Acrylic Binders for Water-borne Industrial Coatings



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Dow Coating Materials Industrial Coatings Solutions Acrylic Binders for Water-borne Industrial Coatings Version January 2016

Dow Coating Materials 2 Industrial Coatings Solutions

Industrial Coatings: tough performers for tough environments. Content 04 The Acrylic Advantage 05 About Dow 06 Industrial Coatings 06 Maintenance and Protective 07 Rail and Container Coatings 08 Concrete 09 Road Marking 10 Furniture and Polished Wood Trademark of The Dow Chemical Company ( Dow ) or an affiliated company of Dow. 3

Dow Coating Materials Introduction The Acrylic Advantage Few binder chemistries for industrial coatings match the simplicity and performance offered by water-borne acrylic resins from Dow Coating Materials. In the field, our acrylic chemistries help applicators set up faster, spray safer and return to service sooner. In the factory, they help manufacturers maintain production speed, increase volume, and satisfy consumer preference. All with a signature combination of high performance and low VOC. PRIMAL Emulsions Based on nationally recognized acrylic emulsion technology, PRIMAL Emulsions are used extensively in the industrial coating of wood, metal, plastic and concrete substrates. They offer easy handling, low- VOC capability and high performance in water-borne coatings. ROSHIELD Emulsions From factory-coated furniture to fieldcoated joinery, ROSHIELD Emulsions offer fast dry, excellent hardness and resistance properties, and warmth over fine wood substrates. These properties are helping formulators, coaters and manufacturers meet increasingly stringent VOC targets while maintaining aesthetics, process speed and productivity. MAINCOTE Emulsions Featuring the industry s first water-borne binder for direct-to-metal (DTM) application, MAINCOTE Emulsions continue to set the standard for low-voc metal coatings. Available as one-component and two-component solutions for new build and maintenance of structural steel, storage tanks, bridges, railcars, and interior and exterior coatings for commercial buildings. AVANSE Technology From one-coat finishing to multi-layer maintenance and protection, coatings made with AVANSE Technology offer onecomponent convenience and performance level that stands up to a wide range of environments. These properties are helping to expand the use of water-borne coatings for maintenance and protective applications. FASTRACK Emulsions Acrylic water-based traffic paints are not flammable, can be applied at ambient temperatures and offer the potential to reduce VOC (Volatile Organic Compounds) emissions related to road striping by up to 90 %. Combined with their excellent road performance, this makes them a preferred road-marking solution from the points of view of worker s safety and environmental impact. 4 Industrial Coatings Solutions

About Dow Dow is a leading supplier of acrylic resins for water-borne industrial coatings that can offer safer and easier handling, faster set-up and application, lower VOC emissions, and performance properties that equal or surpass traditional solvent-borne options. Whether your application requires corrosion resistance for direct-to-metal (DTM) applications, early block resistance for wood furniture, or a durable, high-gloss finish for concrete flooring, water-borne acrylics from Dow offer a wide spectrum of performance properties that can be tailored to suit your application needs. Set up faster and spray safer with water-borne coatings powered by Dow. Replacing solvent-borne coatings with high-performance waterborne alternatives can offer many advantages, including reduced solvent exposure and associated health risks, fewer concerns with flammability and the impact on insurance costs, easy soap-and-water clean-up, less hazardous waste disposal and associated cost, and, in the case of one-component coatings, less mixing and less waste. Dow technologies can help you make the transition quickly and effectively, with minimal capital cost or downtime, equal or better coating performance, and all the ease and convenience that comes with the use of water-borne coatings. More Performance Dow Acrylic Emulsions help water-borne coatings perform at a level that is comparable to solvent-borne coatings and in some cases better. More Safety Low odor, low VOC and no flammability are key applicator benefits offered by Dow Water-borne Acrylics for industrial coatings. More Flexibility Making the switch from solvent-borne to water-borne coatings often allows for trades to work side by side, helping to keep project schedules on track. Less Mixing Acrylic Emulsions from Dow bring high performance to one-component water-borne coatings that are ready to spray with less mixing and no induction time. Less Clean-Up Spray equipment is easier to clean and rinse water is easier to dispose of when applications are made with water-borne coatings powered by Dow Acrylics. Less Waste One-component coatings powered by Dow Water-borne Acrylics have no pot life. Applicators can use what they need and save the rest. Trademark of The Dow Chemical Company ( Dow ) or an affiliated company of Dow. 5

Industrial Coatings Maintenance and Protective Offering environmental, health, and safety benefits, as well as proven performance in real world exposures, water-borne acrylics are an excellent choice for painting in light-tomedium-duty environments. Today, Dow advances in acrylic latex design and formulation are expanding the utility of water-borne acrylic coatings to more demanding environments across a range of metal substrates, including structural steel, chemical and processing equipment, storage tanks and commercial architecture. Product Wgt Solids % ph MFFT C Density gm/ml Applications Thermoplastic water-borne Acrylic Copolymers MAINCOTE 1100 50.5 9.0 14 1.040 Excellent corrosion resistance, durability, metal adhesion and formulation versatility. Based on AVANSE Self-crosslinking Emulsion Technology. Low VOC capability (100 g/lt or less). MAINCOTE HG-86 43.5 8.5 31 1.026 Excellent corrosion resistance, gloss, durability, metal adhesion and chemical resistance. MAINCOTE PR-71K 50.5 9.0 20 1.050 Excellent adhesion to untreated aluminium, galvanised steel. Excellent corrosion resistance. New construction and maintenance painting of tanks, bridges, structural steel. Steel and concrete structures, railcars, Commercial architecture and DIY. New construction and maintenance painting of steel structures, railcars, bridges, concrete and masonry. Maintenance primers. Corrosion-resistant primers. Storage tanks, bridges, railcars, etc. Ambient Curing Two-Component Crosslinking Technology MAINCOTE AEH-20 50.5 7.0 1.060 MAINCOTE AEH-20 Acrylic- Epoxy Hybrid Resin is designed for two-pack (2K) ambient-cure coatings (with water-borne aminebased curing agent). Paints based on MAINCOTE AEH-20 Acrylic- Epoxy Hybrid Resin offer excellent anti-corrosion resistance, abrasion resistance, chemical resistance and hardness, which can be close to traditional 2K water-borne epoxy/ amine thermo-set coatings. It can also be formulated into water-borne concrete coatings. Reduced VOC, Zero to < 50 g/lt. Better low temperature cure/dry time. Improved UV resistance compared to traditional epoxy coatings. Increased productivity via longer pot-life and faster return to service. Improved cost-effective solution. Well suited for concrete floor and wall coatings, Industrial maintenance and protective coatings and civil engineering applications. (These are typical properties, not to be construed as specifications.) 6 Industrial Coatings Solutions

Rail and Container Coatings Rail Car and Freight Container Coatings require resins that can stand up to the destructive nature of the elements, including water, temperature swings, sunlight, and corrosive salts and chemicals. Dow water-borne binders offer easy direct-to-metal (DTM) spray application plus cross-linking for exceptional chemical resistance and durability. Additional properties include excellent early water resistance, corrosion resistance, gloss and color retention, abrasion resistance and flexibility/impact resistance, making these resins ideal for exteriors of boxcars, hopper cars, tank cars and other rail transportation applications. Product Wgt Solids % ph MFFT C Density gm/ml Applications Thermoplastic water-borne Acrylic Copolymers MAINCOTE 1100A 50.5 9.0 14 1.040 Excellent corrosion resistance, durability, metal adhesion and formulation versatility. Based on AVANSE Self-crosslinking Emulsion Technology. Low VOC capability (100 g/lt or less). MAINCOTE HG-86 43.5 8.5 31 1.026 Excellent corrosion resistance, gloss, durability, metal adhesion and chemical resistance. PRIMAL WL-100 49.5 9.0 48 1.044 Highest gloss and DOI (Distinctness of Image) of the WL line. New construction and maintenance painting of tanks, bridges, structural steel. Steel and concrete structures, railcars, Commercial architecture and DIY. New construction and maintenance painting of steel structures, railcars, bridges, concrete and masonry. High gloss metal, plastics Ambient Curing Two-Component Crosslinking Technology Ambient Curing Two-Component Crosslinking Technology MAINCOTE AEH-20 50.5 7.0 1.060 MAINCOTE AEH-20 Acrylic- Epoxy Hybrid Resin is designed for two-pack (2K) ambient-cure coatings (with water-borne aminebased curing agent). Paints based on MAINCOTE AEH-20 Acrylic-Epoxy Hybrid Resin offer excellent anti-corrosion resistance, abrasion resistance, chemical resistance and hardness, which can be close to traditional 2K water-borne epoxy/amine thermo-set coatings. It can also be formulated into water-borne concrete coatings. Reduced VOC, Zero to < 50 g/lt. Better low temperature cure/dry time. Improved UV resistance compared to traditional epoxy coatings. Increased productivity via longer pot-life and faster return to service. Improved cost-effective solution. Well suited for concrete floor and wall coatings, Industrial maintenance and protective coatings and civil engineering applications. (These are typical properties, not to be construed as specifications.) Trademark of The Dow Chemical Company ( Dow ) or an affiliated company of Dow. 7

Industrial Coatings Concrete Making the switch from solvent-borne to water-borne concrete coatings brings many immediate advantages, including lower VOC emissions, lower odor and reduced fire hazard. Water-borne acrylic resins from Dow can combine enhanced user safety with high performance properties, including excellent resistance to water blushing, low water pickup, low coalescent demand, good exterior weatherability, and reduced water vapor permeability. Product Wgt Solids % ph MFFT C Density gm/ml Applications Thermoplastic water-borne Acrylic Copolymers MAINCOTE 1100A 50.5 9.0 14 1.040 Excellent corrosion resistance, durability, metal adhesion and formulation versatility. Based on AVANSE Self-crosslinking Emulsion Technology. Low VOC capability (100 g/lt or less). MAINCOTE HG-86 43.5 8.5 31 1.026 Excellent corrosion resistance, gloss, durability, metal adhesion and chemical resistance. PRIMAL WL-91 41.5 7.5 57 1.036 Best solvent and chemical resistance in the WL line. Good adhesion and stability with reactive pigments. MAINCOTE AEH-20 50.5 7.0 1.060 MAINCOTE AEH-20 Acrylic- Epoxy Hybrid Resin is designed for two-pack (2K) ambient-cure coatings (with water-borne aminebased curing agent). Paints based on MAINCOTE AEH-20 Acrylic- Epoxy Hybrid Resin offer excellent anti-corrosion resistance, abrasion resistance, chemical resistance and hardness, which can be close to traditional 2K water-borne epoxy/amine thermo-set coatings. It can also be formulated into water-borne concrete coatings. New construction and maintenance painting of tanks, bridges, structural steel. Steel and concrete structures, railcars, Commercial architecture and DIY. New construction and maintenance painting of steel structures, railcars, bridges, concrete and masonry. Textured finishes and business machine coatings. Commercial architecture. Clear sealers for concrete. Reduced VOC, Zero to < 50 g/lt. Better low temperature cure/dry time. Improved UV resistance compared to traditional epoxy coatings. Increased productivity via longer pot-life and faster return to service. Improved cost-effective solution. Well suited for concrete floor and wall coatings, Industrial maintenance and protective coatings and civil engineering applications. (These are typical properties, not to be construed as specifications.) 8 Industrial Coatings Solutions

Road Marking Road markings, which provide lane delineation and important guidance to drivers, pedestrians, cyclists, and other roadway users, are essential to roadway safety. Since Dow introduced the first fast drying water-based road marking binders in the early 1990 s, FASTRACK Emulsions have been the market leader and set the standard in highway markings worldwide. FASTRACK Emulsions used in conjunction with glass beads give excellent durability for a long service life and allow for high levels of retroref lectivity for good night time visibility. Dow s FASTRACK Emulsions range allows the paint formulator to produce paints to achieve the required durability, dry speed and budgets of the market. Product Solids % MFFT C FASTRACK 3427A 50.5 24 FASTRACK 3427A Emulsion is a 2nd generation 100 % acrylic polymer for fast-dry water-borne traffic marking paints with improved durability and adhesion. Traffic marking paints based on FASTRACK 3427A Emulsion feature fast dry over a broad range of application conditions and excellent durability in terms of retention of glass beads for night visibility, and wear properties over asphalt, concrete and old markings. FASTRACK 53 51.5 34 FASTRACK 53 Emulsion is a 100 % acrylic polymer designed for use in water-borne traffic marking paints, especially when application occurs under marginal conditions of temperature, humidity and air flow. Commercial applications and road trials have proven that traffic marking paints formulated with FASTRACK 53 Emulsion are significantly faster drying in high humidity, low temperatures and poor air flow conditions, compared to conventional water-based traffic paints. This fast dry capability dramatically improves the resistance of markings to early rain showers (early wash-out resistance) and the higher Tg offers improved dirt resistance. FASTRACK HD-21A 49.2 25 FASTRACK HD-21A Emulsion is a 100 % acrylic polymer for high-durability traffic markings. It is designed for situations where existing water-borne paint equipment is available, and where the additional benefits of rapid drying and excellent glass bead retention are critical. (These are typical properties, not to be construed as specifications.) Trademark of The Dow Chemical Company ( Dow ) or an affiliated company of Dow. 9

Furniture and Polished Wood Regulatory and consumer-driven interest in lowering VOCs and HAPS are giving wood and composite wood manufacturers strong incentive to replace solvent-borne coatings with water-borne alternatives. Dow high-performance acrylic binders for furniture, kitchen cabinets, molding, joinery and other wood and engineered wood products are low-voc capable and offer performance properties that are comparable to solvent-borne standards, including excellent chemical and stain resistance, scratch and mar resistance, early block and print resistance and excellent film clarity. Applications Coating System Product Wgt Solids % ph MFFT C Antique look furniture European style furniture Joinery Special application Clear primer Clear topcoat Pigmented primer Pigmented topcoat Stain Thermoplastic water-borne Acrylic Copolymers ROSHIELD 530 46.5 7.8 25 Emulsion with superior water whitening resistance. Good durability for exterior application, good adhesion on special substrates like bamboo and rattan. ROSHIELD 3311 40.5 7.5 42 New generation core-shell selfcrosslinking 100 % Acrylic emulsion with high transparency. Good water resistance and chemical resistance. X X X X X X X X Thermoplastic water-borne Styrene Acrylic Copolymers ROSHIELD 530 38.0 8.0 62 New generation hard 100 % Acrylic Emulsion with excellent water resistance and film hardness. Good early sanding ability and block resistance. X X X X X X Polyurethane modified Acrylic Copolymers PROSPERSE 100 40.0 7.6 27 Polyurethane acrylic emulsion with ambient self-crosslinking technology. Good balance of hardness and flexibility. Good water and chemical resistance, quick hardness development and early block resistance. X X X (These are typical properties, not to be construed as specifications.) 10 Industrial Coatings Solutions

Trademark of The Dow Chemical Company ( Dow ) or an affiliated company of Dow. 11

Picture credits istockphoto LP: Title, P. 2 pic. 02 08, P. 3, P. 5 pic. 01 + 02, P. 6, P.7, P. 8, P. 9, P. 10 Thinkstock: P. 2 pic. 01, P. 4 Note: except otherwise expressly specified, the graphs and tables presented in this document originate from internal studies conducted by Dow in 2016 For more information please consult our web site www.dowcoatingmaterials.com Dow Chemical International Pvt. Ltd. 1st Floor, Block B-02, Godrej IT Park, Pirojshanagar, LBS Marg, Vikhroli West, Mumbai, Maharashtra 400079, India Phone: +91 22 6674 1500 Fax: +91 2266741825 infoindia@dow.com Notice No freedom from infringement of any patent owned by Dow or others is to be inferred. Because use conditions and applicable laws may differ from one location to another and may change with time, Customer is responsible for determining whether products and the information in this document are appropriate for Customer s use and for ensuring that Customer s workplace and disposal practices are in compliance with applicable laws and other government enactments. The product shown in this literature may not be available for sale and/or available in all geographies where Dow is represented. The claims made may not have been approved for use in all countries. Dow assumes no obligation or liability for the information in this document. References to Dow or the Company mean the Dow legal entity selling the products to Customer unless otherwise expressly noted. NO WARRANTIES ARE GIVEN; ALL IMPLIED WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE ARE EXPRESSLY EXCLUDED. Trademark of The Dow Chemical Company ( Dow ) or an affiliated company of Dow. Form No. B28-EUR 843-02260-0116 EN