Late Stages of Stellar Evolution

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Late Stages of Stellar Evolution Low to Intermediate Mass Stars Section 7: Circumstellar Envelopes

CSE Size and Density Because of mass loss, AGB stars are surrounded by a substantial circumstellar envelope (CSE). For a life time of 106 years and a wind velocity of 10 km/s, these would be 1019 cm (3 pc) in size. Mixing with the ISM and motion through the ISM make them smaller. Size of observable CSE: ~1017 cm. For a constant velocity and mass loss rate: 2

Density Variations Nearest C-star: IRC10+216. Scattered light image, showing the dusty CSE, with density variations.

CSE Temperature The temperature of the CSE has two components: Gas temperature: Drops with radius because of adiabatic expansion: T r -4/3 In addition heating and cooling processes operate Heating: collisions with dust grains Cooling: line cooling (H2O, CO, HCN) Typical solution: Tg (r) 400 (1015 cm / r)0.9 Dust temperature: Balance between heating and cooling: Heating: absorption of star light (IR) Cooling: radiation (longer wave lengths) For both the frequency-dependent absorption/emission is crucial. At different wavelengths you see different parts of the dusty envelope. Td (r) T* (R* / 2r)0.4

CSE Chemistry

Chemical Diversity

LTE Chemistry Model Chemical models for 3 different chemical compositions: 2. C<O C O C>O

Known Inter/Circumstellar Molecules 2 3 4 + H2 CH H2O C3 NH3 OH CN H2S MgNC H3O+ SO CO SO2 NaCN H2CO SO+ CS NNH+ CH2 H2CS SiO C2 HNO MgCN HNCO SiS SiC SiH2 HOC+ HNCS NO CP NH2 HCN CCCN + + NS CO H3 HNC HCO2+ HCl HF NNO AlNC CCCH NaCl SH HCO SiCN c-c3h KCl HD HCO+ SiNC CCCO AlCl OCS H2D+ C3S AlF CCH NH2 HCCH PN HCS+ KCN HCNH+ SiN c-sicc HCCN NH CCO H2CN CH CCS c-sic3 CH2D+ 5 6 SiH4 CH3OH CH4 NH2CHO CHOOH CH3CN HC CCN CH3NC CH2NH CH3SH NH2CN C5H H2CCO HC2CHO C 4H CH2=CH2 c-c3h2 H2C4 CH2CN HC3NH+ C5 C5N SiC4 C5S? H 2C 3 HCCNC HNCCC H2COH+ 7 CH3CHO CH3NH2 CH3CCH CH2CHCN H(C C)2CN C 6H c-ch2och2 H2CCHOH 8 CH3CO2H HCO2CH3 CH3C2CN C 7H H 2C 6 CH2OHCHO HC6H 15 ions 5 rings ~100 Carbon Molecules 19 Refractories ~70 isotopomers 9 10 CH3CH2OH CH3COCH3 (CH3)2O CH3(C C)2CN CH3CH2CN (CH2OH)2 H(C C)3CN NH2CH2CO2H H(C C)2CH3 11 C 8H H(C C)4CN 12 13 H(C C)5CN Total = 132

Chemical Reactions in the Gas Phase Slowest reactions: neutralneutral Fastest reactions: radical-radical and moleculeion

Chemical Reactions on Grains

Physical/Chemical Processes on Dust Some chemical reactions (e.g. neutral-neutral) happen much more efficiently on the surfaces of grains. Best known example: formation of H2. Also others: methanol for example.

Chemistry in Observations The complex chemical structure of AGB CSEs can be observed in some case. Here: IRC+10216 (nearby extreme C-star). Molecular shells of varying radii: Abundance of molecule Temperature & radiation field (optical depth effects).

Chemical Networks To calculate the distribution of molecules, so called chemical networks are used: ~12 elements (H, He, C, N, O, S, Si, Fe, Na, Mg, P, Cl). ~400 molecules ~4000 reactions (not all with known rates) Solve for chemical equilibrium: formation rate = destruction rate. To calculate emissivity, the level populations need to be known, so also the radiation field (from star and molecular lines) and the temperature structure needs to be solved for.

Observational Regimes AGB stars and the material in their envelopes emit radiation at different wavelengths: Optical: Stellar photosphere, atoms and molecules. Near-infrared (1-5 μm): CSE, molecules and dust features. Mid-infrared (5 25/40 μm): Molecules, dust Far-infrared (25/40 200/350 μm): Molecules, dust Submm/mm (0.3 5mm): Molecules Cm: SiO, H2O, OH maser emission

Richness of the Submm/mm Regime IRC10+216 at 2mm:

Molecules Observed in Submm-Radio List of molecules detected in the submm-radio regime. Σ indicates the number of objects in which the molecule was found. The Σ=1 cases for Cmolecules is mostly IRC +10216.

Radio/submm Facilities For these long wavelengths, imaging is problematic due to the low resolution of single telescope dishes (λ/d). High resolution imaging requires interferometry. Only a handful submm/mm interferometers exist: IRAM Plateau de Bure, CARMA, SMA. IRAM, PdB SMA with JCMT

ALMA The Atacama Large Millimeter Array is currently under construction at a site at 5km altitude in the Chilean Andes. Partners: NRAO (USA), ESO, Japan. ALMA will consist of some 50 antennas, and be the largest submm facility in the world.

Radio/Submm Data Radio antennas provide signal over a range of frequencies. So, not only emission/image data, but also velocity data. In the best case this allow one to map a source as a function of frequency: image cube or channel maps. In the worst case this gives you only a line profile (no image data).

TT Cyg Different velocities give you different cross section of the shell

Velocity Mapping vexp Observer v= -vexp v=0 v=vexp

Line Shapes When good image capability is lacking (source is too small for your telescope), the velocity information can still be used to derive properties of CSE. a): optically thin, unresolved. b): optically thick, unresolved c): optically thin, resolved d): optically thick, resolved e): thin shell, resolved f): double component g,h): masers

Optically Thin & Thick Lines Line emission can be optically thin ( transparent ) and optically thick ( opaque ). Simplified description: In the optically thin case you see emission from the entire emitting region (line width ~ 2vexp). In the optically thick case you only see emission from surfaces of optical depth ~1. Doppler shifts allow you to still see part of the interior (line width still ~ 2vexp). CO is so abundant, its lines quickly becomes optically thick. Observe 13CO lines for optically thin lines.

Far-Infrared Observations The FIR regime contains molecular lines, and thermal radiation from cold dust. It is not at all well explored, since the Earth s atmosphere blocks these wavelengths. There is only limited satellite data: IRAS (1985): images at 60 and 100 μm. Odin (2000-2007): H2O and NH3 detections. End of 2008: launch of Herschel (60 670 µm).

Near/Mid-Infrared Observations This wave length regime is partly observable from Earth, through various atmospheric windows.

Near/Mid-Infrared Satellite Observations For a good continuous coverage of wide wavelength range, space-based spectroscopy is needed. Recent missions: ISO, Spitzer. Especially ISO revealed the richness of NIR/MIR spectroscopy. This wave length range shows absorption/emission lines, but also many features: broad absorption (Δλ/λ~0.1) due to complex molecules, ices and dust. These ISO spectra led to a new field, known as astromineralogy, the study of various minerals around stars and in the ISM and comparison to laboratory spectra (e.g. Fosterite (Mg2SiO4), Enstatite (MgSiO3), Olivine ( (Fe,Mg)SiO4), Spinel (MgAl2O4))

Example of Astromineralogy Observations Lab Post-AGB star: MWC 922 (Molster 2000)

IR: Molecular Lines and Features

ISO Spectra ISO, SWS spectrum for M and C-star, as well as a star showing a mixed chemistry (V778 Cyg). ISO, LWS spectrum for M-star

Masers A special class of observations from AGB stars are formed by the masers. AGB stars show maser emission in the (radio) lines of SiO (43, 86 GHz) H2O (22 GHz) OH (1612, 1622 MHz) And some others (HCN, CS, SiS). The maser phenomenon occurs when there is a population inversion (higher energy state more populated than lower energy state). This requires a so-called maser pump (collisions or radiation).

Maser Mechanism An inverted population means that instead of absorption, stimulated emission becomes dominant. This leads to an amplification of the photon flux ( negative optical depth ).

Maser Physics The maser emission gets amplified as long as the pump can counteract the de-excitation caused by the stimulated emission. Beyond that point the maser is said to saturate. Since the induced emission is like a positive absorption, far from saturation the intensity increases exponentially: This means that masers can be very bright, which makes them easily observable, and to very large distances.

Different Zones

Maser Spots The SiO and H2O maser emission is dominated by maser spots: small regions of bright emission. The spots show shell-like distributions, but are difficult to map back to any density distribution since the maser process is so non-linear. H2O masers spots

OH Maser Shells The OH masers form in the photo-dissociation region of H2O, so at relatively large radii, ~1017 cm. In contrast to the other two types, OH maser emission is often found in shell-like configurations. The spectral line therefore consists of a characteristic double peaked profile. The pump for the OH maser is IR radiation from the star, and so the maser emission follows the variability of the star.

OH Maser Observations The variability of the two peaks are slightly out of phase, because of the light travel time from the star to the OH maser shell: Δt=Dshell/c If we measure the angular size of the shell, we can find the distance to the object.

OH Maser Shell Channel Maps

Astrometry with OH Masers For bright masers, it is also possible to observe them with Very Long Baseline Interferometry (VLBI). This gives a positional accuracy of 1mas. Monitoring the movement of maser spots over many years allows you to find proper motion and parallax to the star: Errors on VLBI distance: 10-20% Vlemmings et al.