predominant Wind Direction - SW to NE SN 14. Leakage from 20 KL storage tank- Stability Class F (2.2) Damage distances for Thermal radiation from pool fire Xylene- 20 MT (20 KL - 1no. of tank at site) Red : less than 10 meters(10.9 yards) --- (37.5 kw/(sq m)) Orange: 32 meters --- (4.0 kw/(sq m)) Yellow: 51 meters --- (1.6 kw/(sq m))

35 Plot Plan: M/s. POLYOLS AND POLYMERS at Plot No. D2/CH-266,267,268, Dahej - II, Tal Vagra, Dist - Bharuch, State Gujarat, India Predominant Wind Direction - SW to NE SN 15. Leakage from 200 meters length Natural Gas pipeline -Stability Class F (2.2) Damage distances for Thermal radiation from jet fire Natural Gas - pipeline supply Red : 10 meters --- (37 kw/(sq m)) Orange: 32 meters --- (4 kw/(sq m)) Yellow: 49 meters --- (1.6 kw/(sq m))

36 CONSEQUENCE ANALYSIS FOR SELECTED CHEMICALS INVENTORY For proposed new Synthetic Resins Manufacturing unit of M/s. POLYOLS & POLYMERS PVT. LTD. At Plot No. D-2/CH/266,267, & 268 Dahej II Ind. Estate, Jolva, District Bharuch, Gujarat, India TABLE OF CONTENTS 1 TOLUENE METHYL ISOBUTYL KETONE (MIBK) CYCLOHEXANONE METHYL ETHYL KETONE ETHYL ACETATE ACRYLO NITRILE ETHYL ACRYLATE ETHYLENE DIAMINE HYDROGEN-HYDROGENATION REACTOR HYDROGEN-HYDROGEN CYLINDER BANK ISOPROPYL ALCOHOL (IPA) METHYL METHACRYLATE BUTYL ACETATE BUTANOL STYRENE ACETIC ACID BUTYL METHACRYLATE FORMALDEHYDE XYLENE PHENOL SULFURIC ACID Siddhi Green Excellence Pvt. Ltd., Ankleshwar Page 1 of 24

37 CONSEQUENCE ANALYSIS FOR SELECTED CHEMICALS INVENTORY For proposed new Synthetic Resins Manufacturing unit of M/s. POLYOLS & POLYMERS PVT. LTD. At Plot No. D-2/CH/266,267, & 268 Dahej II Ind. Estate, Jolva, District Bharuch, Gujarat, India 1 TOLUENE Scenario Most Credible Scenario of Toluene,leakage through 10mm hole Input Data Stability Class D F Temperature,degC atm atm Pressure,barg 4 4 Wind Speed,m/s Atmospheric Temperature,degC Amount of Toluene,KL pool Area,m Output Flash Fire Envelope,m <10 <10 Pool Fire Burn Rate of Pool fire,kg/s Distance to radiation level 37.5kw/m2,..m 16 <10 Distance to radiation level 4kw/m2,..m Distance to radiation level 1.6 kw/m2,..m Assumptions Stability class is D and F. For MCS 10mm hole diameter is considered. (For 3 pipe this is ~10% of pipe diameter ) (Ref 3.A.2.4,Purple Book). The line feeding Toluene to the reactor will be isolated after detection & identification of leak. The release time is taken as 15mins. The leak will form an evaporating puddle. Puddle height is 25mm. No fire water spray system in process area. No gas detection is available in process area. Flammable effects will be analysed. Area is classified area. Flammable Effect: Atmospheric Stability Class D Atmospheric Stability Class F Discussion: The discharge rate through leak is 1.28kg/s.The total material released is 1267kgs. The evaporating pool will release Toluene vapors to atmosphere which will disperse in downwind direction. If the dispersed vapors got ignition then a fire will flash back to source and pool fire will sustained. The total material will burnt out in 5mins. In case of stability class D/F,radiation of 37.5kw/m2 is experienced up to distance 16/less than 10m respectively. But the total spilled material will be burnt within 5 mins. 4.0 & 1.6 kw/m2 distances are 34 & 46m for atmosphere condition D and 30 & 48 m for F. Siddhi Green Excellence Pvt. Ltd., Ankleshwar Page 2 of 24

38 CONSEQUENCE ANALYSIS FOR SELECTED CHEMICALS INVENTORY For proposed new Synthetic Resins Manufacturing unit of M/s. POLYOLS & POLYMERS PVT. LTD. At Plot No. D-2/CH/266,267, & 268 Dahej II Ind. Estate, Jolva, District Bharuch, Gujarat, India 2 METHYL ISOBUTYL KETONE (MIBK) Scenario Most Credible Scenario of MIBK,leakage through 10mm hole Input Data Stability Class D F Temperature,degC atm atm Pressure,barg 4 4 Wind Speed,m/s Atmospheric Temperature,degC Amount of MIBK,KL pool Area,m Output Flash Fire Envelope,m <10 <10 Pool Fire Burn Rate of Pool fire,kg/s Distance to radiation level 37.5kw/m2,..m 14 <10 Distance to radiation level 4kw/m2,..m Distance to radiation level 1.6 kw/m2,..m For all 10mm leak MCS scenarios assumptions are covered in general assumptions and similar to Toluene scenario. Hence these are not repeated for each such scenarios. Flammable Effect: Atmospheric Stability Class D Atmospheric Stability Class F Discussion: The discharge rate through leak is 1.23kg/s.The total material released is 1221kgs. The evaporating pool will release MIBK vapors to atmosphere which will disperse in downwind direction. If the dispersed vapors got ignition then a fire will flash back to source and pool fire will sustained. The total material will burnt out in 6mins. Although for atmospheric stability class F, the temp (10degC) is below flash point of MIBK (14degC), the consequence is calculated considering the fire initiated due to other source. In case of stability class D/F,radiation of 37.5kw/m2 is experienced up to distance 14/less than 10m respectively. But the total spilled material will be burnt within 6 mins. 4.0 & 1.6 kw/m2 distances are 29 & 39m for atmosphere condition D and 27 & 42m for F. Siddhi Green Excellence Pvt. Ltd., Ankleshwar Page 3 of 24

39 CONSEQUENCE ANALYSIS FOR SELECTED CHEMICALS INVENTORY For proposed new Synthetic Resins Manufacturing unit of M/s. POLYOLS & POLYMERS PVT. LTD. At Plot No. D-2/CH/266,267, & 268 Dahej II Ind. Estate, Jolva, District Bharuch, Gujarat, India 3 CYCLOHEXANONE Scenario Most Credible Scenario of Cyclohexanone,leakage through 10mm hole Input Data Stability Class D F Temperature,degC atm atm Pressure,barg 4 4 Wind Speed,m/s Atmospheric Temperature,degC Amount of Cyclohexanone,KL pool Area,m Output Flash Fire Envelope,m <10 <10 Pool Fire Burn Rate of Pool fire,kg/s Distance to radiation level 37.5kw/m2,..m 12 <10 Distance to radiation level 4kw/m2,..m Distance to radiation level 1.6 kw/m2,..m Flammable Effects: Atmosphere Stability Class D Atmosphere Stability Class F Discussion: The discharge rate through leak is 1.34kg/s.The total material released is 1328kgs. The evaporating pool will release Cyclohexanone vapors to atmosphere which will disperse in downwind direction. If the dispersed vapors got ignition then a fire will flash back to source and pool fire will sustained. The total material will burnt out in 8mins. In case of stability class D/F,radiation of 37.5kw/m2 is experienced up to distance 12/<10m respectively.but the total spilled material will be burnt within 8 mins. 4.0 & 1.6 kw/m2 distances are 24 & 33m for atmosphere condition D and 25 & 38m for F. Siddhi Green Excellence Pvt. Ltd., Ankleshwar Page 4 of 24

40 CONSEQUENCE ANALYSIS FOR SELECTED CHEMICALS INVENTORY For proposed new Synthetic Resins Manufacturing unit of M/s. POLYOLS & POLYMERS PVT. LTD. At Plot No. D-2/CH/266,267, & 268 Dahej II Ind. Estate, Jolva, District Bharuch, Gujarat, India 4 METHYL ETHYL KETONE Scenario MEK Leak Through 10mm hole Input Data Stability Class D F Temperature,degC Atm Atm Pressure,barg Atm Atm Wind Speed,m/s Atmospheric Temperature,degC Leak Size,mm pool Area,m Flammability Effect: Output Flash Fire Envelope,m <10 <10 Pool Fire Burn Rate of Pool fire,kg/s Distance to radiation level 37.5kw/m2,..m 12 <10 Distance to radiation level 4kw/m2,..m Distance to radiation level 1.6 kw/m2,..m Atmospheric Stability Class D Atmospheric Stability Class F Discussion: The pool fire due to this spill will last for 5mins and all 1223kgs of spilled MEK will burn within this time. The radiation of 37.5kw/m2 will experienced at 12m for atmospheric class D. The total spilled material will be burnt within 5 mins.the radiation will experience for this time only. 4.0 & 1.6 kw/m2 distances are 26 & 35m for atmosphere condition D and 25 & 39m for F. Siddhi Green Excellence Pvt. Ltd., Ankleshwar Page 5 of 24

41 CONSEQUENCE ANALYSIS FOR SELECTED CHEMICALS INVENTORY For proposed new Synthetic Resins Manufacturing unit of M/s. POLYOLS & POLYMERS PVT. LTD. At Plot No. D-2/CH/266,267, & 268 Dahej II Ind. Estate, Jolva, District Bharuch, Gujarat, India 5 ETHYL ACETATE Scenario Most Credible Scienario of Ethyl Acetate,Spillage from 200Lit Drum Input Data Stability Class D F Temperature,degC atm atm Pressure,barg atm atm Wind Speed,m/s Atmospheric Temperature,degC Amount of Ethyl Acetate,Lits pool Area,m Output Flash Fire Envelope,m <10 <10 Pool Fire Burn Rate of Pool fire,kg/s Distance to radiation level 37.5kw/m2,..m <10 <10 Distance to radiation level 4kw/m2,..m Distance to radiation level 1.6 kw/m2,..m Assumptions: The damage of drum is happened during handling. There can be 10 events of handling. Due to damage total material of the drum is spilled on the ground. Due to the adjacent drums the pool height is considered as 10mm.Hence the pool area is considered as 20m2. The consequence is evaluated assuming that the spill will get an ignition immediately. Flammable Effect: Atmospheric Stability Class D Atmospheric Stability Class F Discussion: The pool fire due to this spill will last for 3mins and all 175kgs of spilled ETHYL ACETATE will burn within this time. The burn rate is 1.09kg/s. The radiation of 37.5kw/m2 will not experienced due to this fire. Due to these reasons there is unlikely that other drums will get damaged and additional ETHYL ACETATE will be spilled. If the explosive mixture is not ignited immediately then the spilled material will be evaporated at rate of 0.29kg/s and it will take 16 mins to evaporate all the spilled material. Siddhi Green Excellence Pvt. Ltd., Ankleshwar Page 6 of 24

42 CONSEQUENCE ANALYSIS FOR SELECTED CHEMICALS INVENTORY For proposed new Synthetic Resins Manufacturing unit of M/s. POLYOLS & POLYMERS PVT. LTD. At Plot No. D-2/CH/266,267, & 268 Dahej II Ind. Estate, Jolva, District Bharuch, Gujarat, India The storage area shall be well ventilated. 6 ACRYLO NITRILE Scenario Most Credible Scenario of ACN,Leakage from 10mm hole Input Data Stability Class D F Temperature,degC atm atm Pressure,barg atm atm Wind Speed,m/s Atmospheric Temperature,degC Amount of ACN,KL IDLH,ppm LD50,ppm Output Evaporation Rate,gm/s Flash Fire Envelope,m <10 <10 Pool Fire Burn Rate of Pool fire,kg/s Distance to radiation level 37.5kw/m2,..m 11 <10 Distance to radiation level 4kw/m2,..m Distance to radiation level 1.6 kw/m2,..m Distance to LC50,m Distance to IDLH,m Assumptions The line feeding ACN to the reactor will be isolated after detection & identification of leak. The release time is taken as 15mins. The leak will form an evaporating puddle. Puddle height is 25mm. ACN Pump should having double mechanical seals. No fire water spray system in process area. Toxic and flammable both effects will be analysed. Area is classified area. Toxic Effect: Atmospheric Stability Class D Atmospheric Stability Class F Siddhi Green Excellence Pvt. Ltd., Ankleshwar Page 7 of 24

43 CONSEQUENCE ANALYSIS FOR SELECTED CHEMICALS INVENTORY For proposed new Synthetic Resins Manufacturing unit of M/s. POLYOLS & POLYMERS PVT. LTD. At Plot No. D-2/CH/266,267, & 268 Dahej II Ind. Estate, Jolva, District Bharuch, Gujarat, India Flammable Effect: Atmospheric Stability Class D Atmospheric Stability Class F Discussion: The discharge rate through leak is 1.23kg/s.The total material released is 1225kgs. The evaporating pool will release ACN vapors to atmosphere which will disperse in downwind direction. LC50 distances are 49 & 26m for atmospheric condition D & F respectively. The cloud will reach these distance within 3 mins of release. The concentration at this point will be 333ppm for 1-2 mins and subsequently it decreases below IDLH value.(as seen in below fig) A part of the emergency plan considers the evacuation of (parts of) the plant, the neighboring plants and people in further surroundings to minimize exposure in case of an Acrylonitrile vapour cloud ACN detectors can be installed at the strategic locations in the plant and battery limit which helps in alarming that ACN is escaping to offsite. To minimize the effects it is suggested that the area where ACN is handled may have bund wall of 300mm.This will limit the spread of ACN spill and reduce the pool area. Eventually evaporation rate and ACN evaporated & released to air can be minimized. If the dispersed vapors got ignition then a fire will flash back to source and pool fire will sustained. The total material will burnt out in 8mins. 4.0 & 1.6 kw/m2 distances are 23 & 31m for atmosphere condition D and 24 & 36 m for F. ACN is Highly reactive and reacts violently with strong oxidising agents.acn emits toxic fumes of hydrogen cyanide and nitrogen oxide when heated to decomposition. In the event of a fire involving acrylonitrile, use alcohol resistant foam, or normal foam if not available, and liquid tight protective clothing with breathing apparatus Siddhi Green Excellence Pvt. Ltd., Ankleshwar Page 8 of 24

44 CONSEQUENCE ANALYSIS FOR SELECTED CHEMICALS INVENTORY For proposed new Synthetic Resins Manufacturing unit of M/s. POLYOLS & POLYMERS PVT. LTD. At Plot No. D-2/CH/266,267, & 268 Dahej II Ind. Estate, Jolva, District Bharuch, Gujarat, India 7 ETHYL ACRYLATE Scenario Most Credible Scenario of Ethyl Acrylate,Leakage from 10mm hole Input Data Stability Class D F Temperature,degC atm atm Pressure,barg atm atm Wind Speed,m/s Atmospheric Temperature,degC Amount of Ethyl Acetate,KL Output Evaporation Rate,gm/s Flash Fire Envelope,m <10 <10 Pool Fire Burn Rate of Pool fire,kg/s Distance to radiation level 37.5kw/m2,..m <10 <10 Distance to radiation level 4kw/m2,..m Distance to radiation level 1.6 kw/m2,..m Flammable Effect: Atmospheric Stability Class D Atmospheric Stability Class F Discussion: The discharge rate through leak is 1.32kg/s.The total material released is 1310kgs. The evaporating pool will release Ethyl Acrylate vapors to atmosphere which will disperse in downwind direction. If the dispersed vapors got ignition then a fire will flash back to source and pool fire will sustained. The total material will burnt out in 8mins. 4.0 & 1.6 kw/m2 distances are 23 & 31m for atmosphere condition D and 22 & 33m for F. Siddhi Green Excellence Pvt. Ltd., Ankleshwar Page 9 of 24

45 CONSEQUENCE ANALYSIS FOR SELECTED CHEMICALS INVENTORY For proposed new Synthetic Resins Manufacturing unit of M/s. POLYOLS & POLYMERS PVT. LTD. At Plot No. D-2/CH/266,267, & 268 Dahej II Ind. Estate, Jolva, District Bharuch, Gujarat, India 8 ETHYLENE DIAMINE Scenario Most Credible Scenario of Ethylene Diamine one drum damage Input Data Stability Class D F Temperature,degC atm atm Pressure,barg atm atm Wind Speed,m/s Atmospheric Temperature,degC Amount of Ethylene Diamine,KL Output Evaporation Rate,gm/s Flash Fire Envelope,m <10 Pool Fire Burn Rate of Pool fire,kg/s 0.65 Distance to radiation level 37.5kw/m2,..m <10 Distance to radiation level 4kw/m2,..m 11 Material Solidify Distance to radiation level 1.6 kw/m2,..m 14 Assumptions: The damage of drum is happened during handling. There can be 50 events of handling. Due to damage total material of the drum is spilled on the ground. Due to the adjacent drums the pool height is considered as 10mm.Hence the pool area is considered as 20m2. The consequence is evaluated assuming that the spill will get an ignition immediately. Flammable Effect: Atmospheric Stability class D At 10degCatmospheric temperature, ethylene diamine is near to solidification state(mp 8.5degC) hence it will solidify once released to atmosphere. Hence no hazardous scenario will be created. It can be handled as per normal plant practices. Discussion: The pool fire due to this spill will last for 4mins and all 175kgs of spilled Ethylene Diamine will burn within this time. The burn rate is 0.65kg/s. The radiation of 37.5kw/m2 will not experienced due to this fire. Due to these reasons there is unlikely that other drums will get damaged and additional Ethylene Diamine will be spilled. Siddhi Green Excellence Pvt. Ltd., Ankleshwar Page 10 of 24

46 CONSEQUENCE ANALYSIS FOR SELECTED CHEMICALS INVENTORY For proposed new Synthetic Resins Manufacturing unit of M/s. POLYOLS & POLYMERS PVT. LTD. At Plot No. D-2/CH/266,267, & 268 Dahej II Ind. Estate, Jolva, District Bharuch, Gujarat, India If the explosive mixture is not ignited immediately then the spilled material will be evaporated at rate of 0.038kg/s The storage area shall be well ventilated 9 HYDROGEN-HYDROGENATION REACTOR Scenario Hydrogenation Reactor Catastrophic Failure Input Data Stability Class D F Temperature,degC atm atm Pressure,barg Wind Speed,m/s Atmospheric Temperature,degC Volume of reactor,m3 5 5 Output Released Quantity,Kg Explosion Distance to overpressure level 8.0psi,..m - - Distance to overpressure level 3.5psi,..m <10 <10 Distance to overpressure level 0.5psi,..m Assumptions: The catastrophic failure will release all the contents to atmosphere almost instantaneously. The 50% of reactor volume contains hydrogen which is available for explosion. The release will catch fire immediately as MIE of hydrogen is very less (0.017mJ) and result in explosion. Total released material is 10.7 kg. Flammable Effect (Explosion): Atmospheric Stability Class D Atmospheric Stability Class F Discussion: The failure of hydrogenation reactor will result in release of reactants and the content will splash with force exerted due to 100barg pressure. Almost instantaneously the released hydrogen will explode as hydrogen do not need any separate ignition source as its required minimum ignition energy is very low (0.017mJ). The explosion will result in overpressure. The analysis results shows that overpressure wave more than 8psi will not be experienced. At distance of 24/75 m, the overpressure experienced is 0.5psi for stability class D/F respectively.it can cause injuries due to glass shattering of windows. It can be protected by applying safety laminates on the windows which come under this area Siddhi Green Excellence Pvt. Ltd., Ankleshwar Page 11 of 24

47 CONSEQUENCE ANALYSIS FOR SELECTED CHEMICALS INVENTORY For proposed new Synthetic Resins Manufacturing unit of M/s. POLYOLS & POLYMERS PVT. LTD. At Plot No. D-2/CH/266,267, & 268 Dahej II Ind. Estate, Jolva, District Bharuch, Gujarat, India 10 HYDROGEN-HYDROGEN CYLINDER BANK Scenario Hydrogen Cylinders Tubing Leak,(Leak Size 0.75 in) Input Data Stability Class D F Temperature,degC Pressure,barg Wind Speed,m/s Atmospheric Temperature,degC Volume of cylinder,m Output Released Quantity,Kg Explosion Distance to overpressure level 8.0psi,..m - - Distance to overpressure level 3.5psi,..m - - Distance to overpressure level 0.5psi,..m - 25 Jet Fire Flame Length,m 1 1 Distance to radiation level 37.5kw/m2,..m <10 <10 Distance to radiation level 4kw/m2,..m <10 <10 Distance to radiation level 1.6 kw/m2,..m <10 <10 Assumptions: Atmospheric stability class F & D. Leak is from instrument tubing which is disconnected and of size ¾. The leak will cat fire immediately as MIE of hydrogen is very less(0.017mj).a jet fire will sustain at the leak. The leak is assumed to be for 15mins before detection and isolation. Flammable Effect Explosion No Explosion Atmospheric Stability Class D Atmospheric Stability Class F Discussion: At the release rate of & kg/s for stability class D & F.The burning will occur and it will end within 20 secs (completely burning 1.08 / 1.22 kgs in one cylinder). At this rate the radiation effect of Jet Fire are maximum. All radiation effects are within less than 10m from jet source. The flame length is 1m at start. This is due to high pressure inside of the cylinder. Practically it will take more time but with less release rate. As pressure will reduce inside cylinder the release rate will also reduced. In case of stability class F, the explosion effects are also experienced.0.5 psi overpressure is experienced upto 25m.This overpressure can shatter glasses. Siddhi Green Excellence Pvt. Ltd., Ankleshwar Page 12 of 24

48 CONSEQUENCE ANALYSIS FOR SELECTED CHEMICALS INVENTORY For proposed new Synthetic Resins Manufacturing unit of M/s. POLYOLS & POLYMERS PVT. LTD. At Plot No. D-2/CH/266,267, & 268 Dahej II Ind. Estate, Jolva, District Bharuch, Gujarat, India 11 ISOPROPYL ALCOHOL (IPA) Scenario Most Credible Scenario of IPA,leakage through 10mm hole Input Data Stability Class D F Temperature,degC atm atm Pressure,barg 4 4 Wind Speed,m/s Atmospheric Temperature,degC Amount of IPA,KL pool Area,m Output Flash Fire Envelope,m <10 <10 Pool Fire Burn Rate of Pool fire,kg/s Distance to radiation level 37.5kw/m2,..m <10 <10 Distance to radiation level 4kw/m2,..m Distance to radiation level 1.6 kw/m2,..m Flammable Effect: Atmospheric Stability Class D Atmospheric Stability Class F Discussion: The discharge rate through leak is 1.23kg/s.The total material released is 1208kgs. The evaporating pool will release IPA vapors to atmosphere which will disperse in downwind direction. If the dispersed vapors got ignition then a fire will flash back to source and pool fire will sustained. The total material will burnt out in 9mins. Although for atmospheric stability class F,the temp (10degC) is below flash point of IPA (11.67degC), the consequence is calculated considering the fire initiated due to other source. 4.0 & 1.6 kw/m2 distances are 20 & 27m for atmosphere condition D and 21 & 32m for F. Siddhi Green Excellence Pvt. Ltd., Ankleshwar Page 13 of 24

49 CONSEQUENCE ANALYSIS FOR SELECTED CHEMICALS INVENTORY For proposed new Synthetic Resins Manufacturing unit of M/s. POLYOLS & POLYMERS PVT. LTD. At Plot No. D-2/CH/266,267, & 268 Dahej II Ind. Estate, Jolva, District Bharuch, Gujarat, India 12 METHYL METHACRYLATE Scenario Most Credible Scenario of Methyl Methacrylate,leakage through 10mm hole Input Data Stability Class D F Temperature,degC atm atm Pressure,barg 4 4 Wind Speed,m/s Atmospheric Temperature,degC Amount of Methyl Methacrylate,KL pool Area,m Output Flash Fire Envelope,m <10 <10 Pool Fire Burn Rate of Pool fire,kg/s Distance to radiation level 37.5kw/m2,..m <10 <10 Distance to radiation level 4kw/m2,..m Distance to radiation level 1.6 kw/m2,..m Flammable Effects: Atmospheric Stability Class D Atmospheric Stability Class F Discussion: The discharge rate through leak is 1.33kg/s.The total material released is 1319kgs. The evaporating pool will release Methyl Methacrylate vapors to atmosphere which will disperse in downwind direction. If the dispersed vapors got ignition then a fire will flash back to source and pool fire will sustained. The total material will burnt out in 8mins. 4.0 & 1.6 kw/m2 distances are 23 & 30m for atmosphere condition D and 22 & 33m for F. Siddhi Green Excellence Pvt. Ltd., Ankleshwar Page 14 of 24

50 CONSEQUENCE ANALYSIS FOR SELECTED CHEMICALS INVENTORY For proposed new Synthetic Resins Manufacturing unit of M/s. POLYOLS & POLYMERS PVT. LTD. At Plot No. D-2/CH/266,267, & 268 Dahej II Ind. Estate, Jolva, District Bharuch, Gujarat, India 13 BUTYL ACETATE Scenario Most Credible Scenario of Butyl Acetate,leakage through 10mm hole Input Data Stability Class D F Temperature,degC atm atm Pressure,barg 4 4 Wind Speed,m/s Atmospheric Temperature,degC Amount of Butyl Acetate,KL pool Area,m Output Flash Fire Envelope,m <10 <10 Pool Fire Burn Rate of Pool fire,kg/s Distance to radiation level 37.5kw/m2,..m 11 <10 Distance to radiation level 4kw/m2,..m Distance to radiation level 1.6 kw/m2,..m Flammable Effects: Atmospheric Stability class D Atmospheric Stability class F Discussion: The discharge rate through leak is 1.307kg/s.The total material released is 1294kgs. The evaporating pool will release Butyl Acetate vapors to atmosphere which will disperse in downwind direction. If the dispersed vapors got ignition then a fire will flash back to source and pool fire will sustained. The total material will burnt out in 7mins. Although for atmospheric stability class F,the temp (10degC) is below flash point of butyl acetate (23.9degC), the consequence is calculated considering the fire initiated due to other source. In case of stability class D,radiation of 37.5kw/m2 is experienced up to distance 11m.But the total spilled material will be burnt within 6 mins. 4.0 & 1.6 kw/m2 distances are 24 & 32m for atmosphere condition D and 23 & 35m for F. Siddhi Green Excellence Pvt. Ltd., Ankleshwar Page 15 of 24

51 CONSEQUENCE ANALYSIS FOR SELECTED CHEMICALS INVENTORY For proposed new Synthetic Resins Manufacturing unit of M/s. POLYOLS & POLYMERS PVT. LTD. At Plot No. D-2/CH/266,267, & 268 Dahej II Ind. Estate, Jolva, District Bharuch, Gujarat, India 14 BUTANOL Scenario Most Credible Scenario of Butanol,leakage through 10mm hole Input Data Stability Class D F Temperature,degC atm atm Pressure,barg 4 4 Wind Speed,m/s Atmospheric Temperature,degC Amount of Butanol,KL pool Area,m Output Flash Fire Envelope,m <10 <10 Pool Fire Burn Rate of Pool fire,kg/s Distance to radiation level 37.5kw/m2,..m 11 <10 Distance to radiation level 4kw/m2,..m Distance to radiation level 1.6 kw/m2,..m Flammable Effects: Atmospheric Stability Class D Atmospheric Stability Class F Discussion: The discharge rate through leak is 1.24 kg/s. The total material released is 1227 kgs. The evaporating pool will release Butanol vapors to atmosphere which will disperse in downwind direction. If the dispersed vapors got ignition then a fire will flash back to source and pool fire will sustained. The total material will burnt out in 8 mins. Although for atmospheric stability class F, the temp (10degC) is below flash point of Butanol (28.9degC), the consequence is calculated considering the fire initiated due to other source. In case of stability class D/F,radiation of 37.5kw/m2 is experienced up to distance 11/less than 10m.But the total spilled material will be burnt within 9 mins. 4.0 & 1.6 kw/m2 distances are 22 & 29m for atmosphere condition D and 23 & 34m for F. Siddhi Green Excellence Pvt. Ltd., Ankleshwar Page 16 of 24

52 CONSEQUENCE ANALYSIS FOR SELECTED CHEMICALS INVENTORY For proposed new Synthetic Resins Manufacturing unit of M/s. POLYOLS & POLYMERS PVT. LTD. At Plot No. D-2/CH/266,267, & 268 Dahej II Ind. Estate, Jolva, District Bharuch, Gujarat, India 15 STYRENE Scenario Most Credible Scenario of styrene,leakage through 10mm hole Input Data Stability Class D F Temperature,degC atm atm Pressure,barg 4 4 Wind Speed,m/s Atmospheric Temperature,degC Amount of styrene,kl pool Area,m Output Flash Fire Envelope,m <10 <10 Pool Fire Burn Rate of Pool fire,kg/s Distance to radiation level 37.5kw/m2,..m 15 <10 Distance to radiation level 4kw/m2,..m Distance to radiation level 1.6 kw/m2,..m Flammable Effect: Atmospheric Stability Class D Atmospheric Stability Class F Discussion: The discharge rate through leak is 1.31kg/s. The total material released is 1298kgs. The evaporating pool will release Styrene vapors to atmosphere which will disperse in downwind direction. If the dispersed vapors got ignition then a fire will flash back to source and pool fire will sustained. The total material will burnt out in 5 mins. Although for atmospheric stability class F, the temp (10degC) is below flash point of Styrene (31.1degC), the consequence is calculated considering the fire initiated due to other source. In case of stability class D/F,radiation of 37.5kw/m2 is experienced up to distance 15/less than 10 m.but the total spilled material will be burnt within 5 mins. 4.0 & 1.6 kw/m2 distances are 31 & 42m for atmosphere condition D and 29 & 46m for F. Siddhi Green Excellence Pvt. Ltd., Ankleshwar Page 17 of 24

53 CONSEQUENCE ANALYSIS FOR SELECTED CHEMICALS INVENTORY For proposed new Synthetic Resins Manufacturing unit of M/s. POLYOLS & POLYMERS PVT. LTD. At Plot No. D-2/CH/266,267, & 268 Dahej II Ind. Estate, Jolva, District Bharuch, Gujarat, India 16 ACETIC ACID Scenario Most Credible Scenario of Acetic Acid,leakage through 10mm hole Input Data Stability Class D F Temperature,degC atm atm Pressure,barg 4 4 Wind Speed,m/s Atmospheric Temperature,degC Amount of Acetic Acid,KL pool Area,m Solid Output Flash Fire Envelope,m <10 Pool Fire Burn Rate of Pool fire,kg/s 1.28 Distance to radiation level 37.5kw/m2,..m <10 Distance to radiation level 4kw/m2,..m 12 Distance to radiation level 1.6 kw/m2,..m 15 Solid at 10degC Flammable Effect: Acetic acid will solidify below 16degC at atmospheric pressure. Hence no hazardous scenario is analysed Atmospheric Stability Class D Atmospheric Condition F:. Discussion: The discharge rate through leak is 1.41kg/s. The total material released is 1397kgs. The evaporating pool will release Acetic Acid vapors to atmosphere which will disperse in downwind direction. If the dispersed vapors got ignition then a fire will flash back to source and pool fire will sustained. The total material will burnt out in 18 mins. Although for atmospheric stability class F, at temp (10degC) acetic acid will solidify(below 16degC) In case of stability class D,radiation of 37.5kw/m2 is not experienced 4.0 & 1.6 kw/m2 distances are 12 & 15m for atmosphere condition D Siddhi Green Excellence Pvt. Ltd., Ankleshwar Page 18 of 24

54 CONSEQUENCE ANALYSIS FOR SELECTED CHEMICALS INVENTORY For proposed new Synthetic Resins Manufacturing unit of M/s. POLYOLS & POLYMERS PVT. LTD. At Plot No. D-2/CH/266,267, & 268 Dahej II Ind. Estate, Jolva, District Bharuch, Gujarat, India 17 BUTYL METHACRYLATE Scenario Most Credible Scienario of Butyl Acrylate,Spillage from 200Lit Drum Input Data Stability Class D F Temperature,degC atm atm Pressure,barg atm atm Wind Speed,m/s Atmospheric Temperature,degC Amount of Butyl Acrylate,Lits pool Area,m Output Flash Fire Envelope,m <10 Pool Fire Burn Rate of Pool fire,kg/s 1.19 Distance to radiation level 37.5kw/m2,..m <10 Distance to radiation level 4kw/m2,..m 16 Distance to radiation level 1.6 kw/m2,..m 21 Non flammable(flash point- 52.2degC, is quite higher 10degC) Assumptions: The damage of drum is happened during handling. There can be 10 events of handling. Due to damage total material of the drum is spilled on the ground. Due to the adjacent drums the pool height is considered as 10mm.Hence the pool area is considered as 20m2. Although the flash point 52.2degC is higher than atmospheric temperature,the consequence is evaluated assuming that the spill will get an ignition immediately. The consequence is evaluated for class D only. Flammable Effect: Atmospheric Stability Class D Discussion: The pool fire due to this spill will last for 2 mins and all 175kgs of spilled BUTYL METHACRLATE will burn within this time. The burn rate is kg/s. The radiation of 37.5kw/m2 will not experienced due to this fire. Due to these reasons there is unlikely that other drums will get damaged and additional BUTYL METHACRLATE will be spilled. If the explosive mixture is not ignited immediately then the spilled material will be evaporated at rate of 0.29kg/s and it will take 16 mins to evaporate all the spilled material. Siddhi Green Excellence Pvt. Ltd., Ankleshwar Page 19 of 24

55 CONSEQUENCE ANALYSIS FOR SELECTED CHEMICALS INVENTORY For proposed new Synthetic Resins Manufacturing unit of M/s. POLYOLS & POLYMERS PVT. LTD. At Plot No. D-2/CH/266,267, & 268 Dahej II Ind. Estate, Jolva, District Bharuch, Gujarat, India The storage area shall be well ventilated. 18 FORMALDEHYDE Scenario Most Credible Scenario of Formaldehyde,Spillage from 10mm hole Input Data Stability Class D F Temperature,degC Pressure,barg 4 4 Wind Speed,m/s Atmospheric Temperature,degC Amount of Formaldehyde,KL IDLH,ppm 20 Output Solution Release rate,kg/hr Formaldehyde release rate,kg/hr Flash Fire Envelope,m <10 <10 Distance to IDLH,m Discharge Calculations The discharge is modeled as liquid flow through sharp edged orifice The Discharge Rate of Formaldehyde Soln. : 1.44 kg/s The release rate of formaldehyde from solution can be done in following two basis, 1. There is certain volume over the pool whose composition can be found out by vapor pressure (0.34psi) of formaldehyde solution at ambient conditions. This formaldehyde is available for dispersion. It can be modeled as direct source in ALOHA as instantaneous release. 2. The emission rates of formaldehyde from 37% solution are available in literature. (Ref: Estimating Formaldehyde Emission in Air by EPA;1991) For different process and storages rates are reported. Maximum of these rates (0.35kg/Mg) can be used in ALOHA and modeled in ALOHA as direct source with continuous rate. Based on vapor pressure,on conservative side it is assumed that from the released solution 2.5% of the amount of formaldehyde gas is released to atmosphere. The release rate of formaldehyde gas : 1.44*0.37*2.5% = kg/s This much formaldehyde is available to disperse in downwind direction.it is modeled as direct source - continuous in ALOHA. Flash Fire Envelope: The envelope diameter is <10m for both atmospheric stability classes. Siddhi Green Excellence Pvt. Ltd., Ankleshwar Page 20 of 24

56 CONSEQUENCE ANALYSIS FOR SELECTED CHEMICALS INVENTORY For proposed new Synthetic Resins Manufacturing unit of M/s. POLYOLS & POLYMERS PVT. LTD. At Plot No. D-2/CH/266,267, & 268 Dahej II Ind. Estate, Jolva, District Bharuch, Gujarat, India Toxic Effect: The Area is patchy hence not shown. Atmospheric Stability Class D Atmospheric Stability Class F Discussion: It is assumed that after isolation and control of the formaldehyde solution leak(ie 15mins) still there will be release of formaldehyde gas from spilled solution but it is assumed that it will be negligible as all 37% formaldehyde is released during the leak. The IDLH distance for stability class D & F is 45 and 162m. For atmospheric class D the area of dispersion is not wide and it is patchy,hence ALOHA has not given the map. For class F also the spread of area along the line of concentration is not more than 5m. At these distances the horizontal spread of vapour cloud is not more than 10m maximum. The toxic effect is more severe than flammable effects. Siddhi Green Excellence Pvt. Ltd., Ankleshwar Page 21 of 24

57 CONSEQUENCE ANALYSIS FOR SELECTED CHEMICALS INVENTORY For proposed new Synthetic Resins Manufacturing unit of M/s. POLYOLS & POLYMERS PVT. LTD. At Plot No. D-2/CH/266,267, & 268 Dahej II Ind. Estate, Jolva, District Bharuch, Gujarat, India 19 XYLENE Scenario Most Credible Scienario of xylene,spillage from 10mm hole Input Data Stability Class D F Temperature,degC atm atm Pressure,barg atm atm Wind Speed,m/s Atmospheric Temperature,degC Amount of xylene,kl pool Area,m Output Flash Fire Envelope,m <10 <10 Pool Fire Burn Rate of Pool fire,kg/s Distance to radiation level 37.5kw/m2,..m 17 <10 Distance to radiation level 4kw/m2,..m Distance to radiation level 1.6 kw/m2,..m Flammable Effect: Atmospheric Stability Class D Atmospheric Stability Class F Discussion: The discharge rate through leak is 1.28kg/s.The total material released is 1268kgs. The evaporating pool will release Xylene vapors to atmosphere which will disperse in downwind direction. If the dispersed vapors got ignition then a fire will flash back to source and pool fire will sustained. The total material will burnt out in 4mins. Although for atmospheric stability class F,the temp (10degC) is below flash point of xylene (24degC), the consequence is calculated considering the fire initiated due to other source. In case of stability class D/F,radiation of 37.5kw/m2 is experienced up to distance 17/less than 10m.But the total spilled material will be burnt within 4 mins. 4.0 & 1.6 kw/m2 distances are 35 & 48m for atmosphere condition D and 32 & 51m for F Siddhi Green Excellence Pvt. Ltd., Ankleshwar Page 22 of 24

58 CONSEQUENCE ANALYSIS FOR SELECTED CHEMICALS INVENTORY For proposed new Synthetic Resins Manufacturing unit of M/s. POLYOLS & POLYMERS PVT. LTD. At Plot No. D-2/CH/266,267, & 268 Dahej II Ind. Estate, Jolva, District Bharuch, Gujarat, India 20 PHENOL Scenario Most Credible Scenario of Phenol,Spillage from 10mm hole Input Data Stability Class D F Temperature,degC Pressure,barg 4 4 Wind Speed,m/s Atmospheric Temperature,degC Amount of Phenol,KL IDLH,ppm LD50,ppm Output Evaporation rate,kg/hr Distance told50,m <10 Distance to IDLH,m <10 Burn Rate of Pool fire,kg/s 2.48 Material Solidify Distance to radiation level 37.5kw/m2,..m 11 Distance to radiation level 4kw/m2,..m 21 Distance to radiation level 1.6 kw/m2,..m 28 Flammable Effect: Atmospheric Stability Class D Atmospheric Stability Class F Toxic Effect: All the toxic endpoint distances are less than 10m. Discussion: LD50 and IDLHconcentration will not reach more than 10m. The flash point (79degC) is more than atmospheric temp. Then also the radiation effects are analyzed considering it will burning due to fire. The 37.5 kw/m2 radiation will experienced upto 11m. 4 & 1.6 kw/m2 will experienced up to distance of 21&28m. Siddhi Green Excellence Pvt. Ltd., Ankleshwar Page 23 of 24

59 CONSEQUENCE ANALYSIS FOR SELECTED CHEMICALS INVENTORY For proposed new Synthetic Resins Manufacturing unit of M/s. POLYOLS & POLYMERS PVT. LTD. At Plot No. D-2/CH/266,267, & 268 Dahej II Ind. Estate, Jolva, District Bharuch, Gujarat, India 21 SULFURIC ACID Scienaro 1 Catastrophic Failure of Sulfuric acid Tank Input Data Stability Class D F Temperature,degC atm atm Pressure,kg/cm2g 1 1 Wind Speed,m/s Atmospheric Temperature,degC Volume of vessel,m Diameter,m 2 2 Height,m 3 3 ERPG2,mg/m Output Evaporation Rate,kg/min LC50 Distance,m <10 <10 ERPG2 Distance,m 13 <10 Assumptions For this worst-case analysis, it was conservatively assumed that the sulfuric acid stored in the tank contains 4% sulfur trioxide (oleum). However, the actual amount of oleum in 96% sulfuric acid is negligible. Nevertheless, to be conservative, a 4% oleum concentration was used as input into the ALOHA model to simulate a release of sulfuric acid The release is instantaneous. The release will be modeled as burning / evaporating puddle. Atmospheric stability class is D (Wind velocity 8.33m/s).This is worst case for pool formation, evaporation. With the heat available from ground and atmosphere is at these conditions, the pool evaporation rate is maximum. The dyke around sulfuric acid tank is not designed to contain total volume of tank. The pool height is 10mm(1cm) Toxic Effect: All toxic endpoints distances are less than 10m. Discussion: ERPG 2 concentration will not reach more than 13m. The release rate of SO3 from sulfuric acid is 1.5gm/s and amount released in air is 5.39kgs.(for stability class D) The release rate of SO3 from sulfuric acid is 0.12gm/s and amount released in air is 368gms.(for stability class F) It is suggested to have 300mm bund wall around sulfuric acid tank and pumping area. This will help to restrict sulfuric acid spill to minimum area.the area inside bund can be of acid resistant material. Siddhi Green Excellence Pvt. Ltd., Ankleshwar Page 24 of 24

60 Project: Baseline Environmental Studies Client: Polyols & Polymers Conducted by: Siddhi Green Excellence Pvt Ltd, Ankleshwar Duration for Baseline Environmental Studies Oct 2014 to Dec 2014 (Post monsoon) AAQM monitoring dates for stations Jolva, Vadadla, Galenda, Dahej, Ambetha OCTOBER NOVEMBER DECEMBER WK SUN MON TUE WED THU FRI SAT WK SUN MON TUE WED THU FRI SAT WK SUN MON TUE WED THU FRI SAT Project: Baseline Environmental Studies Client: Polyols & Polymers Conducted by: Siddhi Green Excellence Pvt Ltd, Ankleshwar Duration for Baseline Environmental Studies Oct 2014 to Dec 2014 (Post monsoon) AAQM monitoring dates for stations Janiyadra, Padariya, Koliyad, Vav, Project site OCTOBER NOVEMBER DECEMBER WK SUN MON TUE WED THU FRI SAT WK SUN MON TUE WED THU FRI SAT WK SUN MON TUE WED THU FRI SAT

61 Project: Proponent: Project site: Documents: Proposed new manufacturing unit for synthetic organic products M/s. Polyols & Polymers Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India List of Partners for proposed project List of Partners: Sr.No. List of partners Contact No. Address 1 Prabir Kumar Dutt Bhupendra Mohan Dutt 2 Mrs. Archana Dutt Kali Bhusan Sadananda Dutt 3 Mr. Supratik Dutt Prabir Kumar Dutt 4 Patel Navnitbhai Durlabhbhai Patel Durlabhbhai Zinabhai , Bhagyoday Society Chala, Vapi: (0260) , Bhagyoday Society Chala, Vapi: , Bhagyoday Society Chala, Vapi: At & Po. Kalwada, Dist. Valsad I.T. PAN No. : AHNPP7136L/Ward-2, Valsad 5 Patel Gitaben Navnitbhai Dayabhai Ghelabhai Patel (02632) At & Po. Kalwada, Dist. Valsad I.T. PAN No. : ASGPP&031C/Ward-2, Valsad Page 1 of 1

62 Area Profile of Vagra sub-district of Bharuch district, Gujarat state Number of Households 16,767 Average Household Size(per Household) 5.0 Population-Total 82,647 Proportion of Urban Population (%) 0 Population-Rural Sex Ratio 913 Population-Urban 0 Sex Ratio(0-6 Year) 962 Population(0-6Years) 12,813 Sex Ratio (SC) 940 SC Population 4,459 Sex Ratio (ST) 932 ST Population 21,276 Proportion of SC (%) 5.0 Literates 50,838 Proportion of ST (%) 26.0 Illiterates 31,809 Literacy Rate (%) 73.0 Total Workers 35,269 Work Participation Rate (%) 43.0 Main Worker 28,201 % of Main Workers 34.0 Marginal Worker 7,068 % of Marginal Worker 9.0 Non Worker 47,378 % of non Workers 57.0 CL (Main+Marginal) 8,939 Proportion of CL (%) 25.0 Al (Main+Marginal) 13,801 Proportion of AL (%) 39.0 HHI (Main+Marginal) 328 Proportion of HHI (%) 1.0 OW (Main+Marginal) 12,201 Proportion of OW (%) 35.0

63

64

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66 26.5 P2 (FOR CAR) Lab on FF Utility Tank farm area COMMON OPEN PLOT Petroleum Class A U/g tankfarm HYDROGEN TROLLY 2. HYDROGEN REACTOR 3. RM STORAGE BAGS 4. RM STORAGE DRUMS 5. FG STORAGE DRUMS 6. FG STORAGE BAGS 7. EXPLOSIVE RM STORAGE AREA 8. BOILER, THF, CP, DG, ALL UTILITIES GREEN BELT AREA Proposed Plant Layout: M/s. POLYOLS AND POLYMERS at Plot No. D2/CH-266,267,268, Dahej - II, Tal Vagra, Dist - Bharuch, State Gujarat, India

67 M/s. POLYOLS & POLYMERS Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate Village: Jolva, Taluka - Vagra, Dist. Bharuch List of Raw Material (For proposed New Unit) Sr No Product Name Proposed production capacity MT/Month Raw materials Consumption Kg/kg of MT/Month product 1 (a) Acrylic resin 60 Methyl methacrylate Butyl methacrylate Acrylic Acid Poly Vinyl Alcohol Benzoyl peroxide (Initiator) (b) Acrylic Polyols 150 Toluene Acrylic monomers Benzoyl peroxide (Initiator) (c) Acrylic emulsion 150 Methyl methacrylate Sodium lauryl sulphate Ammonium persulphate Other acrylic monomers which shall be used in product no. 1 (a), (b), (c) as per product spec. are : Acrylonitrile, Methyl Acrylate, Ethyl Acrylate, Butyl Acrylate, 2 ethyl Hexyl Acrylate, Methoxyethyl Acrylate, Dimethyl amino Acrylate, Methacrylic Acid, Ethyl methacrylate, Isobutyl methacrylate, 2 ethyl hexyl methacrylate, Lauryl methacrylate, Stearic methacrylate, Di methyl amino methacrylate, Allyl methacrylate, 2 Hydroxy ethyl Acrylate, 2 Hydroxy Propyl Acrylate, 2 Hydroxy ethyl methacrylate, 2 Hydroxy Propyl methacrylate, Acryl amide, Methacrylamide, Glycidyl Acrylate, Styrene 2 Hydrogenated ketonic resin 150 Ketonic resin Butyl acetate /Ethyl acetate/mek/ipa/butanol Hydrogen gas Raney nickel (catalyst) Ketonic Resin 300 Cyclohexanone Optional components : Methyl Cyclohexanone Acetophenone Methyl Ethyl Ketone MIBK Formaldehyde (37%) / Paraformaldehyde Caustic soda flakes Page 1 of 3 Project: Proponent: Project site: Documents: Proposed new manufacturing unit for synthetic organic products M/s. Polyols & Polymers Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India Raw materials list for proposed project

68 M/s. POLYOLS & POLYMERS Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate Village: Jolva, Taluka - Vagra, Dist. Bharuch Sr No Product Name Proposed production capacity MT/Month 4 Oil based polyester Polyols (L) Raw materials Consumption Kg/kg of MT/Month product 1500 Castor oil Ketonic Resin Di butyl tinoxide Optional raw materials which shall be used in product no. 4 as per product spec. are :Acrylic Polyols, Glycerol, Trimethylolpropane Propoxylate 5 (a) Phenol formaldehyde resin (a) Phenol formaldehyde / alkyl phenol formaldehyde resin NOVOLACS 750 Phenol / Para tertiary butyl phenol/ Nonyl phenol Formaldehyde (37%) / paraformaldehyde Oxalic acid / hydrochloric acid - catalyst (b) Phenol formaldehyde resin (b) alkyl Phenol formaldehyde resin resole 6 (a) Polyamide resin (a) Co solvent grade polyamide resin 6 (b) Polyamide resin (b) Alcohol soluble polyamide resin 6 (c) Polyamide resin (c) Reactive poly amide resin 7 Polyester Resins - Saturated/ Unsaturated / polyester Polyols 300 Para tertiary butyl phenol Formaldehyde (37%) / paraformaldehyde Caustic Soda flakes Sulphuric acid Toluene Dimer acid / Fatty acid (Soya fatty acid/ Tall oil fatty acid) Ethylene Diamine / TETA Dimer acid Acetic acid Ethylene Diamine / TETA Dimer acid Soya Fatty Acid Ethylene Diamine / TETA *Hexanediol #Adipic Acid Tri methylolpropane(tmp)/ Glycerol/ Tri methylolethane(tme) #Iso Pthalic Acid Page 2 of 3 Project: Proponent: Project site: Documents: Proposed new manufacturing unit for synthetic organic products M/s. Polyols & Polymers Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India Raw materials list for proposed project

69 M/s. POLYOLS & POLYMERS Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate Village: Jolva, Taluka - Vagra, Dist. Bharuch Sr No Product Name Proposed production capacity MT/Month Raw materials Consumption Kg/kg of MT/Month product *Other optional diols : Ethylene Glycol( EG ), Propylene Glycol ( PG), 1,4Butanediol (BD), 1,5Pentanediol (PD), Di ethylene Glycol (DEG ), 3 Methyl -1,5pentanediol(MPD), 2,2,4 Trimethyl-1,3 Pentanediol ( TMPD), Tri ethylene glycol (TEG), Hexyleneglycol (HG), Tri ethylene glycol (TEG), NPG ester,esterdiol, Bisphenol A, Propoxylated Bisphenol A #Other optional difunctional acids :- Maleic Anhydride, Succinic Anhydride, 1,2,3,6 Tetra hydro Pthalic acid anhydride, Fumaric Acid, Succinic Acid, Di glycolic Acid, Adipic Acid, Pthalic Anhydride, Iso Pthalic Acid, Terepthalic Acid, Azelaic Acid Sebacic Acid, Trimellitic Anhydride (TMA),Citric Acid,Tri mellitic Acid, Styrene, Xylene\ Other High Functionality Alcohols: Pentaerythritol Sorbitol Di pentaerythritol & Mono functional acids Benzoic Acid Pelargonic Acid p-tertiary butyl benzoic Acid 8 (a),9 Rosin Based Resins (a) Modified Phenolic Resin & Turpentine 8 (b),9 Rosin Based Resins (b) Maleic Resin & Turpentine 10 Styrene Maleic Anhydride Resin 11 Xylene Formaldehyde Resin 600 Gum Rosin Para Tertiary butyl Phenol/ Nonyl phenol Para Formaldehyde Pentaerythritol Gum Rosin Pentaerythritol Fumaric Acid Styrene Maleic Anhydride Toluene Xylene ( L ) Formaldehyde 37% / Para formaldehyde Sulphuric Acid Sodium Carbonate solution Page 3 of 3 Project: Proponent: Project site: Documents: Proposed new manufacturing unit for synthetic organic products M/s. Polyols & Polymers Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India Raw materials list for proposed project

70 Project: Proponent: Project site: Documents: Proposed new manufacturing unit for synthetic organic products M/s. Polyols & Polymers Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India Manufacturing Process for proposed project Product-1: (a) Acrylic resins: Acrylic Resins are formed by addition polymerization reactions.. Unlike condensation polymerization, addition polymerization leads to high mol weight polymers. There is also no release of water or other small molecules characteristic of condensation polymers. Process: Thermoplastic Acrylic Resins Reaction: Process consists of charging DM water in the reactor and dissolving the PVA under stirring. On completion of the dissolution the contents of the reactor are heated to the desired temperature. MMA, n-bma and acrylic acid are slowly added along with the initiator at a measured rate, taking care not to let the temperature rise beyond a certain required level.. When the required temperature level is reached the reactants are maintained at that temperature for the required time. Cooling & Washing: At the end of the reaction period the contents are cooled and discharged into a neutch filter and drain the water. The resin is further washed with water to free the resin of any impurities. Packing: The filtered resin is then dried and packed. Filterate is given electrochemical oxidation treatment followed by Biomass treatment Chemical reaction: C5H8O2 + C8H14O2 + C3H4O2 INITIATOR C5H8O2 C8H13O2 CH2=CH-COOH Methyl methacrylate n- butyl methacrylate acrylic acid acrylic resin Mol. Wt. 100 Mol. Wt. 142 Mol. Wt. 72 Mol. Wt. 314 Page 1 of 29

71 Project: Proponent: Project site: Documents: Proposed new manufacturing unit for synthetic organic products M/s. Polyols & Polymers Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India Manufacturing Process for proposed project Flow sheet: Poly vinyl alcohol 0.300kg DM water 1000kg Dissolution kg Methyl Meth Acrylate 330 kg n- Butyl Meth Acrylate 460 kg Acrylic acid 240 kg Benzyl peroxide 21 kg Heating Cooling kg Filtration kg Filtrate 1021 kg sent to ETP Water 500 kg Washing Drying kg kg Effluent 500 kg sent to ETP Thermo plastic acrylic resin 1000 kg INPUT = OUTPUT Proposed production capacity 60 MT/month Freshwater Consumption 90 KL/month 3.0 KL/day Wastewater generation KL/month KL/day Page 2 of 29

72 Project: Proponent: Project site: Documents: Proposed new manufacturing unit for synthetic organic products M/s. Polyols & Polymers Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India Manufacturing Process for proposed project Product-1: (b) Acrylic polyols Process: Reaction: In this process of manufacture the reactions are taken in a solvent in which the produced resin is soluble. Solvent (toluene/ MEK/ Butanol). This is an addition polymerization reaction. The acrylic monomers required along with the initiator are added slowly in the solvent in the reaction vessel fitted with stirrer system and reflux condenser. Cooling & Packing: As this is an exothermic reaction the temperature of the contents of the reactor rises and is controlled by jacket cooling as and when required When the required temperature is reached, the reactants are allowed to be maintained for a required time and then cooled and packed in barrels. Chemical reaction: + Methyl Methacrylate 2- OH Ethyl Acrylate Mol. Wt 100 Mol. Wt 116 CH3 H H2 C CH2 C COOCH3 Ethyl Hexyl Acrylate Mol. Wt COOCH2CH2OH n Page 3 of 29

73 Project: Proponent: Project site: Documents: Proposed new manufacturing unit for synthetic organic products M/s. Polyols & Polymers Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India Manufacturing Process for proposed project Flow sheet: Acrylic monomers 490Kg kg k kg Toluene 500 Kg Benzyl peroxide 10 Kg Polymerization Reflux 1000kg Cooling 1000kg 1000 kg Packing in barrels Acrylic polyols 1000 kg INPUT = OUTPUT 1000 kg 1000kg 1000kg Proposed production capacity Freshwater Consumption Wastewater generation 150 MT/month NIL NIL Page 4 of 29

74 Project: Proponent: Project site: Documents: Proposed new manufacturing unit for synthetic organic products M/s. Polyols & Polymers Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India Manufacturing Process for proposed project Product-1: (c): Acrylic Emulsion: Process: A typical MMA Emulsion Polymers: Mix 8 Kg sodium lauryl sulphate in 595 Kg DM water is SS reactor fitted with a stirrer, reflex condenser, thermometer nitrogen inlet tube and two liquid addition inlets. Solution ammoniums per sulphate in DM water is prepared and of this solution and methyl methacrylate monomer are added to the flask. The stirrer and nitrogen flow are switched on and the flask slowly heated to 75 C. The emulsion is maintained at 75 C for 40 minutes after the end of the monomer addition to complete the reaction. The non-volatile content is determined and further initiator added if below theoretical, and the hold is continued for a further hour. Chemical reaction: MW: Page 5 of 29

75 Project: Proponent: Project site: Documents: Proposed new manufacturing unit for synthetic organic products M/s. Polyols & Polymers Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India Manufacturing Process for proposed project Flow sheet: DM Water 595kg Sodium lauryl sulphate 8 Kg kkkgkg Ammonium persulphate 1 Kg kgmethyl methacrylate 396 kg Polymerization Reflux 1000 kg Cooling 1000 kg 1000 kg Packing in barrels Acrylic emulsion 1000 kg INPUT = OUTPUT 1000 kg 1000kg Proposed production capacity 150 MT/month Freshwater Consumption KL/month KL/day Wastewater generation NIL Page 6 of 29

76 Project: Proponent: Project site: Documents: Proposed new manufacturing unit for synthetic organic products M/s. Polyols & Polymers Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India Manufacturing Process for proposed project Product-2 : Hydrogenated Ketonic Resin: Process: Reaction: Process consists of dissolving ketonic resin in the solvent (Butyl acetate/ MEK / ethyl acetate/ IPA/ butanol) and charging the solution along with the catalyst in the Hydrogenation reactor. Necessary amount of hydrogen is charged in the reactor and the reactor will be under pressure. Temperature of the reactants is increased to the required level. As the reaction progresses there will be reduction of the pressure in the reactor indicating consumption of Hydrogen. Filtration: At the end of the reaction the solution of hydrogenated ketonic resin is filtered to recover the catalyst which shall be used in the next batch. The solution is then distilled in a separate reaction vessel Distillation, Cooling & Packing: The solvent is distilled out and is condensed and is to be used in the next batch. When the solvent is distilled out, molten resin is left in the reactor which is poured in trays for cooling and solidification. Chemical reaction: O C O C O CH 2 OH KETONIC RESIN n H2 H 2 H 2 O C O C O CH 2 OH n HYDROGENATED KETONIC RESIN Page 7 of 29

77 Project: Proponent: Project site: Documents: Proposed new manufacturing unit for synthetic organic products M/s. Polyols & Polymers Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India Manufacturing Process for proposed project Flow sheet: Ketonic resin 900 kg Butyl acetate 400 kg Hydrogen gas 100 kg Raney nickel 2 kg Dissolution Cooling Filtration Distillation Cooling 1300 kg 1402 kg 1399 kg 1020 kg Spent catalyst 3 kg (Recovered & reuse in next batch) Butyl acetate 379 kg (Recovered & reuse in next batch) Hydrogenated ketonic resin 1020 kg INPUT = OUTPUT Proposed production capacity Freshwater Consumption Wastewater generation 150 MT/month NIL NIL Page 8 of 29

78 Project: Proponent: Project site: Documents: Proposed new manufacturing unit for synthetic organic products M/s. Polyols & Polymers Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India Manufacturing Process for proposed project Product-3 : Ketonic resin: Process: Reaction: Process consists of charging water, suspension agent, Ketone (e.g. Cyclohexanone ), Formaldehyde in the reaction kettle fitted with a stirrer system, condenser. Caustic soda (flaks/lye) is added as a catalyst to start the reaction. It is an exothermic reaction. The temp rises after addition of the catalyst and is controlled by jacket cooling and is maintained at the required temp level for required time. Cooling & washing: At the end of the reaction the contents of the reactor are cooled and then discharged on a neutch filter. The resin is then washed with water to free the resin from adhering & catalyst impurities. Packing: Then the resin is dried and packed in bags. Chemical reaction: H 2 H 2 O O C O C O CH 2 O CH 2 OH + 4H 2 O n CYCLOHEXANONE 37 % FORMALDEHYDE KETONIC RESIN STRAIGHT CHAIN (M.Wt. 98) (M.Wt. 30) (M.Wt Approx ) Page 9 of 29

79 Project: Proponent: Project site: Documents: Proposed new manufacturing unit for synthetic organic products M/s. Polyols & Polymers Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India Manufacturing Process for proposed project Flow sheet: Cyclohexanone 800 kg 37%Formaldehyde 1200 kg Caustic soda 56 kg Water 1400 kg Water 5000 kg Reaction Cooling Filtration Washing 3456kg 3456kg 1030kg ML Filtration Effluent 2406 kg sent to ETP Resin waste 20 kg Sent to co processing or incineration Effluent 5000 kg sent to ETP 1030 kg Drying & Packing in bags Ketonic resin 1000 kg INPUT = OUTPUT Proposed production capacity 300 MT/month Freshwater Consumption 1920 KL/month 64KL/day Wastewater generation KL/month 74.06KL/day Page 10 of 29

80 Project: Proponent: Project site: Documents: Proposed new manufacturing unit for synthetic organic products M/s. Polyols & Polymers Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India Manufacturing Process for proposed project Product-4: Oil Based Polyester Polyols: Natural oil based polyols- castor oil based polyols Process: Reaction: This product is prepared by mixing different polyols e.g Glycerol, Trimethyl prapanol,ketonic resin polyols or others in castor oil. Castor oil which is a fatty acid containing hydroxyl groups is taken and mixed with different polyols to impart required properties to the oil based polyol. This is just a mixing operation and does not involve any reaction. Chemical reaction: CH3 (CH2)5 CH (OH) CH2 CH = CH (CH2)7 COOH + HO-R1---(-----OOC-R-COOR1 ---)----OH CASTOR OIL POLYESTER RESIN Mol. Wt 934 Mol. Wt 650 CH3 (CH2)5 CH (OH) CH2 CH = CH (CH2)7 COO R1---(-----OOC-R-COOR1 ---)----OH + H2O POLYESTER POLYOLS Mol. Wt Mol. Wt 18 Flow sheet: Castor oil 800 kg Ketonic resin 199 kg Di butyl tin oxide 1 kg Mixing Oil based polyester polyols 1000 kg INPUT = OUTPUT Proposed production capacity Freshwater Consumption Wastewater generation 1500 MT/month NIL NIL Page 11 of 29

81 Project: Proponent: Project site: Documents: Proposed new manufacturing unit for synthetic organic products M/s. Polyols & Polymers Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India Manufacturing Process for proposed project Product-5: Phenol Formaldehyde Resins: (A) Phenol formaldehyde / Alkyl phenol formaldehyde resin - NOVOLACS: Process: Reaction: Process consists of charging Formaldehyde (37%) and Phenol in a reactor provided with a stirrer system and a condenser. After completion of charging the raw materials acid (catalyst) is added and the contents are heated slightly. Reflux & cooling: This is a exothermic reaction and the temperature starts rising slowly. The water in the formaldehyde gets evaporated and is refluxed. After reaction Reactants are cooled by jacket cooling. Distillation: At the end of the reaction, the condenser is set for distillation and the contents of the reactor are heated by passing steam in the reactor jacket. The water is evaporated and condensed and collected in a receiver tank. Melting, Cooling & Packing: When the desired melting point of the resin is obtained the molten resin is discharged in trays. When the molten mass cools down the resin is broken into lumps and packed in bags. Chemical reaction: Page 12 of 29

82 Project: Proponent: Project site: Documents: Proposed new manufacturing unit for synthetic organic products M/s. Polyols & Polymers Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India Manufacturing Process for proposed project Flow sheet: 37%Formaldehyde 672 kg Phenol 970 kg Oxalic acid 20 kg Reaction Reflux 1662 kg Cooling 1662 kg 1662 kg Distillation Distillate mainly water 662 kg sent to ETP 1000 kg Melting & cooling Breaking in lumps & Packing in bags 1000 kg INPUT = OUTPUT Phenolic resin 1000 kg Proposed production capacity 750 MT/month Freshwater Consumption NIL Wastewater generation 496.5KL/month 16.55KL/day Page 13 of 29

83 Project: Proponent: Project site: Documents: Proposed new manufacturing unit for synthetic organic products M/s. Polyols & Polymers Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India Manufacturing Process for proposed project (B) Alkyl phenol formaldehyde resin RESOLE : Process: Reaction: Process consists of Charging Formaldehyde in the reactor followed by PTBP (Para tertiary butyl phenol) and catalyst - caustic soda ( flaks/ lye). After some time the exothermic takes place and the temperature of the reactants rise. Cooling & Neutralization: The temp is maintained within the required temperature range by jacket cooling and the reactants are then maintained at a particular temp range for the required amount of time and the resin formed is checked for completion. At the end of the reaction the contents of the reactor are neutralized by sulphuric acid. Toluene is added to get a solution of the resin and the contents are allowed to settle. Layer separation & Distillation: The water layer is drained and is sent to the ETP. The remaining solution of the resin in toluene is heated to distill out the toluene in a receiver. This toluene can be used in the subsequent batches. Cooling & Packing: When the toluene is almost stipped the molten resin is poured in trays and allowed to cool. After cooling and solidification of the resin, it is broken into small lumps and bagged. Chemical reaction: H 2 2 C6H4OHC(CH3)3 + CH 2 O NaOH (CH3)3C OH C OH C(CH3)3 PARATERTIARY BUTYL PHENOL FORMALDEHYDE + H 2 O (M.Wt.150) (M.Wt.30) R PHENOLIC RESIN [M.Wt. 312) M. Wt. 18 Page 14 of 29

84 Project: Proponent: Project site: Documents: Proposed new manufacturing unit for synthetic organic products M/s. Polyols & Polymers Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India Manufacturing Process for proposed project Flow sheet: Formaldehyde 730 kg p- tertiary butyl phenol 1000 kg NaOH 18 kg Sulphuric acid 30 kg Toluene 100 kg Reaction Cooling Neutralization Layer separation Distillation Cooling 1748 kg 1748 kg 1878 kg 1095 kg 1000 kg 1000 kg Breaking of lumps &Packing in bags Aq. Layer 783 kg sent to ETP Toluene 95 kg recovered & reuse in next batch Phenolic resin 1000 kg INPUT = OUTPUT Proposed production capacity 300 MT/month Freshwater Consumption NIL Wastewater generation KL/month 7.83 KL/day Page 15 of 29

85 Project: Proponent: Project site: Documents: Proposed new manufacturing unit for synthetic organic products M/s. Polyols & Polymers Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India Manufacturing Process for proposed project Product-6 : Polyamide Resins Process: Esterification: Basically this is a Esterification reaction between a dimer acid and di-amine resulting in the formation of a polyester and water of reaction Process consists of charging all the raw materials in a stirred reaction vessel fitted with a condenser. Heating & Distillation: The contents of the reaction vessel is heated and after about couple of hours the acid value and the amine values are checked at periodic intervals till the required acid value and amine value is achieved. The water of reaction is distilled at the high reaction temperature and condensed in the condenser. The distillate consists mainly of water and traces of impurities which is sent to ETP Cooling & Packing: The molten resin is poured in trays and allowed to cool. After cooling and solidification of the resin, it is broken into lumps and packed in bags. Chemical reaction: HOOC-R-COOH + CH 3 -COOH + C 2 H 4 (NH 2 ) 2 HOOC-R-CONHR 1 -NH 2 +H 2 O Dimer acid acetic acid ethylene diamine polyamide resin Water M.Wt.: 560 M.Wt: 60 M.Wt: 60 M. Wt : 662 M. Wt : 18 Where R & R 1 are aliphatic hydrocarbons Page 16 of 29

86 Project: Proponent: Project site: Documents: Proposed new manufacturing unit for synthetic organic products M/s. Polyols & Polymers Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India Manufacturing Process for proposed project (a) Flow sheet for co solvent grade polyamide resins: Dimer acid 850 kg Fatty acid 134 kg Ethylene diamine/ Tri ethylene tetra amine 107 kg Reaction Heating 1091 kg 1091 kg Cooling 1091 kg Distillation Distillate mainly water 91kg sent to ETP Cooling 1000 kg 1000 kg Breaking of lumps & Packing in bags Co solvent grade polyamide resin 1000 kg INPUT = OUTPUT Proposed production capacity 600 MT/month (max.) Freshwater Consumption NIL Wastewater generation 54.6 KL/month 1.82 KL/day Page 17 of 29

87 Project: Proponent: Project site: Documents: Proposed new manufacturing unit for synthetic organic products M/s. Polyols & Polymers Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India Manufacturing Process for proposed project (b) Flow sheet for Alcohol soluble polyamide resins: Dimer acid 816 kg Acetic acid 146 kg Ethylene diamine/ Tri ethylene tetra amine 155 kg Reaction Heating 1117 kg 1117kg Cooling 1117kg Distillation Distillate mainly water 117kg sent to ETP Cooling 1000 kg 1000 kg Breaking of lumps & Packing in bags Alcohol soluble Polyamide resin 1000 kg Proposed production capacity Freshwater Consumption 600 MT/month (max.) NIL INPUT = OUTPUT Wastewater generation 70.2 KL/month 2.34 KL/day Page 18 of 29

88 Project: Proponent: Project site: Documents: Proposed new manufacturing unit for synthetic organic products M/s. Polyols & Polymers Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India Manufacturing Process for proposed project (c) Flow sheet for reactive polyamide resins: Dimer acid 790 kg Soya fatty acid 154 kg Ethylene diamine/ Tri ethylene tetra amine 74kg Reaction Heating 1000 kg 1000 kg Distillation Distillate mainly water 18kg sent to ETP 1000 kg Packing in barrels Reactive Polyamide resin 1000 kg INPUT = OUTPUT Proposed production capacity 600 MT/month (max.) Freshwater Consumption NIL Wastewater generation 10.8 KL/month 0.36 KL/day Page 19 of 29

89 Project: Proponent: Project site: Documents: Proposed new manufacturing unit for synthetic organic products M/s. Polyols & Polymers Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India Manufacturing Process for proposed project Product- 7: Polyester resin saturated / unsaturated / polyester polyols: Process: Basically this is a Esterification reaction between a di acid and diol resulting in the formation of a polyester and water of reaction Reaction: Process consists of charging all the raw materials in a stirred reaction vessel fitted with a condenser. The contents of the reaction vessel is heated and after about couple of hours the acid value is checked at periodic intervals till the required acid value is achieved. Distillation: The water of reaction is distilled at the high reaction temperature and condensed in the condenser. The distillate consists mainly of water and traces of impurities which is sent to ETP & reaming in product is packed in barrels. Chemical reaction: Page 20 of 29

90 Project: Proponent: Project site: Documents: Proposed new manufacturing unit for synthetic organic products M/s. Polyols & Polymers Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India Manufacturing Process for proposed project Flow sheet: Adipic acid 425 kg Hexane diol 690 kg Tri methylol propane 7 kg Isophthalic acid 9 kg Esterification Heating 1131 kg 1131 kg Distillation Distillate mainly water 131 kg Sent to ETP 1000 kg Packing in barrels Polyester polyols 1000 kg INPUT = OUTPUT Proposed production capacity 300 MT/month Freshwater Consumption NIL Wastewater generation 39.3 KL/month 1.31 KL/day Page 21 of 29

91 Project: Proponent: Project site: Documents: Proposed new manufacturing unit for synthetic organic products M/s. Polyols & Polymers Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India Manufacturing Process for proposed project Product-8 : Rosin based Resins & Product no. 9: Turpentine: (A) Modified Phenolic Resin: Process: Rosin based resins are made by basically Esterification process wherein the yield is 90%. The distillate is around 10 % which consists of distilled terpene oil and reaction water. This effluent (distillate) consists of 80% Turpentine is recovered in turpentine recovering system and 20% Effluent is sent to bio treatment plant for treatment. Chemical reaction: ADDITION CH 2 OH CH 2 OH REACTION R-COOH + R-OH + HCHO -OH Ph - CH 2 Ph O - + R-COOH ADDUCT M.wt: 323 M. Wt: 150 M.Wt: 30 ESTERIFICATION WITH PENTAERYTHRYTOL REDUCTION C 5 H 12 O 4 - R1 (OH) 4 R1 = C 5 H 8 C CH2 - Ph - CH2OH R1OOC [ O - Ph - CH2 - Ph ] + 2H 2 O CH2OH MODIFIED PHENOLIC RESIN M.Wt: 467 Water M.Wt : 18 R-COOH -Rosin (Lavopemeric acid) R-OH - Alkyl phenol (alkyl phenol can be para tertiary butyl phenol, nonyl phenol etc here it is PTBP ) HCHO - Formaldehyde Page 22 of 29

92 Project: Proponent: Project site: Documents: Proposed new manufacturing unit for synthetic organic products M/s. Polyols & Polymers Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India Manufacturing Process for proposed project Flow sheet: Pentaerythritol 135 kg Gam rosin 700 kg para tertiary butyl phenol 325 kg p- Formaldehyde 173 kg Reaction Heating Cooling 1333 kg 1000 kg 1000 kg Packing Modified phenolic resin 1000 kg Condensation Layer separation Effluent 266kg sent to ETP INPUT = OUTPUT Turpentine 67 kg Modified phenolic resin proposed production capacity Turpentine Proposed production capacity Freshwater Consumption 600 MT/month 40.2MT/month Wastewater generation 159.6KL/month 5.32 KL/day NIL Page 23 of 29

93 Project: Proponent: Project site: Documents: Proposed new manufacturing unit for synthetic organic products M/s. Polyols & Polymers Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India Manufacturing Process for proposed project (B) Maleic Resin: Chemical reaction: O R-COOH + CH - C - OH CH - C - OH REACTION AT ELEVATED TEMPERATURE O R- CH - C CH - C O ADDUCT OF LAEVOPIMARIC ACID AND FUMARIC ACID O O M.Wt : 323 M.Wt : 125 FUMERIC ACID CH 3 COOH O ESTERIFICATION WITH PENTAERYTHRYTOL REDUCTION C 5 H 12 O 4 - R1 (OH) 4 R1 = C 5 H 8 M.Wt : 136 R1OOC - R- CH - C CH 3 CH - C O + H 2 O R = ABIETIC ACID CH 3 C H O M.Wt : 430 Maleic resin CH 3 Page 24 of 29

94 Project: Proponent: Project site: Documents: Proposed new manufacturing unit for synthetic organic products M/s. Polyols & Polymers Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India Manufacturing Process for proposed project Flow sheet: Pentaerythritol 125 kg Gum rosin 800 kg Fumaric acid 295 kg Reaction Heating Packing 1220 kg 1000 kg Cooling 1000 kg Maleic resin 1000 kg Condensation Layer separation Effluent 176kg sent to ETP INPUT = OUTPUT Turpentine 44 kg Maleic resin proposed production capacity 600 MT/month Turpentine Proposed production capacity 26.4 MT/month Freshwater Consumption NIL Wastewater generation 105.6KL/month 3.52 KL/day Page 25 of 29

95 Project: Proponent: Project site: Documents: Proposed new manufacturing unit for synthetic organic products M/s. Polyols & Polymers Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India Manufacturing Process for proposed project Product-9: styrene Maleic Anhydride Resins: Process: Reaction: Process consists of charging requisite quantities of toluene, styrene, and maleic anhydride along with initiator in the reaction vessel fitted with a stirrer system and reflux condenser. The contents are stirred till a homogenous solution is achieved. Heating & Cooling: The mixture is then heated to the required temperature and stirred for a required time to complete the reaction. At the end of the reaction the contents are cooled to room temp and the SMA co polymer is precipitated. Filtration, Drying & Packing: The copolymer is filtered, dried and is then packed. The filtered toluenes along with the residual monomers are reused in the next batch and necessary adjustments are made for the maleic anhydride and styrene present in the toluene. Chemical reaction: ADDITION POLYMERISATION STYRENE Mol. Wt 104 MALEIC ANHYDRIDE Mol. Wt 98 SMA RESIN Mol. Wt Page 26 of 29

96 Project: Proponent: Project site: Documents: Proposed new manufacturing unit for synthetic organic products M/s. Polyols & Polymers Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India Manufacturing Process for proposed project Flow sheet: Styrene 500 kg Maleic anhydride 550 kg Toluene 1000 kg Reaction Reflux Heating Cooling 2050 kg 2050 kg 2050 kg Filtration Drying 2050kg 1050 kg Filtrate contain toluene 950 kg & 50kg unreacted styrene recovered & reuse in next batch SMA resin 1000 kg INPUT = OUTPUT Proposed production capacity Freshwater Consumption Wastewater generation 300 MT/month NIL NIL Page 27 of 29

97 Project: Proponent: Project site: Documents: Proposed new manufacturing unit for synthetic organic products M/s. Polyols & Polymers Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India Manufacturing Process for proposed project Product-10: Xylene- Formaldehyde Resins: Process: Reaction: In the basic process xylene as a solvent is added, followed by the calculated amount of aqueous formaldehyde solution. Than sulfuric acid is added directly into the lower aqueous phase under smooth agitation. The reaction temperature of the slightly exothermic process is around 100 C. Therefore the quality of formalin solution is important (concentration, amount of methanol). The reaction is carried out under reflux for min. 6h. The reaction temperature is in that time increasing up to 105 C while the formaldehyde get consumed and reacted with Xylene. Layer Separation & Neutralization: After that the aqueous phase is going to be separated, neutralized and disposed. The organic phase has to be neutralized after that with aqueous sodium carbonate solution followed by a phase separation again. Packing: Organic solution is a product & Packing in barrels. Chemical reaction: Xylene + formaldehyde CH3-C6H4-CH3 + HCHO H2SO4 Reflux 7hrs Xylene formaldehyde C9H12O Mol. Wt 106 mol. Wt 30 mol. Wt 136 Page 28 of 29

98 Project: Proponent: Project site: Documents: Proposed new manufacturing unit for synthetic organic products M/s. Polyols & Polymers Plot No. D-2/CH/266, 267 & 268, Dahej II - Industrial estate Village: Jolva, Taluka - Vagra, Dist. Bharuch, State - Gujarat, India Manufacturing Process for proposed project Flow sheet: Sulphuric acid 290 kg Xylene 800kg Formaldehyde (37%) 970 kg Sodium carbonate sol.100 kg Reaction 2060 kg Layer separation 1020kg Neutralization 1120kg Layer separation Sodium carbonate sol.100 kg Neutralization Aqueous layer 1140kg Sent to ETP Aqueous layer 120 kg Sent to ETP Packing 1000kg Xylene- Formaldehyde resin 1000 kg INPUT = OUTPUT Proposed production capacity Freshwater Consumption Wastewater generation 90 MT/month NIL KL/month, 3.78 KL/day Page 29 of 29

99 Sr.No Chemical Name CAS No. Type of Hazard Hazards Toxicological information LD50 (LC50) Flash Point BP Sp Gravity LEL UEL Solubility With Water Incompeteble Material NFPA Hazardous Combustion Products Health Fire Reacti ERPG,ppm ppm degc degc % % H F R vity 1 Butyl Methacrylate Flammable / Toxic Yes yes yes insoluble in cold and hot water reactive with oxidicing agent and reducing agent,acids,alkali. And with moisture Carbon Dioxide Carbon Monoxide 2 Butyl Acetate Flammable Yes yes No Partially soluble in cold water Not Available Carbon Dioxide Carbon Monoxide 3 Ethyl Acetate Flammable Yes yes No 5620 (LC ) open cup 7.2 close cup Soluble in cold and hot water Reactiv with oxidising agents, acid and alkali Carbon Dioxide Carbon Monoxide 4 Formaldehyde 37% Flammable Yes yes No 100 open cup 60 close cup Easily Soluble in hot and cold water reactive with oxidicing agent and reducing agent,acids,alkali Carbon Dioxide Carbon Monoxide 5 Phenol Flammable Yes yes No 270 open cup 85 close cup Soluble in cold water reactive with oxidicing agent, metals, acids,alkali Carbon Dioxide Carbon Monoxide 6 Sulphuric Acid Non Flammable Yes No yes 2140 Not Applicable NA NA Easily Soluble in cold water reactive with oxidicing agent, Reducing agents, Cumbustible material, Organic material, metals, acids,alkali, moisture Not Available 7 Styrene Flammable Yes yes yes 2650 open cup 36.7 close cup Very slightly Soluble in cold water Not Available Carbon Dioxide Carbon Monoxide 8 Xylene Flammable Yes yes No 4300 open cup 37.8 close cup insoluble in cold and hot water Reactive with oxidicing agent, acids Carbon Dioxide Carbon Monoxide 9 Acetic Acid Flammable Yes yes No 3310 open cup 43 close cup Easily Soluble in Hot and cold water Reactive with oxidicing agent, metals, acids,alkali Carbon Dioxide Carbon Monoxide 10 Ethylne Diamine Flammable Yes yes No Easily Soluble in cold water Not Available Carbon Dioxide and nitrogen oxides NO,NO2 Carbon Monoxide 11 Cyclohexanone Flammable Yes yes No 1516 open cup 46 close cup Partially Soluble in Hot and cold water Reactive with oxidicing agent, acids,alkali Carbon Dioxide Carbon Monoxide 12 Toluene Flammable Yes yes No 636 open cup 16 close cup Practically insoluble in water Reactive with oxidicing agent Carbon Dioxide Carbon Monoxide

100 Sr.No Chemical Name CAS No. Type of Hazard Hazards Toxicological information LD50 (LC50) Flash Point BP Sp Gravity LEL UEL Solubility With Water Incompeteble Material NFPA Hazardous Combustion Products Health Fire Reacti ERPG,ppm ppm degc degc % % H F R vity 13 Hydrogen Gas Extreamly Flammable No yes No Not Available No Information Available soluble in water Reactive with oxidicing agent Not Available 14 Acrylonitrile Flammable / Toxic Yes Yes No STEL Very slightly soluble in cold water, hot water incompatible with oxidizing agents, such as metals, acids, alkalis Carbon Dioxide Carbon Monoxide 15 Methyl Ethyl Ketone(MEK) Flammable/To xic Yes Yes No STEL:300ppm Soluble in cold water Reactive with oxidizing agents, metals, acids, alkalis Carbon Oxides ( CO2,CO) 16 IPA (Isopropyl Alcohol) Flammable Yes Yes No NA NA Easily soluble in cold water, hot water, Reactive with oxidizing agents, acids, alkalis Carbon Oxides ( CO2,CO) 17 Ethyl Acrylate Flammable/To xic Yes yes yes TWA 25ppm (1414) Partially soluble in cold water The product may undergo hazardous decomposition, condensation or polymerization, it may react violently with water to emit toxic gases Carbon Oxides ( CO2,CO) 18 Methyl Methacrylate Flammable/To xic Yes yes yes TWA 100 ppm 7872mg/ kg Partially soluble in cold water Reactive with metals, acids, alkalis Carbon Oxides ( CO2,CO) 19 Butanol Flammable Yes yes no NA NA Easily soluble in methanol, diethyl ether. Partially soluble in cold water, hot water, n- octanol Highly reactive with oxidizing agents, reducing agents. Slightly reactive to reactive with organic materials, acids, alkalis Carbon Oxides ( CO2,CO) 20 MIBK Flammble No yes No NA NA Imiscible Avoid oxidizing & reducing agents Carbon Oxides ( CO2,CO)

101 Rapid EIA for Proposed Synthetic Organic Chemicals Manufacturing unit at D-2/CH-266,267,268, Ta. Vagra, Dist. Bharuch Details of Hazardous Chemicals Inventory, hazardous properties Polyols Polymers Sr. No. Full name of the raw material State i.e, solid / Liquid / Gas Inventory B.P. C, M.P. C Fl. P. C LD50 mg/kg or LC50 mg/l Vapour pressure Source As per Haz. Chemicals rules,2000 Consumption No. of No. MT Pressure Temp C MT/Month days kg/cm2 1 Acetic acid L Al or SS Tank - AGT 1 10 Atm C BP C MP 16.6 C 39 LD mg/kg LC kpa@ indigenous Sch-1,part-I(b)-HF & Part-II 5620 mg/l-1h 20 C 2 Acrylic Acid L Drum Atm C BP 141 C MP 14 C 50 LD mg/kg LC kpa@ indigenous Sch-1,part-I(a)-Toxic & Part-II 5300 mg/l- 2h 20 C 3 Acryl amide S MT Jumbo bag Atm C BP 125 C MP 84.5 C 138 LD mg/kg NA indigenous Sch-1,part-I(a)-Toxic & Part-II 4 acrylonitrile L CS Tank - AGT Atm C BP 77.3 C MP -82 C LD50-78 mg/kg LC kpa@ indigenous Sch-1,part-I(b)-VHF 5 Benzoyl peroxide S kg bag Atm C BP 103 C MP C NA 333 LD50- mg/l-4h 7710 mg/kg 20 C NA indigenous Sc-I, part-ii 6 Bisphenol-A S MT Jumbo bag Atm C BP 220 C MP C 227 LD mg/kg NA indigenous Sc-I, part-ii LC mg/l-6h 7 Butanol L CS or SS Tank - AGT 1 10 Atm C BP C MP LD mg/kg 0.6 kpa@ 20 C indigenous Sch-1,part-I(b)-HF 8 Butyl acetate L CS or SS Tank - AGT Equipment consider No. of container & Size at site MAH threshold qty.mt Storage Parameters 1 10 Atm C BP 126.5, MP LD mg/kg 1.3 kpa@ 20 C indigenous Sch-1,part-I(b)-HF 9 butyl acrylate L Drum Atm C BP 145 C MP C 29 LD mg/kg 0.5 kpa@ indigenous Sch-1,part-I(b)-HF 10 Butyl methacrylate L Drum Atm C BP 160 C MP -75 C 52.2 LD LC mg/kg mg/l-4h C kpa@ indigenous Sch-1,part-I(b)-HF 10 Caustic soda flakes S Jambo Bag Atm C BP 1388 C MP 323 C NA NA 20 C NA indigenous Sc-I, part-ii 11 Cyclohexanone L CS or SS Tank Atm C BP C MP -31 C LD mg/kg 0.7 imported / indigenous Sch-1,part-I(b)-HF AGT 26.7 C 12 Di butyl tinoxide S Drum Atm C MP >300 C NA oral-ld mg/kg NA indigenous Sch-1,part-I(a)-highly Toxic 13 Ethyl acetate L Drum 10 2 Atm C BP 77 C, MP -83 C -4.4 LD mg/kg, LC kpa@ indigenous Sch-1,part-I(b)-VHF, Sc-I, part-ii mg/l -6h 20 C 14 ethyl acrylate L CS or SS Tank Atm C BP 99.4 C MP -72 C -2 LD mg/kg 29 mm Hg indigenous Sch-1,part-I(b)-VHF AGT LC C 15 Ethyl methacrylate L Drum Atm C BP C MP -60 C 19 LD mg/kg indigenous Sc-I,part-I(b)-VHFpart-II LC ppm-4h 20 C 16 Ethylene Diamine L 93 3 Drum Atm C BP C MP 8.5 C 34 LD mg/kg, LC mm Hg indigenous Sch-1,part-I(b)-HF, Sc-I, part-ii C 17 ethylene glycol L Drum Atm C BP C MP -13 C 111 LD mg/kg 6 mm indigenous Sc-I, part-ii LC mg/m-4h 20 C 18 Formaldehyde (37%) L CS or SS Tank Atm C BP 98 C MP -15 C 50 LD mg/kg, 20 C indigenous Sch-1,part-I(b)-HF, Sc-I, part-ii AGT mg/l -4h 19 Hydrogen gas G Cylinder C BP C MP -259 C NA NA NA indigenous Sc-I, part-ii 20 Iso Propyl Alcohol L CS or SS Tank Atm C BP 82.5 C MP C 11.7 LD mg/kg 4.4 kpa@ indigenous Sc-I, part-ii AGT 20 C 21 methacrylic acid L Drum Atm C BP 163 C MP 16 C 77 LD mg/kg mm indigenous Sch-1,part-I(b)-F 20 C 22 methyl acrylate L Drum Atm C BP 80.5 C MP C LD mg/kg NA indigenous Sch-1,part-I(b)-VHF 23 methyl cyclohexanone L Drum Atm C BP C MP C 48 LD mg/kg imported / indigenous Sch-1,part-I(b)-HF 20 C 24 Methyl Ethyl Ketone L CS Tank - AGT 1 10 Atm C BP 79.6 C, MP -86 C -9 LD mg/kg, LC kpa@ imported / indigenous Sch-1,part-I(b)-VHF mg/m -8h 20 C 25 methyl isobutyl ketone L CS Tank - AGT 1 20 Atm C BP C MP -84 C 14 LD mg/kg 15.7 mm Hg imported / indigenous Sch-1,part-I(b)-VHF LC C 26 Methyl methacrylate L CS or SS Tank Atm C BP 100 C MP -48 C 13 LD mg/kg LC50-29 mm Hg indigenous Sch-1,part-I(b)-VHF, Sc-I, part-ii AGT C 27 Paraformaldehyde S Jambo Bag Atm C MP C 70 LD mg/kg, LC50- NA imported / indigenous Sch-1,part-I(b)-F 1070 mg/m-4h 28 Phenol L CS Tank - AGT 1 40 Atm C BP 182 C, MP 42 C 79 LD 50-dermal- 630 mg/kg NA imported Sch-1,part-I(a)- Toxic, Sch-1,part-I(b)-F, Sc-I, part-ii 29 Poly Vinyl Alcohol S kg bag Atm C MP 200 C 79 LD50->20000 mg/kg NA indigenous Sch-1,part-I(b)-F 30 propylene glycol L Drum Atm C BP 188 C MP -59 C 99 LD mg/kg 0 kpa@ indigenous Sc-I, part-ii 20 C 31 Styrene L CS Tank - AGT 2 40 cool C BP C MP C 31.1 LD mg/kg, 4.5 mm Hg imported/ indigenous Sch-1,part-I(b)-HF, Sc-I, part-ii LC C 32 Sulphuric acid L CS Tank - AGT 1 10 Atm C BP C, MP -35 C NA LD mg/kg, NA indigenous Corrosive,Sc-I, part-ii LC50-510mg/m -2h 33 Toluene L CS Tank -UGT 2 40 Atm C BP C, MP -95 C 4.44 LD mg/kg, LC indigenous Sch-1,part-I(b)-VHF, Sc-I, part-ii mg/m-4h 25 C 34 Xylene L CS Tank -UGT 1 20 Atm C BP C MP C 24 LD mg/kg 0.9 kpa@ indigenous Sch-1,part-I(b)-HF, Sc-I, part-ii 20 C 35 Terpentine-Product L 67 9 CS Tank -AGT 1 20 Atm C BP 165 C 35 LD mg/kg AGT - Aboveground Tank UGT - Underground tank HF - Highly flammable VHF - Very Highly flammable

102 EIA & EMP and Risk Assessment & DMP report For proposed unit of Polyols & Polymer. at Plot No. D-2/CH/266,267 & 268, Dahej-II, Notified Industrial Estate, Jolva, Ta: Vagra,Dist - Bharuch, State Gujarat, India SAMPLING AND ANALYTICAL METHODS ADOPTED FLOW CHART FOR MEASUREMENT OF SULPHUR DIOXIDE Place 30 ml of absorbing media in an impinge Connect it to the gas-sampling manifold of gas sampling device (RDS/HVS). Draw air at a sampling rate of 1 lpm for four hours Check the volume of sample at the end of sampling and record it Transfer the exposed samples in storage bottle and preserve Prepare calibration graph as recommended in method Take 10/20 ml. aliquot of sample in 25 ml. Vol. Flask Take 10/20 ml. of unexposed sample in 25 ml. Vol. Flask (blank) Add 1 ml Sulphamic acid. Keep it 10 minutes Add 2 ml formaldehyde Add 2 ml working PRA Make up to mark (25 ml.) with distilled water. Keep it 30 minutes for reaction Set Zero of spectrophotometer with Distilled water Measure absorbance at 560 nm Calculate concentration using calibration graph Calculate concentration of Sulphur Dioxide in μg/m3 FLOW CHART FOR MEASUREMENT OF NITROGEN DIOXIDE Place 30 ml of absorbing media in an impinge Connect it to the gas sampling manifold of gas sampling device (RDS/HVS). Draw air at a sampling rate of 1 lpm for four hours Check the volume of sample at the end of sampling and record it Transfer the exposed samples in storage bottle and preserve Prepare calibration graph as recommended in method Take 10 ml. aliquot of sample in 50 ml. Vol. Flask Page 1 of 7

103 EIA & EMP and Risk Assessment & DMP report For proposed unit of Polyols & Polymer. at Plot No. D-2/CH/266,267 & 268, Dahej-II, Notified Industrial Estate, Jolva, Ta: Vagra,Dist - Bharuch, State Gujarat, India SAMPLING AND ANALYTICAL METHODS ADOPTED Take 10 ml. of unexposed sample in 50 ml. Vol. Flask (blank) Add 1 ml hydrogen peroxide, Add 10 ml sulphanilamide Add 1.4 ml NEDA Make up to mark (50 ml.) with distilled water. Keep it 10 minutes for reaction Set Zero of spectrophotometer with Distilled water Measure absorbance at 540 nm Calculate concentration using calibration graph Calculate concentration of Nitrogen Dioxide in μg/m3 FLOW CHART FOR MEASUREMENT OF PM 10 Check the filter for any physical damages Mark identification number on the filter Condition the filter in conditioning room / desiccator for 24 hours Record initial weight Place the filter on the sampler Run the sampler for eight hours Record the flow rate on hourly basis Remove the filter from the sampler Keep the exposed filter in a proper container Record the total time of sampling & average flow rate Again condition the filter in conditioning room / desiccator for 24 hours Record final weight Calculate the concentration of PM10 in μg/m3 Page 2 of 7

104 EIA & EMP and Risk Assessment & DMP report For proposed unit of Polyols & Polymer. at Plot No. D-2/CH/266,267 & 268, Dahej-II, Notified Industrial Estate, Jolva, Ta: Vagra,Dist - Bharuch, State Gujarat, India SAMPLING AND ANALYTICAL METHODS ADOPTED FLOW CHART FOR MEASUREMENT OF PM2.5 Check the filter for any physical damages Mark identification number on the filter Condition the filter in conditioning room / desiccator for 24 hours Record initial weight Place the filter on the sampler Run the sampler for eight hours Record the flow rate on hourly basis Remove the filter from the sampler Keep the exposed filter in a proper container Record the total time of sampling & average flow rate Again condition the filter in conditioning room / desiccator for 24 hours Record final weight Calculate the concentration of PM2.5 in μg/m3 FLOW CHART FOR MEASUREMENT OF BENZO(A)PYRENE EPM 2000 filter paper Ultrasonic extraction with Toluene (50 ml 3 times) Filter & dry with Anhydrous Sodium Sulphate Concentration with Rotary Evaporator Clean up with Silica Gel Column Chromatography Elution with Cyclo-Hexane (5 ml 3 times) Evaporate to nearly dryness under Nitrogen Re-dissolved in 0.5 to 1.0 ml Toluene Capillary GC-FID or GC-MS Re-dissolved in 2.5 ml Methanol HPLC/UV-Fluorescence Detector Page 3 of 7

105 EIA & EMP and Risk Assessment & DMP report For proposed unit of Polyols & Polymer. at Plot No. D-2/CH/266,267 & 268, Dahej-II, Notified Industrial Estate, Jolva, Ta: Vagra,Dist - Bharuch, State Gujarat, India SAMPLING AND ANALYTICAL METHODS ADOPTED Analysis of Ground water and surface waters Sr. No. Test Test Method 1 TemperatureºC APHA 21 st ed. 2550B 2 Colour Pt Co Colour units APHA 21 st ed. 2120B Visual Comparison 3 Odour APHA 21 st ed. 2150B Thresold odour 4 Turbidity IS 3025 (Part 10) 1984 reaffirmed 2002 Nephlometric 5 Total Solids A PHA 21 st ed B TS dried at c 6 Total Dissolved Solids APHA 21 st ed. 2540C TDS dried at 180 c 7 Total Suspended Solids APHA 21 st ed. 2540D TSS dried at c 8 Dissolved Oxygen IS 3025 (part 38) : 1989 reaffirmed Azide Modification 9 Biochemical Oxygen Demand 3-days BOD test(is mg/l 3025(part44)1993 Reaffirmed 1999) 10 Chemical Oxygen Demand IS method Open Reflux 11 PH Value IS:3025 (Part-11) Alkalinity IS Part ) 13 Acidity IS Part ) 14 Ammonical Nitrogen APHA 21 st ed NH3 C Titration 15 Total Kjedhal Nitrogen APHA 21 st ed N org B Macro-kjedhal method 16 Nitrates IS 3025 (Part 34) : 1988 Devada s alloy reduction 17 Phosphates APHA 21 st ed. 4500C vanadomolybdophosphoric acid 18 Sulphates APHA 21 st ed. 4500E Turbidimetric 19 Chlorides APHA 21 st ed. 4500B Argentometric 20 Residual Chlorine APHA 21 st ed. 4500B Iodometric 21 Silica APHA 21 st ed. 4500C Molybdo silicate 22 Calcium APHA 21 st ed Ca B EDTA Titrametric 23 Magnesium APHA 21 st ed Mg B calculation method 24 Hardness APHA 21 st ed. 2340C EDTA Titrimetric 25 Sodium APHA 21 st ed Na B Flame Emission Photometric 26 Potassium APHA 21 st ed K BFlame Emission Photometric 27 Iron IS 3025 (part 53) 2003 Phenanthroline method 28 Sulphide APHA 21 st ed. 4500S2- F Iodometric method 29 Flourides APHA 21 st ed. 4500F-D SPADNS method 30 Manganese (as Mn) APHA 21 st ed Mn AAS 31 Lead (as Pb) APHA 21 st ed pb AAS 32 Zinc(as Zn) APHA 21 st ed Zn- AAS 33 Chromium(as Cr) APHA 21 st ed Cr- AAS 34 Hexavalent Chromium(as Cr+6) APHA 21 st ed Cr-B - colorimetric 35 Copper(as Cu) APHA 21 st ed Cu-B-Neocuproine Method 36 Arsenic( as As) APHA 21 st ed As-AAS 37 Mercury (as Hg) APHA 21 st ed Hg-cold vapour AAS 38 Cadmium(as Cd) APHA 21 st ed Cd-AAS 39 Nickel APHA 21 st ed Ni-AAS 40 Oil & Grease IS 3025 (Part 39) : 1991 liq-liq Partition Gravimetric 41 Phenolic Compounds APHA 21 st ed D Direct photometric 42 Microbiological Analysis (Total bacterial count, MPN/100ml, E.coli, Coliform,) APHA 21 st ed Microbiological Examination 43 Biological analysis (Benthos and plankton) APHA 21 st ed Microbiological Examination Page 4 of 7

106 EIA & EMP and Risk Assessment & DMP report For proposed unit of Polyols & Polymer. at Plot No. D-2/CH/266,267 & 268, Dahej-II, Notified Industrial Estate, Jolva, Ta: Vagra,Dist - Bharuch, State Gujarat, India SAMPLING AND ANALYTICAL METHODS ADOPTED METHOD EMPLOYED FOR FLORAL DOCUMENTATION: A road survey in all the accessible areas and in addition on foot surveys were conducted to document the flora. The local floral was identified by visual cues, such as its size and shape, morphology of the leaf and stem, phenology, flowering and fruiting status and with all these characters the flora was classified broadly into five categories Trees, Shrubs, Herbs, Climber and Aquatic Plants or Hydrophytes. The plants that were not identified were collected, brought to the laboratory and identified using standard herbarium references. Photo documentation of some of the key species present in the study area was also done. METHODS EMPLOYED FOR FAUNAL DOCUMENTATION: Terrestrial Fauna: The major terrestrial fauna in the area consisted of higher invertebrates and vertebrates. These groups were identified and mainly documented through Visual Encounter Method. Minor combing operations were done at some of the sites for documenting the fauna which otherwise remains concealed with the environment and could be missed out. The combing process included upturning of stones, small rocks, fallen logs, boulders and disturbing small shrubs and sweeping of leaf litter. Indirect evidences were used as cues for documenting mammalian fauna. Secondary data for the entire region was procured from Environment Information Centre (A centre with MoEF) and the same was validated through ground reality. For validating the secondary data coloured pictures of animals were shown to the villagers and their presence in the area was confirmed. Wherever possible, photo documentation was done using Digital Camera of sufficiently high resolution. The methodology adopted for faunal survey involved : Random survey, Opportunistic observations, Diurnal bird observation, active search for reptiles, faunal habitat assessment, active search for scats and foot prints and review of previous studies, Desktop literature review was conducted to indentify the representative spectrum of threatened species, population and ecological communities. METHODS FOR DOCUMENTATION OF MICRO BIOTA A) Collection of Plankton: Samples were collected from the sampling sites considering the tidal cycle (during high tide) and weather condition. Sampling of planktons was done by filtering 1 liter of water through plankton (bag) net of pore size 70µm for phytoplankton and 200µm for zooplankton (Figure 2). A sieve was used on top of the bag net during filtration to separate out debris and excess silt. The residue left in both the nets after filtration was then carefully washed with distilled water and collectively conditioned in plastic containers with inert cap liners. Figure 2: Standard Plankton Net with attached Collection Bottle Page 5 of 7

107 EIA & EMP and Risk Assessment & DMP report For proposed unit of Polyols & Polymer. at Plot No. D-2/CH/266,267 & 268, Dahej-II, Notified Industrial Estate, Jolva, Ta: Vagra,Dist - Bharuch, State Gujarat, India SAMPLING AND ANALYTICAL METHODS ADOPTED The samples were fixed in 2% Formaldehyde and Lugol s Solution (0.3%) for 5 days. 10ml of this fixed sample was then centrifuged at 1500 rpm for 10 minutes. Supernatant was discarded and the concentrated sample was taken for further microscopic observations. 0.5 ml of the sample was taken on Sedgwick Rafter Counting Cell (Figure 3) and plankton number was counted. The identification was done using a Stereo-microscope under 45X or 100X magnification. The planktons were then compared with the descriptive and/or photographic identification keys given by Desikachary, 1959; Prescott, 1959; Sournia, 1974; Boltovskoy, 1981; Matsumura Tundisi, 1986; Round et al., 1990; Santhanam, 1993 etc. The plankton were identified as much possible up to species level. Figure 3: Sedgwick Rafter Counter for counting the Plankton B) Collection of Benthos: The benthic fauna can be broadly grouped into two categories namely micro-benthos and macro-benthos. Sampling of macro-benthos involved sampling of a portion of the sediment, from which the macro-invertebrates as well as the vertebrates could be separated. Grabs or Dredges of various types are employed for this purpose. However, in the current study Ekman Dredge, one of the simple dredge was been used extensively (Figure 4). It is been reported that this dredge might not work accurately in some specific situations, e.g., for accurate investigation of the sediment microlayer. The Liebman Core Sampler is suitable for hard bottom but as the substratum here was muddy Ekman Dredge served the purpose. As the study area essentially included coastal wetland, samples were collected from the coast as shown in figure 1, and were analyzed for their benthic fauna. A total of 3 stations were selected for the sampling, i.e. upstream, midstream and downstream of the entire focal study area. Three samples were collected from each of site and the distance between each sample was 500 m or more. Page 6 of 7

108 EIA & EMP and Risk Assessment & DMP report For proposed unit of Polyols & Polymer. at Plot No. D-2/CH/266,267 & 268, Dahej-II, Notified Industrial Estate, Jolva, Ta: Vagra,Dist - Bharuch, State Gujarat, India SAMPLING AND ANALYTICAL METHODS ADOPTED Figure 4: Ekman Dredge used for sampling Benthic Fauna C) Handling and Preservation: The samples were first sieved and then washed from the sediment. From this, the samples were transferred along with some water to a coarse sieve with a mesh size of 0.5 to 0.6 mm and a fine one with a mesh width of less than 0.2 mm, one over the other. Sieving yields a residue mixture of animals and sediment. The organisms were either hand-picked or picked using forceps from this mixture. After sorting, macro-invertebrates were identified to the lowest practical identification level (LPIL) which in most cases was to the species level unless the organism was a juvenile, damaged, or otherwise unidentifiable. Macro-invertebrates were preserved in 10% formalin. Use of 70% Ethyl Alcohol solution is recommended if organisms are having calcareous shells or exoskeleton. D) Identification: Identification of the organisms was done using a stereo-microscope. Pennak (1978), Tonapi (1980) Ward and Whipple (1992) and other monographs were used as standard reference as identification manuals. Page 7 of 7

109 Guidelines issued by GPCB for coal handling units and proposed compliance actions by proponent Polyols & Polymers for coal handling at proposed new unit at D-II, Ta. Vagra, Dist. Bharuch, Gujarat, India. GUIDE LINES FOR COAL HANDLING UNITS:- Guideline (A) Location criteria: 1. Coal handling unit/agency shall not use any agriculture land and shall be located at a minimum distance of 250 meters away from the surrounding agriculture land. 2. Government waste land not suitable for any agriculture purpose meeting with the requisite siting / distance criteria shall be preferred for establishing coal handling units. 3. Coal handling unit/agency shall be minimum 500 meters away from the residential area, school/colleges, Historical Monuments, Religious Places, Ecological sensitive area as well as forests area. 4. Coal handling unit/agency shall be located at a minimum 500 meters away from the Railway line, Express ways, National Highways, State ways and District Roads and from water bodies like River, Nala, Canal, Pond etc. 5. In case of coal handling activities at the ports and jetties or extension thereof, the distance and land use criteria may be relaxed and compensated by advanced/sophisticated pollution control measures and mechanization & thick plantation, however all such ports and jetties, where coal handling is carried out, shall provide closed conveyor belt and mechanization for handling of coal. (B) Storage and handling criteria: 6. Coal handling unit/agency shall store coal in such a way that coal heap should not be higher than 5 meter and clear distance between two adjoining heaps at G.L. should be 5 meters, so that in case of fire, approach is available. 7. There should be mechanized loading/ unloading system from the loading /unloading area to the stacking yards and in to the vehicles. 8. Coal handling unit/agency shall take all corrective steps to resolve the issue of air pollution at permitted coal storage/handling area where coal is being stored. (C) Transport criteria: 9. Coal handling unit/agency shall ensure that all trucks before leaving the storage yard shall be showered with water with adequate system, Shall be covered with tarpaulin or any other effective measure/device completely and also that trucks are not over loaded as well as there is no spillage during transportation. 10. The vehicle carrying the coal should not be overloaded by raising the height of carriage. Weigh scale shall be provided within the loading area only and port / coal park authority shall ensure that no overloading is done. 11. The top of the vehicle should be covered with fixed cover instead of tarpaulin cover to avoid spillage or dusting of coal. 12. Coal handling unit/agency shall obtain transport permission from the local Administration under the relevant rules. (D) Pollution prevention criteria: Proposed action Complied, plot land is acquired by GIDC Complied, plot land is acquired by GIDC Complied, plot is > 500 m away from residential area, school/colleges, Historical Monuments, Religious Places, Ecological sensitive area as well as forests area. Complied, plot is > 500 m away from Railway line, Express ways, National Highways, State ways and District Roads and from water bodies like River, Nala, Canal, Pond etc. Not applicable Shall be complied Shall be complied Shall be complied Shall be complied Shall be complied Shall be complied Transport permission shall be obtained from local administration after grant of EC Page 1 of 3

110 Guidelines issued by GPCB for coal handling units and proposed compliance actions by proponent Polyols & Polymers for coal handling at proposed new unit at D-II, Ta. Vagra, Dist. Bharuch, Gujarat, India. Guideline 13. Coal handling unit/agency shall provide paved approach with adequate traffic carrying capacity. 14. Coal handling unit/agency shall construct compound wall all along periphery of the premises with minimum 9 meters height. 15. Continuous water sprinkling shall be carried out on the top of the heap at regular intervals to prevent dusting, fire & smoke. To prevent fugitive emission during loading/unloading, fixed pipe network with sufficient water storage and pump shall be installed. Water sprinkling shall be carried out at each and every stage of handling to avoid generation of coal, dust or other dust within premises. 16. Coal handling unit/agency shall ensure regular sweeping of coal, dust from internal and main road and also ensure that there is adequate space for free movement of vehicles. 17. The following adequate Air Pollution Control Measures shall be installed and to be operated efficiently. (a) Dust containment cum suppression system for the coal stack, loading and unloading. (b) Construction of effective wind breaking wall suitable to local condition to prevent the suspension of particles from the heaps. (c) Construction of metal road & RCC Pucca flooring in the plot area/ godown etc. (d) System for regular cleaning and wetting of the floor area within the premises. (e) Entire coal storage area/ godown should be covered with permanent weather shed roofing and side walls i.e., in closed shed, in case of crushing/sieving/grading activity is carried out (i.e. G. I. Sh eet) along with adequate additional APCM should be installed. 18. Coal handling unit/agency shall carryout three rows plantation with tall growing tress all along the periphery of the coal handling premises, inside & outside of the premises along with road. 19. Proper drainage system shall be provided in all coal storage area so that water drained from sprinkling & runoff is collected at a common tank and can be reused after screening through the coal slit or any other effective treatment system. 20. All the engineering control measures and state of art technology including covered conveyer belts, mechanized loading and unloading, provision of silo etc. shall be provided in addition to the measures recommended in the environmental guidelines for curbing the pollution. (E) Safety requirement: 21. Coal handling unit/agency shall provide adequate fire fighting measure to avoid any fire or related hazards including adequate water storage facility, and the premises shall be exclusively used for storage of the coal. 22. An onsite emergency plan shall be prepared and implemented by coal handling unit. Page 2 of 3 Proposed action 10 m wide internal paved road shall be provided for access to coal storage yard Shall be complied Shall be complied Regular cleaning of floor area with wet mopping or vacuum cleaning shall be done There is no coal crushing or pulverizing involved, hence dust containment and suppression system shall not be required. Shall be provided as and where required. All internal roads and passages shall be RCC pucca flooring Regular cleaning of floor area with wet mopping or vacuum cleaning shall be done Coal storage area shall be adequately covered No mechanical crushing involved. Garland drains shall be provided around the coal storage area and water collected out of sprinkling shall be reused after removal of coal silt. Shall be provided as per requirement Fire hydrant system and fire extinguishers shall be provided at the coal storage area Onsite emergency plan shall be prepared, hazards at coal storage area and handling areas shall be included.

111 Guidelines issued by GPCB for coal handling units and proposed compliance actions by proponent Polyols & Polymers for coal handling at proposed new unit at D-II, Ta. Vagra, Dist. Bharuch, Gujarat, India. Guideline (F) Legal criteria: 23. Necessary permission from all the applicable regulatory authorities and adequate steps under the provisions of applicable environmental acts/ rules shall be taken. 24. Coal handling unit/agency shall prepare EMP (Environment Management Plan) and implement the same in true spirit and thus maintain overall environment of that area. 25. Coal handling unit/agency shall not carry out the operation of loading/unloading of coal/coal dust at any place, till adequate air pollution control equipment for dust control/suppression are installed and efficiently operated and the consent under the provisions of Air (Prevention & Control of Pollution) Act, 1981 is obtained by the coal yard owners/ Coal handling unit/agency / coal importers. 26. Coal handling unit/agency shall operate continuous Ambient Air Quality Monitoring Stations as per CPCB guideline. The results of parameters like SPM, RSPM, and SO 2 and NO x shall be submitted to the SPCB every month. 27. In case of port which provides the facility to individual developers an agreement /MoU shall be made between port authority and developer for curtailment of pollution. Port authority shall be responsible for supervising and controlling the pollution control related activities and implementation of the environmental guidelines. 28. The concentration of the following parameters in the ambient air within the premises and a distance of 10 meters from the source (other than the stack/vent) shall not exceed the following levels. Proposed action Shall be complied EMP for entire unit shall be prepared and implemented Shall be complied Shall be complied Not applicable Shall be complied PARAMETERS Particulate Matter- 10 (PM 10 ) Particulate Matter- 2.5 (PM 2.5 ) PERMISSIBLE LIMIT 24 Hrs Annual Average Microgram/M 3 Microgram/M Microgram/M 3 Microgram/M 3 SO 2 50 Microgram/M 3 80 Microgram/M 3 NO x 40 Microgram/M 3 80 Microgram/M 3 Page 3 of 3

112 EIA activities carried out by Associate FAEs and team members involved in the EIA for Proposed project of Synthetic Organic Chemicals Unit of Polyols & Polymers at D-2/CH-266,267,268, Dahej Pjase II, Ta. Vagra, Dist. Bharuch, Gujarat State, India Functional Area AP Associate FAE :- 1. Ms. Bhumika Bhuva Designation : Environment Engineer Individual activities carried out :- Preparation of study area maps Prepare monitoring calendar for AAQM Co-ordination with team members Record keeping Compilation of baseline AAQM monitoring results in tabular and graphical formats Procurement of meteorological data of nearest station of IMD and compiling the statistics. Compilation of hourly meteorological data of weather monitoring station (primary baseline monitoring of site specific meteorology) Generating windrose plots Collecting all technical details related to stack emissions :-sources, pollutants, stack details, details of APCD Project Data Collection Secondary data procurement Verify completeness and correctness of information obtained from proponent Data collection for Alternative Analysis Filling up of salient features table and comparing with siting guidelines of MoEF Under guidance of FAE :- Identification of impacting activities of project w.r.t air pollution. Identifying other sources of air pollution by studying each project activity at each phase Prediction of impacts and scoring in impact-activity matrices fugitive emission estimation on TANKS software Post project monitoring plan for AP management Assistance in report preparation Team members :- 1. Mr. Vikram Gohil Designation :- Field Supervisor & Lab Chemist Baseline monitoring :- Survey work for baseline sampling and monitoring. GPS measurements and photography of sampling sites. Selecting Air quality monitoring stations, networking, scheduling, supervising equipment installation and sampling, recording analysis results and evaluating baseline status. Co-ordinating with client for monitoring schedules and visits Supervising equipment installations and arranging for necessary field support and supplies guiding monitoring teams troubleshooting while monitoring and sampling Supervising sample storage and transport procedures Inhouse lab analysis and compilation of analytical data Verification of sampling results and assessment of baseline status Collecting all technical details related to stack emissions :-sources, pollutants, stack details, details of scrubber systems already installed and operational. 2. Mrs. Femida Kundawala Designation : Environment Engineer Preparation of study area maps Prepare monitoring calender. Compilation of baseline AAQM monitoring results in tabular and graphical formats Estimating the emission loads from material balance and reactions Calculation flue gas emission factors Siddhi Green Excellence Pvt. Ltd., Ankleshwar Page 1 of 5

113 EIA activities carried out by Associate FAEs and team members involved in the EIA for Proposed project of Synthetic Organic Chemicals Unit of Polyols & Polymers at D-2/CH-266,267,268, Dahej Pjase II, Ta. Vagra, Dist. Bharuch, Gujarat State, India Functional Area WP Associate FAE :- 1. Mrs. Khushbu Patel Designation : Environment Engineer Individual activities carried out :- Preparation of study area maps Co-ordination with team members Record keeping Collection of analytical data for SW and GW analysis and compilation in tabular format for data review, authentication and verification Conducting ion balancing for SW and GW samples Collecting secondary baseline data from Govt. publications and websites and compilation of the same for comparison Final drafting of GW and SW baseline results Carrying out Water balance calculations for process and utilities and assessment of effluent generation sources, quantification of effluent streams Identifying and segregating the effluent streams Identification of impacting activities of project w.r.t water pollution. Prediction of impacts and scoring in impact-activity matrices Estimating the rainwater harvesting potential Assist in report preparation Under guidance of FAE Estimation of boiler blowdown Hydraulic calculations for capacity rating of proposed ETP unit Suggestions for water conservation measures 2. Mrs. Femida Kundawala Designation : Environment Engineer Under guidance of FAE :- Preparation of study area maps Collecting secondary baseline data from Govt. publications & comparison of primary data with secondary data. Carrying out Water balance calculations for process and utilities and assessment of effluent generation sources, quantification of effluent streams Identifying and segregating the effluent streams Hydraulic calculations for capacity rating of proposed ETP units Team Members 1. Mr. Vikram Gohil Designation : Field Supervisor and Lab Chemist - Survey work & field visit for baseline sampling for SW & GW. GPS measurements and photography of sampling sites. - Sampling preparation work - guiding monitoring teams - troubleshooting while sampling - Inhouse lab analysis - Verification of analytical data for authenticity, completeness, relevance and accuracy - Identify impacting activities and their significance through impact matrices - Review proposed treatment scheme for adequacy based on treatability results and make suggestions - Review adequacy of contingency storage proposed - Prediction of impacts and assessment of required mitigation measures and finalization - Propose Post-project environment monitoring plan w.r.t WP - Identification and prediction of construction phase impacts on water and proposed mitigation measures - Suggest additional mitigative measures if required 2. Dr. Vinod B. Gaur Designation : Laboratory Manager - Guide for Laboratory preparations for surfacewater and ground water sampling, collection, preservation and transport etc. - Conduct QC/QA procedures for checking errors and flaws - Execute instrument calibration procedures and intermediate checks - Supervise analytical work and record-keeping - Participate in review of results and interpretation - Participate in preparation of Post project monitoring plan 3. Ms. Neha H. Solanki Designation : Lab Chemist Individual activities Selection of parameters for Environmental Analysis of baseline survey samples of GW, SW, marine samples, soil etc. Siddhi Green Excellence Pvt. Ltd., Ankleshwar Page 2 of 5

114 EIA activities carried out by Associate FAEs and team members involved in the EIA for Proposed project of Synthetic Organic Chemicals Unit of Polyols & Polymers at D-2/CH-266,267,268, Dahej Pjase II, Ta. Vagra, Dist. Bharuch, Gujarat State, India Analysis of samples of GW, SW, marine samples, soil etc. Calibration and intermediate check of instruments Under guidance of FAE :- - QA/QC activities as per QMS and SOPs - Participate in data interpretation for SW and GW baseline results and conclusion FA - Hazardous Wastes Management Associated FAE :- 1. Ms. Bhumika Bhuva Designation : Environment Engineer Individual activities Site Visit and study area visit Identification of project activities Identification of impacts from project activities Evaluating the types of solid wastes to be generated from each project activity during each phase of the project. Quantifying the industrial wastes generated from material balance. Categorization of industrial wastes as per HW rules Determining the segregation of the wastes, method of collection and disposal of each waste in compliance with the applicable HW rules. Collecting status of common TSDF and incineration facilities proposed for disposal. Details of management of the hazardous wastes to be generated from the project stating detail of storage area for each type of waste, its handling, its utilization and disposal etc. Collecting information on proposed methodology of de-contamination and disposal of discarded containers and its record keeping and assessing its suitability and feasibility as well as effectiveness Impact assessment of waste generation during construction phase. Assess measures proposed for hazardous waste management, quantity generated, storage facilities, treatment facilities Assess disposal methods proposed are in compliance with applicable rules and whether the receiving bodies have the capacity to accept the wastes Impact assessment of waste generation during commissioning & operation phase. Under guidance of FAE :- EMP for construction phase under FAE guidance. Measures for waste minimization Possibilities of co-processing of incinerable wastes Management of non-hazardous wastes Assigning scores in impact activity matrices under guidance of FAE. Assist in Report preparation. EMP for commissioning & operation phase. 2. Mrs. Femida Kundawala Designation : Environment Engineer Under guidance of FAE :- Identification of project activities Identification of impacts from project activities Evaluating the types of solid wastes to be generated from each project activity during each phase of the project. Quantifying the industrial wastes generated from material balance. Categorization of industrial wastes as per HW rules Determining the segregation of the wastes, method of collection and disposal of each waste in compliance with the applicable HW rules. Details of management of the hazardous wastes to be generated from the project stating detail of storage area for each type of waste, its handling, its utilization and disposal etc. Assigning scores in impact activity matrices under guidance of FAE. Assist in Report preparation. FA SE Associated FAE :- 1. Mr. MahendraSinh K. Rathod Designation : Executive Socio economic studies(proposed FAE for SE) Primary data collection for socio economic survey within study area. Photography of survey. Compilation of survey information gathered in questionnaires Secondary data collection of Govt. publications, census & comparison of primary data with secondary data. Verification of legal aspects of the project related socio-economics with prevailing policies and regulations in India Participate in CSR planning and need assessment review Siddhi Green Excellence Pvt. Ltd., Ankleshwar Page 3 of 5

115 EIA activities carried out by Associate FAEs and team members involved in the EIA for Proposed project of Synthetic Organic Chemicals Unit of Polyols & Polymers at D-2/CH-266,267,268, Dahej Pjase II, Ta. Vagra, Dist. Bharuch, Gujarat State, India FA EB Associate FAE 1. Priti D. Raval Designation : Environment Engineer Study area visit for ecological survey Collecting secondary ecological data and verifying it through surveys determining status of endangered species of animals and plants Identification of nearest ecologically sensitive areas around project site Verification of applicability of prevailing policies and regulations in India Assisting FAE for assessment of impact of the various project activities on the ecology and biodiversity of the project area during all phases of the project. Assistance in Report drafting for EIA Assisting FAE in recommending species suitable for pollution abatement and ecological conservation as suggested in CPCB guidelines and SEAC guidelines for the given agroclimatic zone of the region 2. Mrs. Khushbu Patel Designation : Environment Engineer Study area visit for ecological survey Collecting secondary ecological data and verifying it through surveys Sampling for aquatic studies and analysis of plankton determining status of endangered species of animals and plants Identification of nearest ecologically sensitive areas around project site Verification of applicability of prevailing policies and regulations in India Assisting FAE for assessment of impact of the various project activities on the ecology and biodiversity of the project area during all phases of the project. Assistance in Report drafting for EIA 3. Mrs. Twinkle H. Modi Designation : Technical Manager and Microbiologist Planning & Scheduling for baseline ecological survey for EIA studies determining status of endangered species of animals and plants organizing the baseline data collection Sampling for aquatic studies and analysis of plankton Identification of impacting activities of project w.r.t ecology and biodiversity of the study area Review of Greenbelt development requirement of the project Lab management activities, Laboratory analysis & identify species and Lab QMS implementation FA HG Associate FAE 1. Mr. Vikram Gohil Designation : Field Supervisor and Lab Chemist selection of locations for soil sampling within the study area Arrangements for collection of soil samples Supervision of Soil Analysis and characterization Survey work & field visit for baseline sampling for soil. GPS measurements and photography of sampling sites. guiding monitoring teams troubleshooting while sampling Inhouse lab analysis and compilation of analytical data Team member 1. Ms. Neha H. Solanki Designation : Lab Chemist - Environmental Analysis of baseline survey samples of soil Verification of sampling results and assessment of baseline status Submit the outcomes in form of report FA AQ Associate FAE 1. Mrs. Femida Kundawala Designation : Environment Engineer - Collecting input data related to meteorological and stack emission for GLC simulation FA Noise FAE :- 1. Mr. Vikram Gohil Designation: Field Supervisor and Lab Chemist Planning and scheduling of noise measurement at selected locations of study area GPS & photography during monitoring. Siddhi Green Excellence Pvt. Ltd., Ankleshwar Page 4 of 5

116 EIA activities carried out by Associate FAEs and team members involved in the EIA for Proposed project of Synthetic Organic Chemicals Unit of Polyols & Polymers at D-2/CH-266,267,268, Dahej Pjase II, Ta. Vagra, Dist. Bharuch, Gujarat State, India Review of baseline noise levels, sources and their compliance with permissible limits Identify sources of noise generation from the project and predict resultant increase in noise levels of sensitive receptors of the study area Collection and compilation of analytical data Calculating equivalent noise levels from measured noise Associate FAE 1. Ms. Priti D. Raval Designation: Environment Engineer Planning and scheduling of noise measurement at selected locations of study area sampling and monitoring jobs and guiding monitoring teams Collection and compilation of analytical data Calculating equivalent noise levels from measured noise levels and compilation in tabular form determine status of noise environment, existing sources of major noise generation To predict noise levels of different project activities and anticipate the increase in the baseline noise levels in residential, industrial and commercial zones as well as noise due to increase in road traffic Compilation of the outcomes of the assessment in report form and submission to EIA Co-coordinator Team Member 1. Mr. Ajit Parmar Designation: Lab Assistant Noise monitoring within study area, GPS & photography during monitoring. Assist team during monitoring 2. Mr. Moshin Mansuri Designation: Lab Assistant Noise monitoring within study area, GPS & photography during monitoring. Assist team during monitoring. 3. Mr. MahendraSinh K. Rathod Designation: Executive Socio economic studies Noise monitoring within study area, GPS & photography during monitoring. Assist team during monitoring. FA LU Associate FAE 1.Ms. Bhumika Bhuva Designation : Environment Engineer Reference map preparation for classification and determine baseline LULC of the area. Identification of impacts, Prediction of impacts on land use pattern and land cover. Identification of talukas and villages as well as major landforms covered in the study area using google earth, wikimapia, census datasheets 2. Mrs. Khushbu Patel Designation: Environment Engineer Reference map preparation for classification and determine baseline LULC of the area. Identification of impacts, Prediction of impacts on land use pattern and land cover. Identification of talukas and villages as well as major landforms covered in the study area using google earth, wikimapia, census datasheets. FA RH Associate FAE 1. Ms. Bhumika Bhuva Designation: Environment Engineer Identification of hazardous chemical w.r.t haz. Chemical schedules & their antidotes. Hazardous chemical Consequence analysis using ALOHA, mapping of threat zones and plot affected areas of study area and plant sections. Collecting data regarding fire-fighting arrangements and occupational safety measures 2. Mrs. Khushbu Patel Designation: Environment Engineer Identification of hazardous chemical w.r.t haz. Chemical schedules & their antidotes. Hazardous chemical Consequence analysis using ALOHA, mapping of threat zones and plot affected areas of study area and plant sections Siddhi Green Excellence Pvt. Ltd., Ankleshwar Page 5 of 5

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