SINTEF Energy Research Life Cycle Climate Performance (LCCP) of Mobile Air-Conditioning Systems



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Life Cycle Climate Performance (LCCP) of Mobile Air-Conditioning Systems 1 2004 Armin Hafner, Arne Jakobsen and Petter Nekså, SINTEF Energy Research, Trondheim Norway Jostein Pettersen Norwegian University of Science and Technology NTNU Trondheim Norway with input and support from: Audi, BMW, DaimlerChrysler, Denso, LuK, Modine, Obrist Engineering, Shecco Technology, U of Illinois, Visteon

2 Overview Improvements in R-744 system design since SAE AR CRP testing Performance of enhanced HFC-134a vs 2002 R-744 system, using SAE AR CRP test matrix Comparison of Life Cycle Climate Performance (LCCP) and seasonal energy use Some comments Conclusion and suggestions

3 Summary of R-744 system improvements Improved COP: More efficient evaporator Reduced gas cooler temperature approach Improved compressor efficiency More compact heat exchangers: Evaporator core volume 76 % of enhanced HFC-134a (1-slab R-744) Gas cooler core volume 90 % of enhanced HFC-134a condenser Gas cooler face area 69 % of enhanced HFC-134a condenser

COP data 900 rpm (idling, 20% of the usage) 5 o C air from evaporator or equal capacity HFC data from SAE AR CRP (2002), R-744 data from Hrnjak (2003) 8 7 +7 to +19 % 4 COP 6 5-1 to +8 % - 6 to -10 % 4 3 EnR134a 2 R-744 2002 2-slab evaporator 1 R-744 2002 Small 0 10 15 20 25 30 35 40 Air inlet temperature, o C

COP data 2500 rpm (driving, 80% of the usage) 5 o C air from evaporator or equal capacity HFC data from SAE AR CRP (2002), R-744 data from Hrnjak (2003) 8 5 7 6 +28 to +39 % COP 5 4 3 +21 to +34 % - 3 to +11% 2 EnR134a 1 R-744 2002 2-slab evaporator R-744 2002 Small 0 10 15 20 25 30 35 40 Air inlet temperature, o C

Typical efficiency at varying condenser/gas cooler air inlet temperature 6 COP R-744 R-134a More than 90% of operation COP is important Less than 10% of operation Capacity is important Condenser/gas cooler air inlet temperature

What if R-744 system is allowed to operate with max capacity at high ambient? 7 10 Maximum Evaporator Capacity for 35 o C Ambient Condition o 9 Evaporator Capacity [kw] 8 7 6 5 4 3 2002 R744 Small +15% +11% En R134a +15% 2 1 0 900 rpm 1500 rpm 2500 rpm Even with the smaller evaporator, R-744 capacity is superior to En R134a

8 Summary of test results R-744 COP is equal or better than R-134a at most relevant temperatures Significant improvement in COP at the dominant conditions: Moderate temperature and higher rpm Because R-744 gives higher maximum capacity, we achieve faster pulldown at warm ambient

Simplified LCCP analysis assumptions (1) 9 Compressor power from SAE AR CRP data for enhanced HFC-134a (SAE ARCRP, 2002) 2002 R-744 Pilot Project data from Hrnjak (2003) Small system Driving/idle cycle 80/20%. Total hours with AC system on based on climate data and usage profiles from Sand et al. (1997), and Duthie et al. (2003) R-744 system 1.6 kg heavier than HFC-134a system Current prototypes show less weight difference than this Fuel use due to transportation of AC system was taken from (AFEAS, 1991)

Simplified LCCP analysis assumptions (2) 10 Direct HFC-134a emission data per vehicle based on: Controlled losses (Schwartz and Harnisch, 2003) of 53 g/yr, plus estimate for uncontrolled losses from Öko-Recherche of 16 g/yr, plus estimate for service losses 10 g/yr: total 80 g/yr Achievable total controlled losses of 35 g/yr suggested by Fernqvist (2003), plus uncontrolled and service losses: total 60 g/yr End-of-life recovery 80% Production of HFC-134a gives emissions of 77 kg CO 2 - equivalents per kg HFC (Campbell and McCulloch, 1998)

11 Temperature bin data (Sand et al. 1997) USA Midwest, Chicago USA Sourtheast, Miami USA Southwest, Phoenix Japan, Kadena Japan, Misawa United Kingdom Germany Greece Italy Spain 35 o C 4500 4000 3500 3000 2500 2000 1500 1000 500 0 Hours -30-20 -10 0 10 20 30 40 50 Ambient temperature ( o C) Temperatures above 35 o C hardly ever occurs

12 AC system usage profile (Phoenix) Total AC operating hours - 278 of 410 70 Compressor on time [hours] 60 50 40 30 20 10 0-31.7 Driving Idling Phoenix Based on 80/20%, driving/idle -26.1-20.6-15 -9.4-3.9 1.7 7.2 12.8 18.3 23.9 29.4 35 40.6 46.1 Ambient temperature [ C]

13 AC system usage profile (Kadena - Japan) Total AC operating hours 138 of 160 Compressor on time [hours] 70 60 50 40 30 20 10 0-31.7 Driving Idling Kadena Based on 80/20%, driving/idle -26.1-20.6-15 -9.4-3.9 1.7 7.2 12.8 18.3 23.9 29.4 35 40.6 46.1 Ambient temperature [ C]

14 AC system usage profile (Spain) Total AC operating hours 157 of 250 Compressor on time [hours] 70 60 50 40 30 20 10 0-31.7 Driving Idling Spain Based on 80/20%, driving/idle -26.1-20.6-15 -9.4-3.9 1.7 7.2 12.8 18.3 23.9 29.4 35 40.6 46.1 Ambient temperature [ C]

15 AC system usage profile (Miami) Total AC operating hours 322 of 410 160 Compressor on time [hours] 140 120 100 80 60 40 20 0-31.7 Driving Idling Miami Based on 80/20%, driving/idle -26.1-20.6-15 -9.4-3.9 1.7 7.2 12.8 18.3 23.9 29.4 35 40.6 46.1 Ambient temperature [ C]

16 AC system usage profile (Germany) Total AC operating hours 100 of 250 Compressor on time [hours] 70 60 50 40 30 20 10 0 Driving Idling Germany Based on 80/20%, driving/idle -32-26 -21-15 -9.4-3.9 1.7 7.2 12.8 18.3 23.9 29.4 35 40.6 46.1 Ambient temperature [ C]

LCCP Comparison R134a leakage: 80 g/year SINTEF Energy Research 17 HFC-134a R-744 HFC-134a R-744 HFC-134a R-744 Germany Kadena, Japan Spain Indirect Mass Direct HFC-134a R-744 HFC-134a R-744 Phoenix Miami 0 1000 2000 3000 4000 5000 6000 7000 8000 9000 LCCP, kg CO 2

LCCP Comparison R134a leakage: 60 g/year SINTEF Energy Research 18 HFC-134a R-744 Germany Indirect Mass Direct HFC-134a R-744 HFC-134a R-744 Kadena, Japan Spain HFC-134a R-744 HFC-134a R-744 Phoenix Miami 0 1000 2000 3000 4000 5000 6000 7000 8000 9000 LCCP, kg CO 2

LCCP and energy use: 19 Summary & comments Results based on small 2002 R-744 system show 20 to 40 % reduction in LCCP About 10 % reduction in energy (fuel) use in: Spain, Japan, Miami & Germany About 3 % reduction in energy (fuel) use in Phoenix Energy use would be even lower with the full-size R-744 evaporator Heat pump operation not included in analysis HFC-134a system has better COP only at conditions that seldom occurs. These conditions do not matter for energy (fuel) use

20 These good results were achieved even though conditions were difficult for R-744 Very good baseline in SAE Enhanced HFC-134a system: Extremely high COP Large heat exchanger sizes Condenser with high air flow rate and low refrigerant-side pressure drop Limited focus of test program: Focus on very high ambient temperature conditions Focus on COP data at high ambient, instead of seasonal comparison of energy use No test points above 2500 rpm Unfortunate R-744 compressor sizing: Large displacement giving significant part-load losses

Conclusion SINTEF Energy Research 21 The test data have reconfirmed that COP is no argument against R-744 Fuel use of R-744 system is significantly lower than with HFC-134a, even in the warm climates considered here LCCP is reduced by 20-40% compared to HFC-134a system From now on, R-744 should not imitate HFC-134a. Instead, we should develop and compare based on merits of each system Let s get started!

22 Acknowledgement Audi, BMW, DaimlerChrysler, Denso, LuK, Modine, Obrist Engineering, Shecco Technology, U of Illinois, Visteon Written paper will be available in the final proceedings of this meeting

23 References AFEAS 1991. Energy and Global Warming Impacts of CFC Alternative Technologies, December 1991 Fernqvist, H., 2003. Fuel efficient leak tight HFC-134a systems through design and quality improvements, presented at MAC Summit, Brussels, Belgium, February 10-11 2003 Hrnjak, P., 2003. Design and performance of improved R744 System Based on 2002 technology, presented at SAE Automotive Alternate Refrigerant Systems Symposium, Scottsdale, Arizona, July 15-17 2003. Campbell N.J. and A. McCulloch, 1998. The Climate Change Implications of Manufacturing Refrigerants - -- A Calculation of Production Energy Contents of Some Common Refrigerants, Transactions of the Institution of Chemical Engineers, Vol. 76, Part B, August 1998. Duthie, G.S., Harte, S. and Jajasheela, 2002. European Average Mobile A/C Customer Usage Model, Visteon Climate Control Group. presented at SAE Automotive Alternate Refrigerant Systems Symposium, Scottsdale, Arizona, July 2002. Memory, S., and Vetter, F., 2003. Automotive AC/HP Systems Using R744 (CO 2 ), Sixth Vehicle Thermal Management Systems Conference (VTMS6), Brighton, UK, May 18-21. SAE ARCRP, 2002. Alternate Refrigerant Coperative Research Project, Update Report November 2002 http://www.sae.org/technicalcommittees/nov-2002-overview.pdf Sand, J. R., Fischer, S. K., and Baxter, V. D., 1997. Energy and global warming impacts of HFC refrigerants and emerging technologies, AFEAS/DOE report Schwartz, W., and Harnisch, J., 2003. Establishing the leakage rates of mobile air conditioners, final report (B4-3040/2002/337136/MAR/C1) prepared by Öko-Recherche and Ecofys for the European Commission (DG Environment), 17 April 2003