Seawater Reverse Osmosis Design and Optimization

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Advanced Membrane Technologies Stanford University, May 07, 2008 Seawater Reverse Osmosis Design and Optimization Nikolay Voutchkov, PE, BCEE

Typical Desalination Cost-of-Water Breakdown Item Percent of Total Cost of Water (*)( SWRO System 40 % Energy 30 % Intake, Discharge & Pretreatment 15 % Other Costs 15 % Total Cost of Water 100 % (*) Note: Percentage Could Vary Depending on Project-Specific Factors

Performance Optimization Focus SWRO System Design & Operations; Energy Reduction; Intake & Discharge Configuration/Collocation;

Optimizing RO System Performance Size Matters! Large SWRO Trains; Large RO Membrane Elements; Alternative RO Train Configurations; Internally Staged Design.

Trinidad SWRO Plant the Largest SWRO Trains In Use 5.5 MGD

Large SWRO Membrane Elements Large Size RO Membranes Advantages Potential Space Savings 10 to 15 %. Capital Cost Savings 5 to 10 %. Total Cost of Water Savings 4 to 6 % Standard 8 RO Membrane Element 16 RO Membrane Element Potential Disadvantages Loading Requires Special Equipment and Extra Space. Uneven Flow Distribution Accelerated Fouling. Special Vessels Needed.

Large Element Space Savings Could Be Elusive! Brackish Desalination Plant Yuma, Arizona 12-inch RO Elements Large Space Needed For the Machine For Element Loading!

Large-Diameter SWRO Vessels in Vertical Position I 17 Easy Load 16 Vertically Positioned PV Large & Smart Membranes 13 Brine Pro R 15 Brine Pro R Brine Pro R Brine Pro R Brine Pro R Brine Pro R 10 11 31 31 31 33 12 Feed Pro F 14 Feed Pro F Feed Pro F Feed Pro F Feed Pro F Feed Pro F Source: IDE

Optimizing Performance by Redistributing Flux/Energy Flux of First Element Can Be Reduced by: 1.Increase in Permeate Pressure: Permeate Pressure Control Valve; Permeate Interconnector Disk (Acciona). 2. Inter-stage Design: Low Permeability/High Permeability Membrane Combo. 3. Decrease in Feed Pressure: Two Pass RO System w/ Interstage Booster Pump; Nano-Nano Configuration. Flux is Proportional to the Difference of the Feed and Permeate Pressure

Internally Staged Design (1-1-5) Element Flow at Standard Test Conditions ~7500 ~9000 ~12500 gpd gpd gpd Compared to standard SWRO design, ISD SWRO offers: - Higher average permeate flux with same lead element flux; - Good permeate quality; - Energy Savings - 5% - 10%; Courtesy: Dow Chemical

Two-Pass RO Systems TDS < 50 mg/l Interstage Booster Pumps Two-Pass RO Systems (Perth, Tuas, Trinidad)

34 MGD Point Lisas SWRO Plant, Trinidad Two Pass /Two-stage SWRO System TDS = 35 ppt TDS = 85 mg/l

Reducing Power Use A Hair Rising Challenge? Putting Power Use in Prospective; Improving Energy Recovery; Maximizing Pump Efficiency; Desalination Plant Collocation; Source Water Salinity & Energy.

Putting Desalination Power Use In Prospective Power Needed to Produce Drinking Water from Seawater for One Family for One Year is Over Two Times Lower than the Power Used by Family s Water Heater! Treatment Power Use (kwh/kgal) Conventional Surface Water 0.8 to 1.6 Water Imports - Pumping 6.0 to 10.6 Reclamation Of Municipal Wastewater 3.0 to 5.0 Seawater Desalination 7.5 to 10.0

Reducing Energy for SWRO Practical Solutions Pressure Exchanger Energy Recovery (35 to 40 % Energy Reduction); Use of Alternative RO Membrane Vessel Configurations (10 to 15 % Energy Reduction); Application of Large RO Trains/Pumps (3 to 5 % Energy Reduction); Use of Warm Power Plant Cooling Seawater (5 to 10% Energy Reduction).

Improving Energy Recovery Pressure Exchangers Dhekelia, Cyprus SWRO Plant Barbados SWRO Plant 5 to 15 % Better Recovery than Traditional Pelton Wheel Systems

Maximizing Pump Efficiency Pump Efficiency ~ n x (Q/H) 0.5 x (1/H) 0.25 Carboneras, Spain & Perth One Pump per 2 RO Trains Where: n = pump speed (min - ¹); Q = nominal pump capacity (m³/s); Ashkelon, Israel Two Pumps per 16 RO Trains H = pump head (m). Pump Efficiency: One Pump Per Train 83 %

Flattening the Pump Curve For Wide Range of Flows - The Three-Center Design Lowest Energy Use SWRO Plant Worldwide 14.4 kwh/kgal @ 40 ppt

Change in SWRO Plant Operations Paradigm! Tri-Center Design Delivers Varying Flow by Change in Recovery Rather than By Turning RO Trains On & Off!

Energy Use and Temperature Energy Use (kwh/m3) Use of Warm Water May Be Beneficial! Use of Intake Wells or Deep Intakes May Result in Energy Penalty! 4.5 4 3.5 3 2.5 2 Disproportional Increase Above 12 C Proportional to Temperature Between 12 and 38 C 4 8 12 16 20 24 28 32 36 40 Temperature, degrees C

Collocation with Power Plant Desalination Plant Intake & Discharge Connection to Power Plant Discharge Avoids Construction of: New Intake; New Discharge; New Screening Facilities.

Potential Energy Benefits of Collocation Reduced Intake and Discharge Pumping Costs (1-2% Power Savings). Power Cost Savings due to Warmer Source Water (5-15 % Power Use Reduction). Use of Power Plant Spinning Reserve Energy Where Available. Potential Avoidance of Power Grid Connection Charges/Power Tariff Fees.

Collocation Capital Cost Savings Avoidance of Construction of New Intake & Discharge Facilities 10 to 50 % of Construction Costs; Avoidance of Construction & Operation of New Screening Facilities; Electrical System Cost Savings: Lower or No Power Grid Use Tariff Charge; Use of the Spinning Reserve of Must Run Power Plants.

Collocation in Tampa, Florida

Collocation Concepts in Ashkelon Power Plant Desalination Plant Ashkelon Power Generation Plant - Waste Heat Used to Warm Intake Seawater Co-discharge of Cooling Water and Concentrate

Main Areas Expected to Yield Cost Savings in the Next 5 Years Improvements in Membrane Element Productivity: - Nano-composite SWRO Membranes; - Larger Membrane RO Elements (16 Diameter or Higher). Increased Membrane Useful Life and Reduced Fouling: - Increased Membrane Material Longevity; - Use of Systems for Continuous RO Membrane Cleaning; - UF/MF Membrane Pretreatment. Wider Use of Pressure Exchanger Type Energy Recovery Systems; Co-Location With Power Plants; Larger RO Trains and Equipment; Full Automation of All Treatment Processes.

SWRO Performance Optimization - Future Improvements Will Come From Better Membranes and Lower Cost Materials! Questions?