Figure 1 Wafer with Notch

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Glass Wafer

2 SCHOTT is an international technology group with more than 125 years of experience in the areas of specialty glasses, materials and advanced technologies. With our high-quality products and intelligent solutions, we contribute to our customers success and make SCHOTT part of everyone s life. SCHOTT Advanced Optics, with its deep technological expertise, is a valuable partner for its customers in developing products and customized solutions for applications in optics, lithography, astronomy, opto-electronics, life sciences, and research. With a product portfolio of more than 100 optical glasses, special materials and components, we master the value chain: from customized glass development to high-precision optical product finishing and metrology. SCHOTT: Your Partner for Excellence in Optics. Figure 1 Wafer with Notch

3 Unique Wafer Portfolio with Solutions for Your Applications As Your Partner for Excellence in Optics Advanced Optics holds very close relationship with its customers and develops solutions and products reflecting the market needs. This is a reason why SCHOTT is today the world s leading supplier of thin and ultra thin glass wafers made of different materials in sizes between 4 and 12 with different surface qualities and customized features. Applying proprietary production processes, leveraging a selection of different materials and the continuous expansion of state-of-the-art processing capabilities make our wafer-offerings unique in the industry. Our wafer-offerings and processing technologies are presented in this catalog.

4 Typical Applications Wafers are used in a great variety of applications within the Semiconductor, Electronics and Biotech industry. Wafers can be found in nearly every CMOS (complementary metal oxide semiconductor) or CCD (charges coupled device) image sensor in the market of smart phones, tablet PCs and digital cameras. The combination of semiconductor image sensors and SCHOTT glass wafers in state-of-the-art packaging technologies such as Wafer Level Chip Size Packaging (WLCSP) meets the demands for smallest form factors and highest quality levels. Thin glass wafers are also used as carrier substrates and spacers for compact and cost efficient lens systems. For other applications like MEMS (micro electro mechanical systems) sensors in automotive and consumer products SCHOTT is supplying structured glass wafers with holes or cavities to meet the specific needs of those products. Figure 2 Structured glass wafer

5

6 Thin Glass at SCHOTT SCHOTT has a long standing history in producing thin glass and developed various proprietary production processes. The thinnest glass substrates available from SCHOTT are less than 50 µm in thickness and will soon be even commercially available on a reel. This expertise forms the principle pillar for being the leading supplier for Wafers. The relevant materials for our waferofferings are made in a special down-draw process. Detailed characteristics of these glass types (AF 32 eco, D 263 T eco, MEMpax ) are presented on the following pages. SCHOTT is also contributing to environmental safety and sustainability and offers the green glass types AF 32 eco and D 263 T eco from a melting process which does not utilize any hazardous refining agents. Through offering such eco glass types SCHOTT has done a major step in supporting the realization of green end-user products.

7 Down-Draw Process The key characteristics of the down-draw process (AF 32 eco, D 263 T eco, MEMpax ) are: Molten glass Fire-polished surface with surface roughness < 1 nm Wide thickness range, from 1.1 mm down to 25 µm Fast changeover between different glass types High flexibility regarding throughput and thickness Roller Annealing furnace Figure 3 Thin glass (50 μm) Figure 4 Down-Draw process at SCHOTT Roller Glass ribbon

8 AF 32 eco Thin Glass Technical Data Dimensions Thickness Round and square custom size wafer formats, e. g. 6, 8 or 12 0.03 mm up to 1.1 mm Luminous transmittance τ vd65 (d = 0.5 mm) 91.9 % Coefficient of mean linear thermal expansion α (20 C; 300 C) (static measurement) 3.2 10 6 K 1 Transformation temperature T g 717 C Dielectric constant ε r at 1 MHZ 5.1 Refractive index n D 1.5099 Density ρ (annealed at 40 C/h) 2.43 g/cm 3 Specifications CTE matching silicon High transmittance Fire-polished surface with low roughness Environmentally friendly production without hazardous refining agents Applications Wafer Level Chip Size Packaging Wafer Level Optics Microsheet Forms of Supply Wafer from 4 to 12 diameter Sheet up to 300 mm x 300 mm Microsheet on reel (sampling)

9 D 263 T eco Thin Glass Technical Data Dimensions Thickness 440 mm x 360 mm, other size on request 0.03 mm up to 1.1 mm Luminous transmittance τ vd65 (d = 1.1 mm) 91.7 % Coefficient of mean linear thermal expansion α (20 C; 300 C) (static measurement) 7.2 10 6 K 1 Transformation temperature T g 557 C Dielectric constant ε r at 1 MHZ 6.7 Refractive index n D 1.5230 Density ρ (annealed at 40 C/h) 2.51 g/cm 3 Specifications High chemical resistance Stable against sunlight and heat High luminous transmittance Environmentally friendly production without hazardous refining agents Applications Resistive touch panel applications Substrate glass for IR cut-off filter for camera modules in mobile phones Microsheet Forms of Supply Wide range of thicknesses Variety of in-stock sizes and shapes Microsheet on reel (sampling)

10 Figure 5 Structured wafer for sensor application

11 MEMpax Technical Data Dimensions Thickness 6, 8 or 12 Wafer 0.1 mm to 1.1 mm Luminous transmittance τ vd65 (d = 0.5 mm) 91,7 % Coefficient of mean linear thermal expansion α (20 C; 300 C) (static measurement) 3.25 10 6 K 1 Transformation temperature T g 525 C Dielectric constant ε r at 1 MHZ 4.6 Refractive index n D 1.4714 Density ρ (annealed at 40 C/h) 2.2 g/cm 3 Specifications Fire-polished surface CTE matching silicon High thermal stability Enabling anodic bonding with silicon wafers Excellent transmission Physical and chemical properties identical with Borofloat 33 Applications MEMS Wafer level packaging Biotechnology Optical sensors Lighting solutions Forms of Supply 6, 8 or 12 wafer

12 Figure 6 Structured glass wafer

13 Main Competences in Glass Wafer Processing Besides offering wafers made of different materials and different sizes SCHOTT has built up extensive experiences and know-how in glass processing. Learning from a SCHOTT history of glass melting and processing of more than 125 years and leveraging a strong network with experts and partners SCHOTT is able to offer wafers in almost any customized structure, surface quality and with individual features. This makes our products unique! Here you find an overview, details of our competencies are gives on the following pages. Process capabilities Cutting Laser or Diamond Cutting Wafer sizes 4 12 (round) Substrates up to 400 x 500 mm Edge Treatment Flat or Notch C- or facet shape Seaming Surface Refinement Polishing or Lapping Coating Structuring Ultrasonic Lapping Powder Blasting Washing Process Ultrasonic Washing End cleaning with DI water Clean Room Packaging Clean Room Production Inspection and Measurement under Clean Room Conditions Packaging into flow boxes

14 Our Competencies in Detail Polishing With our state-of-art polishing operations and long experience in polishing of thin glass, we can meet and exceed all industry standards and customer requirements. Properties Fire polishing Standard polishing Advanced polishing Table 1 Options for polishing Materials Edge grinding AF 32 eco D 263 T eco MEMpax Cut C-shape Facet AF 32 eco D 263 T eco BOROFLOAT 33 C-shape Facet AF 32 eco D 263 T eco BOROFLOAT 33 C-shape Facet Notch Possible Possible SEMI TTV 5 µm 10 µm < 2 µm to 5 µm Flatness (warp) Depending on raw material Roughness (Ra) < 0.8 nm < 2 nm Surface defects (Scratch / Digs) according to MIL-PRF 13830B 5/1 to 10/5 (cut 40/10) 20 µm 10 µm to 20 µm 10/5 to 20105 5/1 to 10/5 (> 3 µm to 5 µm visible) 5/1 to 10/5 (> 3 µm to 5 µm visible) Structuring With the Powder blasting technology and the Ultrasonic lapping process SCHOTT has established a variety of capabilities to provide specific solutions for structured glass wafers. Figure 7 Sonotrode Figure 8 Structured substrate

15 Ultrasonic lapping Powder blasting Table 2 Process capabilities Size 100 mm to 200 mm Max. 400 mm x 400 mm Thickness range 0.4 mm up to 3 mm 0.05 mm up to 3 mm Different hole configurations Round holes Round, rectangular holes and caverns Positioning tolerances ± 65 µm* ± 65 µm* Min. hole diameter 0.4 mm 0.1 mm * Tighter tolerances on request Edge Treatment Our expertise in edge treatment offers the choice between flat and notch orientation marking according SEMI industry standards. Wafer edges can be processed to C-shape or facet shape. Options for edge processing Flats Notches C-Shape Facet Shape

16 Ultra Sonic Washing Our expertise in ultra sonic washing under clean room conditions enables us to provide highest precision and to deliver products into the semiconductor industry. Key characteristics of the washing process High cleaning results with sour and alkaline cleaner End cleaning with DI-Water Drying with Infrared lamps Situated in a clean-room (Class 1000) and packaged in flowboxes (class 100) Out side Clean Room class 1000 process flow additional clean room benches IR-drying buffer feed in station 1 2 3 4 5 6 7 8 9 Clean Room Packaging We have the capability of Clean Room Production where all wafers are inspected under clean room conditions (class 1000) using special measurement and testing instrumentation. Wafers can be packed in wafer shipment boxes (flow boxes) and under clean room condition. Figure 9 Ultra sonic washing process Figure 10 Carrier with structured glass wafers

17

18 Wafer Manufacturing Network Advanced Optics SCHOTT AG Mainz, Germany Headquarter, R & D, Product Management Advanced Optics SCHOTT AG Grünenplan, Germany Production & Thin Glass Competence Center SCHOTT Customer Service & Technology Center China, Japan SCHOTT Glass Malaysia Sdn. Bhd. SCHOTT Glass Malaysia Components Sdn. Bhd. Perai, Penang, Malaysia Wafer Processing, Polishing, Structuring

19 Quality Assurance Quality control is based on statistical process control, as well as on rigorous final inspection of the finished component. Glass properties are measured for every melt. Measurement instruments include a broad range of interferometers, spectrophotometers, physical property test systems, vision systems, and a laser test bed. Figure 11 EN ISO 9001:2008 Certificate

Advanced Optics SCHOTT AG Hattenbergstrasse 10 55122 Mainz Germany Phone +49 (0)6131/66-1812 Fax +49 (0)3641/2888-9047 info.optics@schott.com www.schott.com/advanced_optics 10363 ENGLISH-UK 01120.75 kn/odd Printed in Germany