Relatex activ / GH 40 BLIZ-O

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1 1. Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Trade name Relatex activ / GH 40 BLIZ-O 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/preparation Oxygen bleach and stain removal agent 1.3. Details of the supplier of the safety data sheet Address van Baerle AG Schützenmattstrasse Münchenstein Telephone no Fax no Information provided Dangerous Good Officer / by / telephone address of person responsible for this SDS 1.4. Emergency telephone number Swiss Toxicological Information Centre 145 (international ) 2. Hazards identification 2.1. Classification of the substance or mixture Classification (Regulation (EC) No. 1272/2008) Classification (Regulation (EC) No. 1272/2008) Acute Tox. 4 H302 Eye Dam. 1 H318 Classification in accordance with EC directives Classification Xn, R22 Xi, R Label elements Labelling according to regulation (EC) No 1272/2008 Hazard pictograms Signal word Danger Page 1(9)

2 Hazard statements H302 Harmful if swallowed. H318 Causes serious eye damage. Precautionary statements P280.2 Wear protective gloves/eye/face protection. P301 IF SWALLOWED: P312 Call a POISON CENTER or doctor if you feel unwell. P305 IF IN EYES: P351 Rinse cautiously with water for several minutes. P338 Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER or doctor. Hazardous component(s) to be indicated on label (Regulation (EC) No. 1272/2008) contains sodium percarbonate Labelling in accordance with EC directives 1999/45/EC and 67/548/EEC The product is classified and labelled in accordance with EC directives/the relevant national laws. Hazard symbols Harmful R phrases 22 Harmful if swallowed. 41 Risk of serious damage to eyes. S phrases 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 39 Wear eye/face protection. 60 This material and its container must be disposed of as hazardous waste. 22 Do not breathe dust. 8 Keep container dry. Hazardous component(s) to be indicated on label contains sodium percarbonate 2.3. Other hazards In case of fire, danger of decomposition with oxygen release that can intensify the fire. 3. Composition/information on ingredients Chemical characterization Alkaline, peroxide releasing granules. Hazardous ingredients sodium percarbonate CAS No EINECS no Concentration >= 50 % Classification Xi, R41 Xn, R22 O, R8 Classification (Regulation (EC) No. 1272/2008) Page 2(9)

3 Ox. Sol. 2 Acute Tox. 4 Eye Dam. 1 H272 H302 H318 Concentration limits (Regulation (EC) No. 1272/2008) Eye Irrit. 2 H319 = 10 = 25 % Eye Dam. 1 H318 > 25 % Acute Tox. 4 H302 > 25 % 4. First aid measures 4.1. Description of first aid measures Remove contaminated clothing immediately and dispose of safely. Adhere to personal protective measures when giving first aid. Clean body thoroughly (bath, shower). In any case show the physician the Safety Data Sheet. After inhalation Move to fresh air. Do not inhale dust. After skin contact After contact with skin, wash immediately with plenty of water. Consult a doctor if skin irritation persists. After eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Eye treatment by an Occulist. Remove contact lenses After ingestion Rinse out mouth and give plenty of water to drink. Do not induce vomiting. Take medical treatment. Adhere to personal protective measures when giving first aid First aider: Pay attention to self-protection! 4.2. Most important symptoms and effects, both acute and delayed Until now no symptoms known so far Indication of any immediate medical attention and special treatment needed Hints for the physician / hazards In the case of swallowing with subsequent vomiting, aspiration of the lungs can occur which can lead to chemical pneumonia or asphyxiation. 5. Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Water, Extinguishing measures to suit surroundings Non Suitable extinguishing media Full water jet 5.2. Special hazards arising from the substance or mixture In case of fire, danger of decomposition with oxygen release that can intensify the fire Advice for firefighters Special protective equipment for fire-fighting Wear protective clothing. Use self-contained breathing apparatus. Page 3(9)

4 Other information Collect contaminated fire-fighting water separately, must not be discharged into the drains. Fire residues and contaminated fire-fighting water must be disposed of in accordance with the local regulations. Observe manufacturer's / distributor`s instructions. 6. Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Use personal protective clothing. Avoid dust formation. Avoid contact with skin, eyes and clothing Environmental precautions Do not flush into surface water or sanitary sewer system Methods and material for containment and cleaning up Shovel or sweep up. Use a suitable vacuum cleaner. Rinse away rest with plenty of water Reference to other sections Refer to protective measures listed in sections 7 and Handling and storage 7.1. Precautions for safe handling Advice on safe handling Avoid dust formation. Provide exhaust ventilation if dust is formed. Keep away from heat and sources of ignition. For industrial application only Conditions for safe storage, including any incompatibilities Recommended storage temperature Value < 40 C Storage stability As a rule, the storage time should not exceed twelve months. Requirements for storage rooms and vessels Keep only in the original container. Hints on storage assembly Store away from food, animal feeding stuffs and drugs. Do not store with combustible materials. Do not store together with acids. Further information on storage conditions Keep in a cool place. Protect from light. Store in a dry place. Protect from heat and direct sunlight. 8. Exposure controls/personal protection 8.1. Control parameters Other information Contains no substances with occupational exposure limit values Exposure controls General protective and hygiene measures Observe the usual precautions for handling chemicals. Wash hands and face before breaks and immediately after handling the product. Do not eat, drink or smoke during work time. Avoid product stains on clothing. Respiratory protection Half mask with a particle filter P2 (European Norm EN 143 = former DIN 3181). Page 4(9)

5 Hand protection Nitrile gloves. Eye protection Safety glasses Body protection Clothing as usual in the chemical industry. 9. Physical and chemical properties 9.1. Information on basic physical and chemical properties Form crystalline Colour white Odour faint odour of acetic acid Odour threshold ph Value = 10 Concentration/H2O 1 % Melting point Freezing point Boiling point Flash point Value > 250 C Evaporation rate (ether = 1) : Flammability Explosion limits Vapour pressure Vapour density Density Value = 870 g/l Solubility in water Value appr. 23 g/l Temperature = 20 C Solubility in other solvents Octanol/water partition coefficient (log Pow) Ignition temperature Page 5(9)

6 Thermal decomposition Value from 60 C Viscosity Explosive properties Oxidising properties 9.2. Other information Bulk density Value = 750 to 900 g/l Other information None known 10. Stability and reactivity Reactivity No hazardous reactions when stored and handled according to prescribed instructions Chemical stability No hazardous reactions known Possibility of hazardous reactions No hazardous reactions known Conditions to avoid Stable under recommended storage conditions. Protect from atmospheric moisture and water. Protect from light. Thermal decomposition Value from 60 C Incompatible materials Acids, Bases, Reactions with combustible substances. Reducing agents Hazardous decomposition products None 11. Toxicological information Information on toxicological effects Acute oral toxicity Reference substance Sodium carbonate peroxyhydrate Species rat LD50 = 1034 mg/kg Acute dermal toxicity Species rabbit LD50 > 2000 mg/kg Acute inhalational toxicity Skin corrosion/irritation Page 6(9)

7 evaluation Irritating to skin and mucous membranes. Serious eye damage/irritation evaluation strongly irritant Sensitization Subacute, subchronic, chronic toxicity Mutagenicity Reproductive toxicity Carcinogenicity Specific Target Organ Toxicity (STOT) Experience in practice Inhalation may lead to irritation of the respiratory tract. Ingestion causes local irritation of mouth, pharynx and esophagus. Other information Under normal use, this product has no known adverse effect on human health. 12. Ecological information Toxicity Fish toxicity Reference substance Sodium carbonate peroxyhydrate LC50 = 70.7 mg/l NOEC = 25 ppm(v) Duration of exposure = 48 h Daphnia toxicity Reference substance Sodium carbonate peroxyhydrate EC50 = 4.9 mg/l EC50 = 133 to 226 mg/l Duration of exposure = 48 h Persistence and degradability Biodegradability Reference substance Sodium carbonate peroxyhydrate Degradability: not applicable because inorganic Bioaccumulative potential Octanol/water partition coefficient (log Pow) Page 7(9)

8 12.4. Mobility in soil Results of PBT and vpvb assessment Other adverse effects / ecology Do not allow to enter soil, waterways or waste water canal. Avoid release into the atmosphere. 13. Disposal considerations Waste treatment methods Disposal recommendations for the product EWC waste code * detergents containing dangerous substances In accordance with local and national regulations. Disposal recommendations for packaging Completely emptied packagings can be given for recycling. 14. Transport information Land transport ADR/RID Non-dangerous goods Marine transport IMDG/GGVSee The product does not constitute a hazardous substance in sea transport. Air transport ICAO/IATA The product does not constitute a hazardous substance in air transport. 15. Regulatory information Chemical safety assessment For this preparation a chemical safety assessment has not been carried out. 16. Other information Follow instructions on labels and product data sheet, if available. R-phrases listed in Chapter 3 22 Harmful if swallowed. 41 Risk of serious damage to eyes. 8 Contact with combustible material may cause fire. Hazard statements listed in Chapter 3 H272 May intensify fire; oxidiser. H302 Harmful if swallowed. H318 Causes serious eye damage. CLP categories listed in Chapter 3 Page 8(9)

9 Acute Tox. 4 Acute toxicity, Category 4 Eye Dam. 1 Serious eye damage, Category 1 Ox. Sol. 2 Oxidising solid, Category 2 Supplemental information Relevant changes compared with the previous version of the safety data sheet are marked with: *** This information is based on our present state of knowledge. However, it should not constitute a guarantee for any specific product properties and shall not establish a legally valid relationship. Page 9(9)

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