list of active substances, all matrices



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list of s, all matrices number of validated s according to SANCO/12571/2013 in multi residue method (MRM): 467 reporting limit (mg/kg) according to matrices* multi residue method (MRM) 2,4,5-T (F) LC-MS/MS ESI- 2,4,5-TP (Fenoprop) LC-MS/MS ESI- 2,4,6-trichlorophenol GC-MS/MS 2,4-D (sum of 2,4-D and its esters express LC-MS/MS ESI- 2,4-DB LC-MS/MS ESI- 2-phenylphenol aromatic hydrocarbon GC-MS EI SIM 2-phenylphenol aromatic hydrocarbon GC-MS/MS 0,05 0,05 0,05 3,4,5-Trimethacarb carbamate LC-MS/MS ESI+ 3-Hydroxycarbofuran LC-MS/MS ESI+ acephate organophosphate LC-MS/MS ESI+ Acetamiprid (R) LC-MS/MS ESI+ acetochlor chloroacetamide GC-MS/MS acibenzolar-s-methyl LC-MS/MS ESI+ 0,05 aclonifen diphenyl ether GC-MS NCI aclonifen diphenyl ether GC-MS/MS acrinathrin (F) pyrethroid, acaricide GC-MS NCI acrinathrin (F) pyrethroid, acaricide GC-MS/MS alachlor chloroacetamide GC-MS/MS alanycarb LC-MS/MS ESI+ aldicarb carbamate LC-MS/MS ESI+ aldicarb-sulfone LC-MS/MS ESI+ aldicarb-sulfoxide carbamate LC-MS/MS ESI+ aldrin organochlorine GC-MS NCI

aldrin organochlorine GC-MS/MS ametryn triazine LC-MS/MS ESI+ amitraz amidin, acaricide LC-MS/MS ESI+ anthraquinone GC-MS/MS 0,05 atrazine (F) triazine GC-MS/MS atrazine, desethyl- triazine LC-MS/MS ESI+ azamethiphos organophosphate LC-MS/MS ESI+ azinphos-ethyl (F) organophosphate, acaricide GC-MS/MS azinphos-methyl (F) organophosphate LC-MS/MS ESI+ azoxystrobin strobilurin type GC-MS NCI azoxystrobin strobilurin type GC-MS/MS Benalaxyl phenylamide GC-MS/MS Bendiocarb carbamate LC-MS/MS ESI+ Benfluralin (F) dinitroaniline GC-MS/MS Benfuracarb carbamate LC-MS/MS ESI+ Benomyl benzimidazole LC-MS/MS ESI+ Bensulfuron-methyl LC-MS/MS ESI+ Bentazone LC-MS/MS ESI- Benthiavalicarb-isopropyl carbamate LC-MS/MS ESI+ Bifenazate GC-MS/MS 0,05 Bifenox (F) diphenyl ether GC-MS NCI Bifenox (F) diphenyl ether GC-MS/MS Bifenthrin (F) pyrethroid, acaricide GC-MS/MS Bifenthrin (F) pyrethroid, acaricide GC-MS NCI Bioallethrine pyrethroid GC-MS/MS 0,05 Biphenyl aromatic hydrocarbon GC-MS/MS Biphenyl aromatic hydrocarbon GC-MS EI SIM

Bitertanol (F) triazole LC-MS/MS ESI+ Boscalid (F) (R) pyridinecarboxamide GC-MS NCI Boscalid (F) (R) pyridinecarboxamide GC-MS/MS Bromacil uracil GC-MS NCI Bromacil uracil GC-MS/MS Bromocyclen organochlorine, acaricide GC-MS/MS Bromophos-ethyl organophosphate, acaricide GC-MS NCI Bromophos-ethyl organophosphate, acaricide GC-MS/MS Bromophos-methyl organophosphate GC-MS NCI Bromophos-methyl organophosphate GC-MS/MS Bromopropylate (F) benzilate acaricide GC-MS NCI Bromopropylate (F) benzilate acaricide GC-MS/MS Bromoxynil LC-MS/MS ESI- Bromuconazole (sum of diasteroisomers) triazole GC-MS/MS Bromuconazole (sum of diasteroisomers) triazole LC-MS/MS ESI+ Bupirimate GC-MS/MS Bupirimate GC-MS NCI Buprofezin (F), acaricide GC-MS/MS Butocarboxim LC-MS/MS ESI+ Butocarboxim sulfoxide LC-MS/MS ESI+ Butoxycarboxim, acaricide LC-MS/MS ESI+ Cadusafos organophosphate, nematicide GC-MS/MS Captan phthalimide GC-MS NCI Captan phthalimide GC-MS/MS 0,02 0,02 Carbaryl (F) carbamate LC-MS/MS ESI+ Carbendazim benzimidazole LC-MS/MS ESI+ Carbetamide carbamate LC-MS/MS ESI+

Carbofuran carbamate LC-MS/MS ESI+ Carbophenothion GC-MS/MS Carbosulfan LC-MS/MS ESI+ Carboxin GC-MS/MS Cekafix GC-MS/MS 0,1 Chinomethionat, acaricide GC-MS NCI Chinomethionat, acaricide GC-MS/MS Chlorantraniliprole (DPX E-2Y45) (F) LC-MS/MS ESI- Chlordane, cis organochlorine GC-MS NCI Chlordane, cis organochlorine GC-MS/MS Chlordane, trans organochlorine GC-MS/MS Chlordimeform GC-MS/MS Chlorfenapyr, acaricide GC-MS NCI Chlorfenapyr, acaricide GC-MS/MS Chlorfenson (F) acaricide GC-MS NCI Chlorfenson (F) acaricide GC-MS/MS Chlorfenvinphos (F) organophosphate, acaricide GC-MS/MS Chlorfenvinphos (F) organophosphate, acaricide GC-MS NCI Chloridazon LC-MS/MS ESI+ Chlorobenzilate (F) acaricide GC-MS/MS Chlorothalonil (R) organochlorine GC-MS NCI 0,05 Chlorothalonil (R) organochlorine GC-MS/MS 0,05 0,05 0,05 chlorotoluron urea LC-MS/MS ESI+ Chlorpropham carbamate, plant growth re GC-MS EI SIM Chlorpropham carbamate, plant growth re GC-MS/MS Chlorpyrifos (F) organophosphate GC-MS NCI Chlorpyrifos (F) organophosphate GC-MS/MS

Chlorpyrifos-methyl (F) organophosphate, acaricide GC-MS NCI Chlorpyrifos-methyl (F) organophosphate, acaricide GC-MS/MS Chlorsulfuron LC-MS/MS ESI+ Chlorthal-dimethyl GC-MS NCI Chlorthal-dimethyl GC-MS/MS Chlorthion GC-MS/MS Chlozolinate GC-MS NCI Chlozolinate GC-MS/MS Cinosulfuron LC-MS/MS ESI+ Clethodim LC-MS/MS ESI- Climbazole GC-MS/MS 0,03 Clodinafop-propargylester LC-MS/MS ESI+ Clofentezine (R) acaricide LC-MS/MS ESI+ Clomazone GC-MS/MS Cloquintocet-1-mexyl GC-MS/MS Clothianidin LC-MS/MS ESI+ Coumaphos organophosphate GC-MS NCI Coumaphos organophosphate GC-MS/MS Cyanazin triazine LC-MS/MS ESI+ Cyanofenphos organophosphate GC-MS/MS Cyanofenphos organophosphate GC-MS NCI Cyazofamid LC-MS/MS ESI+ Cyclanilide (F) LC-MS/MS ESI- Cycloxydim LC-MS/MS ESI+ Cyflufenamid GC-MS/MS Cyflufenamid LC-MS/MS ESI- Cyfluthrin (cyfluthrin including other mixt pyrethroid GC-MS NCI

Cyfluthrin (cyfluthrin including other mixt pyrethroid GC-MS/MS Cymiazol acaricide, ixodicide GC-MS/MS Cymoxanil LC-MS/MS ESI+ Cypermethrin (cypermethrin including ot pyrethroid GC-MS NCI Cypermethrin (cypermethrin including ot pyrethroid GC-MS/MS Cyphenothrine pyrethroid GC-MS/MS 0,05 Cyproconazole (F) triazole GC-MS/MS Cyproconazole (F) triazole LC-MS/MS ESI+ Cyprodinil (F) (R) anilinopyrimidine GC-MS/MS Cyromazine LC-MS/MS ESI+ DDD, o,p- organochlorine GC-MS NCI DDD, o,p- organochlorine GC-MS/MS DDD, p,p- organochlorine GC-MS/MS DDD, p,p- organochlorine GC-MS NCI DDE, o,p- organochlorine GC-MS NCI DDE, o,p- organochlorine GC-MS/MS DDE, p,p- organochlorine GC-MS NCI DDE, p,p- organochlorine GC-MS/MS DDT, o,p- organochlorine GC-MS NCI DDT, o,p- organochlorine GC-MS/MS DDT, p,p- organochlorine GC-MS NCI DDT, p,p- organochlorine GC-MS/MS Deltamethrin (cis-deltamethrin) (F) pyrethroid GC-MS/MS Deltamethrin (cis-deltamethrin) (F) pyrethroid GC-MS NCI Demeton-S-methyl organophosphate, acaricide LC-MS/MS ESI+ Demeton-S-methylsulfon organophosphate, acaricide LC-MS/MS ESI+ Desmetryn GC-MS/MS

Diafenthiuron LC-MS/MS ESI+ Dialifos, acaricide GC-MS/MS Diazinon (F) organophosphate, acaricide GC-MS NCI Diazinon (F) organophosphate, acaricide GC-MS/MS Dicamba LC-MS/MS ESI- 0,05 Dichlobenil benzonitrile GC-MS NCI 0,03 Dichlobenil benzonitrile GC-MS/MS 0,03 Dichlofenthion organophosphate, nematicide GC-MS/MS Dichlofenthion organophosphate, nematicide GC-MS NCI Dichlofluanid sulfamide GC-MS NCI 0,03 Dichlofluanid sulfamide GC-MS/MS 0,03 0,03 dichlorprop LC-MS/MS ESI- Dichlorvos organophosphate, acaricide GC-MS/MS Dichlorvos organophosphate, acaricide LC-MS/MS ESI+ Diclobutazol triazole LC-MS/MS ESI+ Dicloran organochlorine GC-MS NCI Dicloran organochlorine GC-MS/MS Dicofol organochlorine acaricide GC-MS NCI Dicofol organochlorine acaricide GC-MS/MS 0,05 dicofol, o,p'- GC-MS/MS 0,05 Dicrotophos organophosphate, acaricide LC-MS/MS ESI+ Dieldrin organochlorine GC-MS NCI Dieldrin organochlorine GC-MS/MS Diethofencarb carbamate LC-MS/MS ESI+ Diethyl-m-tolylamid (DEET) repellent GC-MS/MS 0,03 Difenoconazole triazole GC-MS/MS Difenoconazole triazole LC-MS/MS ESI+

Diflubenzuron (F) (R) LC-MS/MS ESI- Diflufenican pyridinecarboxamide GC-MS NCI Diflufenican pyridinecarboxamide GC-MS/MS Dikegulac LC-MS/MS ESI+ Dimethachlor chloroacetamide LC-MS/MS ESI+ Dimethenamid chloroacetamide GC-MS/MS Dimethoate organophosphate, acaricide LC-MS/MS ESI+ Dimethomorph LC-MS/MS ESI+ Dimoxystrobin strobilurin type GC-MS/MS Diniconazole triazole GC-MS NCI Diniconazole triazole GC-MS/MS Dinocap, acaricide LC-MS/MS ESI- Dinotefuran LC-MS/MS ESI+ Dioxathion organophosphate, acaricide LC-MS/MS ESI+ 0,05 0,05 Diphenylamine GC-MS/MS Disulfoton organophosphate, acaricide GC-MS NCI Disulfoton organophosphate, acaricide GC-MS/MS Disulfoton-sulfone organophosphate, acaricide LC-MS/MS ESI+ Disulfoton-sulfoxide organophosphate, acaricide LC-MS/MS ESI+ Ditalimfos organophosphate GC-MS NCI Ditalimfos organophosphate GC-MS/MS Diuron urea LC-MS/MS ESI+ DMST metabolit GC-MS/MS DNOC, acaricide, her LC-MS/MS ESI- Dodine LC-MS/MS ESI+ 0,05 Emamectin LC-MS/MS ESI+ Endosulfane sulfate organochlorine, acaricide GC-MS/MS

Endosulfane sulfate organochlorine, acaricide GC-MS NCI Endosulfane, alpha- organochlorine, acaricide GC-MS/MS Endosulfane, alpha- organochlorine, acaricide GC-MS NCI Endosulfane, beta- organochlorine, acaricide GC-MS/MS Endosulfane, beta- organochlorine, acaricide GC-MS NCI Endrin (F) organochlorine GC-MS NCI Endrin (F) organochlorine GC-MS/MS EPN organophosphate, acaricide GC-MS/MS Epoxiconazole (F) LC-MS/MS ESI+ Etaconazole GC-MS/MS Ethiofencarb carbamate LC-MS/MS ESI+ Ethion organophosphate, acaricide GC-MS NCI Ethion organophosphate, acaricide GC-MS/MS Ethirimol LC-MS/MS ESI+ Ethofumesate LC-MS/MS ESI+ Ethoprophos organophosphate, nematicide GC-MS NCI Ethoprophos organophosphate, nematicide GC-MS/MS Ethoxyquin (F) GC-MS/MS Ethoxyquin (F) LC-MS/MS ESI+ Etofenprox (F) pyrethroid LC-MS/MS ESI+ Etofenprox (F) pyrethroid GC-MS/MS Etoxazole acaricide LC-MS/MS ESI+ Etridiazole triazole GC-MS/MS Etrimfos organophosphate LC-MS/MS ESI+ Famoxadone strobilurin type GC-MS NCI Famoxadone strobilurin type GC-MS/MS Fenamidone imidazole LC-MS/MS ESI+

Fenamiphos organophosphate nematicide LC-MS/MS ESI+ Fenamiphos-sulfone organophosphate nematicide GC-MS/MS Fenamiphos-sulfoxide nematicide LC-MS/MS ESI+ Fenarimol GC-MS NCI Fenarimol GC-MS/MS Fenazaquin acaricide LC-MS/MS ESI+ Fenbuconazole triazole LC-MS/MS ESI+ Fenhexamid hydroxyanilide GC-MS NCI Fenhexamid hydroxyanilide GC-MS/MS Fenhexamid hydroxyanilide LC-MS/MS ESI+ Fenitrothion organophosphate GC-MS NCI Fenitrothion organophosphate GC-MS/MS Fenoxycarb carbamate LC-MS/MS ESI+ Fenpropathrin pyrethroid, acaricide GC-MS/MS Fenpropathrin pyrethroid, acaricide GC-MS NCI Fenpropidin (R) LC-MS/MS ESI+ Fenpropimorph (R) LC-MS/MS ESI+ Fenpyroximate (F) acaricide LC-MS/MS ESI+ Fenson acaricide GC-MS/MS Fensulfothion nematicide GC-MS/MS Fenthion organophosphate LC-MS/MS ESI+ Fenthion-oxon organophosphate metabolite GC-MS/MS Fenthion-sulfon organophosphate GC-MS NCI Fenthion-sulfon organophosphate GC-MS/MS Fenthion-sulfoxide organophosphate LC-MS/MS ESI+ Fenvalerate and Esfenvalerate (Sum of R pyrethroid GC-MS NCI Fenvalerate and Esfenvalerate (Sum of R pyrethroid GC-MS/MS

Fenvalerate and Esfenvalerate (Sum of R pyrethroid, acaricide GC-MS NCI Fenvalerate and Esfenvalerate (Sum of R pyrethroid, acaricide GC-MS/MS Fipronil phenylpyrazole GC-MS NCI Fipronil phenylpyrazole GC-MS/MS Fipronil phenylpyrazole LC-MS/MS ESI- Fipronil, desulfinyl- LC-MS/MS ESI- Fipronil-sulfide LC-MS/MS ESI- Fipronil-sulfone LC-MS/MS ESI- Flonicamid LC-MS/MS ESI- Fluazifop aryloxyphenoxypropionate LC-MS/MS ESI- Fluazifop-P-butyl aryloxyphenoxypropionate GC-MS/MS Fluazinam (F) LC-MS/MS ESI- Flubendiamide (F) LC-MS/MS ESI+ 0,02 Flucythrinate (F) (R) pyrethroid GC-MS/MS Flucythrinate (F) (R) pyrethroid GC-MS NCI Fludioxonil phenylpyrrole LC-MS/MS ESI- Flufenacete strobilurin type LC-MS/MS ESI+ Flufenoxuron (F), acaricide LC-MS/MS ESI+ Flumioxazine GC-MS/MS Fluopicolide benzamide GC-MS/MS fluopyram GC-MS/MS Fluquinconazole (F) triazole GC-MS NCI Fluquinconazole (F) triazole GC-MS/MS Flurochloridone LC-MS/MS ESI+ Fluroxypyr LC-MS/MS ESI- Flurtamone Flurtamone LC-MS/MS ESI GC-MS/MS

Flusilazole (F) (R) triazole LC-MS/MS ESI+ Flutolanil LC-MS/MS ESI+ Flutriafol triazole GC-MS/MS Flutriafol triazole LC-MS/MS ESI+ Folpet phthalimide GC-MS NCI Folpet phthalimide GC-MS/MS 0,02 0,02 Fonofos organophosphate GC-MS/MS Fonofos organophosphate LC-MS/MS ESI+ Fonofos organophosphate GC-MS NCI Formetanate: Sum of formetanate and its carbamate LC-MS/MS ESI+ Formothion organophosphate, acaricide GC-MS NCI Formothion organophosphate, acaricide GC-MS/MS Fosethyl LC-MS/MS ESI+ Fosthiazate organophosphate nematicide LC-MS/MS ESI+ Fuberidazole benzimidazole LC-MS/MS ESI+ Furathiocarb carbamate LC-MS/MS ESI+ Haloxyfop aryloxyphenoxypropionate LC-MS/MS ESI- Haloxyfop-ethoxyethyl aryloxyphenoxypropionate GC-MS/MS Haloxyfop-methyl aryloxyphenoxypropionate GC-MS/MS Heptachlor organochlorine GC-MS/MS Heptachlor organochlorine GC-MS NCI Heptachlor-endo-epoxide, trans- metabolite GC-MS/MS Heptachlorepoxid, cis- metabolite GC-MS/MS Heptachlorepoxid, cis- metabolite GC-MS NCI Heptenophos organophosphate LC-MS/MS ESI+ Hexabromobenzene organochlorine GC-MS/MS Hexachlorobenzene (F) organochlorine GC-MS NCI

Hexachlorobenzene (F) organochlorine GC-MS/MS Hexachlorociclohexane (HCH), alpha-iso organochlorine GC-MS/MS Hexachlorociclohexane (HCH), alpha-iso organochlorine GC-MS NCI Hexachlorociclohexane (HCH), beta-isom organochlorine GC-MS NCI Hexachlorociclohexane (HCH), beta-isom organochlorine GC-MS/MS Hexachlorociclohexane (HCH), delta-isom organochlorine GC-MS NCI Hexachlorociclohexane (HCH), delta-isom organochlorine GC-MS/MS Hexaconazole triazole GC-MS/MS Hexaconazole triazole GC-MS NCI Hexaflumuron LC-MS/MS ESI- Hexazinon triazine LC-MS/MS ESI+ Hexythiazox acaricide LC-MS/MS ESI+ Imazalil triazole LC-MS/MS ESI+ Imazaquin imidazole LC-MS/MS ESI+ Imazosulfuron LC-MS/MS ESI- Imidacloprid LC-MS/MS ESI+ Indoxacarb as sum of the isomers S and oxadiazine GC-MS/MS Indoxacarb as sum of the isomers S and oxadiazine GC-MS NCI Iodofenphos, acaricide, ixod GC-MS/MS Ioxynil LC-MS/MS ESI- Iprobenfos phosphorothiolate GC-MS/MS Iprodione (R) dicarboximide GC-MS NCI Iprodione (R) dicarboximide GC-MS/MS Iprovalicarb carbamate LC-MS/MS ESI+ Isobenzan GC-MS/MS Isocarbofos organophosphate, acaricide GC-MS/MS Isodrin GC-MS/MS

Isofenphos organophosphate LC-MS/MS ESI+ Isofenphos-methyl organophosphate LC-MS/MS ESI+ Isoprocarb carbamate LC-MS/MS ESI+ Isoprocarb carbamate GC-MS/MS Isoprothiolane, plant growth reg LC-MS/MS ESI+ Isoproturon urea LC-MS/MS ESI+ Kresoxim-methyl (F) (R) oximinoacetat GC-MS NCI Kresoxim-methyl (F) (R) oximinoacetat GC-MS/MS Lambda-Cyhalothrin (F) (R) pyrethroid GC-MS/MS Lambda-Cyhalothrin (F) (R) pyrethroid GC-MS NCI Lenacil uracil LC-MS/MS ESI+ Lindane (Gamma-isomer of hexachloroci organochlorine GC-MS/MS Lindane (Gamma-isomer of hexachloroci organochlorine GC-MS NCI Linuron urea LC-MS/MS ESI+ Lufenuron(F), acaricide LC-MS/MS ESI- Malaoxon organophosphate GC-MS NCI 0,02 Malaoxon organophosphate GC-MS/MS Malaoxon organophosphate LC-MS/MS ESI+ Malathion organophosphate, acaricide GC-MS/MS Malathion organophosphate, acaricide LC-MS/MS ESI+ Malathion organophosphate, acaricide GC-MS NCI Mandipropamid LC-MS/MS ESI+ MCPA LC-MS/MS ESI- MCPA-methyl ester GC-MS/MS MCPB LC-MS/MS ESI- Mecarbam organophosphate GC-MS NCI Mecarbam organophosphate GC-MS/MS

Mecoprop LC-MS/MS ESI- mecoprop-methyl ester GC-MS/MS Mepanipyrim LC-MS/MS ESI+ Mepronil LC-MS/MS ESI+ meptyldinocap LC-MS/MS ESI- Metaflumizone (sum of E- and Z- isomers LC-MS/MS ESI- Metalaxyl phenylamide GC-MS/MS Metalaxyl phenylamide LC-MS/MS ESI+ Metamitron triazinon LC-MS/MS ESI+ Metazachlor chloroacetamide GC-MS/MS Metconazole (F) LC-MS/MS ESI+ Methabenzthiazuron LC-MS/MS ESI+ Methacrifos (F) organophosphate, acaricide GC-MS/MS Methamidophos, acaricide LC-MS/MS ESI+ Methidathion organophosphate, acaricide GC-MS NCI Methidathion organophosphate, acaricide GC-MS/MS Methidathion organophosphate, acaricide LC-MS/MS ESI+ Methiocarb carbamate, molluscocide LC-MS/MS ESI+ Methiocarb-sulfon LC-MS/MS ESI+ Methiocarb-sulfoxid LC-MS/MS ESI+ Methomyl carbamate, acaricide LC-MS/MS ESI+ Methoxychlor (F) organochlorine GC-MS/MS Methoxyfenozide (F) LC-MS/MS ESI+ Metobromuron urea LC-MS/MS ESI+ Metolachlor chloroacetamide GC-MS/MS Metosulam LC-MS/MS ESI+ Metrafenone LC-MS/MS ESI+

Metribuzin triazinon GC-MS NCI Metribuzin triazinon GC-MS/MS Mevinphos (sum of E- and Z-isomers) organophosphate, acaricide LC-MS/MS ESI+ Monocrotophos organophosphate, acaricide LC-MS/MS ESI+ Monolinuron LC-MS/MS ESI+ Myclobutanyl (R) triazole GC-MS NCI Myclobutanyl (R) triazole GC-MS/MS N-2,4-Dimethylphenyl-N'-methylformamidi LC-MS/MS ESI+ Naled LC-MS/MS ESI+ Napropamide alkanamide LC-MS/MS ESI+ Nitenpyram LC-MS/MS ESI+ Nitrofen (F) diphenyl ether GC-MS NCI Nitrofen (F) diphenyl ether GC-MS/MS Novaluron (F) LC-MS/MS ESI+ 0,05 Nuarimol (Trimidal) GC-MS NCI Nuarimol (Trimidal) GC-MS/MS Omethoate organophosphate, acaricide LC-MS/MS ESI+ Oxadiazon oxadiazole GC-MS/MS Oxadixyl phenylamide LC-MS/MS ESI+ Oxamyl carbamate, acaricide, ne LC-MS/MS ESI+ oxy-chlordane metabolite GC-MS NCI oxy-chlordane metabolite GC-MS/MS Oxydemeton-methyl organophosphate LC-MS/MS ESI+ Oxyfluorfen diphenyl ether GC-MS/MS Paclobutrazol triazole plant growth regulator LC-MS/MS ESI+ Paraoxon-ethyl organophosphate LC-MS/MS ESI+ Paraoxon-ethyl organophosphate GC-MS/MS

Paraoxon-methyl GC-MS NCI Paraoxon-methyl LC-MS/MS ESI+ Parathion (F) organophosphate, acaricide GC-MS/MS Parathion (F) organophosphate, acaricide LC-MS/MS ESI+ Parathion (F) organophosphate, acaricide GC-MS NCI Parathion-methyl organophosphate GC-MS NCI Parathion-methyl organophosphate GC-MS/MS PCB 101 GC-MS NCI PCB 101 GC-MS/MS PCB 118 GC-MS/MS PCB 138 GC-MS NCI PCB 138 GC-MS/MS PCB 153 GC-MS NCI PCB 153 GC-MS/MS PCB 180 GC-MS NCI PCB 180 GC-MS/MS PCB 209 GC-MS NCI PCB 209 GC-MS/MS PCB 28 GC-MS/MS PCB 52 GC-MS/MS PCB 52 GC-MS NCI Penconazole (F) triazole GC-MS/MS Penconazole (F) triazole GC-MS NCI Pencycuron (F) phenylurea LC-MS/MS ESI+ Pendimethalin (F) dinitroaniline GC-MS/MS Pendimethalin (F) dinitroaniline GC-MS NCI Pentachloroaniline GC-MS NCI

Pentachloroaniline GC-MS/MS Pentachloroanisol GC-MS/MS Pentachloroanisol GC-MS NCI pentachlorobenezene GC-MS/MS 0,05 pentachlorophenol GC-MS/MS 0,02 Permethrin (sum of isomers) pyrethroid GC-MS NCI Permethrin (sum of isomers) pyrethroid GC-MS/MS Phenmedipham (R) LC-MS/MS ESI+ Phenothrin pyrethroid GC-MS/MS Phentoate organophosphate, acaricide GC-MS/MS Phentoate organophosphate, acaricide GC-MS NCI Phorate organophosphate, acaricide, ne GC-MS/MS Phorat-sulfone metabolite LC-MS/MS ESI+ Phorat-sulfoxide metabolite LC-MS/MS ESI+ Phosalone organophosphate, acaricide GC-MS NCI Phosalone organophosphate, acaricide GC-MS/MS Phosmet organophosphate, acaricide GC-MS/MS Phosmet organophosphate, acaricide GC-MS NCI phosmet oxon GC-MS/MS Phosphamidon organophosphate, acaricide LC-MS/MS ESI+ Phoxim (F) LC-MS/MS ESI+ Picolinafen pyridinecarboxamide GC-MS/MS Picoxystrobin (F) strobilurin type GC-MS/MS Picoxystrobin (F) strobilurin type LC-MS/MS ESI+ Piperonyl butoxide synergist synergist GC-MS/MS Piperonyl butoxide synergist synergist LC-MS/MS ESI+ Piperonyl butoxide synergist synergist GC-MS EI SIM

Pirimicarb carbamate LC-MS/MS ESI+ Pirimicarb carbamate GC-MS/MS Pirimicarb, Desmethyl- carbamate LC-MS/MS ESI+ Pirimicarb, desmethyl formamido carbamate LC-MS/MS ESI+ Pirimiphos-ethyl organophosphate GC-MS/MS Pirimiphos-methyl (F) organophosphate, acaricide GC-MS EI SIM Pirimiphos-methyl (F) organophosphate, acaricide GC-MS/MS Pirimiphos-methyl (F) organophosphate, acaricide LC-MS/MS ESI+ Prochloraz triazole LC-MS/MS ESI+ Procymidone (R) dicarboximide GC-MS/MS Procymidone (R) dicarboximide GC-MS NCI Profenofos (F) organophosphate, acaricide GC-MS NCI Profenofos (F) organophosphate, acaricide GC-MS/MS Profluralin GC-MS/MS Profluralin GC-MS NCI Promecarb carbamate LC-MS/MS ESI+ Prometryn triazine LC-MS/MS ESI+ Propachlor chloroacetamide GC-MS/MS Propachlor chloroacetamide LC-MS/MS ESI+ Propamocarb (Sum of propamocarb and i carbamate LC-MS/MS ESI+ Propaquizafop aryloxyphenoxypropionate LC-MS/MS ESI+ Propargite (F) acaricide LC-MS/MS ESI+ Propazine triazine GC-MS/MS Propham carbamate, plant growth re LC-MS/MS ESI+ Propiconazole triazole GC-MS/MS Propiconazole triazole GC-MS NCI Propoxur carbamate LC-MS/MS ESI+

Propyzamide (F) (R) benzamide GC-MS/MS Propyzamide (F) (R) benzamide GC-MS NCI Proquinazid LC-MS/MS ESI+ Prosulfocarb LC-MS/MS ESI+ Prosulfuron LC-MS/MS ESI- Prothioconazole (R) triazole LC-MS/MS ESI+ Prothioconazole-desthio metabolit LC-MS/MS ESI+ Prothiophos organophosphate GC-MS/MS Prothiophos organophosphate GC-MS NCI Pymetrozine LC-MS/MS ESI+ Pyraclostrobin (F) strobilurin type LC-MS/MS ESI+ Pyrazophos (F) organophosphate GC-MS NCI Pyrazophos (F) organophosphate GC-MS/MS Pyrethrine (Pyrethrum) pyrethroid, acaricide GC-MS/MS 0,25 Pyridaben (F), acaricide GC-MS/MS 0,02 Pyridaben (F), acaricide LC-MS/MS ESI+ Pyridaben (F), acaricide GC-MS NCI 0,02 Pyridalyl GC-MS/MS Pyridaphenthion organophosphate, acaricide GC-MS NCI Pyridaphenthion organophosphate, acaricide LC-MS/MS ESI+ Pyridaphenthion organophosphate, acaricide GC-MS/MS Pyrifenox GC-MS NCI Pyrifenox GC-MS/MS Pyrimethanil anilinopyrimidine LC-MS/MS ESI+ Pyrimisulfuron-methyl LC-MS/MS ESI+ 0,2 Pyriproxyfen (F) LC-MS/MS ESI+ Quinalphos organophosphate, acaricide GC-MS NCI

Quinalphos organophosphate, acaricide GC-MS/MS Quinmerac LC-MS/MS ESI+ Quinoxyfen (F) phthalimide GC-MS NCI Quinoxyfen (F) phthalimide GC-MS/MS Quintozene organochlorine GC-MS NCI Quintozene organochlorine GC-MS/MS Quizalofop LC-MS/MS ESI- 0,05 Quizalofop-ethyl aryloxyphenoxypropionate GC-MS/MS Resmethrin (resmethrin including other pyrethroid LC-MS/MS ESI+ Rotenone, acaricide LC-MS/MS ESI+ S 421 GC-MS/MS Silafluofen pyrethroid, non-ester GC-MS/MS Simazine triazine LC-MS/MS ESI+ Simazine triazine GC-MS/MS Spinosyn A strobilurin type LC-MS/MS ESI+ Spinosyn D strobilurin type LC-MS/MS ESI+ Spirodiclofen (F) acaricide LC-MS/MS ESI+ Spiromesifen, acaricide GC-MS/MS Spiromesifen, acaricide GC-MS NCI spirotetramate LC-MS/MS ESI+ spirotetramat-enol metabolite LC-MS/MS ESI+ spirotetramat-enol-glucoside metabolite LC-MS/MS ESI+ spirotetramat-keto-hydroxy metabolite LC-MS/MS ESI+ spirotetramat-mono-hydroxy metabolite LC-MS/MS ESI+ spiroxamine GC-MS/MS spiroxamine LC-MS/MS ESI+ Sulfentrazone triazolinone LC-MS/MS ESI-

Sulfotep organophosphate, acaricide LC-MS/MS ESI+ tau-fluvalinate (F) pyrethroid, acaricide GC-MS NCI 0,02 tau-fluvalinate (F) pyrethroid, acaricide GC-MS/MS 0,02 Tebuconazole triazole LC-MS/MS ESI+ Tebufenozide (F) LC-MS/MS ESI+ Tebufenpyrad (F) acaricide GC-MS/MS Tecnazene (F) GC-MS/MS Tecnazene (F) GC-MS NCI Teflubenzuron LC-MS/MS ESI- Tefluthrin (F) pyrethroid GC-MS NCI Tefluthrin (F) pyrethroid GC-MS/MS Terbufos organophosphate LC-MS/MS ESI+ Terbufos-sulfon LC-MS/MS ESI+ Terbufos-sulfoxid LC-MS/MS ESI+ Terbuthylazin, Desethyl- metabolite LC-MS/MS ESI+ Terbuthylazine triazine GC-MS/MS Terbuthylazine triazine LC-MS/MS ESI+ Terbutryn triazine LC-MS/MS ESI+ Tetrachlorvinphos organophosphate, acaricide GC-MS/MS Tetrachlorvinphos organophosphate, acaricide GC-MS NCI Tetraconazole (F) triazole GC-MS/MS Tetradifon acaricide GC-MS NCI Tetradifon acaricide GC-MS/MS Tetrahydrophthalimid metabolit GC-MS/MS 0,02 Tetramethrin pyrethroid GC-MS/MS Tetramethrin pyrethroid GC-MS NCI Tetrasul acaricide GC-MS/MS

Thiabendazole (R) benzimidazole LC-MS/MS ESI+ Thiacloprid (F) LC-MS/MS ESI+ Thiamethoxam, LC-MS/MS ESI+ Thiocyclam LC-MS/MS ESI+ 0,05 Thiodicarb, molluscocide LC-MS/MS ESI+ Thiofanox-sulfone, acaricide LC-MS/MS ESI+ Thiometon organophosphate, acaricide GC-MS/MS 0,05 Thiophanate-methyl (R) benzimidazole LC-MS/MS ESI+ TNFA (4-(trifluoromethyl)nicotinic acid) metabolite LC-MS/MS ESI- TNFG (N-(trifluoromethylnicotinoyl)glycin metabolite LC-MS/MS ESI- Tolclofos-methyl organophosphate GC-MS/MS Tolclofos-methyl organophosphate GC-MS NCI Tolylfluanid phenylsulfamide GC-MS/MS 0,03 0,03 Tolylfluanid phenylsulfamide GC-MS NCI 0,03 Transfluthrin pyrethroid GC-MS/MS Triadimefon triazole LC-MS/MS ESI+ Triadimenol triazole LC-MS/MS ESI+ Tri-allate LC-MS/MS ESI+ 0,03 Triazamat LC-MS/MS ESI+ Triazophos (F) organophosphate, acaricide, ne LC-MS/MS ESI+ Trichlorfon GC-MS/MS 0,1 0,1 Trichlorfon LC-MS/MS ESI+ Trichloronat organophosphate GC-MS/MS Triclopyr LC-MS/MS ESI- Tricyclazole LC-MS/MS ESI+ Trifloxystrobin (F) strobilurin type GC-MS/MS Trifloxystrobin (F) strobilurin type GC-MS NCI

trifloxysulfuron LC-MS/MS ESI+ Triflumizole imidazole LC-MS/MS ESI+ Triflumuron (F) LC-MS/MS ESI- 0,05 0,05 Trifluralin dinitroaniline GC-MS NCI Trifluralin dinitroaniline GC-MS/MS Triticonazole triazine LC-MS/MS ESI+ 0,05 0,05 Vamidothion organophosphate, acaricide LC-MS/MS ESI+ Vinclozolin dicarboximide GC-MS NCI Vinclozolin dicarboximide GC-MS/MS Zoxamide benzamide LC-MS/MS ESI+ single residue method (SRM) benzyldimethyldecylammonium chloride ( quaternary ammonium biozide LC-MS/MS ESI+ 0,5 benzyldimethyldodecylammonium chlorid quaternary ammonium biozide LC-MS/MS ESI+ 0,5 benzyldimethylhexadecylammonium chlo quaternary ammonium biozide LC-MS/MS ESI+ 0,5 benzyldimethyltetradecylammonium chlo quaternary ammonium biozide LC-MS/MS ESI+ 0,5 chlorate LC-MS/MS ESI- Chlormequat quaternary ammonium plant growth regulator LC-MS/MS ESI+ didecyldimethylammoniumchloride (DDA quaternary ammonium biozide LC-MS/MS ESI+ 0,5 dithiocarbamates GC-MS EI SIM Ethephon plant growth regulator LC-MS/MS ESI- Glyphosate glycine derivative LC-MS/MS ESI- 0,1 Maleic hydrazide (R) plant growth regulator LC-MS/MS ESI+ 0,1 Mepiquat quaternary ammonium plant growth regulator LC-MS/MS ESI+ perchlorate LC-MS/MS ESI- phosphorous acid LC-MS/MS ESI+ 0,1

*for not named matrices the scope ' ' will be analyzed **for these s validation data are available, they are not yet in the routine methode - but can be analysed on request.