CLASSIFICATİON OF HERBICIDES ACCORDING TO SITE OF ACTION

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1 CLASSIFICATİON OF HERBICIDES ACCORDING TO SITE OF ACTION HRAC A B acetyl CoA carboxylase (ACCase) acetolactate synthase ALS (acetohydroxyacid synthase AHAS) Aryloxyphenoxypropionate FOPs Cyclohexanedione DIMs Phenylpyrazoline DEN Sulfonylurea clodinafop-propargyl cyhalofop-butyl diclofop-methyl fenoxaprop-p-ethyl fluazifop-p-butyl haloxyfop-r-methyl propaquizafop quizalofop-p-ethyl alloxydim butroxydim clethodim cycloxydim profoxydim sethoxydim tepraloxydin tralkoxydim pinoxaden amidosulfuron azimsulfuron bensulfuron-methyl chlorimuron-ethyl chlorsulfuron cinosulfuron cyclosulfamuron ethametsulfuron-methyl ethoxysulfuron flazasulfuron flupyrsulfuron-methyl-na foramsulfuron halosulfuron-methyl imazosulfuron iodosulfuron mesosulfuron metsulfuron-methyl nicosulfuron oxasulfuron primisulfuron-methyl prosulfuron pyrazosulfuron-ethyl rimsulfuron sulfometuron-methyl sulfosulfuron thifensulfuron-methyl triasulfuron tribenuron-methyl trifloxysulfuron triflusulfuron-methyl tritosulfuron 1 2

2 C1 photosynthesis at photosystem II Imidazolinone Triazolopyrimidine Pyrimidinyl(thio)benzoate Sulfonylaminocarbonyltriazolinone Triazine Triazinone Triazolinone Uracil Pyridazinone Phenyl-carbamate imazapic imazamethabenz-methyl imazamox imazapyr imazaquin imazethapyr cloransulam-methyl diclosulam florasulam flumetsulam metosulam penoxsulam bispyribac-na pyribenzoxim pyriftalid pyrithiobac-na pyriminobac-methyl flucarbazone-na propoxycarbazone-na ametryne atrazine cyanazine desmetryne dimethametryne prometon prometryne propazine simazine simetryne terbumeton terbuthylazine terbutryne trietazine hexazinone metamitron metribuzin amicarbazone bromacil lenacil terbacil pyrazon = chloridazon desmedipham phenmedipham 5

3 C2 C3 D E photosynthesis at photosystem II photosynthesis at photosystem II Photosystem-I-electron diversion protoporphyrinogen oxidase (PPO) Urea Amide Nitrile Benzothiadiazinone Phenyl-pyridazine Bipyridylium Diphenylether Phenylpyrazole N-phenylphthalimide Thiadiazole Oxadiazole Triazolinone Oxazolidinedione Pyrimidindione chlorobromuron chlorotoluron chloroxuron dimefuron diuron ethidimuron fenuron fluometuron (see F3) isoproturon isouron linuron methabenzthiazuron metobromuron metoxuron monolinuron neburon siduron tebuthiuron propanil pentanochlor bromofenoxim bromoxynil ioxynil bentazon pyridate pyridafol diquat paraquat acifluorfen-na bifenox chlomethoxyfen fluoroglycofen-ethyl fomesafen halosafen lactofen oxyfluorfen fluazolate pyraflufen-ethyl cinidon-ethyl flumioxazin flumiclorac-pentyl fluthiacet-methyl thidiazimin oxadiazon oxadiargyl azafenidin carfentrazone-ethyl sulfentrazone pentoxazone benzfendizone butafenacil pyraclonil profluazol flufenpyr-ethyl

4 F1 F2 F3 G H I K1 Bleaching: carotenoid biosynthesis at the phytoene desaturase step (PDS) Bleaching: 4- hydroxyphenyl-pyruvatedioxygenase (4-HPPD) Bleaching: carotenoid biosynthesis (unknown target) EPSP synthase glutamine synthetase DHP (dihydropteroate) synthase Microtubule assembly inhibition K2 mitosis / microtubule organisation K3 VLCFAs (see Remarks) ( cell division) Pyridazinone norflurazon 12 Pyridinecarboxamide Triketone diflufenican picolinafen beflubutamid fluridone flurochloridone flurtamone mesotrione sulcotrione Isoxazole isoxachlortole Isoxazole isoxaflutole Pyrazole benzofenap Pyrazole pyrazolynate pyrazoxyfen benzobicyclon Triazole amitrole 11 (in vivo inhibition of lycopene cyclase) Isoxazolidinone clomazone 13 Urea fluometuron (see C2) Diphenylether aclonifen Glycine glyphosate 9 sulfosate Phosphinic acid glufosinate-ammonium 10 bialaphos = bilanaphos Carbamate asulam 18 Dinitroaniline benefin = benfluralin 3 butralin dinitramine ethalfluralin oryzalin pendimethalin trifluralin Phosphoroamidate amiprophos-methyl butamiphos Pyridine dithiopyr thiazopyr Benzamide propyzamide = pronamide tebutam Benzoic acid DCPA = chlorthal-dimethyl 3 Carbamate chlorpropham 23 propham carbetamide Chloroacetamide acetochlor 15 alachlor butachlor 27

5 L M N O cell wall (cellulose) synthesis Uncoupling (Membrane disruption) lipid synthesis - not ACCase inhibition Action like indole acetic acid (synthetic auxins) Acetamide Oxyacetamide Tetrazolinone Nitrile dimethachlor dimethanamid metazachlor metolachlor pethoxamid pretilachlor propachlor propisochlor thenylchlor diphenamid napropamide naproanilide flufenacet mefenacet fentrazamide anilofos cafenstrole piperophos dichlobenil chlorthiamid Benzamide isoxaben 21 Triazolocarboxamide flupoxam Quinoline carboxylic acid quinclorac (for monocots) (also group O) 26 Dinitrophenol DNOC 24 dinoseb dinoterb Thiocarbamate Phosphorodithioate Benzofuran Chloro-Carbonic-acid Phenoxy-carboxylic-acid Benzoic acid butylate cycloate dimepiperate EPTC esprocarb molinate orbencarb pebulate prosulfocarb thiobencarb = benthiocarb tiocarbazil triallate vernolate bensulide benfuresate ethofumesate TCA dalapon flupropanate clomeprop 2,4-D 2,4-DB dichlorprop = 2,4-DP MCPA MCPB mecoprop = MCPP = CMPP chloramben dicamba TBA

6 Pyridine carboxylic acid clopyralid fluroxypyr picloram triclopyr Quinoline carboxylic acid quinclorac (also group L) quinmerac benazolin-ethyl P auxin Phthalamate naptalam 19 transport Semicarbazone diflufenzopyr-na R S Z Unknown Arylaminopropionic acid Flamprop-M-methyl /-isopropyl 25 Note: While the site of action of herbicides in Z is unknown it is likely that they differ in site of action between themselves and from other groups. Pyrazolium difenzoquat 26 Organoarsenical DSMA 17 MSMA bromobutide (chloro)-flurenol cinmethylin cumyluron dazomet dymron = daimuron methyl-dimuron= methyl-dymron etobenzanid fosamine indanofan metam oxaziclomefone oleic acid pelargonic acid pyributicarb

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