Thermoplastic Composites

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Thermoplastic Composites A trend to keep an eye on Jos Lobée Polymer Innovation Day November 11 th 2014

Jos Lobée Education TU Delft 1985 GE Plastics 1987 2000, TNO Industry, Pezy Development Modified Materials BV 2008 - Engineering competences: product development polymer properties and polymer processing - Green projects - Co-operation Innovation coach DPI Value Centre

Thermoplastic composites Who are you? What is thermoplastic composite, and what can your company do with it? - Affordable strength and stiffness - Family of materials - Not suited for mirror-finish surfaces

Thermoplastic composites

Composites Mother Nature developed e.g. wood Fiber - binder combination, with good interaction: wetting and adhesion

Comparing with Thermosets Thermosets - Low viscosity resin, easily penetrating fibre material - Chemical bond to the fibre surface Thermoplastics - Viscous melt - Polymer modifications needed to get adhesion => Pre-impregnated materials

Impregnation with thermoplastics Fabric - Solvents method - Film stacking - Double belt press UD-Tape and Long Fiber granules - Impregnator head

Fibers Length of the fiber is a key determining factor: - Stiffness, Strength, Impact Fibers are supplied in several materials, forms and weights/m 2 - Glass, Carbon, Aramid, Basalt - Seizing - Fabric weave types: plain, twill, satin, random, Uni Directional

Fiber type, fiber content Practical limit % Strength, Stiffness, Cost Uni Directional Woven Fabric Random fiber % fiber 25 50 75

How to process Thermoplastic composites Heat, shape, cool Fibers can be curved, not stretched. 2D ++ Welding vs. adhesive bonding Recycle by hacking and melting Combine with other processes

K 2013 Three suppliers Arburg, Engel, Kraus Maffei with un-manned, automatic running production unites.

What is happening in the market? Important major trends: Reduce CO2, increase fuel efficiency Deep water oil-gas drilling Increased comfort, reduce fysical efforts Fast moving machine parts High pressure containers for CNG and H2

Boeing 787 Dreamliner

BMW i3 en i8

Cato

Automated high speed tape processing AFPT : Tape placement 10 30 kg per uur

Where is it happening? Germany, in the Achen and Munich region - Mega clusters, mega budgets - We need to speed up to keep up The Netherlands - Tech University Enschede and Delft - TPRC and NLR - Saxion, Windesheim, InnHolland - Multinationals: Sabic, DSM, Fokker, Ten Cate, Voest Alpine, PPG - Less than 10 SME s, few applications at OEM s

For you: long fiber granules Standard injection moulding material - Increased stiffness: E = 7000 N/mm2 and more - Increased strength: LG-PP is stronger than GF-PA - Increased impact: min. factor 2 vs short glass - Improved creep resistance - Lower orientation CMB, Hendrikx, Peters, MoMa Needed: mild screw, gating

For you: tape Winding around mould or plastic product Hot air gun, and rotating axis CMB, Hendrikx, Peters, MoMa

For you: tape properties Fiber is the determining factor - E-module 70 Gpa - Strength 2 GPa - Glass content 60% (wt) 35 % (vol) 0,35*25 mm tape contains ca. 3 mm2 glass. Theoretical tensile strength 6000 N in length direction Thermoplastic material determines e.g. use temperature, processing, adhesion. In bending the thermoplastic material transmits the loads

For you: Fabric Voest Alpine Roosendaal

For you: Fabric properties Properties are depending on fiber direction, weave, polymer etc. Example: Tepex dynalite 104-RG600 47% glass-pp Fiber direction 80-20 80% 20% - Tensile modulus 30 Gpa 14 Gpa - Tensile strength 470 Mpa 160 Mpa - Flex modulus 24 Gpa 10 Gpa - Flex strength 545 Mpa 160 Mpa

Challenges Supply and development Young industry, part manufacturing capacity is being built Part developments are more complex, co-operation is likely and smart Colours Technology Surface quality Edge finish Thermal expansion differences

Possible applications Pressurised systems - Piping and couplings, storage tanks Moving systems - Automotive, scooters, bicycles - Buggy s, wheel chairs - Machine parts Portable systems - Measing devices, tools - Sporting goods, care market - Furniture Material replacement: metal assemblies, die-cast aluminum, thermosets, thick wall injection products.

DPI Value Centre Thermoplastic composites multi discipline - Thermoplastics - Fibers / textile - Composite engineering, QA DPI Value Centre s role is to speed up and improve innovation at SME s. Building networks and clusters is daily work. We are planning to set up cluster projects in Q1 2015. Please contact me if you are interested.

Thank you!