Contamination Control



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www.pall.com Contamination Control for the Oil and Gas Industry

2 www.pall.com Pall specializes in fluid management, leveraging our unmatched capabilities to make your operation more successful

Introduction to Pall Corporation Pall - Your Integrated partner in the Oil and Gas industry Pall Corporation is a global company solving complex contamination, separation and purification problems. Pall serves the oil and gas, refinery, petrochemical, chemical, and power generation markets around the world. With a broad line of products and services, Pall can help you improve fluid quality and increase profitability by optimizing the performance of processing equipment. Benefit from Pall s expertize and customized services Pall is much more than a filter company. Pall specializes in fluid management, leveraging our unmatched capabilities to make your operation more successful. Our expertise has enabled us to build a large library of proprietary core materials, which we can modify to separate, remove, or selectively capture the most elusive contaminants. Total Fluid ManagementSM(TFM) The oil and gas industry trusts Pall as a solution provider For more than thirty years, Pall has been a major equipment supplier and solution provider to oil and gas companies at both onshore and offshore plants. Regardless of your specialization, Pall has filtration and separation solutions to meet your increasing production and processing needs. Our products are designed to meet your requirements for separation efficiency, reliability, economy, and size. Pall can solve your purification challenges in any size of application, from small flows and simple installations to large flows and complex systems, from the supply of filter elements to fully-integrated turnkey systems. Pall has the ability to design, manufacture, and install economical, integrated systems as well as service them. Our systems can cost effectively treat all of the incoming process fluids, systems fluids, and waste streams in your plant. By meeting critical needs, we build lasting customer relationships that grow stronger year after year. We call this Total Fluid Management, a comprehensive approach, that leverages our strengths and provides you with real value. www.pall.com 3

Contamination Control Why is it so important to take care of fluid cleanliness? Solid, liquid, and salt-like contaminants present in gas and liquid well-injection fluids, process fluids (crude oil, gas, NGL, amine, glycol, water ), systems fluids (hydraulic and lubrication oil) can lead to operating and maintenance issues at wells, on treating units, and machinery and equipment. Increase in operating and maintenance costs, decrease in production throughputs, production shutdowns or equipment failure can significantly affect productivity of oil and gas production plants, gas treating plants, LNG plants, and transmission stations. Such issues can be solved by the use of effective, reliable, correctly applied filtration and separation technologies. New low NOx burner tip Let Pall help you optimize the performance of your processing units and equipment by improving fluids contamination control! Experience has demonstrated that improving fluids cleanliness can enable oil and gas producers: To eliminate operating issues due to: - foaming in contactor towers - premature fouling of adsorbents and catalysts - off-spec products To decrease operating costs due to: - energy consumption linked to clogging of adsorbents and catalysts, heat exchangers, reboilers, cold box, and columns - premature replacement of adsorbents and catalysts solvent make-ups or use of chemicals such as antifoams To eliminate untimely or unplanned maintenance operations due to: - cleaning of heat exchangers, reboilers, cold box, columns, compressors - replacement of turbine/compressor bearings and other internals - corrosion of equipment and pipelines To eliminate unforeseen shutdowns due to clogging or failure of compressors or turbines To comply with Health, Safety, and Environment specifications Before Pall filtration After Pall filtration Damaged NOx burner tip due to contaminants 4 www.pall.com

Pall Filtration & Separation Technologies The potential application of Pall technonologies is vast. The following schematic diagrams represent three typical oil and gas Industry processes to provide an indication of how and where Pall filtration and separation solutions can be applied. Pall Filtration and Separation Applications at Oil and Gas Production Plants 6 7 4 5 8 11 1 2 3 14 9 11 9 10 12 11 13 13 Production and Treating processes vary and layout and equipment may differ. Consequently not all purification steps listed may apply Filtration Recommendations Each Pall solution within the flow diagram above is labelled and described in the chart below. # Application Challenge Solution 1 Glycol contactor protection Prevent hydrocarbon or amine aerosols, and solids from contaminating the glycol system, which could result in foaming, solvent losses, and off-specification gas. Recover valuable NGL or amine for re-use. 2 Upstream activated carbon bed in amine or glycol 3 Downstream of activated carbon bed in amine or glycol Remove solid contaminants from solvent to avoid foaming in the contactor and protect the activated carbon bed from plugging. Remove any activated carbon fines released from the activated carbon bed to avoid solvent contamination. 4 Compressor protection Improve reliability of the compressor by preventing fouling from liquid aerosols and solids. Recover valuable NGL or glycol for re-use. 5 Compressor protection Prevent solid particles from contaminating the lubrication and hydraulic oil systems, to avoid abrasion of bearings, and to protect servo-valves. Monitor oil cleanliness for predictive maintenance. 6 Turbine protection Eliminate liquid aerosols and solids from fuel gas, which could result in operation problems of the turbine and fouling of burner tips. 7 Turbine protection Eliminate free water and solids from diesel, which could result in corrosion and fouling of burner tips. Install liquid/gas coalescers to remove finely dispersed liquid droplets and solids from the gas before it enters the glycol system. Install high efficiency rated particle filters upstream of the activated carbon bed. Install high efficiency rated particle filters downstream of the activated carbon bed. Install liquid/gas coalescers to remove finely dispersed liquid droplets and solids from the gas. Install high efficiency rated particle filters on oil systems, and use diagnostic devices to control the oil cleanliness level. Install liquid/gas coalescers to remove finely dispersed liquid droplets and solids from the fuel gas. Install liquid/liquid coalescers to remove free water from diesel. www.pall.com 5

Pall Filtration and Separation Applications at Gas Processing Plants 1 20 2 3 2 11 16 3 15 17 11 18 19 9 11 13 13 Filtration Recommendations Each Pall solution within the flow diagram above is labelled and described in the chart below. # Application Challenge Solution 8 Turbine protection Prevent solid particles from contaminating the lubrication and hydraulic oil systems, to avoid abrasion of bearings, and to protect servo-valves. Monitor oil cleanliness for predictive maintenance. 9 Condensate dewatering Provide hydrocarbon condensate with low water content to avoid corrosion problems in export pipeline. 10 Crude oil desalting Provide crude oil with low water content to avoid corrosion problems in export pipeline. 11 Prefiltration prior to liquid/liquid coalescer 12 Produced water and waste water treatment 13 Produced water and waste water treatment 6 www.pall.com Ensure that the liquid/liquid coalescer has a long service life. Protect downstream equipment from upsets and maintenance issues due to large amounts of hydrocarbons and solids. Ensure that the water meets quality or environmental specifications prior to overboard discharge, re-injection, or further treatment. 14 Seawater injection Prevent fine solids and microorganisms from fouling the injection wells. 15 Amine contactor protection Prevent hydrocarbon or glycol aerosols, and solids from contaminating the amine system, which could result in foaming, solvent losses, and off-specification gas. Recover valuable NGL. Production and Treating processes vary and layout and equipment may differ. Consequently not all purification steps listed may apply Install high efficiency rated particle filters on oil systems, and use diagnostic devices to control the oil cleanliness level. Install liquid/liquid coalescers or a Lucid Separator to remove free water from hydrocarbon condensate. Install a Lucid Separator to remove free water from crude oil. Install high efficiency rated particle filters upstream of the liquid/liquid coalescers. Install a Lucid Separator to remove free hydrocarbons and solids from produced or waste water. Install liquid/liquid coalescers or tangential flow membrane modules to remove free hydrocarbons and solids from water. Install high efficiency rated filters upstream of the injection pumps. Install liquid/gas coalescers to remove finely dispersed liquid droplets and solids from the gas before it enters the amine system.

Pall Filtration and Separation Applications at LNG (Liquified Natural Gas) Plants 20 4 21 3 2 15 11 16 22 11 18 9 11 13 4 13 23 Production and Treating processes vary and layout and equipment may differ. Consequently not all purification steps listed may apply Filtration Recommendations Each Pall solution within the flow diagram above is labelled and described in the chart below. # Application Challenge Solution 16 Rich amine treatment Improve the reliability of the amine regenerator by removing liquid hydrocarbons and solids. 17 Gas metering protection Ensure an accurate gas flowrate measurement by preventing liquids from depositing. 18 Stabilization plant protection Prevent free water and solids from entering the fractionation column, which could result in corrosion and salts and solid deposits. 19 Glycol regenerator protection Prevent solid particles from entering the regenerator, which could result in fouling of the column and reboiler. 20 Molecular sieve drier protection Increase cycle time between regeneration of the molecular sieve drier, and extend the bed life. Recover valuable glycol or NGL. 21 Regeneration gas filtration Avoid molecular sieve fines being entrained with the regeneration gas, which could result in process contamination or fouling of downstream equipment. 22 Dry gas filtration Prevent molecular sieve fines from fouling downstream equipment. 23 Cold Box protection Ensure a consistent productivity of the cold box by preventing solid fines from fouling the heat exchanger. Install liquid/liquid coalescers to remove free liquid hydrocarbons from the rich amine solvent prior the regenerator. Install liquid/gas coalescers to remove finely dispersed liquid droplets prior the gas metering device. Install liquid/liquid coalescers to remove free water from the hydrocarbon condensate. Install high efficiency rated particle filters upstream of the regenerator. Install liquid/gas coalescers to remove finely dispersed liquid droplets before they foul the molecular sieve drier. Install gas particle filters to effectively remove any carryover molecular sieves fines. Install gas particle filters to effectively remove any carryover molecular sieves fines. Install gas particle filters to effectively remove any carryover solid fines. For further information please request a copy of the Pall Filtration and SeparationTechnology interactive CD-ROM from your local Pall sales office or distributor. www.pall.com 7

Pall Technology Services What is Total Fluid Management? Total Fluid Management (TFM) is the integration of properly selected filtration and separation technologies and services into a production process to yield the highest efficiency at the lowest cost. Pall s TFM program covers a wide range of filtration products, advanced technologies, and services to improve system operation and increase productivity. Our global team of scientists and engineers support TFM Pall offers a variety of services to help you maximize productivity within your plant. We deliver TFM to you with the support of our global teams of Scientific and Laboratory Services (SLS). Located in more than 30 countries, our scientists and engineers provide these services locally, with broad-based assistance from Pall s worldwide technical support network. Our experts work directly with you to determine how Pall products and technologies can benefit your process. Our customized system services include: Consultancy Cleanliness audit / Piloting A cleanliness audit can uncover contamination problems and their detrimental effects. Our laboratory staff and field engineers have at your disposal lab-scale and analytical equipment and field pilot-scale units. By sampling at various locations throughout the process, we collect, quantify and identify solid and liquid contaminants to determine their origin and provide you with recommendations for corrective action. Our recommendations are designed to help you optimize your processes and increase the reliability of your equipment at the lowest possible cost. Piloting Rigs Process audits / Consultancy Pall offers troubleshooting, audit and consulting services to identify opportunities for process improvements that lead to increased productivity. Improvements are defined for instance as the reduction of operating costs or maintenance operations. An audit involves data collection and proposal review, followed by a technical report documenting the findings and suggestions for improvement. Flushing Services Filtration equipment rental When you need to rent filtration and purification equipment to conduct spot depollution of gas treating fluids or systems fluids, to conduct large-scale pilot testing, or to use while permanent equipment is being manufactured, contact Pall. Our rental services can provide equipment on the spot, so that you can handle upsets promptly Filtration Equipment Hire 8 www.pall.com

Filtration and Separation Technologies for Process Fluids Pall filtration and separation technology Pall designs and supplies a wide range of media, filters, and systems to remove contaminants from liquids and gases. These products, along with our service capabilities and technical expertise, enable us to fulfill diverse fluid purification requirements whether in oil and gas production, oil refining, gas processing, chemical production, or polymer processing. Particulate filters for Liquid and Gas Pall gas and liquid particulate filters are used to remove the primary sources of contamination that cause system failures. Elements are designed in depth or pleated media configurations for maximum surface area and long service life. Pall Products: Ultipleat High Flow, Ultipor, Ultipleat SRT, Profile Coreless, Nexis, Epocel and Claris filters Liquid / Gas Coalescers Pall liquid / gas coalescers remove entrained liquid aerosols from gas such as condensed hydrocarbons or pipeline chemicals. The graded media matrix allows small droplets in the incoming gas to merge (coalesce) into larger drops that are easier to separate. All Pall liquid/gas coalescers are chemically treated to lower the surface energy of the medium and promote rapid drainage of the wasted liquids. Pall Products: SepraSol and SepraSol Plus liquid/gas coalescers Ultipleat High Flow/Profile Coreless Filter Elements Liquid / Liquid Coalescers Pall liquid/liquid coalescers are designed to efficiently separate liquid/liquid emulsions. Constructed of a variety of polymers and flouropolymers, these high-efficiency coalescers are effective in systems with low interfacial tension without losing performance due to the presence of surfactants (dis-arming). Their long service life means the cartridges require fewer changeouts thereby reducing maintenance and waste disposal costs. Pall Products: AquaSep Plus and PhaseSep liquid/liquid coalescers Liquid/Gas Coalescer Lucid Phase Separator The Lucid separator has the ability to effectively remove gross levels of contaminant water or aqueous fluid in droplet form from liquid phase hydrocarbons and/or conversely, remove contaminant hydrocarbons from water or aqueous solutions. This new separation technology is simple to install, compact, self-cleaning, and requires no auxiliary utilities, electrostatics, controls, or chemical additives to function. The hardware has no moving parts, is compatible with a broad range of fluids, and is resistant to even the most erosive solids. Membrane Technologies Membrane Technologies are by far the most effective methods for water processing applications. The Pall range of membrane systems includes microfiltration, ultrafiltration and reverse osmosis membrane technology. Pall Aria water treatment systems for example use hollow fiber microfiltration membranes to produce pure water from any water source. They remove bacteria, iron, manganese, arsenic, and other solid particulate to deliver water that consistently measures up to the toughest cleanliness and quality standards. Pall Products: Pall Aria systems, Disc Tube Module Reverse Osmosis systems, Membralox ceramic membranes. LUCID Pilot Rig Pall Aria System www.pall.com 9

Cleanliness Monitoring and System Fluid Contamination Control Obtaining accurate and reliable fluid cleanliness data quickly in order to detect abnormal contamination is a key factor in ensuring the efficiency of industrial processes and reducing downtime. Reliable monitoring solutions...whatever the conditions whatever the fluid Pall have portable devices that resolve detection problems by giving plant operators the ability to measure the cleanliness of even the most troublesome fluids reliably, simply, and quickly, and prevent unnecessary and costly machinery downtime. The Pall PCM400W Cleanliness Monitor can confirm cleanliness of almost every kind of system fluid. The Pall PCM400W uses multiple mesh blockage technology to address the common problem of inaccurate or unreliable results when monitoring fluids that are dark, cloudy, or contaminated by water or air. Additionally it can read fluid temperature and saturated water content (when appropriate). Pall Water Sensors PCM400W Cleanliness Monitor Wherever possible, oils should be operated without the presence of free or emulsified water. Pall set the standard for high performance hydraulic oil and lube filters in the fluid power industry. The drive for enhanced performance continues with the Pall Ultipleat SRT filter range for hydraulic oil and lubrication fluids. Pall Ultipleat SRT Filters Stress Resistant Technology The Pall Ultipleat SRT elements combine an innovative media design and stress resistant media technology to provide the greatest possible overall performance and value. Features of the Ultipleat SRT filter range include: Laid-over Pleating Maximises filter area, Increases flow handling capability and reduces element size Coreless/Cageless Construction Stress-Resistant Media Excellent resistance to operating system stresses. Auto-Pull filter element removal system Enables simple and quick maintenance of blocked filter elements Anti-static design Minimizes electrostatic charge generation at high flows Pall Oil Purifiers If or when water is detected it can be removed quickly and efficiently using a Pall Oil purifier. Pall Water Sensors detect water in solution within the fluid, displayed as a percentage saturation or expressed as a parts per million (PPM) reading. Options include the handheld unit for a point-in-time reading or the permanent unit which can provide continuous or timed monitoring. 10 www.pall.com WS08, WS09 and WS010 Water Sensors Highly efficient vacuum dehydration separation technology combined with high performance solid particulate filtration purifies fluids such as hydraulic and lube oils, dielectric fluids and fuels. Pall oil purifiers can extend fluid life by removing 100 % of free water and gases and up to 90 % of dissolved water and gases. HNP Series Oil Purifier

Our systems can cost effectively treat all of the incoming process fluids, systems fluids, and waste streams in your plant www.pall.com 11

Research and Development Scientific and Laboratory Services Sales and Support Quality Working with equipment A principal element in The sales and support The policy of Pall is to and component Pall s customer support team comprises a group design and manufacture manufacturers in these operations is our Scientific of experienced specialists products to the highest markets, Pall custom and Laboratory Services located in Europe, the and most current designs products and (SLS) Department. USA and across Asia standards of quality, purification systems that Filtration problems arising with distributors and safety and reliability. are fully integrated into in the field can be representatives worldwide. To implement this policy, oil and gas industry assessed and simulated We offer a comprehensive the organisational structure applications. in the laboratory. Close sales and service support and the procedures by These products extend component service life, enhance safety and improve the operating reliability of all processing systems. monitoring by Pall scientists can determine the engineered solution to your contamination and separation problems and advise accordingly. to all customers around the world. which Pall operates are fully defined in quality management systems, approved to ISO 9001:2000 To see how Pall is helping enable a greener, safer and more sustainable future, visit www.pall.com/green. Fuels and Chemicals 25 Harbor Park Drive Port Washington, NY 11050 +1 516 484 3600 telephone +1 888 333 7255 toll free US Portsmouth - UK +44 (0)23 9233 8000 telephone +44 (0)23 9233 8811 fax industrialeu@pall.com Visit us on the Web at www.pall.com Pall Corporation has offices and plants throughout the world. For Pall representatives in your area, please go to www.pall.com/contact Please contact Pall Corporation to verify that the product conforms to your national legislation and/or regional regulatory requirements for water and food contact use. Because of technological developments related to the products, systems, and/or services described herein, the data and procedures are subject to change without notice. Please consult your Pall representative or visit www.pall.com to verify that this information remains valid. Products in this document may be covered by one or more of the following patent numbers: EP 930,926; US 5,443,724; US 6,332,987; EP 1,165,205; US 6,342,283; US 6,662,842; EP 442,410; US 5,143,614; EP 830,191; US 5,591,335; US 5,653,833; US 5,681,469; US 5,690,782; US 5,730,820; US 5,733,581; US 5,741,395; US 5,783,011; EP 930,926; US 5,480,547; US 6,332,987; EP 433,661; EP 667,800; EP 982,061; EP 1,380,331; US 5,543,047; US 5,690,765; US 5,725,784; US 6,113,784; US 7,083,564; US 7,318,800; EP 470,485; US 5,252,207; US 5,552,048. Copyright 2012, Pall Corporation. Pall,, Pall Aria, AquaSep, Claris, Disc Tube, Epocel, LUCID, Membralox, Nexis, PhaseSep, Profile, SepraSol, Ultipleat and Ultipor are trademarks of Pall Corporation. indicates a trademark registered in the USA. ENABLING A GREENER FUTURE and Filtration. Separation. Solution.SM are service marks of Pall Corporation. FCOILGASENc Produced in the UK May 2012